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    • 6. 发明授权
    • Antidoted herbicide compositions and antidote compositions
    • 抗除草剂组合物和解毒剂组合物
    • US5055125A
    • 1991-10-08
    • US507314
    • 1990-04-10
    • Gyorgy MatolcsyAntal GimesiAntalne TomborBarna BordasJanosne BenczikZoltan KolonicsCsaba SopteiSandor BorosAgota KenerDenzso SebokGeza SzaboImre Varga
    • Gyorgy MatolcsyAntal GimesiAntalne TomborBarna BordasJanosne BenczikZoltan KolonicsCsaba SopteiSandor BorosAgota KenerDenzso SebokGeza SzaboImre Varga
    • A01N25/14A01N25/32A01N37/22A01N43/76A01N47/10A01N47/12A01N47/24A01P13/00C07C233/88C07D263/04C07D263/52C07D295/21C07D487/04
    • C07D263/04A01N25/32A01N47/12C07C233/88C07D263/52C07D295/21C07D487/04
    • Herbicidal compositions comprising a substituted thiolcarbamate derivative corresponding to the formula (I) wherein R.sub.1, R.sub.2 and R.sub.3 are selected independently from alkyl groups having 1 to 4 carbon atoms and/or a chloroacetanilide derivative corresponding to the formula (II) wherein R.sub.4 and R.sub.5 are hydrogen or alkyl group having 1 to 4 carbon atoms, identical or different, R.sub.6 is an alkoxyalkyl group corresponding to the formula --R.sub.7 --O--R.sub.8 in which R.sub.7 and R.sub.8 are selected from alkyl groups having 1 to 4 carbon atoms and, as an antidote, a thiocarbamic acid derivative corresponding to the formula (III) wherein R.sub.9 and R.sub.10 independently from each other are alkyl or alkenyl group having 1 to 4 carbon atoms, or R.sub.9 and R.sub.10 taken together with one or two nitrogen atoms form a heterocyclic group, which may contain one oxygen atom or they form a soiro-heterocyclic or condensated ring, which can be substituted with alkyl groups having 1 to 4 carbon atoms or an aryl group, R.sub.11 is an alkyl or alkenyl group having 1 to 3 carbon atoms or a benzyl group containing one or 2 substituents, carboxy methylene, 1-methylene naphtyl, acetophenon-(2)-yl-, carb-(.alpha.)naphthoxy-methylene, N-methylene o-benzoic acid sulphimide, N-isopropyl-N-phenylacetamidyl, N,N-disubstituted-2-acetamidyl group containing alkyl, alkylene groups having 1 to 3 carbon atoms, alkoxyalkyl, phenyl or dialkyl phenyl group.
    • 包含对应于式(I)的取代的硫代氨基甲酸酯衍生物的除草组合物,其中R 1,R 2和R 3独立地选自具有1至4个碳原子的烷基和/或对应于式(II)的氯代乙酰苯胺衍生物,其中R 4和R 5是 氢或具有1〜4个碳原子的烷基相同或不同,R6是对应于式-R7-O-R8的烷氧基烷基,其中R 7和R 8选自具有1至4个碳原子的烷基,作为 解毒剂,对应于式(III)的氨基甲酸衍生物,其中R 9和R 10彼此独立地为具有1至4个碳原子的烷基或烯基,或者R 9和R 10与一个或两个氮原子一起形成杂环基, 其可以含有一个氧原子,或者它们形成可以被具有1至4个碳原子的烷基或芳基取代的单环或缩合的环,R 11是烷基或链烯基 具有1至3个碳原子的苄基或含有一个或两个取代基的苄基,羧基亚甲基,1-亚甲基萘基,苯乙酮 - (2) - 基 - ,碳 - (α)萘氧基 - 亚甲基,N-亚甲基邻苯甲酸 亚磺酰亚胺,N-异丙基-N-苯基乙酰胺基,含有N,N-二取代-2-乙酰氨基的烷基,具有1至3个碳原子的亚烷基,烷氧基烷基,苯基或二烷基苯基。
    • 8. 发明授权
    • Process for preparing N-sulphonyl-ureas
    • 制备N-磺酰脲的方法
    • US4954628A
    • 1990-09-04
    • US317769
    • 1989-03-02
    • Gabor BesenyeiSandor NemethLaszlo SimandiMaria BelakMaria SzaboJozsef DukaiLajos NagyElemer TomordiCsaba SopteiErzsebet E. Dioszegine
    • Gabor BesenyeiSandor NemethLaszlo SimandiMaria BelakMaria SzaboJozsef DukaiLajos NagyElemer TomordiCsaba SopteiErzsebet E. Dioszegine
    • C07D251/16B01J27/13B01J31/16C07B61/00C07C311/60C07D213/75C07D239/42C07D251/18C07D251/22C07D251/46C07D333/34C07D521/00
    • C07D521/00C07C311/60
    • The invention relates to a process for preparing sulphonyl-ureas of the general formula (I) ##STR1## wherein Ar.sub.1 represents a phenyl, naphthyl or thienyl group, the derivatives thereof substituted by C.sub.1-4 alkyl, C.sub.1-4 haloalkyl, (halo)alkoxycarbonyl, (halo)alkyloxy, nitro, cyano groups as well as by halogen atoms,Ar.sub.2 represents a phenyl, pyridyl, pirimidinyl or triazinyl group and the derivatives thereof substituted by C.sub.1-4 (halo)alkyl, C.sub.1-4 (halo)alkyloxy, amino, O-acyl, O-arylsulphonyl, O-(substituted carbamoyl) groups as well as by halogen atoms.According to the invention N-halogen aryl sulphonamidate is reacted in the presence of a carbonylating catalyst, carbon monoxide and an aromatic amine, optionally in the presence of a phase transfer catalyst, or N-halogen aryl sulphonamidate is reacted with carbon monoxide in the presence of a carbonylating catalyst, and optionally in the presence of a phase transfer catalyst, then the obtained reaction mixture is further reacted with an aromatic amine or an N-halogen-arylamine-alkali metal salt is reacted with aryl-sulphonamid in the presence of a carbonylating catalyst, carbon monoxide and optionally in the presence of a phase transfer catalyst or an amine, amine dihalogenid, aryl sulphonamid are reacted in the presence of a carbonylating catalyst and carbon monoxide and the obtained reaction mixture is worked up in a known manner.The thus prepared sulphonyl-ureas are biologically active compounds, which are used in the pharmaceutical industry and for regulating plant growth.
    • 本发明涉及一种制备通式(I)的磺酰脲的方法,其中Ar 1表示苯基,萘基或噻吩基,其衍生物被C 1-4烷基,C 1-4卤代烷基, (卤代)烷氧基羰基,(卤代)烷氧基,硝基,氰基以及卤素原子,Ar 2表示苯基,吡啶基,吡啶基或三嗪基,其衍生物被C 1-4(卤代)烷基, 卤代)烷氧基,氨基,O-酰基,O-芳基磺酰基,O-(取代的氨基甲酰基)基团以及卤素原子。 根据本发明,N-卤素芳基磺酰胺酸酯在羰基化催化剂,一氧化碳和芳族胺的存在下,任选地在相转移催化剂存在下反应,或N-卤素芳基磺酰胺盐与一氧化碳在存在下反应 的羰基化催化剂,并且任选地在相转移催化剂存在下,然后将所得反应混合物进一步与芳族胺反应或N-卤素 - 芳基胺 - 碱金属盐在芳基 - 磺酰胺存在下与 羰基化催化剂,一氧化碳和任选在相转移催化剂或胺,胺二卤代芳基磺酰胺存在下,在羰基化催化剂和一氧化碳的存在下反应,并将所得反应混合物以已知方式处理。 如此制备的磺酰脲是生物活性化合物,其用于制药工业和调节植物生长。