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    • 5. 发明申请
    • ORGANIC EL ELEMENT, DISPLAY DEVICE, AND LIGHT-EMITTING DEVICE
    • 有机EL元件,显示器件和发光器件
    • US20130126846A1
    • 2013-05-23
    • US13742575
    • 2013-01-16
    • PANASONIC CORPORATION
    • Kenji HARADASeiji NISHIYAMATakahiro KOMATSUTakayuki TAKEUCHISatoru OHUCHIHirofumi FUJITAShinya FUJIMURA
    • H01L51/50
    • H01L51/5088H01L27/3246H01L27/3283H05B33/02
    • An organic EL element comprising: an anode; a cathode; banks; a functional layer between the anode and the cathode, the functional layer including one or more sublayers including a light-emitting sublayer, the light-emitting sublayer defined by the banks and containing an organic material; and a hole injection layer between the anode and the functional layer, wherein the hole injection layer comprises tungsten oxide. An Ultraviolet Photoelectron Spectroscopy (UPS) spectrum, obtained from a UPS measurement, has a protrusion appearing near a Fermi surface and within a region corresponding to a binding energy range lower than a top of a valence band. The tungsten oxide contained in the hole injection layer satisfies a condition, determined from an X-ray Photoelectron Spectroscopy (XPS) measurement, that a ratio in a number density of atoms other than tungsten atoms and oxygen atoms to the tungsten atoms does not exceed approximately 0.83.
    • 一种有机EL元件,包括:阳极; 阴极 银行; 阳极和阴极之间的功能层,所述功能层包括一个或多个包括发光子层的子层,所述发光子层由堤形成并含有有机材料; 以及在所述阳极和所述功能层之间的空穴注入层,其中所述空穴注入层包含氧化钨。 从UPS测量获得的紫外光电子能谱(UPS)光谱具有在费米表面附近出现的突起,并且在对应于低于价带顶部的结合能范围的区域内。 包含在空穴注入层中的氧化钨满足由X射线光电子能谱(XPS)测定确定的钨原子和氧原子之间的原子数与钨原子之间的密度比不超过约的条件 0.83。
    • 6. 发明申请
    • ORGANIC EL ELEMENT AND PRODUCTION METHOD FOR SAME
    • 有机EL元件及其生产方法
    • US20130126843A1
    • 2013-05-23
    • US13740348
    • 2013-01-14
    • PANASONIC CORPORATION
    • Seiji NISHIYAMASatoru OHUCHITakahiro KOMATSUYoshiaki TSUKAMOTOShinya FUJIMURAHirofumi FUJITA
    • H01L51/50H01L51/56
    • H01L51/5088H01L51/5209H01L51/5218H01L51/56H01L2251/5369
    • An organic EL element includes a hole injection layer yielding excellent hole conduction efficiency, and comprises: an anode; a cathode; a functional layer disposed between the anode and the cathode, and including a light-emitting layer containing organic material; the hole injection layer disposed between the anode and the functional layer; and a bank defining an area in which the light-emitting layer is to be formed, wherein the hole injection layer includes tungsten oxide, tungsten atoms constituting the tungsten oxide include both tungsten atoms with a valence of six and tungsten atoms with a valence less than six, the hole injection layer includes a crystal of the tungsten oxide, a particle diameter of the crystal being on an order of nanometers, an inner portion of the hole injection layer is depressed to define a recess, and an upper peripheral edge of the recess is covered with a part of the bank.
    • 有机EL元件包括产生优异的空穴传导效率的空穴注入层,并且包括:阳极; 阴极 设置在阳极和阴极之间的功能层,并且包括含有有机材料的发光层; 所述空穴注入层设置在所述阳极和所述功能层之间; 以及限定要形成发光层的区域的堤,其中,空穴注入层包括氧化钨,构成氧化钨的钨原子包括六价钨原子和价数小于等于六价的钨原子 如图6所示,空穴注入层包括氧化钨的晶体,晶体的粒径为数量级左右,空穴注入层的内部被压下以形成凹部,凹部的上周缘 被银行的一部分覆盖。