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1. 发明授权

US06511714B2 Process for combating the appearance of mist during the coating of flexible supports with a crosslinkable liquid silicone composition in a roll device 失效
标题翻译：用于在辊装置中用可交联液体硅酮组合物涂覆柔性载体时防止雾的外观的方法
公开(公告)号：US06511714B2
公开(公告)日：2003-01-28
申请号：US09888617
申请日：2001-06-26
申请人： Paul Branlard , Frédéric Garnes , Yves Giraud , Christophe Guyot , Frédéric Magd
发明人： Paul Branlard , Frédéric Garnes , Yves Giraud , Christophe Guyot , Frédéric Magd
IPC分类号： B05D302
CPC分类号： C09D183/04 , C08L2666/14 , C08L2666/54 , C08L2666/04
摘要： The invention relates to a process for combating the appearance of mist (misting) during the coating of flexible supports with at least one liquid silicone (RTV polyaddition) composition which is a precursor of silicone coating(s) using a roll coating device operating at high speed. The targeted aim is to increase the speed of appearance of the misting and subsequently to improve the appearance, the coverage and the mechanical properties of the silicone coating and industrial hygiene. For this, use is made of a liquid coating composition obtained by mixing: a silicone phase comprising one or more POSs (A) and optionally one or more (crosslinking) compound(s) (B), the viscosity &eegr; of which at 25° C. is between 100 and 800 mPa·s; with 1 to 10% by weight of noncellulose antimist particles (talc, silica, kaolin, TiO2), the D50 (in &mgr;m) of which is: 0.01≦D50≦2; and optionally with a liquid (D)—water/solvent.
摘要翻译：本发明涉及一种使用至少一种液体硅氧烷（RTV加聚）组合物涂覆柔性载体的雾（雾）的外观的方法，该液体硅氧烷（RTV加聚）组合物是使用在高温下操作的辊涂装置的硅氧烷涂层的前体速度。目标是提高雾化的出现速度，从而改善硅胶涂层的外观，覆盖和机械性能以及工业卫生。为此，使用通过混合获得的液体涂料组合物：包含一种或多种POS（A）和任选的一种或多种（交联）化合物（B）的硅氧烷相，其粘度et在25° C为100至800mPa.s;具有1至10重量％的非纤维素抗微粒（滑石粉，二氧化硅，高岭土，TiO 2），D50（母体）为：0.01 <= D50 <= 2; 和任选用液体（D） - 水/溶剂。

2. 发明授权

US07972705B2 Use of a crosslinkable silicone-based inverse emulsion for producing “breathable waterproof” coatings 失效
标题翻译：使用可交联的硅酮反相乳液制造“透气防水”涂料
公开(公告)号：US07972705B2
公开(公告)日：2011-07-05
申请号：US12068245
申请日：2008-02-04
申请人： Paul Branlard , Martial Deruelle , Yves Giraud , Nadia Martin
发明人： Paul Branlard , Martial Deruelle , Yves Giraud , Nadia Martin
IPC分类号： B32B25/20
CPC分类号： C09D183/04 , D06M15/643 , D06M15/65 , D06N3/128 , Y10T428/31663
摘要： Silicone coating on various soft supports, for instance textiles, made of synthetic polymers (polyamide, polyester) provides an efficient method for producing water impermeable and water permeable coatings, on soft supports, said method enabling to improve permeability to water vapor of the silicones while preserving impermeability to water. The inventive method enabling this consists mainly in: coating one of the surfaces of the support with a film formed by an invert water-in-oil silicone emulsion comprising a continuous oily silicone phase phi s, crosslinkable into elastomer and including a polyorganosiloxane (POS) A crosslinkable by addition polymerization, by cationic process or free-radical process; optionally a crosslinking organosilicon compound B; and optionally at least a catalyst C; an aqueous phase phi a; a stabilizing agent; and in ensuring crosslinking of the silicone phase phi s and elimination of water. The invention also concerns water impermeable and water vapor permeable soft polyamide or polyester substrates obtained by using an invert water-in-oil silicone emulsion.
摘要翻译：在合成聚合物（聚酰胺，聚酯）制成的各种柔软载体（例如纺织品）上的硅氧烷涂层提供了一种在软质载体上生产不透水和水可渗透涂层的有效方法，所述方法能够改善硅氧烷的水蒸汽渗透性，保持对水的不渗透性。能够实现的本发明的方法主要在于：用由包含连续油性硅氧烷相的交联的弹性体包含聚有机硅氧烷（POS）的反相油包水硅氧烷乳液形成的膜涂覆载体的一个表面，通过加成聚合，通过阳离子法或自由基法进行交联; 任选的交联有机硅化合物B; 和任选地至少一种催化剂C; 水相phi; 稳定剂; 并确保硅酮相的交联和消除水分。本发明还涉及通过使用反相的水包油硅氧烷乳液获得的不透水和水蒸汽可渗透的软质聚酰胺或聚酯基材。

3. 发明申请

US20080293876A1 Use of a crosslinkable silicone-based inverse emulsion for producing "breathable waterproof" coatings 失效
标题翻译：使用可交联的硅酮反相乳液制造“透气防水”涂料
公开(公告)号：US20080293876A1
公开(公告)日：2008-11-27
申请号：US12068245
申请日：2008-02-04
申请人： Paul Branlard , Martial Deruelle , Yves Giraud , Nadia Martin
发明人： Paul Branlard , Martial Deruelle , Yves Giraud , Nadia Martin
IPC分类号： C08L83/04
CPC分类号： C09D183/04 , D06M15/643 , D06M15/65 , D06N3/128 , Y10T428/31663
摘要： Silicone coating on various soft supports, for instance textiles, made of synthetic polymers (polyamide, polyester) provides an efficient method for producing water impermeable and water permeable coatings, on soft supports, said method enabling to improve permeability to water vapor of the silicones while preserving impermeability to water. The inventive method enabling this consists mainly in: coating one of the surfaces of the support with a film formed by an invert water-in-oil silicone emulsion comprising a continuous oily silicone phase phi s, crosslinkable into elastomer and including a polyorganosiloxane (POS) A crosslinkable by addition polymerization, by cationic process or free-radical process; optionally a crosslinking organosilicon compound B; and optionally at least a catalyst C; an aqueous phase phi a; a stabilizing agent; and in ensuring crosslinking of the silicone phase phi s and elimination of water. The invention also concerns water impermeable and water vapor permeable soft polyamide or polyester substrates obtained by using an invert water-in-oil silicone emulsion.
摘要翻译：在合成聚合物（聚酰胺，聚酯）制成的各种柔软载体（例如纺织品）上的硅氧烷涂层提供了一种在软质载体上生产不透水和水可渗透涂层的有效方法，所述方法能够改善硅氧烷的水蒸汽渗透性，保持对水的不渗透性。能够实现的本发明的方法主要在于：用由包含连续油性硅氧烷相的交联的弹性体包含聚有机硅氧烷（POS）的反相油包水硅氧烷乳液形成的膜涂覆载体的一个表面，通过加成聚合，通过阳离子法或自由基法进行交联; 任选的交联有机硅化合物B; 和任选地至少一种催化剂C; 水相phi; 稳定剂; 并确保硅酮相的交联和消除水分。本发明还涉及通过使用反相的水包油硅氧烷乳液获得的不透水和水蒸汽可渗透的软质聚酰胺或聚酯基材。

4. 发明申请

US20050123689A1 Use of a crosslinkable silicone invert emulsion for producing breathable coatings 审中-公开
标题翻译：使用可交联的硅氧烷反相乳液生产透气涂料
公开(公告)号：US20050123689A1
公开(公告)日：2005-06-09
申请号：US10503726
申请日：2003-02-07
申请人： Paul Branlard , Martial Deruelle , Yves Giraud , Nadia Martin
发明人： Paul Branlard , Martial Deruelle , Yves Giraud , Nadia Martin
IPC分类号： D06M11/79 , D06M13/513 , D06M15/643 , D06M15/65 , D06N3/12 , C08J7/04
CPC分类号： C09D183/04 , D06M15/643 , D06M15/65 , D06N3/128 , Y10T428/31663
摘要： The invention relates to the general field of silicone coating on various pliable supports, for example textiles, made of synthetic polymers (polyamide, polyester, etc.). An aim of the invention is to propose an effective process for producing coatings that are waterproof and permeable to moisture vapour, on pliable supports, this process allowing an improvement in the moisture vapour-permeability of the silicones while at the same time conserving the waterproofness. The process according to the invention which achieves this aim consists essentially in coating one of the faces of the support with a film formed by a water-in-oil inverse silicone emulsion comprising a continuous oily silicone phase φs, which can be crosslinked into an elastomer and which comprises a polyorganosiloxane (POS) A that is crosslinkable by polyaddition, by polycondensation, by cationic means or by free-radical means; optionally a crosslinking organosilicic compound B; optionally at least one catalyst C, an aqueous phase φa, a stabilizer, and in seeing to it that the silicone phase φs crosslinks and that removal of water occurs. The invention also relates to pliable supports made of polyamide or polyester, that are waterproof and permeable to moisture vapour, obtained by using a water-in-oil inverse silicone emulsion.
摘要翻译：本发明涉及在合成聚合物（聚酰胺，聚酯等）制成的各种柔韧载体上的硅酮涂层的一般领域，例如纺织品。本发明的目的是提出一种在柔韧的支撑物上生产防水和透湿的涂层的有效方法，该方法允许提高硅氧烷的透湿度，同时保持防水性。实现该目的的根据本发明的方法主要在于用由油包水反相硅氧烷乳液形成的膜涂覆载体的一个表面，所述油包水反相硅氧烷乳液包含连续的油性硅氧烷相phis，其可交联成弹性体并且其包含通过加聚可交联的聚有机硅氧烷（POS）A，通过缩聚，通过阳离子手段或通过自由基手段进行交联; 任选交联的有机硅化合物B; 任选地至少一种催化剂C，水相phia，稳定剂，并且认为有机硅相交联并发生水的除去。本发明还涉及通过使用油包水反相硅氧烷乳液获得的由聚酰胺或聚酯制成的柔性支撑体，其是防水的并且是透湿的。

5. 发明授权

US06437163B1 Method for preparing silicones with arylalkyl function(s) by hydrosilylation 失效
标题翻译：通过氢化硅烷化制备具有芳烷基官能团的硅氧烷的方法
公开(公告)号：US06437163B1
公开(公告)日：2002-08-20
申请号：US09647995
申请日：2001-02-23
申请人： Paul Branlard , Gérard Mignani , Philippe Olier , Claudie Willemin
发明人： Paul Branlard , Gérard Mignani , Philippe Olier , Claudie Willemin
IPC分类号： C07F708
CPC分类号： A61Q13/00 , A61K8/895 , A61Q15/00
摘要： The invention concerns a method for preparing high purity polyorganosiloxanes with arylalkyl function(s) by: hydrosilylation of a hydrogenopolyorganosiloxane, reagent (SiH), and an aromatic monovinyl compound, reagent (Vi), with simultaneous introduction of reagent (SiH) and reagent (Vi), in a reaction medium containing an inert solvent and a hydrosilylation catalyst; then elimination of the solvent, the possible residual reagents (SiH) and (Vi), and/or hydrogenation, the hydrogenation process being optionally followed by an elimination process (or another elimination process) of the products other than polyorganosiloxanes with arylalkyl function(s). The resulting silicones with arylalkyl function(s) can be used as emollients and/or carriers in cosmetic compositions, or as solubilizing agents and emollients in perfume compositions.
摘要翻译：本发明涉及通过以下方法制备具有芳基烷基官能团的高纯度聚有机硅氧烷的方法：通过氢化有机硅氧烷，试剂（SiH）和芳族单乙烯基化合物，试剂（Vi）的氢化硅烷化，同时引入试剂（SiH）和试剂（ Vi），在含有惰性溶剂和氢化硅烷化催化剂的反应介质中; 然后消除溶剂，可能的残余试剂（SiH）和（Vi）和/或氢化，氢化过程任选地随后除了具有芳烷基官能团的聚有机硅氧烷以外的产物的消除方法（或另一消除方法））。所得到的具有芳基烷基官能团的硅氧烷可用作化妆品组合物中的润肤剂和/或载体，或作为香料组合物中的增溶剂和润肤剂使用。

6. 发明授权

US06395704B1 Perfume composition using organopolysiloxanes 失效
标题翻译：使用有机聚硅氧烷的香料组合物
公开(公告)号：US06395704B1
公开(公告)日：2002-05-28
申请号：US09463678
申请日：2000-04-21
申请人： Paul Branlard , Gérard Mignani , Claudie Willemin , Philippe Olier
发明人： Paul Branlard , Gérard Mignani , Claudie Willemin , Philippe Olier
IPC分类号： A61K700
CPC分类号： A61Q13/00 , A61K8/585 , A61K8/895 , A61Q15/00
摘要： The invention concerns a perfume composition comprising a perfume base and a lipophilic solubilizing agent based on at least an organopolysiloxane having according to Hansen solubility parameter the following characteristics: &dgr;D London interactions ranging from (8) to (21) (J/cm3)½, &dgr;P of Keesom interactions greater than 0 and capable of reaching 25 (J/cm3)½, &dgr;H of hydrogen binding ranging from (0) to (23) (J/cm3)½. Said organotrisiloxanes with polar or polarizsable function of formula (I) are used as solubilizing agents and emollients in perfume composition.
摘要翻译：本发明涉及一种香水组合物，其包含基于至少有机聚硅氧烷的香料基质和亲脂性增溶剂，其具有根据Hansen溶解度参数的以下特征：δD伦敦相互作用范围从（8）至（21）（J / cm 3）1/2， Keesom相互作用的δP大于0并且能够达到从（0）到（23）（J / cm 3）1/2的氢结合的25（J / cm 3）1/2，δH。具有式（I）的极性或极性化功能的所述有机基硅氧烷用作香料组合物中的增溶剂和润肤剂。

7. 发明授权

US5053468A Polymerization of chloroprene with two chain transfer agents 失效
标题翻译：氯二烯与双链转移剂的聚合
公开(公告)号：US5053468A
公开(公告)日：1991-10-01
申请号：US617256
申请日：1990-11-21
申请人： Paul Branlard , Francois Sauterey
发明人： Paul Branlard , Francois Sauterey
IPC分类号： C08F2/00 , C08F2/22 , C08F2/24 , C08F2/26 , C08F2/38 , C08F36/00 , C08F36/16 , C08F36/18 , C09J121/00 , C09J121/02
CPC分类号： C08F36/18 , C08F2/40
摘要： A polychloroprene of sol type, the latices and solutions of which are gel free, exhibit improved rheological and other properties and are useful in the formulation of adhesive compositions, is readily prepared by polymerizing chloroprene in aqueous emulsion in the presence of X and Y chain transfer agents, said X chain transfer agent being present upon initiation of the polymerization and having a relative reaction velocity greater than that of chloroprene, and said Y chain transfer agent being incrementally or continuously added to the polymerization reaction medium over the course of the polymerization reaction and having a relative reaction velocity essentially the same as that of chloroprene.
摘要翻译：溶胶型聚氯丁二烯，其胶乳和溶液不含凝胶，表现出改善的流变性和其他性能，并且可用于粘合剂组合物的配制，可以容易地通过在X和Y链转移存在下在水乳液中聚合氯丁二烯所述X链转移剂在聚合开始时存在，并且具有大于氯丁二烯的相对反应速度，并且所述Y链转移剂在聚合反应过程中逐渐或连续地加入到聚合反应介质中，其相对反应速度基本上与氯丁二烯相同。

8. 发明授权

US08361342B2 Two-layer compacted solid product for water potabilization and preparation method 有权
标题翻译：两层压实固体产品，用于水稳定和制备方法
公开(公告)号：US08361342B2
公开(公告)日：2013-01-29
申请号：US12444541
申请日：2007-10-04
申请人： Paul Branlard , Gilles Rubinstenn
发明人： Paul Branlard , Gilles Rubinstenn
IPC分类号： C02F5/08 , C02F5/10 , C02F1/52 , C02F1/56 , C02F1/76
CPC分类号： C02F1/5245 , C02F1/56 , C02F1/76 , C02F2303/04 , C02F2305/12 , C02F2305/14
摘要： The present invention relates to a compacted solid product for water purification comprising:—at least a first layer comprising at least a coagulant/flocculant system comprising at least one polyvalent inorganic salt, at least one water-soluble cationic polymer and at least one high-molecular-weight anionic polymer,—at least a second layer comprising at least one disinfectant that releases active chlorine on contact with water, characterized in that said coagulant/flocculant system moreover comprises a sodium alginate. The invention also relates to the method for preparing such a product.
摘要翻译：本发明涉及一种用于水净化的压实固体产品，其包括：至少包含至少一种包含至少一种多价无机盐，至少一种水溶性阳离子聚合物和至少一种高分子化合物的凝结剂/絮凝剂体系的第一层，分子量阴离子聚合物， - 至少包含至少一种在与水接触时释放活性氯的消毒剂的第二层，其特征在于，所述絮凝剂/絮凝剂体系还包含藻酸钠。本发明还涉及制备这种产品的方法。

9. 发明申请

US20080039317A1 Double-Layered Compacted Solid Water-Purification Product 有权
标题翻译：双层压实固体水净化产品
公开(公告)号：US20080039317A1
公开(公告)日：2008-02-14
申请号：US11628742
申请日：2005-07-18
申请人： Paul Branlard , Philippe Desmarescaux , Murielle Moneron
发明人： Paul Branlard , Philippe Desmarescaux , Murielle Moneron
IPC分类号： C02F1/56 , C02F1/00 , C02F1/50 , C02F9/04 , C02F1/76 , C02F1/52
CPC分类号： C02F1/50 , C02F1/002 , C02F1/5245 , C02F1/56 , C02F1/76 , C02F2305/14
摘要： The invention relates to a double-layered compacted solid water-purification product, comprising at least one first layer and at least one second layer, characterized in that the first layer comprises at least one flocculating system and at least one dispersion system, the second layer comprises at least one disinfectant which liberates free chlorine on contact with water and at least one excipient for the disinfectant, whereby said excipient releases the disinfectant into the water at a controlled rate such that the combination of excipient and disinfectant releases 0.1 to 100 mg/l of free chlorine per hour. The invention further relates to the method for production of such a product.
摘要翻译：本发明涉及一种双层压实固体水净化产品，其包括至少一个第一层和至少一层第二层，其特征在于，第一层包含至少一种絮凝体系和至少一种分散系统，第二层包括至少一种在与水接触时释放游离氯的消毒剂和用于消毒剂的至少一种赋形剂，由此所述赋形剂以可控制的速率将消毒剂释放到水中，使得赋形剂和消毒剂的组合释放0.1至100mg / l 每小时游离氯。本发明还涉及生产这种产品的方法。

10. 发明授权

US06509023B1 Cosmetic composition comprising a functionalized polyorganosiloxane 失效
标题翻译：包含官能化聚有机硅氧烷的化妆品组合物
公开(公告)号：US06509023B1
公开(公告)日：2003-01-21
申请号：US09463677
申请日：2000-04-13
申请人： Paul Branlard , Gérard Mignani , Claudie Willemin , Philippe Olier
发明人： Paul Branlard , Gérard Mignani , Claudie Willemin , Philippe Olier
IPC分类号： A61K700
CPC分类号： A61Q17/04 , A61K8/585 , A61K8/891 , A61K8/895 , A61Q1/02 , A61Q1/06 , A61Q5/00 , A61Q13/00 , A61Q15/00
摘要： The invention concerns a cosmetic composition comprising a specific functionalized organopolysiloxane which is linear or cyclic. Said functionalized organopolysiloxane is used as emollient and/or carrier and/or anti-transfer agent in cosmetic compositions.
摘要翻译：本发明涉及包含线性或环状的特定官能化有机聚硅氧烷的化妆品组合物。所述官能化有机聚硅氧烷在化妆品组合物中用作润肤剂和/或载体和/或抗转移剂。

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