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    • 4. 发明申请
    • Recovery of Hydrocarbon From Aqueous Streams
    • 从水流回收烃
    • US20110284428A1
    • 2011-11-24
    • US13081125
    • 2011-04-06
    • Olusola B. AdeyinkaRonald D. MyersMainak Ghosh
    • Olusola B. AdeyinkaRonald D. MyersMainak Ghosh
    • C10G1/04C10C3/08
    • C10G1/002B01D21/262C10G21/14C10G33/00C10G33/06C10G53/04C10G2300/206C10G2300/44
    • A process is described for pre-treating an aqueous bituminous feed for downstream bitumen extraction. The process involves removing water from an aqueous bituminous feed having a water content of 60% or more by weight. After water is removed, an effluent comprising 40% water or less is formed, and is ready for downstream extraction. In the downstream extraction process, a dual solvent extraction process may be employed, incorporating agglomeration of fines to simplify subsequent solid-liquid separation. The process permits recovery of hydrocarbon that has conventionally remained in waste streams from oil sands processing, and thus has conventionally been lost. In one embodiment, removing water comprises subjecting the aqueous bituminous feed to a primary water separation system to reduce the water content of the feed, followed by subsequent water removal, thereby producing an effluent having a water content of 40% or less, which can then go on to further processing.
    • 描述了一种用于预处理含水沥青进料用于下游沥青提取的方法。 该方法包括从含水量为60重量%以上的含水沥青进料除去水。 除去水后,形成含有40%以下水的流出物,并准备进行下游萃取。 在下游提取过程中,可以采用双溶剂萃取方法,其中包括细粒团聚以简化随后的固液分离。 该方法允许从油砂处理中常规保留在废物流中的烃的回收,因此传统上已经丢失。 在一个实施方案中,除去水包括将含水沥青进料经受初级水分离系统以减少进料的水含量,随后随后除去水,从而产生水含量为40%或更低的流出物, 继续进行加工。
    • 7. 发明授权
    • Continuous in-situ process for upgrading heavy oil using aqueous base
    • 连续原位使用含水碱升级重油
    • US5635056A
    • 1997-06-03
    • US433907
    • 1995-05-02
    • Glen BronsRonald D. Myers
    • Glen BronsRonald D. Myers
    • C10G19/02C10G19/08C10G29/20
    • C10G19/02C10G19/08
    • The present invention relates to a continuous in-situ process for the removal from heavy oils, of organically bound sulfur in the form of mercaptans, sulfides and thiophenes, heteroatoms selected from the group consisting of nitrogen and oxygen and metals selected from the group consisting of nickel, vanadium and iron, comprising the steps of (a) contacting a heavy oil with aqueous sodium hydroxide at a temperature of about 380.degree. to about 450.degree. C. for a time sufficient to form sodium sulfide; (b) contacting said sodium sulfide of step (a) with water and a transition metal for a time and at a temperature sufficient to form transition metal sulfide, sodium hydroxide, hydrogen and impurities; and (c) recirculating said sodium hydroxide from step (b) to step (a) and removing said transition metal sulfide and said impurities, wherein said impurities are iron, vanadium and nickel. Optionally, molecular hydrogen may be added in the first step. The present invention is useful in removing organically bound sulfur that has been recognized to be difficult to remove, such as thiophenes. Beneficially, the process also removes other heteroatoms (nitrogen and oxygen) and metals (vanadium, iron, nickel) and reduces asphaltene content (n-heptane insolubles), micro concarbon residue, coke, 975.degree. F. fractions, TGA fixed carbon, average molecular weight, density and viscosity.
    • 9. 发明授权
    • Combined steam and vapor extraction process (SAVEX) for in situ bitumen and heavy oil production
    • 用于原位沥青和重油生产的蒸汽和蒸汽萃取工艺(SAVEX)
    • US06662872B2
    • 2003-12-16
    • US10045293
    • 2001-11-07
    • A. M. Harold GutekBrian HarschnitzRonald D. MyersTadahiro Okazawa
    • A. M. Harold GutekBrian HarschnitzRonald D. MyersTadahiro Okazawa
    • E21B4322
    • E21B43/2406E21B43/168E21B43/2408
    • Steam is injected into the reservoir, heats the reservoir to mobilize and recover at least a fraction of reservoir hydrocarbons, forming a steam chamber in the reservoir. The steam is continuously injected into the reservoir to mobilize and recover reservoir hydrocarbons therefrom until at least one of (i) an upper surface of the chamber has progressed vertically to a position that is approximately 25 percent to 75 percent the distance from the bottom of the injection well to the top of the reservoir, and (ii) the recovery rate of the hydrocarbons is approximately 25 percent to 75 percent of the peak predicted recovery rate using steam-assisted gravity drainage. A viscosity-reducing hydrocarbon solvent is injected into the reservoir, the solvent being capable of existing in vapor form in the chamber and being just below the solvent's saturation pressure in the chamber, mobilizing and recovering additional hydrocarbons from the reservoir.
    • 将蒸汽注入储存器中,加热储存器以调动和回收至少一部分储层烃,在储层中形成蒸汽室。 蒸汽被连续地注入到储存器中以从其中移动和回收储存器碳氢化合物,直到(i)室的上表面中的至少一个垂直地进行到从底部的距离的大约25%到75%的位置 注入井的顶部,(ii)碳氢化合物的回收率约为使用蒸汽辅助重力排水的峰值预测回收率的25%至75%。 将降粘烃溶剂注入储存器中,溶剂能够在室中以蒸气形式存在,并且刚好低于溶剂在室中的饱和压力,从储存器中移动和回收另外的烃。
    • 10. 发明授权
    • Continuous in-situ combination process for upgrading heavy oil
    • 连续原位组合工艺提升重油
    • US5935421A
    • 1999-08-10
    • US734322
    • 1996-10-21
    • Glen BronsRonald D. MyersRoby Bearden
    • Glen BronsRonald D. MyersRoby Bearden
    • C10G29/04C10G67/02C10G19/02
    • C10G29/04C10G67/02
    • The invention relates to an integrated, continuous process for the removal of organically bound sulfur (e.g., mercaptans, sulfides and thiophenes) comprising the steps of contacting a heavy oil, sodium hydroxide, hydrogen and water at a temperature of from about 380.degree. C. to 450.degree. C. to partially desulfurize the heavy oil and to form sodium sulfide, contacting said sodium sulfide via steam stripping to convert the sodium sulfide to sodium hydroxide and the sulfur recovered as hydrogen sulfide. The sodium hydroxide is recirculated for reuse. The partially desulfurized, dewatered heavy oil is treated with sodium metal under desulfurizing conditions, typically at a temperature of from about 340.degree. C. to about 450.degree. C., under a hydrogen pressure of at least about 50 psi to essentially desulfurize the oil, and form sodium sulfide. Optionally, the sodium salt generated can be regenerated to sodium metal using regeneration technology. The process advantageously produces essentially sulfur-free product oils having reduced nitrogen, oxygen and metals contents and reduced viscosity, density, molecular weight and heavy ends.
    • 本发明涉及用于去除有机结合硫(例如硫醇,硫化物和噻吩)的一体化连续方法,包括以下步骤:在约380℃的温度下使重质油,氢氧化钠,氢气和水接触。 至450℃,以部分重硫脱硫并形成硫化钠,通过汽提将硫化钠接触,将硫化钠转化为氢氧化钠,硫作为硫化氢回收。 将氢氧化钠再循环以重新使用。 部分脱硫的脱水重油在脱硫条件下,通常在约340℃至约450℃的温度下,在至少约50psi的氢气压力下用金属钠处理以使油基本上脱硫, 并形成硫化钠。 任选地,所生成的钠盐可以使用再生技术再生成金属钠。 该方法有利地产生具有降低的氮,氧和金属含量以及降低的粘度,密度,分子量和重量的基本上无硫产品油。