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    • 4. 发明授权
    • Gas diffusion electrode for electrochemical cell and process of
preparing same
    • 用于电化学电池的气体扩散电极及其制备方法
    • US5846670A
    • 1998-12-08
    • US858898
    • 1997-05-19
    • Masahiro WatanabeKazunori TsurumiNoriaki Hara
    • Masahiro WatanabeKazunori TsurumiNoriaki Hara
    • H01M4/92H01M4/96H01M4/29H01M4/88
    • H01M4/926H01M4/96
    • Disclosed are a gas diffusion electrode for an electrochemical cell which comprises a catalyst layer formed by binding, by means of poiytotrafluoroethylene, catalyst-supporting carbon black and catalyst-non-supporting carbon black having a fluorinated polyolofine film on substantially whole surface, the catalyst layer being integrated on a substrate, and a process of preparing same. Since the carbon black employed for the formation of the gas network in the catalyst layer of the gas diffusion electrode having the above constitution in accordance with the present invention is completely hydrophobically treated, no electrolyte permeates this portion and the carbon black exhibits high hydrophobicity so that the wet-proofing is maintained even after the long operation period to enable the gas supply to the catalyst particles so as to provide the gas diffusion electrode with a long life and high electrode performances.
    • 公开了一种用于电化学电池的气体扩散电极,其包括通过聚四氟乙烯在催化剂负载的炭黑和在基本上整个表面上具有氟化聚四烯酚膜的催化剂不支撑炭黑结合形成的催化剂层,催化剂层 整合在基板上,以及其制备方法。 由于在根据本发明的上述结构的气体扩散电极的催化剂层中用于形成气体网络的炭黑被完全疏水化处理,所以没有电解质渗透该部分,并且炭黑表现出高的疏水性,因此 即使经过长时间操作,也能保持湿气保护,能够使催化剂粒子的气体供给,从而为气体扩散电极提供长寿命和高电极性能。
    • 6. 发明授权
    • Process of preparing fluorinated material
    • 制备氟化材料的工艺
    • US5869132A
    • 1999-02-09
    • US037301
    • 1993-03-26
    • Masahiro WatanabeNoriaki Hara
    • Masahiro WatanabeNoriaki Hara
    • H01M4/86H01M4/96B05D7/00B05D5/12
    • H01M4/8605H01M4/96
    • Disclosed is a process of preparing fluorinated material which comprises thermally treating the mixture of carbon black and hydrocarbon polymer compound powder for covering the surface of the carbon black with the latter and fluorinating the hydrocarbon polymer compound. The thermal treatment can be conducted in two stages.The fluorinated material prepared in accordance with the present invention can provide much more pore volumes acting as gas networks in, for example, an electrode which exhibits high gas permeability or gas supplying ability. Further, the hydrophobicity is as high as that of the material prepared in accordance with mixing carbon black with hydrocarbon polymer compound dispersed in an organic solvent, and is higher than that of the conventional mixture of carbon black and polytetrafluoroethylene particles. The fluorinated material is preferably employed to a fuel cell as gas network material.
    • 公开了一种制备氟化材料的方法,该方法包括热处理炭黑和烃聚合物化合物粉末的混合物,用于将碳黑的表面覆盖并且氟化烃聚合物化合物。 热处理可以分两个阶段进行。 根据本发明制备的氟化材料可以在例如表现出高气体渗透性或气体供应能力的电极中作为气体网络提供更多的孔体积。 此外,疏水性与根据分散在有机溶剂中的炭黑与烃类高分子化合物混合制备的材料的疏水性高,高于常规的炭黑和聚四氟乙烯颗粒的混合物。 氟化材料优选用作燃料电池作为气体网络材料。