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1. 发明授权

US08685871B2 Multifunctional additives in engineering thermoplastics 有权
标题翻译：工程热塑性塑料中的多功能添加剂
公开(公告)号：US08685871B2
公开(公告)日：2014-04-01
申请号：US12971542
申请日：2010-12-17
申请人： Paul Mark Cross , Richard Thomas Price , Dominique Ponsolle , Patrick Terence McGrail
发明人： Paul Mark Cross , Richard Thomas Price , Dominique Ponsolle , Patrick Terence McGrail
IPC分类号： B32B27/04 , D04H13/00 , C08L61/16 , C08L71/12 , C08L81/04 , C08L81/06
CPC分类号： C08G75/20 , C08G59/4021 , C08G59/4064 , C08G59/5033 , C08G59/504 , C08G65/08 , C08G75/23 , C08L61/02 , C08L63/00 , C08L65/02 , C08L71/12 , C08L81/06 , Y10T428/24994 , Y10T442/186 , Y10T442/696
摘要： A toughening agent for use in making composites comprises an epoxy curing agent and a thermoplastic. Compositions, composites that comprise the toughening agent and associated methods of making and using the toughening agent are also disclosed.
摘要翻译：用于制造复合材料的增韧剂包括环氧固化剂和热塑性塑料。还公开了包含增韧剂的组合物，以及制造和使用增韧剂的相关方法。

2. 发明申请

US20110152469A1 MULTIFUNCTIONAL ADDITIVES IN ENGINEERING THERMOPLASTICS 有权
标题翻译：工程热力学中的多功能添加剂
公开(公告)号：US20110152469A1
公开(公告)日：2011-06-23
申请号：US12971542
申请日：2010-12-17
申请人： Paul Mark Cross , Richard Thomas Price , Dominique Ponsolle , Patrick Terence McGrail
发明人： Paul Mark Cross , Richard Thomas Price , Dominique Ponsolle , Patrick Terence McGrail
IPC分类号： C08L63/00 , C08L81/00
CPC分类号： C08G75/20 , C08G59/4021 , C08G59/4064 , C08G59/5033 , C08G59/504 , C08G65/08 , C08G75/23 , C08L61/02 , C08L63/00 , C08L65/02 , C08L71/12 , C08L81/06 , Y10T428/24994 , Y10T442/186 , Y10T442/696
摘要： A toughening agent for use in making composites comprises an epoxy curing agent and a thermoplastic. Compositions, composites that comprise the toughening agent and associated methods of making and using the toughening agent are also disclosed.
摘要翻译：用于制备复合材料的增韧剂包括环氧固化剂和热塑性塑料。还公开了包含增韧剂的组合物，以及制造和使用增韧剂的相关方法。

3. 发明申请

US20120115388A1 COMPATIBLE CARRIER FOR SECONDARY TOUGHENING 审中-公开
标题翻译：兼容载体用于二次加固
公开(公告)号：US20120115388A1
公开(公告)日：2012-05-10
申请号：US13289434
申请日：2011-11-04
申请人： Alexandre A. Baidak , Patrick Terence McGrail , Dominique Ponsolle , Robert Blackburn
发明人： Alexandre A. Baidak , Patrick Terence McGrail , Dominique Ponsolle , Robert Blackburn
IPC分类号： B32B5/28 , C08L31/02 , C08L63/00 , C08L33/12 , B32B37/14 , C08L77/06 , C08L81/06 , B32B5/26 , B29C47/06 , B32B38/00 , B29C45/14 , C08L21/00
CPC分类号： D04H3/005 , B29C45/14508 , B29C70/02 , B29C70/44 , C08J5/24 , Y10T442/60 , Y10T442/659 , Y10T442/673
摘要： Embodiments of the invention are directed to carriers providing a primary toughening function and incorporating a secondary toughening agent therein. According to embodiments of the invention, the carrier/agent combination may be used in liquid resin infusion applications. The carrier may be any polymer-based material having a solubility characteristic in a thermosetting resin. The secondary toughening agent may be of a material such as a thermoplastic, a thermoset, a cross-linked thermoset, a rubber, a rubbery-like material or a combination thereof and may be in the form of a particle, a micro-fiber (fibril) or a fibrous network. In some embodiments, the carrier is soluble in the resin while the secondary toughening agent is insoluble in the resin when subjected to a cure cycle.
摘要翻译：本发明的实施方案涉及提供初级增韧功能并在其中并入次级增韧剂的载体。根据本发明的实施方案，载体/药剂组合可用于液体树脂注射应用中。载体可以是在热固性树脂中具有溶解度特性的任何聚合物基材料。二次增韧剂可以是诸如热塑性材料，热固性材料，交联热固性材料，橡胶，橡胶状材料或其组合的材料，并且可以是颗粒，微纤维（原纤维）或纤维网络。在一些实施方案中，当经历固化循环时，载体可溶于树脂，而次级增韧剂不溶于树脂。

4. 发明申请

US20110040045A1 REVERSIBLE DERIVATIZATION OF POLY (ARYL ETHER KETONES) 审中-公开
标题翻译：聚合物（ARYL ETHER KETONES）的可逆衍生物
公开(公告)号：US20110040045A1
公开(公告)日：2011-02-17
申请号：US12601093
申请日：2008-05-16
申请人： Howard Matthew Colquhoun , Francois Pierre Vincent Paoloni , Philip Hodge , Patrick Terence McGrail , Paul Mark Cross
发明人： Howard Matthew Colquhoun , Francois Pierre Vincent Paoloni , Philip Hodge , Patrick Terence McGrail , Paul Mark Cross
IPC分类号： C08F283/00 , G01N30/00
CPC分类号： C08J5/24 , C08G65/48 , C08J2381/02 , C08L71/10 , C08L81/06
摘要： The embodiments of the present disclosure present systems and methods for the reversible solubilization of (aryl ether ketones) (PAEKs). A thioacetalization process is employed to modify the PAEKs into poly (aryl ether thioacetals) which, unlike PAEKs, are substantially soluble in common solvents. This modification allowing selected analysis techniques to be more easily performed on PAEKs1 such as gel permeation chromatography. The thioacetalization may be reversed through a deprotection reaction to recover the original PAEK without substantial degradation, allowing for non-destructive characterization of the PAEK. Advantageously, the thioacetalization process is generally applicable to a broad range of PAEKs, unlike presently known methods of solubilizing PAEKs. Solubilization of PAEKs further expands the utility of the PAEKs, opening up additional routes to chemical modification of PAEKs, as well as allowing for the possibility of processing PAEKs from solution.
摘要翻译：本公开的实施方案提供了（芳基醚酮）（PAEK）的可逆增溶的系统和方法。使用硫缩醛化方法将PAEK改性为聚（芳基醚硫缩醛），其与PAEK不同，基本上可溶于常用溶剂。该修改允许在PAEK1上更容易地进行选择的分析技术，例如凝胶渗透色谱法。通过去保护反应可以使硫代缩醛反转，以恢复原始PAEK而不会明显降解，从而允许PAEK的非破坏性表征。有利地，与目前已知的增溶PAEK的方法不同，硫代缩醛化方法通常适用于广泛的PAEK。 PAEK的溶解进一步扩大了PAEK的用途，为PAEK的化学改性开辟了额外的途径，并且允许从溶液中处理PAEK的可能性。

5. 发明申请

US20090151860A1 FLEXIBLE POLYMER ELEMENT FOR A CURABLE COMPOSITION 审中-公开
标题翻译：用于可固化组合物的柔性聚合物元件
公开(公告)号：US20090151860A1
公开(公告)日：2009-06-18
申请号：US12335480
申请日：2009-02-27
申请人： Jeffrey Thomas Carter , Carmelo Lo Faro , Robin Kelvin Maskell , Patrick Terence McGrail
发明人： Jeffrey Thomas Carter , Carmelo Lo Faro , Robin Kelvin Maskell , Patrick Terence McGrail
IPC分类号： D04H13/00 , B32B7/08 , B29C70/52
CPC分类号： C08J3/24 , C08J5/24
摘要： A flexible polymer element for a curable composition wherein the flexible polymer element is in solid phase and adapted to undergo at least partial phase transition to fluid phase on contact with a component of the curable composition in which it is soluble at a temperature which is less than the temperature for substantial onset of gelling and/or curing of the curable composition; a method for the preparation thereof, a support structure or carrier for a curable composition comprising the at least one flexible polymer element together with reinforcing fibres, configurations of support structures and carriers, methods for preparation thereof, a curable composition comprising the at least one flexible polymer element or the support structure or carrier and a curable resin matrix, a kit of parts comprising the components thereof and a method for selection thereof, a method for preparation and curing thereof, and a cured composite or resin body obtained thereby, and known and novel uses thereof.
摘要翻译：一种用于可固化组合物的柔性聚合物元件，其中所述柔性聚合物元件为固相并且适于在与可固化组合物的组分接触时经受至少部分相转变为其可溶解的温度小于可固化组合物胶凝和/或固化的实质性开始的温度; 其制备方法，用于可固化组合物的载体结构或载体，其包含所述至少一种柔性聚合物元素与增强纤维，支撑结构和载体的构型，其制备方法，包含所述至少一种柔性聚合物聚合物元件或支撑结构或载体和可固化树脂基质，包含其组分的试剂盒及其选择方法，其制备和固化方法以及由此获得的固化的复合物或树脂体，以及已知和其用途。

6. 发明授权

US06372846B1 Polymer composition 失效
标题翻译：聚合物组成
公开(公告)号：US06372846B1
公开(公告)日：2002-04-16
申请号：US09508241
申请日：2000-11-02
申请人： Patrick Terence McGrail , Stephen Derek Jenkins , Christopher Ian Lindsay , Gordon Thomas Emmerson
发明人： Patrick Terence McGrail , Stephen Derek Jenkins , Christopher Ian Lindsay , Gordon Thomas Emmerson
IPC分类号： C08F800
CPC分类号： C08F279/02 , C08F265/06 , C08F291/02
摘要： A polymer composition, a process for its preparation and a molded article formed from the polymer composition are claimed. The polymer composition comprises (a) a base polymer that is a poly(alkyl(meth)acrylate; and (b) a rubber toughening agent selected from the group consisting of (i) copolymers of (alkyl)acrylate rubbers, (ii) copolymers of vinyl aromatic monomers with (alkyl)acrylates, (iii) copolymers of vinyl aromatic monomers with conjugated diolefins; (iv) copolymers of vinyl aromatic monomers with monoethylenically unsaturated monomers, in which the rubber toughening agent is present in the polymer composition as discrete islands substantially surrounded by the base polymer and in which islands are sub-islands of the base polymer.
摘要翻译：一种聚合物组合物，其制备方法和由该聚合物组合物形成的模塑制品。聚合物组合物包含（a）作为聚（（甲基）丙烯酸烷基酯的基础聚合物;和（b）橡胶增韧剂，其选自（i）（烷基）丙烯酸酯橡胶的共聚物，（ii）乙烯基芳族单体与（烷基）丙烯酸酯的共聚物，（iii）乙烯基芳族单体与共轭二烯烃的共聚物;（iv）乙烯基芳族单体与单烯属不饱和单体的共聚物，其中橡胶增韧剂作为离散岛存在于聚合物组合物中基本上被基础聚合物包围，其中岛是基础聚合物的子岛。

7. 发明授权

US06265491B1 Curable thermoset resin composition 有权
标题翻译：可固化热固性树脂组合物
公开(公告)号：US06265491B1
公开(公告)日：2001-07-24
申请号：US09202280
申请日：1999-06-14
申请人： Jeffrey T. Carter , Patrick Terence McGrail
发明人： Jeffrey T. Carter , Patrick Terence McGrail
IPC分类号： C08L6300
CPC分类号： C08L63/00 , C08G59/68 , C08L101/00 , C08L2666/22 , C08L81/00 , C08L2666/14
摘要： A curable composition including a thermoset resin a curing agent component, an amount of a thermoplast component having reactive pendant and/or end groups, an organometallic curing catalyst component. The organometallic curing catalyst component is capable of forming cross-links with reactive pendant and/or end groups of the thermoset and thermoplast resins and comprises an organometallic complex compound of the formula I=M(R)n, where M is selected from titanium, zirconium, hafnium, cerium, vanadium, niobium, R is selected from mono-, bi- and tri and/or tetra dentate organic ligands and n is four or six.
摘要翻译：包含热固性树脂固化剂组分的固化组合物，具有反应性侧基和/或端基的热塑性组分的量，有机金属固化催化剂组分。有机金属固化催化剂组分能够与热固性树脂和热塑性树脂的反应性侧基和/或端基形成交联，并且包含式I = M（R）n的有机金属络合物，其中M选自钛，锆，铪，铈，钒，铌，R选自单，双和三和/或四齿有机配体，n为四或六。

8. 发明授权

US08927662B2 Binder of reactive polyarylethersulphone and epoxy resin 有权
标题翻译：反应性聚芳砜砜和环氧树脂的粘结剂
公开(公告)号：US08927662B2
公开(公告)日：2015-01-06
申请号：US10432463
申请日：2001-11-06
申请人： Patrick Terence McGrail , Jeffrey Thomas Carter , Carmelo LoFaro
发明人： Patrick Terence McGrail , Jeffrey Thomas Carter , Carmelo LoFaro
IPC分类号： C08L63/00 , C08L63/02 , C08L63/04 , C08L81/06 , C08J5/24 , C08L33/04 , C08L61/02 , C08L61/10 , C08L61/24 , C08L61/28 , C08L67/06
CPC分类号： C08J5/24 , B29B15/105 , B29K2101/10 , B29K2101/12 , C08L81/06 , C08L2666/22
摘要： A resin binder composition for the production of a fiber preform comprising an amount of at least one polyarylether thermoplast resin component and an amount of at least one thermoset resin component in weight ratio 80/20-10/90, in substantial absence of a catalyst which is active at the prevailing preform production temperature, wherein the polyarylether thermoplast has number average molecular weight (Mn) in the range 2,000-20,000, and comprises ether linked phenyl units and ether linked arylsulphone units and reactive end groups, method for producing a fiber preform using the thermally stable binder resin composition, a perform obtained with use of the method and composition, a method for injecting or infusing the preform with curable matrix resin, the curable injected or infused preform resin, a method for curing thereof and a cured composite obtained with the method.
摘要翻译：一种用于生产纤维预型体的树脂粘合剂组合物，其基本上不存在催化剂，其包含至少一种聚芳醚热塑性树脂组分和至少一种重量比为80 / 20-10 / 90的热固性树脂组分的量在当前的预成型体生产温度下是活跃的，其中聚芳醚类热塑性塑料的数均分子量（Mn）在2,000-20,000的范围内，并且包括醚连接的苯基单元和醚连接的芳基砜单元和反应性端基，使用所述热稳定性粘合剂树脂组合物，使用所述方法和组合物获得的性能，用于将所述预成型体注入或注入可固化基质树脂的方法，所述可固化注射或注入的预成型树脂，其固化方法和固化复合物用该方法。

9. 发明授权

US07084213B2 Compositions adapted for chain linking 有权
标题翻译：适用于链接的组合物
公开(公告)号：US07084213B2
公开(公告)日：2006-08-01
申请号：US10362502
申请日：2001-08-20
申请人： Patrick Terence McGrail , Jeffrey Thomas Carter
发明人： Patrick Terence McGrail , Jeffrey Thomas Carter
IPC分类号： C08L65/02 , C08L25/18 , C08L63/02 , C08L81/00
CPC分类号： C08G75/23 , C08G81/00 , C08L81/06
摘要： A polymer composition comprising chains of at least one aromatic polymer or a mixture thereof together with at least one chain linking component wherein the at least one aromatic polymer comprises polymer chains of number average molecular weight (Mn) in a first range and characterised by a polymer flow temperature, and having at least one reactive end group, and wherein the at least one chain linking component comprises at least two linking sites, characterised in that a plurality of the polymer chain end groups are adapted to react with the linking sites at chain linking temperature in excess of the polymer flow temperature to form linked polymer chains of number average molecular weight (Mn) in a second range which is in excess of the first range, substantially thermoplastic in nature; process for the preparation thereof; prepreg, composite or shaped product obtained therewith and the use thereof.
摘要翻译：一种聚合物组合物，其包含至少一种芳族聚合物或其混合物的链与至少一种链接组分，其中所述至少一种芳族聚合物包含在第一范围内的数均分子量（Mn）的聚合物链，并且其特征在于聚合物流动温度，并且具有至少一个反应性端基，并且其中所述至少一个链连接组分包含至少两个连接位点，其特征在于多个所述聚合物链端基适于与链连接处的连接位点反应温度超过聚合物流动温度，以在超过第一范围的第二范围内形成数均分子量（Mn）的连接聚合物链，其性质基本上是热塑性的; 制备方法; 预浸料，复合或成型制品及其用途。

10. 发明授权

US4093458A Polyurethane-polyanhydride subbing layer for photo sensitive elements 失效
标题翻译：用于光敏元件的聚氨酯 - 聚酐底层
公开(公告)号：US4093458A
公开(公告)日：1978-06-06
申请号：US691461
申请日：1976-06-01
申请人： Patrick Terence McGrail , Stephen Richard Smith , Frederick Robert Bannister , David Leonard Boutle
发明人： Patrick Terence McGrail , Stephen Richard Smith , Frederick Robert Bannister , David Leonard Boutle
IPC分类号： G03C1/93 , G03C1/78
CPC分类号： G03C1/93 , Y10T428/31565 , Y10T428/31797 , Y10T428/31942
摘要： Polymeric subbing compositions for polyester photobase, especially polyethylene terephthalate films, comprising, a mixture of a polyurethane resin with a homopolymer or copolymer or a mixture of a homopolymer and a copolymer of an unsaturated cyclic carboxylic acid anhydride, preferably maleic anhydride or itaconic anhydride, in which the mixture contains up to 75% by weight of the anhydride polymer.
摘要翻译：用于聚酯照相的聚合物底胶组合物，特别是聚对苯二甲酸乙二醇酯薄膜，其包含聚氨酯树脂与均聚物或共聚物的混合物，或不饱和环状羧酸酐，优选马来酸酐或衣康酸酐的均聚物和共聚物的混合物，该混合物含有高达75重量％的酸酐聚合物。

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