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1. 发明授权

US06866951B2 Compact precooler and cooling process 有权
标题翻译：紧凑型预冷器和冷却过程
公开(公告)号：US06866951B2
公开(公告)日：2005-03-15
申请号：US10358502
申请日：2003-02-05
申请人： Peter F. Foley , James R. Geschwindt , William T. Unkert , Antonio M. Vincitore
发明人： Peter F. Foley , James R. Geschwindt , William T. Unkert , Antonio M. Vincitore
IPC分类号： F25D7/00 , F25D9/00 , H01M8/04 , H01M8/06 , H01M8/00
CPC分类号： H01M8/0625 , H01M8/04007 , H01M8/0662
摘要： In a hydrocarbon fueled reformed gas fuel cell system having a rated power, a process for cooling reformed gas from a fuel processor prior to feeding the reformed gas to a shift converter includes the steps of providing a cooling zone having a hot gas inlet, a cooled gas outlet and a water inlet, feeding the reformed gas at a temperature of between 600 to 900° F. to the hot gas inlet, redirecting the reformed gas in the cooling zone so as to provide a swirling recirculating flow of the reformed gas in the cooling zone, atomizing water into droplets and contacting the droplets with the redirected reformed gas so as to cool the reformed gas and vaporize the water, and removing a stream of cooled reformed gas from the cooling zone wherein the reformed gas is at a temperature between 400 to 500° F. and the stream is substantially free of water droplets.
摘要翻译：在具有额定功率的烃燃料改性气体燃料电池系统中，在将重整气体供给到换档转换器之前，将来自燃料处理器的重整气体进行冷却的方法包括以下步骤：提供具有热气体入口的冷却区，气体出口和进水口，将重整气体在600至900°F之间的温度下供入热气入口，重新导向冷却区中的重整气体，以便将重整气体的旋流循环流向冷却区，将水雾化成液滴并使液滴与重定向的重整气体接触，以冷却重整气体并汽化水，并从冷却区除去冷却的重整气体流，其中重整气体处于400℃ 至500°F，并且该流基本上不含水滴。

2. 发明授权

US06548198B2 Compact precooler 有权
公开(公告)号：US06548198B2
公开(公告)日：2003-04-15
申请号：US09736868
申请日：2000-12-15
申请人： Peter F. Foley , James R. Geschwindt , William T. Unkert , Antonio M. Vincitore
发明人： Peter F. Foley , James R. Geschwindt , William T. Unkert , Antonio M. Vincitore
IPC分类号： H01M818
CPC分类号： H01M8/0625 , H01M8/04007 , H01M8/0662
摘要： A precooler for use in a fuel cell system between a thermal reformer and a shift converter includes an atomizing water inlet in combination with a swirling inducing reformed gas inlet which act to increase the resistance time of the reformed gas in the precooler so as to effectively cool same.

3. 发明授权

US06832645B2 Compact precooler 失效
标题翻译：紧凑型预冷器
公开(公告)号：US06832645B2
公开(公告)日：2004-12-21
申请号：US10358485
申请日：2003-02-05
申请人： Peter F. Foley , James R. Geschwindt , William T. Unkert , Antonio M. Vincitore
发明人： Peter F. Foley , James R. Geschwindt , William T. Unkert , Antonio M. Vincitore
IPC分类号： F24F314
CPC分类号： H01M8/0625 , H01M8/04007 , H01M8/0662
摘要： A precooler for use in a fuel cell system between a thermal reformer and a shift converter includes an atomizing water inlet in combination with a swirling inducing reformed gas inlet which act to increase the resistance time of the reformed gas in the precooler so as to effectively cool same.
摘要翻译：用于热重整器和变换转换器之间的燃料电池系统的预冷器包括雾化水入口与旋流诱导重整气体入口的组合，其用于增加预冷器中重整气体的阻力时间，从而有效地冷却相同。

4. 发明申请

US20090194459A1 Fuel processing of feedstocks having components harmful to hydrodesulfurization 审中-公开
标题翻译：具有对加氢脱硫有害的成分的原料的燃料加工
公开(公告)号：US20090194459A1
公开(公告)日：2009-08-06
申请号：US12321261
申请日：2009-01-16
申请人： Antonio M. Vincitore , Peter F. Foley , Derek W. Hildreth , John L. Preston , Stephen G. Pixton , Nancy P. Foley
发明人： Antonio M. Vincitore , Peter F. Foley , Derek W. Hildreth , John L. Preston , Stephen G. Pixton , Nancy P. Foley
IPC分类号： C10G67/00 , B01J19/00
CPC分类号： C10G65/04 , C10L3/101 , C10L3/103
摘要： A reformer system (11) having a hydrodesulfurizer (12) provides desulfurized natural gas feedstock to a catalytic steam reformer (16), the outflow of which is treated by a water gas shift reactor (20) and optionally a preferential CO oxidizer (58) to provide reformate gas (28, 28a) having high hydrogen and moderate carbon dioxide content. To avoid damage to the hydrodesulfurizer from overheating, any deleterious hydrogen reactants, such as the oxygen in peak shave gas or olefins, in the non-desulfurized natural gas feedstock (35) are reacted (38) with hydrogen (28, 28a; 71) to convert them to alkanes (e.g., ethylene and propylene to ethane and propane) and to convert oxygen to water in a catalytic reactor (38) cooled (46), below a temperature which would damage the reactor, by evaporative cooling with pressurized hot water (42). Hydrogen for the desulfurizer and the hydrogen reactions may be provided as recycle reformate (28, 28a) or from a mini-CPO (67), or from other sources.
摘要翻译：具有加氢脱硫剂（12）的重整器系统（11）向催化蒸汽重整器（16）提供脱硫天然气原料，其流出物由水煤气变换反应器（20）和任选的优先CO氧化器（58）处理，以提供具有高氢和适度二氧化碳含量的重整气体（28,28a）。为了避免加氢脱硫剂由于过热而损坏，非脱硫天然气原料（35）中任何有害的氢反应物（例如峰值刮削气体或烯烃中的氧）与氢（28,28a; 71）反应（38）将它们转化为烷烃（例如乙烯和丙烯至乙烷和丙烷），并在冷却（46）的催化反应器（38）中将氧转化为水，低于会损坏反应器的温度，通过用加压热水蒸发冷却（42）。用于脱硫剂的氢气和氢气反应可以作为循环重整油（28,28a）或来自小型CPO（67）或其它来源提供。

5. 发明授权

US09745526B2 Fuel processing of feedstocks having components harmful to hydrodesulfurization 有权
公开(公告)号：US09745526B2
公开(公告)日：2017-08-29
申请号：US13416744
申请日：2012-03-09
申请人： Antonio M. Vincitore , Peter F. Foley , Nancy P. Foley , Derek W. Hildreth , John L. Preston , Stephen G. Pixton , James A. Davies
发明人： Antonio M. Vincitore , Peter F. Foley , Derek W. Hildreth , John L. Preston , Stephen G. Pixton , James A. Davies
IPC分类号： B01J8/00 , C10G45/00 , C10G65/04 , C10G45/02 , C10L3/10 , C10G3/00 , C01B3/38 , C01B3/48
CPC分类号： C10G65/04 , C01B3/38 , C01B3/48 , C01B2203/0233 , C01B2203/0283 , C01B2203/044 , C01B2203/065 , C01B2203/1058 , C01B2203/1064 , C01B2203/127 , C01B2203/1276 , C10G3/42 , C10G3/50 , C10G45/00 , C10G45/02 , C10G2300/1025 , C10G2300/202 , C10L3/101 , C10L3/103 , Y10T137/0318
摘要： A reformer system (11) having a hydrodesulfurizer (12) provides desulfurized natural gas feedstock to a catalytic steam reformer (16), the outflow of which is treated by a water gas shift reactor (20) and optionally a preferential CO oxidizer (58) to provide reformate gas (28, 28a) having high hydrogen and moderate carbon dioxide content. To avoid damage to the hydrodesulfurizer from overheating, any deleterious hydrogen reactants, such as the oxygen in peak shave gas or olefins, in the non-desulfurized natural gas feedstock (35) are reacted (38) with hydrogen (28, 28a; 71) to convert them to alkanes (e.g., ethylene and propylene to ethane and propane) and to convert oxygen to water in a catalytic reactor (38) having no sulfide sorbent, and cooled (46), below a temperature which would damage the reactor, by evaporative cooling with pressurized hot water (42). Hydrogen for the desulfurizer and the hydrogen reactions may be provided as recycle reformate (28, 28a) or from a mini-CPO (67), or from other sources.

6. 发明授权

US08673511B2 Apparatus including sodium chlorate electrolysis cell connected by water cooled catalytic reactor to phosphoric acid fuel cell 有权
标题翻译：装置包括用水冷催化反应器连接到磷酸燃料电池的氯酸钠电解槽
公开(公告)号：US08673511B2
公开(公告)日：2014-03-18
申请号：US12998327
申请日：2008-11-17
申请人： Antonio M. Vincitore , Peter F. Foley , Derek W. Hildreth , John L. Preston
发明人： Antonio M. Vincitore , Peter F. Foley , Derek W. Hildreth , John L. Preston
IPC分类号： H01M8/06 , H01M16/00
CPC分类号： H01M8/086 , C01B3/56 , C01B3/58 , C01B5/00 , C01B2203/042 , C01B2203/0435 , C01B2203/0465 , C01B2203/048 , C01B2203/0883 , C01B2203/146 , C25B1/04 , C25B1/265 , H01M8/0656 , H01M8/0662 , Y02E60/366 , Y02P70/56
摘要： A sodium chloride electrolysis cell (9) receives a portion of its electrical power (47, 48: 50, 51) from a phosphoric acid fuel cell (44) which receives fuel at its anode inlet (43) from a water cooled catalytic reactor (26) that converts oxygen in the byproduct output (19) of the sodium chlorate electrolysis cell to hydrogen and water. A utility grid (53) may provide through a converter (55) power to support the electrochemical process in the sodium chlorate electrolysis cell. Temperature of the water cooled catalytic reactor is determined by the vaporization of pressurized hot water, the pressure of which may be adjusted by a controller (36) and a valve (38) in response to temperature (40).
摘要翻译：氯化钠电解槽（9）从其水阳极入口（43）从水冷催化反应器（43）接收燃料的磷酸燃料电池（44）接收其一部分电力（47,48：50,51） 26）将氯酸钠电解池的副产物输出（19）中的氧转化为氢和水。公用电网（53）可以通过转换器（55）提供电力来支持氯酸钠电解池中的电化学过程。水冷催化反应器的温度由加压热水的蒸发决定，其压力可以通过控制器（36）和阀（38）根据温度（40）调节。

7. 发明申请

US20120288412A1 Fuel Processing of Feedstocks Having Components Harmful to Hydrodesulfurization 有权
标题翻译：具有加氢脱硫有害成分的原料的燃料加工
公开(公告)号：US20120288412A1
公开(公告)日：2012-11-15
申请号：US13416744
申请日：2012-03-09
申请人： Antonio M. Vincitore , Peter F. Foley , Nancy P. Foley , Derek W. Hildreth , John L. Preston , Stephen G. Pixton , James A. Davies
发明人： Antonio M. Vincitore , Peter F. Foley , Nancy P. Foley , Derek W. Hildreth , John L. Preston , Stephen G. Pixton , James A. Davies
IPC分类号： B01J8/00 , F17D3/00 , G05D7/00
CPC分类号： C10G65/04 , C01B3/38 , C01B3/48 , C01B2203/0233 , C01B2203/0283 , C01B2203/044 , C01B2203/065 , C01B2203/1058 , C01B2203/1064 , C01B2203/127 , C01B2203/1276 , C10G3/42 , C10G3/50 , C10G45/00 , C10G45/02 , C10G2300/1025 , C10G2300/202 , C10L3/101 , C10L3/103 , Y10T137/0318
摘要： A reformer system (11) having a hydrodesulfurizer (12) provides desulfurized natural gas feedstock to a catalytic steam reformer (16), the outflow of which is treated by a water gas shift reactor (20) and optionally a preferential CO oxidizer (58) to provide reformate gas (28, 28a) having high hydrogen and moderate carbon dioxide content. To avoid damage to the hydrodesulfurizer from overheating, any deleterious hydrogen reactants, such as the oxygen in peak shave gas or olefins, in the non-desulfurized natural gas feedstock (35) are reacted (38) with hydrogen (28, 28a; 71) to convert them to alkanes (e.g., ethylene and propylene to ethane and propane) and to convert oxygen to water in a catalytic reactor (38) having no sulfide sorbent, and cooled (46), below a temperature which would damage the reactor, by evaporative cooling with pressurized hot water (42). Hydrogen for the desulfurizer and the hydrogen reactions may be provided as recycle reformate (28, 28a) or from a mini-CPO (67), or from other sources.
摘要翻译：具有加氢脱硫剂（12）的重整器系统（11）向催化蒸汽重整器（16）提供脱硫天然气原料，其流出物由水煤气变换反应器（20）和任选的优先CO氧化器（58）处理，以提供具有高氢和适度二氧化碳含量的重整气体（28,28a）。为了避免加氢脱硫剂由于过热而损坏，非脱硫天然气原料（35）中任何有害的氢反应物（例如峰值刮削气体或烯烃中的氧）与氢（28,28a; 71）反应（38）将它们转化为烷烃（例如乙烯和丙烯至乙烷和丙烷），并在不具有硫化物吸附剂的催化反应器（38）中将氧转化为水，并在低于将破坏反应器的温度下冷却（46），由用加压热水蒸发冷却（42）。用于脱硫剂的氢气和氢气反应可以作为循环重整油（28,28a）或来自小型CPO（67）或其它来源提供。

8. 发明申请

US20110195326A1 CLOSED LOOP, FUEL CELL POWERED PRODUCTION OF SODIUM CHLORATE 有权
标题翻译：封闭环，燃料电池产生氯酸钠
公开(公告)号：US20110195326A1
公开(公告)日：2011-08-11
申请号：US12998327
申请日：2008-11-17
申请人： Antonio M. Vincitore , Peter F. Foley , Derek W. Hildreth , John L. Preston
发明人： Antonio M. Vincitore , Peter F. Foley , Derek W. Hildreth , John L. Preston
IPC分类号： H01M8/06
CPC分类号： H01M8/086 , C01B3/56 , C01B3/58 , C01B5/00 , C01B2203/042 , C01B2203/0435 , C01B2203/0465 , C01B2203/048 , C01B2203/0883 , C01B2203/146 , C25B1/04 , C25B1/265 , H01M8/0656 , H01M8/0662 , Y02E60/366 , Y02P70/56
摘要： A sodium chlorate electrolysis cell (9) receives a portion of its electrical power (47, 48; 50, 51) from a phosphoric acid fuel cell (45) which receives fuel at its anode inlet (43) from a water cooled catalytic reactor (26) that converts oxygen in the byproduct output (21) of the sodium chlorate electrolysis cell to hydrogen and water. A utility grid (53) may provide through a converter (55) power to support the electrochemical process in the sodium chlorate electrolysis cell. Temperature of the water cooled catalytic reactor is determined by the vaporization of pressurized hot water, the pressure of which may be adjusted by a controller (36) and a valve (38) in response to temperature (40).
摘要翻译：氯酸钠电解池（9）从磷酸燃料电池（45）接收一部分电力（47,48; 50,51），磷酸燃料电池在其阳极入口（43）从水冷催化反应器（43）接收燃料 26）将氯酸钠电解池的副产物输出（21）中的氧转化为氢和水。公用电网（53）可以通过转换器（55）提供电力来支持氯酸钠电解池中的电化学过程。水冷催化反应器的温度由加压热水的蒸发决定，其压力可以通过控制器（36）和阀（38）根据温度（40）调节。

9. 发明授权

US06895746B2 Reducing oxides of nitrogen using hydrogen generated from engine fuel and exhaust 失效
标题翻译：使用发动机燃料和排气产生的氢还原氮氧化物
公开(公告)号：US06895746B2
公开(公告)日：2005-05-24
申请号：US10159369
申请日：2002-05-31
申请人： John G. Buglass , Francis A. Kocum , Ke Liu , Ronald J. Schoonebeek , Antonio M. Vincitore
发明人： John G. Buglass , Francis A. Kocum , Ke Liu , Ronald J. Schoonebeek , Antonio M. Vincitore
IPC分类号： B01D53/94 , F01N3/08 , F01N3/20 , F01N13/04 , F02B37/00 , F01N3/00
CPC分类号： F02B37/00 , B01D53/9431 , F01N3/0807 , F01N3/0814 , F01N3/0842 , F01N3/0878 , F01N3/2066 , F01N5/02 , F01N13/011 , F01N2240/02 , F01N2240/22 , F01N2240/30 , F01N2410/12 , F01N2570/22 , F01N2610/03 , F01N2610/04 , F01N2610/10 , Y02T10/144 , Y02T10/24
摘要： Either (a) the exhaust (20) of an engine (9) and/or (b) inlet air (11) is sent to a hydrogen generator (22) along with diesel fuel (18) to produce hydrogen and carbon monoxide (26) for either (c) mixing with the mainstream of exhaust fed to a catalytic converter (28) or (d) regenerating a pair of NOx adsorption traps (35, 36), thereby reducing oxides of nitrogen (NOx) to provide system exhaust (29) which may have less than 0.20 grams/bhp/hr of NOx and 0.14 grams/bhp/hr of non-methane hydrocarbons. A water recovery unit (52, 63) may extract water from either the exhaust or the effluent of the NOx traps to humidify inlet air (11) for mixture with fuel. Inlet air (11) may be humidified in an air bubbling humidifier (72) that receives water from a condenser (76) that uses inlet air to cool NOx trap effluent.
摘要翻译：（a）发动机（9）和/或（b）入口空气（11）的排气（20）与柴油燃料（18）一起被输送到氢发生器（22）以产生氢气和一氧化碳（26 ）（c）与供给到催化转化器（28）的废气的主流混合或（d）再生一对NOx吸附阱（35,36），从而减少氮氧化物（NOx）以提供系统排气（ 29），其可以具有小于0.20克/ bhp / hr的NOx和0.14克/ bhp / hr的非甲烷烃。水回收单元（52,63）可以从NOx捕集器的废气或流出物中提取水以加湿与燃料混合的入口空气（11）。入口空气（11）可以在从使用入口空气冷却NOx捕集流出物的冷凝器（76）接收水的空气鼓泡加湿器（72）中加湿。

10. 发明授权

US08840775B2 Regenerative gas sensor 有权
标题翻译：再生气体传感器
公开(公告)号：US08840775B2
公开(公告)日：2014-09-23
申请号：US13328558
申请日：2011-12-16
申请人： Lei Chen , Zhiwei Yang , Antonio M. Vincitore , Joseph J. Sangiovanni
发明人： Lei Chen , Zhiwei Yang , Antonio M. Vincitore , Joseph J. Sangiovanni
IPC分类号： G01N27/30 , G01N27/407
CPC分类号： G01N27/30 , G01N27/4045 , G01N27/407 , G01N33/0044
摘要： A gas sensor includes a housing having disposed therein a membrane electrode assembly comprising a sensing electrode, a counter electrode, and a polymer membrane disposed between the sensing electrode and the counter electrode. The polymer membrane comprises an ionic liquid retained therein. The sensor also includes a catalyst support that can be stable in a range of potentials to allow for detection mode and catalyst regeneration mode to be operative. The sensor further includes a circuitry and algorithm to implement the catalyst regeneration mechanism electrochemically. The sensor further includes a chamber for reference gas to which the counter electrode is exposed, and a chamber for test gas to which a gas to be tested is exposed. The sensor also includes a pathway for test gas to enter the chamber and a measured electrical circuit connecting the sensing electrode and the counter electrode.
摘要翻译：气体传感器包括壳体，其中设置有包括感测电极，对电极和设置在感测电极和对电极之间的聚合物膜的膜电极组件。聚合物膜包含保留在其中的离子液体。该传感器还包括催化剂载体，该催化剂载体在一定范围的电位中是稳定的，以允许检测模式和催化剂再生模式可操作。传感器还包括电化学地实现催化剂再生机构的电路和算法。传感器还包括用于对置电极暴露的参考气体的室，以及用于测试气体暴露的测试气体室。该传感器还包括用于测试气体进入室的通路和连接感测电极和对电极的测量电路。

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