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1. 发明授权

US5510516A Process for selective epoxidation of unsaturated (meth)acrylates, new functional (meth)acrylates obtained and their application to the synthesis of new polymers 失效
标题翻译：不饱和（甲基）丙烯酸酯的选择性环氧化方法，获得的新型功能性（甲基）丙烯酸酯及其在合成新聚合物中的应用
公开(公告)号：US5510516A
公开(公告)日：1996-04-23
申请号：US55884
申请日：1993-05-04
申请人： Paul Caubere , Yves Fort , Agnes Ortar
发明人： Paul Caubere , Yves Fort , Agnes Ortar
IPC分类号： B01J23/22 , B01J23/28 , B01J23/30 , B01J27/18 , B01J31/24 , C07B35/06 , C07B41/02 , C07B61/00 , C07C67/29 , C07C69/54 , C07C233/20 , C07C327/28 , C07D301/12 , C07D301/14 , C07D303/16 , C07D303/48 , C07D317/24 , C07D317/30 , C07F7/18 , C08F20/26 , C08F20/28 , C08F20/32 , C08F30/02 , C07C69/52
CPC分类号： C07F7/188 , C07C67/29 , C07C69/54 , C07D303/16 , C07D317/24 , C07F7/1852
摘要： An unsaturated (meth) acrylic compound of formula: ##STR1## (X=O, S, NH, NR.sup.3 (R.sup.3 =C.sub.1-12 -alkyl) or O--(CH.sub.2).sub.n (where n=1-16 approximately); R.sup.2 =C.sub.2-20 straight-chain or branched alkyl, monocyclic or polycyclic cycloalkyl or heterocycloalkyl, or alkylaryl hydrocarbon chain, comprising an olefinic double bond in the chain, or at the end of the chain in the case of alkyl or alkylaryl, or an exocyclic or endocyclic olefinic double bond in the case of monocyclic or polycyclic cycloalkyl or heterocycloalkyl; and R.sup.1 =H or C.sub.1-5 -alkyl), is reacted at 10.degree.-60.degree. C. with at least one oxidising compound (hydrogen peroxide) in the presence of at least one catalyst (alkali metal molybdates and tungstates) and in the presence of at least one phase transfer agent and when R.sup.2 =polycyclic cycloalkyl or hetercycloalkyl, an organic peracid or hydrogen peroxide in the presence of at least one heteropolyacid. To open the epoxide function, the epoxide obtained is reacted with a compound chosen from strong inorganic acids, boron trifluoride etherate complexes, acid salts in the presence of the corresponding acid, halides of trialkylsilanes or trialkoxysilanes, and ketones in the presence of cationic resins.
摘要翻译：（I）（X = O，S，NH，NR 3（R 3 = C 1-12 - 烷基）或O-（CH 2）n）（其中n = 1-16）的不饱和（甲基）丙烯酸化合物）; R2 = C2-20直链或支链烷基，单环或多环环烷基或杂环烷基或烷基芳基烃链，其在链中包含烯属双键，或在烷基或烷基芳基的情况下在链末端，或在单环或多环环烷基或杂环烷基的情况下为环状或内环烯属双键;且R 1 = H或C 1-5 - 烷基）在10°-60℃与至少一种氧化化合物（过氧化氢）在至少一种催化剂（碱金属钼酸盐和钨酸盐）存在下，并且在至少一种相转移剂存在下，并且当R 2 =多环环烷基或杂环烷基时，有机过酸或过氧化氢在至少一种杂多酸。为了打开环氧化物官能团，所得环氧化物与选自强无机酸，三氟化硼醚合物络合物，酸盐在相应的酸，三烷基硅烷或三烷氧基硅烷的卤化物，以及阳离子树脂存在下的酮的化合物反应。

2. 发明授权

US5481012A Process for selective epoxidation of unsaturated (meth)acrylic compounds and new bifunctional (meth)acrylates obtained 失效
标题翻译：选择性环氧化不饱和（甲基）丙烯酸类化合物和新型双官能（甲基）丙烯酸酯的方法
公开(公告)号：US5481012A
公开(公告)日：1996-01-02
申请号：US335960
申请日：1994-11-03
申请人： Paul Caubere , Yves Fort , Agnes Ortar
发明人： Paul Caubere , Yves Fort , Agnes Ortar
IPC分类号： B01J23/28 , B01J23/30 , C07B61/00 , C07D301/12 , C07D303/16 , C07D303/40
CPC分类号： C07D303/40 , C07D303/16
摘要： Process for the epoxidation of an unsaturated (meth)acrylic compound of formula: ##STR1## in which R.sub.1 is chosen from H and C.sub.1 -C.sub.5 -alkyl; R.sub.2 is chosen from H, alkyl and aryl; R.sub.3 is a straight-chain, branched or cyclic alkylene or oxyalkylene radical having from 1 to 12 carbon atoms, it being possible for one of the carbon atoms of R.sub.2, when the latter is an alkyl radical, to be linked to one of the carbon atoms of R.sub.3 to form a ring; and A is chosen from O, S, NH and NR.sub.4, R.sub.4 being a C.sub.1 -C.sub.12 -alkyl group; by the action of hydrogen peroxide on the said unsaturated (meth)acrylic compound, at a temperature of between 10.degree. C. and 50.degree. C., in the presence of at least one catalyst chosen from the alkali metal molybdates and the alkali metal pertungstates and in the presence of at least one phase transfer agent.
摘要翻译：式（I）的不饱和（甲基）丙烯酸化合物的环氧化方法，其中R 1选自H和C 1 -C 5 - 烷基; R2选自H，烷基和芳基; R 3是具有1至12个碳原子的直链，支链或环状的亚烷基或氧亚烷基，当其中一个碳原子为烷基时，R2可以与一个碳原子连接 R3的原子形成环; A选自O，S，NH和NR4，R4是C1-C12-烷基; 通过过氧化氢对所述不饱和（甲基）丙烯酸化合物的作用，在10℃至50℃的温度下，在至少一种选自碱金属钼酸盐和碱金属过钨酸盐的催化剂存在下，并在至少一种相转移剂存在下进行。

3. 发明授权

US5283360A Selective epoxidation of unsaturated (meth)acrylates, new functional (meth)acrylates, and polymers thereof 失效
标题翻译：不饱和（甲基）丙烯酸酯，新功能（甲基）丙烯酸酯及其聚合物的选择性环氧化
公开(公告)号：US5283360A
公开(公告)日：1994-02-01
申请号：US725318
申请日：1991-07-08
申请人： Paul Caubere , Yves Fort , Agnes Ortar
发明人： Paul Caubere , Yves Fort , Agnes Ortar
IPC分类号： B01J23/22 , B01J23/28 , B01J23/30 , B01J27/18 , B01J31/24 , C07B35/06 , C07B41/02 , C07B61/00 , C07C67/29 , C07C69/54 , C07C233/20 , C07C327/28 , C07D301/12 , C07D301/14 , C07D303/16 , C07D303/48 , C07D317/24 , C07D317/30 , C07F7/18 , C08F20/26 , C08F20/28 , C08F20/32 , C08F30/02 , C07C69/52
CPC分类号： C07F7/188 , C07C67/29 , C07C69/54 , C07D303/16 , C07D317/24 , C07F7/1852
摘要： An unsaturated (meth)acrylic compound of formula: ##STR1## (X.dbd.O, S, NH, NR.sup.3 (R.sup.3 =C.sub.1-12 -alkyl) or O--(CH.sub.2).sub.n (where n=1-16 approximately); R.sup.2 =C.sub.2-20 straight-chain or branched alkyl, monocyclic or polycyclic cycloalkyl or heterocycloalkyl, or alkylaryl hydrocarbon chain, comprising an olefinic double bond in the chain, or at the end of the chain in the case of alkyl or alkylaryl, or an exocyclic or endocyclic olefinic double bond in the case of monocyclic or polycyclic cycloalkyl or heterocycloalkyl; and R.sup.1 =H or C.sub.1-5 -alkyl), is reacted at 10.degree.-60.degree. C. with at least one oxidizing compound (hydrogen peroxide) in the presence of at least one catalyst (alkali metal molybdates and tungstates) and in the presence of at least one phase transfer agent and when R.sup.2 =polycyclic cycloalkyl or hetercycloalkyl, an organic peracid or hydrogen peroxide in the presence of at least one heteropolyacid. To open the epoxide function, the epoxide obtained is reacted with a compound chosen from strong inorganic acids, boron trifluoride etherate complexes, acid salts in the presence of the corresponding acid, halides of trialkylsilanes or trialkoxysilanes, and ketones in the presence of cationic resins.
摘要翻译：（I）（X = O，S，NH，NR 3（R 3 = C 1-12 - 烷基）或O-（CH 2）n）（其中n = 1-16）的不饱和（甲基）丙烯酸化合物）; R2 = C2-20直链或支链烷基，单环或多环环烷基或杂环烷基或烷基芳基烃链，其在链中包含烯属双键，或在烷基或烷基芳基的情况下在链末端，在单环或多环环烷基或杂环烷基的情况下为环状或内环烯属双键;且R 1 = H或C 1-5 - 烷基）在10°-60℃下与至少一种氧化化合物（过氧化氢）在至少一种催化剂（碱金属钼酸盐和钨酸盐）存在下，并且在至少一种相转移剂存在下，并且当R 2 =多环环烷基或杂环烷基时，有机过酸或过氧化氢在至少一种杂多酸。为了打开环氧化物官能团，所得环氧化物与选自强无机酸，三氟化硼醚合物络合物，酸盐在相应的酸，三烷基硅烷或三烷氧基硅烷的卤化物，以及阳离子树脂存在下的酮的化合物反应。

4. 发明授权

US5332836A Acrylates, containing an alcohol, aldehyde and/or ether functional group, process for their manufacture and their application to the production of new polymers and copolymers 失效
标题翻译：含有醇，醛和/或醚官能团的丙烯酸酯，其制备方法及其在生产新聚合物和共聚物中的应用
公开(公告)号：US5332836A
公开(公告)日：1994-07-26
申请号：US22226
申请日：1993-02-25
申请人： Marie-Christine Berthe , Paul Caubere , Yves Fort
发明人： Marie-Christine Berthe , Paul Caubere , Yves Fort
IPC分类号： C07C67/343 , C07D307/87 , C07D309/22 , C07D333/24 , C08F20/28 , C07D313/00 , C07D307/02 , C07D307/78
CPC分类号： C07D307/87 , C07C67/343 , C07D309/22 , C07D333/24 , C08F20/28
摘要： Acrylates of the formula ##STR1## in which: R is a radical chosen from alkyl radicals containing from 1 to 12 carbon atoms, cycloalkyl radicals containing from 5 to 12 carbon atoms, and aryl, arylalkyl and alkylaryl radicals,Z is a hydrocarbon radical containing at least two carbon atoms forming with the oxygen and the two adjacent carbons a ring containing from 4 to 8 members.
摘要翻译：式（III）的丙烯酸酯，其中：R为选自含有1至12个碳原子的烷基，含有5至12个碳原子的环烷基，芳基，芳基烷基和烷基芳基，Z为含有至少两个碳原子的烃基与氧和两个相邻的碳形成含有4至8个成员的环。

5. 发明授权

US5556974A Process for the preparation of triazines 失效
标题翻译：制备三嗪的方法
公开(公告)号：US5556974A
公开(公告)日：1996-09-17
申请号：US546150
申请日：1995-10-20
申请人： Marie-Christine Berthe , Paul Caubere , Yves Fort
发明人： Marie-Christine Berthe , Paul Caubere , Yves Fort
IPC分类号： C07C331/10 , C07D251/38 , C08F20/38
CPC分类号： C07C331/10 , C08F20/38
摘要： Monomers of the formulae: ##STR1## and ##STR2## as well as polymers and copolymers thereof wherein n=2-20; R=H, CH.sub.3 or CHOHR' where R'=straight-chain or branched alkyl, optionally substituted by hydroxyl, alkoxy or ester substituents, straight-chain, branched or cyclic alkenyl, aryl, optionally substituted by halogenated, nitro or alkoxy substituents, unsaturated heterocycle, alkylaryl and arylalkyl, R=CH.sub.3 in formula (I) in the case of monomers and homopolymers wherein n=2 and in the case of monomers wherein n=4.
摘要翻译：下式的单体：其中n = 2-20;其中n = 2-20的聚合物和共聚物; R = H，CH 3或CHOHR'，其中R'=直链或支链烷基，任选被羟基，烷氧基或酯取代基取代，直链，支链或环状烯基，任选被卤代，硝基或烷氧基取代基取代的芳基，在其中n = 2的单体和均聚物的情况下以及在n = 4的单体的情况下，式（I）中的R = CH 3，不饱和杂环，烷基芳基和芳基烷基。

6. 发明授权

US5696279A Method of preparing thiocyanoalkyl esters of hydroxy-substituted (meth)acrylic acids 失效
标题翻译：制备羟基取代的（甲基）丙烯酸的氰基氰基烷基酯的方法
公开(公告)号：US5696279A
公开(公告)日：1997-12-09
申请号：US546019
申请日：1995-10-20
申请人： Marie-Christine Berthe , Paul Caubere , Yves Fort
发明人： Marie-Christine Berthe , Paul Caubere , Yves Fort
IPC分类号： C07C331/10 , C07D251/38 , C08F20/38 , C07C31/04
CPC分类号： C07C331/10 , C08F20/38
摘要： Thiocyanoalkyl esters of hydroxy-substituted (meth)acrylic acids are prepared by a process which includes the step of reacting an acrylic compound with an aldehyde of the formula CHOHR' wherein R' is a straight-chain or branched alkyl optionally substituted by hydroxyl, alkoxy or ester substitutents; straight-chain, branched or cyclic alkenyl; aryl radicals, optionally substituted by halogen, nitro or alkoxy, unsaturated heterocyclic radicals; alkylaryl; or arylalkyl radicals.
摘要翻译：羟基取代的（甲基）丙烯酸的硫氰酸烷基酯通过包括使丙烯酸化合物与式CHOHR'的醛反应的方法制备的方法，其中R'是任选被羟基取代的直链或支链烷基，烷氧基或酯取代基; 直链，支链或环状烯基; 任选被卤素，硝基或烷氧基取代的芳基，不饱和杂环基; 烷基芳基或芳基烷基。

7. 发明授权

US5332850A (Meth)acrylic compounds carrying a thiocyanate group 失效
标题翻译：（甲基）丙烯酸酯化合物
公开(公告)号：US5332850A
公开(公告)日：1994-07-26
申请号：US725810
申请日：1991-07-09
申请人： Marie-Christine Berthe , Paul Caubere , Yves Fort
发明人： Marie-Christine Berthe , Paul Caubere , Yves Fort
IPC分类号： C07C331/10 , C07D251/38 , C08F20/38 , C07C331/04
CPC分类号： C07C331/10 , C08F20/38
摘要： Monomers of the formulae: ##STR1## as well as polymers and copolymers thereof wherein n=2-20; R=H, CH.sub.3 or CHOHR' where R'=straight-chain or branched alkyl, optionally substituted by hydroxyl, alkoxy or ester substituents, straight-chain, branched or cyclic alkenyl, aryl, optionally substituted by halogenated, nitro or alkoxy substituents, unsaturated heterocycle, alkylaryl and arylalkyl, R=CH.sub.3 in formula (I) in the case of monomers and homopolymers wherein n=2 and in the case of monomers wherein n=4.
摘要翻译：下式的单体：其中n = 2-20;其中n = 2-20的聚合物和共聚物; R = H，CH 3或CHOHR'，其中R'=直链或支链烷基，任选被羟基，烷氧基或酯取代基取代，直链，支链或环状烯基，任选被卤代，硝基或烷氧基取代基取代的芳基，在其中n = 2的单体和均聚物的情况下以及在n = 4的单体的情况下，式（I）中的R = CH 3，不饱和杂环，烷基芳基和芳基烷基。

8. 发明授权

US5206389A Acrylates containing an alcohol, aldehyde and/or ether functional group, process for their manufacture and their application to the production of new polymers and copolymers 失效
标题翻译：含有醇，醛和/或醚官能团的丙烯酸酯，其制造方法及其生产新聚合物和共聚物的应用
公开(公告)号：US5206389A
公开(公告)日：1993-04-27
申请号：US721751
申请日：1991-06-27
申请人： Marie-Christine Berthe , Paul Caubere , Yves Fort
发明人： Marie-Christine Berthe , Paul Caubere , Yves Fort
IPC分类号： C07C67/343 , C07D307/87 , C07D309/22 , C07D333/24 , C08F20/28
CPC分类号： C07D307/87 , C07C67/343 , C07D309/22 , C07D333/24 , C08F20/28
摘要： These acrylates are those of formulae: ##STR1## where R=C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.12 cycloalkyl, aryl, arylalkyl or alkylaryl; Y=C.sub.1 -C.sub.12 alkyl, C.sub.6 -C.sub.12 aryl, heterocyclic radical whose ring contains from 5 to 10 members and whose heteroatom is chosen from N, O and S, an alkylaryl in which the alkyl part contains from 1 to 4 carbon atoms, Y not being able to denote 1,4-phenylene when R denotes methyl; and Z=hydrocarbon radical containing at least 2 C forming with O and the 2 adjacent Cs a ring containing from 4 to 8 members.To prepare them, an acrylate of formula CH.sub.2 .dbd.CH--COOR is reacted with a dialdehyde OHC--Y--CHO in the presence of an effective quantity of at least one functionalisation catalyst.The invention also relates to the preparation of new polymers and copolymers from the said acrylates.
摘要翻译：（I）其中R = C 1 -C 12烷基，C 5 -C 12环烷基，芳基，芳基烷基或烷基芳基;（C） Y = C1-C12烷基，C6-C12芳基，其环含有5至10个成员且杂原子选自N，O和S的杂环基，其中烷基部分含有1至4个碳原子的烷基芳基，Y 当R表示甲基时，不能表示1,4-亚苯基; Z =含有至少2个C的烃基，O与O形成，2个相邻的C a为含有4至8个成员的环。为了制备它们，在有效量的至少一种官能化催化剂的存在下，式CH 2 = CH-COOR的丙烯酸酯与二醛OHC-Y-CHO反应。本发明还涉及从所述丙烯酸酯制备新的聚合物和共聚物。

9. 发明授权

US5565597A Process for preparing thiocyanoalkyl esters of (meth)acrylic acid 失效
标题翻译：制备（甲基）丙烯酸硫氰酸烷基酯的方法
公开(公告)号：US5565597A
公开(公告)日：1996-10-15
申请号：US411151
申请日：1995-03-27
申请人： Marie-Christine Berthe , Paul Caubere , Yves Fort
发明人： Marie-Christine Berthe , Paul Caubere , Yves Fort
IPC分类号： C07C331/10 , C07D251/38 , C08F20/38 , C07C331/04
CPC分类号： C07C331/10 , C08F20/38
摘要： A process for the preparation of an acrylic or methacrylic compound of formula (I): ##STR1## wherein R is a hydrogen atom or methyl and n is an integer ranging from 2 to 20 inclusive, comprising reacting a halogeno-n-alkyl acrylate or methacrylate of the formula: ##STR2## in which n is as defined above and X is a halogen atom, with a thiocyanate salt in an organic solvent and in the presence of an effective phase-transferring amount of at least one phase-transfer agent.
摘要翻译：一种制备式（I）的丙烯酸或甲基丙烯酸酯化合物的方法：其中R是氢原子或甲基，n是2至20的整数，包括端值范围，包括使卤素 - 烷基丙烯酸酯或甲基丙烯酸酯，其中n定义如上，X为卤素原子，硫代氰酸盐在有机溶剂中，有效相转移量至少为一种相转移剂。

10. 发明授权

US5190671A Process for the synthesis of monohaloalkanoylferrocenes 失效
标题翻译：用于合成单羟基胆碱的方法
公开(公告)号：US5190671A
公开(公告)日：1993-03-02
申请号：US769776
申请日：1991-10-02
申请人： Paul Caubere , Yves Fort , Jean-Claude Gautier , Jean-Claude Mondet
发明人： Paul Caubere , Yves Fort , Jean-Claude Gautier , Jean-Claude Mondet
IPC分类号： B01J27/125 , C07B61/00 , C07F17/02
CPC分类号： C07F17/02
摘要： The present invention relates to a process for the synthesis of monohaloalkanoylferrocenes of general formula (I) ##STR1## in which X=Cl, Br, n is an integer such that 2.ltoreq.n.ltoreq.7, R.sub.1 and R.sub.2 =H, C.sub.1 -C.sub.8 alkyl chain. A ferrocene derivative of general formula (II) ##STR2## in which R.sub.1 and R.sub.2 have the abovementioned meaning, is reacted at a temperature -5.degree. C.
摘要翻译：本发明涉及一种合成通式（I）的单卤代烷酰基二茂铁的方法，其中X = Cl，Br，n是使得2≤n≤7，R1和R2 = H的整数，C1-C8烷基链。其中R1和R2具有上述含义的通式（II）的二茂铁衍生物在温度-5℃<+ 15℃下，在AlCl 3存在下与卤化物反应或通式（III）的酸的酸酐，HOOC-（CH 2）n X，X和n具有上述含义。将AlCl 2和酰卤或酸酐在CH 2 Cl 2中混合得到的酰化溶液，其温度θ为5℃。在15℃下逐渐加入到二茂铁衍生物（II）在CH 2 Cl 2中。酰卤或酸酐与二茂铁衍生物的摩尔比在0.99和1.01之间，AlCl3与二茂铁衍生物的摩尔比在1.05和1.11之间。然后将混合物水解，通过过滤回收粗产物（I），然后蒸发CH 2 Cl 2。该方法能够以产率和纯度高的方式获得粗合成产物。单卤烷酰基二茂铁（I）是药学和自推进中的合成中间体。

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