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    • 9. 发明申请
    • Silsesquioxane Resins
    • 倍半硅氧烷树脂
    • US20110236835A1
    • 2011-09-29
    • US13133050
    • 2009-10-19
    • Peng-Fei FuMoyer EricCraig Yeakle
    • Peng-Fei FuMoyer EricCraig Yeakle
    • G03F7/20B05D5/12
    • C09D183/06C08G77/04C08G77/14G03F7/0752G03F7/091
    • Antireflective coatings produced from silsesquioxane resin comprises the units (Ph(CH2)rSiO(3-x)/2(OR′)x)m (HSiO(3-x)/2(OR′)x)n (MeSiO(3-x)/2(OR′)x)o (RSiO(3-x)/2(OR′)x)p (R1SiO(3-x)/2(OR′)x)q where Ph is a phenyl group, Me is a methyl group; R′ is hydrogen atom or a hydrocarbon group having from 1 to 4 carbon atoms; R is selected from a carboxylic acid group or a carboxylic acid forming group with the proviso that there is a sufficient amount of carboxylic acid groups to make the resin wet etchable after cure; and R1 is selected from substituted phenyl groups, ester groups, polyether groups; mercapto groups, sulfur-containing organic functional groups, hydroxyl producing group, aryl sulphonic ester groups, and reactive or curable organic functional groups; and r has a value of 0, 1, 2, 3, or 4; x has a value of 0, 1 or 2; wherein in the resin m has a value of 0 to 0.90; n has a value of 0.05 to 0.99; o has a value of 0 to 0.95; p has a value of 0.01 to 0.5; q has a value of 0 to 0.5; and m+n+o+p+q≈1.
    • 由倍半硅氧烷树脂制备的抗反射涂层包括单元(Ph(CH2)rSiO(3-x)/ 2(OR')x)m(HSiO(3-x)/ 2(OR')x)n(MeSiO x)/ 2(OR')x)o(RSiO(3-x)/ 2(OR')x)p(R1SiO(3-x)/ 2(OR')x)q其中Ph是苯基, 我是甲基; R'是氢原子或具有1至4个碳原子的烃基; R选自羧酸基团或羧酸形成基团,条件是存在足够量的羧酸基团以使树脂在固化后可湿法蚀刻; 并且R 1选自取代的苯基,酯基,聚醚基团; 巯基,含硫有机官能团,羟基产生基团,芳基磺酸酯基团和反应性或可固化的有机官能团; 并且r的值为0,1,2,3或4; x的值为0,1或2; 其中在树脂中m为0至0.90; n的值为0.05〜0.99; o的值为0〜0.95; p的值为0.01〜0.5; q的值为0〜0.5; 和m + n + o + p +q≈1。
    • 10. 发明申请
    • Silsesquioxane Resins
    • 倍半硅氧烷树脂
    • US20110233489A1
    • 2011-09-29
    • US13133032
    • 2009-10-19
    • Peng-Fei FuEric MoyerCraig Yeakle
    • Peng-Fei FuEric MoyerCraig Yeakle
    • C08G77/12C08G77/06C08G77/445C09D5/00
    • C08G77/14C08G77/04C08G77/12C09D183/06G03F7/0752G03F7/091
    • This invention pertains to silsesquioxane resins useful in antireflective coatings wherein the silsesquioxane resin comprises the units (Ph(CH2)rSiO(3-x)/2(OR′)x)m(HSiO(3-x)/2(OR′)x)n (MeSiO(3-x)/2(OR′)x)c, (RSiO(3-x)/2(OR′)x)p (R1SiO(3-x)/2(OR′)x)q where Ph is a phenyl group, Me is a methyl group; R′ is hydrogen atom or a hydrocarbon group having from 1 to 4 carbon atoms; R is selected from a carboxylic acid group, a carboxylic acid forming group, and mixtures thereof; and R1 is selected from substituted phenyl groups, ester groups, polyether groups; mercapto groups, sulfur-containing organic functional groups, hydroxyl producing group, aryl sulphonic ester groups, and reactive or curable organic functional groups; and r has a value of 0, 1, 2, 3, or 4; x has a value of 0, 1 or 2; wherein in the resin m has a value of 0 to 0.90; n has a value of 0.05 to 0.99; o has a value of 0 to 0.95; p has a value of 0.01 to 0.5; q has a value of 0 to 0.5; and m+n+o+p+q≈1.
    • 本发明涉及可用于抗反射涂料的倍半硅氧烷树脂,其中倍半硅氧烷树脂包含单元(Ph(CH 2)r SiO(3-x)/ 2(OR')x)m(HSiO(3-x)/ 2(OR' x)n(MeSiO(3-x)/ 2(OR')x)c,(RSiO(3-x)/ 2(OR')x)p(R 1 SiO(3-x)/ 2(OR' )q其中Ph是苯基,Me是甲基; R'是氢原子或具有1至4个碳原子的烃基; R选自羧酸基团,羧酸形成基团及其混合物; 并且R 1选自取代的苯基,酯基,聚醚基团; 巯基,含硫有机官能团,羟基产生基团,芳基磺酸酯基团和反应性或可固化的有机官能团; 并且r的值为0,1,2,3或4; x的值为0,1或2; 其中在树脂中m为0至0.90; n的值为0.05〜0.99; o的值为0〜0.95; p的值为0.01〜0.5; q的值为0〜0.5; 和m + n + o + p +q≈1。