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1. 发明授权

US4794198A Catalytic process for the manufacture of oximes 失效
公开(公告)号：US4794198A
公开(公告)日：1988-12-27
申请号：US59536
申请日：1987-06-08
申请人： Paolo Roffia , Mario Padovan , Giuseppe Leofanti , Maria A. Mantegazza , Giordano De Alberti , Giorgio R. Tauszik
发明人： Paolo Roffia , Mario Padovan , Giuseppe Leofanti , Maria A. Mantegazza , Giordano De Alberti , Giorgio R. Tauszik
IPC分类号： B01J29/04 , B01J29/00 , B01J29/89 , C07B61/00 , C07C67/00 , C07C239/00 , C07C249/04 , C07C251/32 , C07C131/04
CPC分类号： C07C249/04 , B01J29/89 , C07C2101/14
摘要： The invention concerns a catalytic process for the manufacture of oximes by reaction, in the liquid phase, of the corresponding carbonylic compounds with NH.sub.3 and H.sub.2 O.sub.2, in which process the catalyst is substantially consisting of a crystalline material with a zeolitic structure containing silicon and titanium, subjected, before use, to an activating treatment with H.sub.2 O.sub.2.

2. 发明授权

US5041652A Method for the preparation of a catalyst for the ammoximation of carboxylic compound 失效
标题翻译：制备羧酸化合物氨肟化催化剂的方法
公开(公告)号：US5041652A
公开(公告)日：1991-08-20
申请号：US584394
申请日：1990-09-17
申请人： Mario Padovan , Giordano De Alberti , Paolo Roffia
发明人： Mario Padovan , Giordano De Alberti , Paolo Roffia
IPC分类号： B01J29/04 , B01J29/89 , C01B37/00 , C01B39/02 , C07B61/00 , C07C249/04 , C07C251/42
CPC分类号： C07C249/04 , B01J29/89 , C01B37/005 , C07C2101/14
摘要： The present invention relates to a method of preparing a catalyst for the ammoximation of carboxylic compounds, consisting of a synthetic, crystaline and porous material based on silicon and titanium oxides, characterized in that a preformed matrix of amorphous silica is impregnated with an aqueous solution, containing a titanium compound and an organic compound of nitrogen, as a templating agent, and that to the thus impregnated material a zeolitic structure is given by means of a hydrothermal synthesis of usual type, shape and size of the matrix being substantially maintained unchanged.

3. 发明授权

US4745221A Catalytic process for preparing cyclohexanone-oxime 失效
标题翻译：用于制备环己酮 - 肟的催化方法
公开(公告)号：US4745221A
公开(公告)日：1988-05-17
申请号：US882718
申请日：1986-07-07
申请人： Paolo Roffia , Mario Padovan , Enrico Moretti , Giordano De Alberti
发明人： Paolo Roffia , Mario Padovan , Enrico Moretti , Giordano De Alberti
IPC分类号： C07D271/12 , B01J21/06 , B01J29/00 , B01J29/04 , B01J29/89 , C07B61/00 , C07C67/00 , C07C239/00 , C07C249/04 , C07C251/44 , C07C251/46 , C07C131/04
CPC分类号： B01J29/89
摘要： A catalytic process for preparing cyclohexanone-oxime, by reacting cyclohexanone with NH.sub.3 and H.sub.2 O.sub.2 in the liquid phase, characterized in that the catalyst substantially consists of a highly crystalline substance, containing SiO.sub.2 and having a zeolitic structure.
摘要翻译：通过使环己酮与液相中的NH 3和H 2 O 2反应制备环己酮 - 肟的催化方法，其特征在于催化剂基本上由含有SiO 2并具有沸石结构的高结晶物质组成。

4. 发明授权

US5320819A Direct catalytic process for the production of hydroxylamine 失效
标题翻译：直接催化工艺生产羟胺
公开(公告)号：US5320819A
公开(公告)日：1994-06-14
申请号：US907679
申请日：1992-07-02
申请人： Maria A. Mantegazza , Mario Padovan , Guido Petrini , Paolo Roffia
发明人： Maria A. Mantegazza , Mario Padovan , Guido Petrini , Paolo Roffia
IPC分类号： B01J21/06 , B01J29/03 , B01J29/04 , B01J29/89 , C01B21/14 , C01B21/20
CPC分类号： B01J21/063 , B01J29/89 , C01B21/1409
摘要： Direct catalytic process for the production of hydroxylamine by means of the oxidation of ammonia with H.sub.2 O.sub.2, wherein the catalyst is composed of silicon, titanium and oxygen and has a crystalline (as in the case of titanium-silicalites, for example) or amorphous structure.
摘要翻译：通过用H 2 O 2氧化氨来生产羟胺的直接催化方法，其中催化剂由硅，钛和氧组成，并具有结晶（如在钛 - 硅沸石的情况下）或无定形结构。

5. 发明授权

US4968842A Catalytic process for the manufacture of oximes 失效
标题翻译：用于制造肟的催化过程
公开(公告)号：US4968842A
公开(公告)日：1990-11-06
申请号：US407733
申请日：1989-09-15
申请人： Mario Padovan , Fausto Genoni , Giuseppe Leofanti , Guido Petrini , Paolo Roffia , Alberto Cesana
发明人： Mario Padovan , Fausto Genoni , Giuseppe Leofanti , Guido Petrini , Paolo Roffia , Alberto Cesana
IPC分类号： B01J21/06 , B01J37/00 , C07B61/00 , C07C249/04 , C07C251/38 , C07C251/42 , C07C251/44 , C07C251/48
CPC分类号： B01J21/063 , C07C249/04 , C07C2101/14
摘要： The invention concerns a catalytic process for the manufacture of oximes by ammoximation of the corresponding carbonyl compounds, characterized in that the catalyst is a solid composition consisting of silicon, titanium and oxygen, chemically combined with each other, and in that the titanium amount, expressed as TiO.sub.2, ranges from 1 to 95% by weight, the XR diffractogam of said composition being a smooth-trend line (halo), typical of the amorphous solids.

6. 发明授权

US4918194A Process for the synthesis of a N,N-dialkyl-hydroxylamine 失效
标题翻译：合成N，N-二烷基 - 羟胺的方法
公开(公告)号：US4918194A
公开(公告)日：1990-04-17
申请号：US262354
申请日：1988-10-25
申请人： Paolo Roffia , Sergio Tonti , Alberto Cesana , Maria Angela Mantegazza , Mario Padovan
发明人： Paolo Roffia , Sergio Tonti , Alberto Cesana , Maria Angela Mantegazza , Mario Padovan
IPC分类号： C07D295/22 , B01J29/035 , B01J29/04 , C07B43/00 , C07B61/00 , C07C239/08 , C07D295/24
CPC分类号： C07D295/24 , Y02P20/582
摘要： The invention relates to a process for the synthesis of an N,N-dialkyl-hydroxylamine by reaction of the corresponding dialkylamine with H.sub.2 O.sub.2, said reaction being carried out in the presence of a catalyst based on titanium-silicalite.

7. 发明授权

US5227525A Multistep process for the liquid phase ammoximation of carbonyl compounds 失效
标题翻译：用于碳化合物的液相氨化的多步骤方法
公开(公告)号：US5227525A
公开(公告)日：1993-07-13
申请号：US822907
申请日：1992-01-21
申请人： Sergio Tonti , Paolo Roffia , Vittorio Gervasutti
发明人： Sergio Tonti , Paolo Roffia , Vittorio Gervasutti
IPC分类号： B01J21/06 , C07B61/00 , C07C249/04 , C07C249/08 , C07C249/14 , C07C251/32 , C07C251/44
CPC分类号： C07C249/04 , C07C2101/14
摘要： A multistep process for the liquid phase ammoximation of carbonyl compounds with H.sub.2 O.sub.2 and NH.sub.3, at 60.degree.-100.degree. C., at 1.5-5 bar and in the presence of a catalyst based on silicon, titanium and oxygen, characterized in that:a) in one or more primary steps, the H.sub.2 O.sub.2 : carbonyl compound molar ratio ranges from 0.9 to 1.15 by mols and the carbonyl component conversion is carried out up to at least 95%;b) in a last (exhaustion) step the H.sub.2 O.sub.2 : carbonyl compound ratio is in a higher range, i.e. from 1.5 to 3.0 by mols.

8. 发明授权

US4356319A Method of recovering in active form the catalyst for the terephthalic acid synthesis 失效
标题翻译：以活性形式回收对苯二甲酸合成催化剂的方法
公开(公告)号：US4356319A
公开(公告)日：1982-10-26
申请号：US226382
申请日：1981-01-19
申请人： Paolo Roffia , Pierangelo Calini , Sergio Tonti
发明人： Paolo Roffia , Pierangelo Calini , Sergio Tonti
IPC分类号： C07C51/265 , B01J23/94 , B01J25/00 , B01J31/40 , B01J38/00 , C07C51/00 , C07C51/42 , C07C63/26 , C07C67/00 , C07C51/29
CPC分类号： B01J31/04 , B01J31/4015 , B01J31/403 , C07C51/42 , B01J2231/70 , B01J2531/72 , B01J2531/845 , Y02P20/52 , Y02P20/584
摘要： A method of recovering the catalyst in active form from the acetic mother liquors from the synthesis of terephthalic acid. From said mother liquors, after removal of water, there is removed by evaporation an amount of from 70 to 90% of the CH.sub.3 COOH present therein. The concentrated liquor is cooled below 60.degree. C. and the solid which precipitates is collected and recycled for reuse in the systhesis. The liquid phase is extracted with water or with an aqueous acetic acid solution in the presence of particular coadjuvants such as isobutyl acetate, and the aqueous phase, which contains the recovered catalyst, is recycled to the original synthesis.
摘要翻译：从对苯二甲酸的合成从乙酸母液中回收活性形式的催化剂的方法。从所述母液中除去水后，通过蒸发除去其中存在的CH 3 COOH的70-90％。将浓缩液冷却至60℃以下，收集析出的固体并将其循环再利用于合成。在特殊的辅助剂如乙酸异丁酯存在下，用水或乙酸水溶液萃取液相，含有回收的催化剂的水相再循环到原始合成中。

9. 发明授权

US4894478A Process of producing ketoximes 失效
标题翻译：生产酮肟的方法
公开(公告)号：US4894478A
公开(公告)日：1990-01-16
申请号：US223403
申请日：1988-07-25
申请人： Paolo Roffia , Giuseppe Paparatto , Alberto Cesana , Giorgio Tauszik
发明人： Paolo Roffia , Giuseppe Paparatto , Alberto Cesana , Giorgio Tauszik
IPC分类号： B01J29/04 , B01J21/06 , B01J29/89 , C07B31/00 , C07B43/00 , C07B61/00 , C07C20060101 , C07C67/00 , C07C239/00 , C07C249/04 , C07C251/32 , C07C251/34 , C07C251/38 , C07C251/42 , C07C251/44
CPC分类号： C07C249/04 , B01J29/89 , C07C2101/14
摘要： The invention relates to a process of producing ketoximes, characterized in that a secondary alcohol, corresponding to the desired ketoxime, is partially oxidated in the liquid phase with O.sub.2, an oxidated mixture being thereby formed, which contains an excess of unreacted alcohol, the ketone corresponding to said alcohol, and H.sub.2 O.sub.2, and that said oxidated mixture is directly reacted with NH.sub.3 in the liquid phase (without isolating the alcohol, the ketone and H.sub.2 O.sub.2) in the presence of an ammoximation catalyst.

10. 发明授权

US4061868A Process for the manufacture of glycols and glycol nono-esters 失效
标题翻译：制备二醇和乙二醇非酯的方法
公开(公告)号：US4061868A
公开(公告)日：1977-12-06
申请号：US616602
申请日：1975-09-25
申请人： Carlo Fumagalli , Giuseppe Caprara , Paolo Roffia
发明人： Carlo Fumagalli , Giuseppe Caprara , Paolo Roffia
IPC分类号： C07C69/16 , B01J23/00 , B01J23/76 , B01J27/06 , B01J31/00 , C07B61/00 , C07C67/05 , C07C29/04
CPC分类号： B01J23/76 , B01J27/06 , C07C67/05
摘要： There is provided an improvement in the process for the preparation of organic monoesters of vicinal glycols and the corresponding free glycols by reacting an olefin with oxygen, water and a carboxylic acid, in the liquid phase, at an initial pH of lower than 7, the improvement comprising contacting the reaction mixture with a catalyst system consisting essentially of (i) iodine or an iodine compound selected from the group consisting essentially of copper iodide, manganese iodide, cerium iodide, an alkali metal iodide, an alkali earth metal iodide and the iodohydride of the olefin, (ii) a copper compound selected from the group consisting essentially of copper oxide, copper hydroxide, copper carbonate, copper iodide, and a copper salt of the carboxylic acid, and (iii) an activating ion selected from the group consisting of manganese cation, cerium cation, an alkali metal cation, an alkaline earth metal cation, nitric anion or a mixture of any of the foregoing, wherein the molar ratio of the carboxylic acid to water is lower than 1, the molar ratio of copper to water is equal to or lower than 2 moles of copper per 100 moles of water, and the molar ratio of iodine to copper is lower than 1.
摘要翻译：在初始pH低于7时，在液相中使烯烃与氧，水和羧酸反应制备连位二醇的有机单酯和相应的游离二醇的方法提供了改进，改进包括使反应混合物与基本上由（i）碘或选自基本上由碘化铜，碘化锰，碘化铈，碱金属碘化物，碱土金属碘化物和碘化氢组成的组中的碘化合物组成的催化剂体系的烯烃，（ii）选自基本上由氧化铜，氢氧化铜，碳酸铜，碘化铜和羧酸铜盐组成的组中的铜化合物，和（iii）选自以下的活化离子：的锰阳离子，铈阳离子，碱金属阳离子，碱土金属阳离子，硝酸阴离子或上述任何一种的混合物，其中摩尔比的羧酸与水的摩尔比低于1，铜与水的摩尔比等于或低于每100摩尔水中2摩尔铜，碘与铜的摩尔比低于1。

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