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1. 发明授权

US6077500A High generation radially layered dendrimers 有权
标题翻译：高产径向层状树枝状大分子
公开(公告)号：US6077500A
公开(公告)日：2000-06-20
申请号：US272096
申请日：1999-03-18
申请人： Petar R. Dvornic , Agnes M. deLeuze-Jallouli , Michael James Owen , Susan Victoria Perz
发明人： Petar R. Dvornic , Agnes M. deLeuze-Jallouli , Michael James Owen , Susan Victoria Perz
IPC分类号： C08G77/60 , C08G73/02 , C08G73/04 , C08G77/54 , C08G83/00 , C08F283/00 , C08L71/00
CPC分类号： B82Y15/00 , C08G83/003 , Y10S424/16
摘要： Higher generation radially layered copolymeric dendrimers having a hydrophilic poly(amidoamine) or a hydrophilic poly(propyleneimine) interior and a hydrophobic organosilicon exterior are prepared by first reacting a hydrophilic dendrimer having --NH.sub.2 surface groups with an organosilicon compound, and then hydrosilating the resulting copolymeric dendrimer with another organosilicon compound in the presence of a noble metal catalyst. In an alternate embodiment, the radially layered copolymeric dendrimers are prepared by reacting a hydrophilic dendrimer having --NH.sub.2 surface groups directly with an organosilicon dendron or organosilicon hyperbranched polymer.
摘要翻译：具有亲水性聚（酰氨基胺）或亲水性聚（丙烯亚胺）内部和疏水性有机硅外部的更高级的径向层状共聚树枝状聚合物通过首先使具有-NH 2表面基团的亲水树枝状聚合物与有机硅化合物反应然后将所得共聚物在贵金属催化剂存在下，使用另一种有机硅化合物进行树状聚合。在另一个实施方案中，通过使具有-NH 2表面基团的亲水树枝状聚合物直接与有机硅树枝状突起或有机硅超支化聚合物反应来制备径向层状的共聚树枝状聚合物。

2. 发明授权

US5739218A Radially layered copoly (amidoamine-organosilicon) dendrimers 失效
标题翻译：径向层状共聚（酰胺胺 - 有机硅）树枝状大分子
公开(公告)号：US5739218A
公开(公告)日：1998-04-14
申请号：US867143
申请日：1997-06-02
申请人： Petar R. Dvornic , Agnes M. deLeuze-Jallouli , Douglas Swanson , Michael James Owen , Susan Victoria Perz
发明人： Petar R. Dvornic , Agnes M. deLeuze-Jallouli , Douglas Swanson , Michael James Owen , Susan Victoria Perz
IPC分类号： C08G77/00 , C08G73/02 , C08G77/452 , C08G77/54 , C08G83/00 , C07F283/00
CPC分类号： C08G83/003
摘要： Radially layered copoly-dendrimers having unusual surface properties and novel applications have been synthesized and characterized. These are the first copolymeric dendrimers composed of a hydrophilic poly(amidoamine) (PAMAM) interior with hydrophobic organosilicon surfaces. These dendrimers have been prepared by surface modifications of an ethylene diamine core PAMAM dendrimer with (3-acryloxypropyl)methyldimethoxysilane, (3-acryloxypropyl)bis(vinyldimethylsiloxy)methylsilane, (3-acryloxypropyl)tris(trimethylsiloxy)silane, chloromethyltrimethylsilane, and chloromethyldimethylvinylsilane, to varying degrees of surface coverage. The obtained products were characterized by .sup.1 H, .sup.13 C, and .sup.29 Si NMR, and by DSC and TGA. The dendrimers with less completely covered organosilicon surfaces are water soluble, and have considerable surface activity, the best of which lowered the surface tension of water to less than 30 mN/m. Areas in their surface, according to the Gibbs adsorption isotherm, are surprisingly small, i.e., of the order of 100 .ANG..sup.2 /mol. More completely hydrophobed dendrimers are water insoluble, and form spread monolayers on water, capable of sustaining surface pressures over 40 mN/m. Areas per molecule are in the 1,000 .ANG..sup.2 /mol range.
摘要翻译：已经合成并表征了具有异常表面性质和新应用的径向层状共聚树枝状聚合物。这些是由具有疏水性有机硅表面的亲水性聚（酰氨基胺）（PAMAM）内部组成的第一共聚树枝状聚合物。（3-丙烯酰氧基丙基）甲基二甲氧基硅烷，（3-丙烯酰氧基丙基）双（乙烯基二甲基甲硅烷氧基）甲基硅烷，（3-丙烯酰氧基丙基）三（三甲基甲硅烷氧基）硅烷，氯甲基三甲基硅烷和氯甲基二甲基乙烯基硅烷的乙二胺核心PAMAM树枝状聚合物的表面改性制备了这些树枝状聚合物，到不同程度的表面覆盖。得到的产物用1H，13C和29Si NMR表征，通过DSC和TGA表征。具有较少完全覆盖的有机硅表面的树枝状大分子是水溶性的并且具有相当大的表面活性，其中最好的将水的表面张力降低到小于30mN / m。根据吉布斯吸附等温线，其表面的面积令人惊讶地很小，即大约为100安培2 /摩尔。更完全疏水的树枝状大分子是水不溶性的，并且在水上形成扩散单层，能够维持超过40mN / m的表面压力。每个分子的面积为1000 ANGSTROM 2 / mol范围。

3. 发明授权

US5902863A Dendrimer-based networks containing lyophilic organosilicon and hydrophilic polyamidoamine nanoscopic domains 失效
标题翻译：基于树枝状聚合物的网络包含亲液性有机硅和亲水性聚酰胺胺纳米视野域
公开(公告)号：US5902863A
公开(公告)日：1999-05-11
申请号：US897943
申请日：1997-07-21
申请人： Petar R. Dvornic , Agnes M. deLeuze-Jallouli , Michael James Owen , Susan Victoria Perz
发明人： Petar R. Dvornic , Agnes M. deLeuze-Jallouli , Michael James Owen , Susan Victoria Perz
IPC分类号： C08L79/00 , C08G73/00 , C08G83/00 , C08L101/00 , C08L77/02
CPC分类号： B82Y15/00 , C08G83/003 , C08L101/005 , Y10S977/788
摘要： Dendrimer-based networks are prepared from copolydendrimer precursors having well defined hydrophilic polyamidoamine (PAMAM) or polypropyleneimine (PPI) interiors, and organosilicon outer layers ending with .tbd.Si--OCH.sub.3 surface groups. These networks have precisely controllable size, shape, and spatial distribution, of nanoscopic hydrophilic and hydrophobic domains. Such constructs are prepared by crosslinking one type of copolydendrimer precursor, or by crosslinking mixtures of different copolydendrimers having different generations of PAMAM or PPI dendrimers in the interior, surrounded by different organosilicon exteriors. Crosslinking can be controlled by adding difunctional, trifunctional, or polyfunctional low molecular weight or oligomeric crosslinking agents; or by exposing a copolydendrimer having hydrolyzable surface groups to atmospheric moisture. Elastomeric dendrimer-based networks have low glass temperatures of -15.degree. C. or below, are optically clear, transparent, colorless; and have a non-stick surface which can be formed into films of small thickness.
摘要翻译：基于树枝状聚合物的网络由具有明确限定的亲水性聚酰胺胺（PAMAM）或聚丙烯亚胺（PPI）内部的共聚聚琥珀内酯前体和以3BOND Si-OCH 3表面基团结束的有机硅外层制备。这些网络具有精确可控的尺寸，形状和空间分布，纳米级亲水和疏水域。通过交联一种类型的共聚聚琥珀酰前体，或通过在不同的有机硅外部包围的内部交联具有不同代的PAMAM或PPI树枝状聚合物的不同共聚缔结聚合物的混合物来制备这种构建体。交联可以通过加入双功能，三官能或多官能的低分子量或低聚交联剂来控制; 或通过将具有可水解表面基团的共聚聚琥珀酰亚胺暴露于大气湿气中。基于弹性树枝状聚合物的网络具有-15℃或更低的玻璃温度低，光学透明，透明，无色; 并且具有可以形成为小厚度的膜的不粘表面。

4. 发明授权

US06077892A Curable polyolefin compositions containing organosilicon compounds as adhesion additives 失效
标题翻译：含有有机硅化合物作为粘合添加剂的可固化聚烯烃组合物
公开(公告)号：US06077892A
公开(公告)日：2000-06-20
申请号：US148805
申请日：1998-09-04
申请人： Qian Jane Feng , Kenneth Michael Lee , Michael Andrew Lutz , Michael James Owen , Susan Victoria Perz , Toshio Suzuki
发明人： Qian Jane Feng , Kenneth Michael Lee , Michael Andrew Lutz , Michael James Owen , Susan Victoria Perz , Toshio Suzuki
IPC分类号： C08J3/24 , C08G77/442 , C08J5/12 , C08K5/1515 , C08K5/541 , C08L23/22 , C08L43/04 , C08L83/04 , C09J123/22 , C08K5/15
CPC分类号： C08K5/541 , C08K5/1515 , C08L23/22 , C08L43/04 , C08L83/04
摘要： The adhesion of cured polyolefin compositions to a variety of substrates is improved using as the adhesion promoter the combination of 1) an organic or organosilicon compound containing at least one epoxy group and 2) at least one compound containing a) at least one silanol or carbinol group or a hydrolyzable silanol group precursor, and b) at least one group that reacts during curing of the polyolefin.
摘要翻译：固化的聚烯烃组合物对各种基材的粘附性被改进，作为粘合促进剂，其组合为1）含有至少一个环氧基的有机或有机硅化合物和2）至少一种含有a）至少一种硅烷醇或甲醇的化合物基团或可水解硅烷醇基前体，和b）至少一个在聚烯烃固化期间反应的基团。

5. 发明授权

US6034179A Polyolefin compositions containing organosilicon compounds as adhesion additives 失效
标题翻译：含有有机硅化合物作为粘合添加剂的聚烯烃组合物
公开(公告)号：US6034179A
公开(公告)日：2000-03-07
申请号：US143410
申请日：1998-08-28
申请人： Qian Jane Feng , Kenneth Michael Lee , Michael Andrew Lutz , Michael James Owen , Susan Victoria Perz , Toshio Suzuki
发明人： Qian Jane Feng , Kenneth Michael Lee , Michael Andrew Lutz , Michael James Owen , Susan Victoria Perz , Toshio Suzuki
IPC分类号： C08J3/24 , C08G77/442 , C08J5/12 , C08K5/5419 , C08L23/22 , C08L83/04 , C09J123/22 , C08F8/00
CPC分类号： C08K5/5419
摘要： The present invention provides adhesion promoters for curable polyolefin compositions wherein said adhesion promoters are selected from a specified group of hydrocarbyloxy-substituted organosilicon compounds and condensation products of these compounds. At least one hydrocarbyloxy group on each silicon atom of the adhesion promoter is derived from a polyhydric alcohol containing at least two hydroxyl groups per molecule and substantially no ethylenic unsaturation.
摘要翻译：本发明提供了可固化聚烯烃组合物的粘合促进剂，其中所述粘合促进剂选自指定的烃氧基取代的有机硅化合物和这些化合物的缩合产物。粘合促进剂的每个硅原子上的至少一个烃氧基衍生自每分子含有至少两个羟基并且基本上不含烯属不饱和度的多元醇。

6. 发明授权

US5973044A Adhesion promoting organosilicon compositions 失效
标题翻译：粘附促进有机硅组合物
公开(公告)号：US5973044A
公开(公告)日：1999-10-26
申请号：US143301
申请日：1998-08-28
申请人： Michael Andrew Lutz , Michael James Owen , Susan Victoria Perz
发明人： Michael Andrew Lutz , Michael James Owen , Susan Victoria Perz
IPC分类号： C08L83/04 , C08G77/04 , C08G77/50 , C09D183/14 , C09J183/04 , C08K5/54
CPC分类号： C09D183/14 , C08G77/50
摘要： This invention relates to organosilicon compositions useful as adhesion promoters for curable organopolysiloxanes, said organosilicon compositions being formed by reacting (A) a polyhydric alcohol, (B) an organosiloxane containing at least one organofunctional group and one hydroxyl or hydrolyzable group per molecule and (C) a silane containing at least three hydrolyzable groups per molecule.
摘要翻译：本发明涉及可用作可固化的有机聚硅氧烷的粘合促进剂的有机硅组合物，所述有机硅组合物通过（A）多元醇，（B）每分子含有至少一个有机官能团和一个羟基或可水解基团的有机硅氧烷与（C））每分子含有至少三个可水解基团的硅烷。

7. 发明授权

US06350384B1 Silicon containing multi-arm star polymers 有权
标题翻译：含硅多臂星形聚合物
公开(公告)号：US06350384B1
公开(公告)日：2002-02-26
申请号：US09637924
申请日：2000-08-14
申请人： Petar Radivoj Dvornic , Jin Hu , Agnes M. de Leuze-Jallouli , Michael James Owen , Paul Lane Parham , Susan Victoria Perz , Scott Daniel Reeves
发明人： Petar Radivoj Dvornic , Jin Hu , Agnes M. de Leuze-Jallouli , Michael James Owen , Paul Lane Parham , Susan Victoria Perz , Scott Daniel Reeves
IPC分类号： C02F162
CPC分类号： C08G83/003 , C08G81/00 , Y10S210/912 , Y10S525/936
摘要： Multi-arm star polymers are derived from silicon containing dendrimers and have arms containing the moiety where each R′ can be the same or different and is an alkyl group containing 1-6 carbon atoms such as methyl and ethyl or an aryl group such as phenyl; R″ is alkylene radical —(CH2)a— in which a has a value of 2 or 3; and R′″ is the —(CH2)bCH3 group in which b has a value of 1-50. These compositions can be used for dissolving metals and other electrophiles.
摘要翻译：多臂星形聚合物衍生自含硅树枝状大分子，并且具有包含部分的臂，其中每个R'可以相同或不同，并且是含有1-6个碳原子的烷基，例如甲基和乙基或芳基如苯基; R“是亚烷基 - （CH 2）a - ，其中a具有2或3的值; 并且R“'是 - （CH 2）b CH 3基团，其中b的值为1-50。这些组合物可用于溶解金属和其它亲电体。

8. 发明授权

US6060559A Curable polyolefin compositions containing organosilicon compounds as adhesion additives 失效
标题翻译：含有有机硅化合物作为粘合添加剂的可固化聚烯烃组合物
公开(公告)号：US6060559A
公开(公告)日：2000-05-09
申请号：US148856
申请日：1998-09-04
申请人： Qian Jane Feng , Robert Edward Kalinowski , Kenneth Michael Lee , Michael Andrew Lutz , Michael James Owen , Susan Victoria Perz , Toshio Suzuki
发明人： Qian Jane Feng , Robert Edward Kalinowski , Kenneth Michael Lee , Michael Andrew Lutz , Michael James Owen , Susan Victoria Perz , Toshio Suzuki
IPC分类号： C08J3/24 , C08G77/442 , C08J5/12 , C08K5/5425 , C08L23/22 , C08L43/04 , C08L83/04 , C09J123/26 , C09J183/04 , C08L47/00
CPC分类号： C08L23/22 , C08K5/5425 , C08L43/04 , C08L83/04
摘要： The presence in curable polyolefin compositions of a moisture curable organosilicon compound containing at least one alkenyloxy group bonded to the silicon atoms improves the adhesion to a variety of substrates that is developed during the curing reaction of polyolefin compositions cured by a hydrosilation reaction. The organosilicon compound is preferably a reaction product of ingredients comprising 1) a silane or bis-silylalkane containing at least three silicon-bonded moisture-reactive groups per molecule and 2) an organic compound containing at least one carbinol group and at least one ethylenically unsaturated group.
摘要翻译：含有与硅原子键合的至少一个烯氧基的可湿气固化的有机硅化合物在可固化聚烯烃组合物中的存在改善了在通过硅氢化反应固化的聚烯烃组合物的固化反应期间所形成的各种基材的粘合性。有机硅化合物优选是成分的反应产物，其包含1）每分子含有至少三个与硅键合的水分反应性基团的硅烷或双甲硅烷基烷烃，和2）含有至少一个甲醇基团和至少一个烯属不饱和基团的有机化合物组。

9. 发明授权

US5969173A Method of making dialkali metal silanolates and siloxanolates 失效
标题翻译：制备二碱金属硅烷醇酯和硅氧烷醇酯的方法
公开(公告)号：US5969173A
公开(公告)日：1999-10-19
申请号：US203317
申请日：1998-12-01
申请人： Stephen Ross Clarke , Daniel Graiver , Janis Gunars Matisons , Michael James Owen
发明人： Stephen Ross Clarke , Daniel Graiver , Janis Gunars Matisons , Michael James Owen
IPC分类号： C07F7/08 , C02F7/08
CPC分类号： C07F7/0836 , C07F7/0858 , C07F7/0874
摘要： Dialkali metal organosilanolate and dialkali metal organosiloxanolate salts are manufactured from cyclic siloxanes or linear silicone polymers using a heterogeneous interfacial reaction process. A stoichiometric excess of an alkali metal hydroxide such as potassium hydroxide or an alkali metal oxide as a solid or dissolved or dispersed in a compatible solvent, is prepared and used as a first phase. The cyclic siloxane or linear silicone polymer is placed in a second phase either dissolved or dispersed in another solvent which is immiscible with the first phase. The resulting silanolate and siloxanolate salts can be used as monomers for solid-liquid phase and liquid-liquid phase interfacial polymerization or in a polycondensation process for the synthesis of alternating siloxane polymers. They can also be used as ring opening initiators for the base catalyzed polymerization of cyclic siloxanes.
摘要翻译： Dialkali金属有机硅烷醇酯和二碱金属有机硅氧烷醇盐由环状硅氧烷或线性硅氧烷聚合物使用异质界面反应方法制备。制备化学计量过量的碱金属氢氧化物如氢氧化钾或作为固体的碱金属氧化物或溶解或分散在相容的溶剂中，并用作第一相。将环状硅氧烷或线性硅氧烷聚合物置于第二相中，溶解或分散在与第一相不混溶的另一种溶剂中。所得的硅烷醇酯和硅氧烷酸盐可用作固 - 液相和液 - 液相界面聚合的单体，或用于合成交替的硅氧烷聚合物的缩聚过程。它们也可以用作环状硅氧烷的碱催化聚合的开环引发剂。

10. 发明授权

US08664595B2 Cluster analysis of unknowns in SEM-EDS dataset 有权
标题翻译： SEM-EDS数据集中未知数的聚类分析
公开(公告)号：US08664595B2
公开(公告)日：2014-03-04
申请号：US13536308
申请日：2012-06-28
申请人： Michael Buhot , Van Hung Phan , Michael James Owen
发明人： Michael Buhot , Van Hung Phan , Michael James Owen
IPC分类号： G21K7/00
CPC分类号： G21K7/00 , G01N23/2252 , G01N2223/616 , H01J2237/24585 , H01J2237/2807
摘要： The present invention discloses a method for determining the mineral content represented by the entire SEM-EDS dataset, including initially unknown data points. SEM-EDS data points are taken and compared to a set of known data points. Any data point that is not sufficiently similar to the known data point is classified as unknown and clustered with like unknown data points. After all data points are analyzed, any clusters of unknown data points with a sufficient number of data points are further analyzed to determine their characteristics. All clusters of unknown data points with an insufficient number of data points to allow further analysis are considered outliers and discarded.
摘要翻译：本发明公开了一种用于确定由整个SEM-EDS数据集表示的矿物质含量的方法，包括最初未知的数据点。取SEM-EDS数据点并与一组已知数据点进行比较。与已知数据点不完全相似的任何数据点都被分类为未知，并且具有类似未知数据点的聚类。在分析了所有数据点之后，进一步分析具有足够数量数据点的未知数据点的任何簇，以确定它们的特性。具有不足数量的数据点的所有未知数据集群允许进一步分析被认为是异常值并被丢弃。

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