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    • 4. 发明申请
    • Glass Compositions, Fiberizable Glass Compositions, and Glass Fibers Made Therefrom
    • US20190039945A1
    • 2019-02-07
    • US16047539
    • 2018-07-27
    • PPG Industries Ohio, Inc.
    • Hong LiPaul A. Westbrook
    • C03C13/00C08K7/14C03C3/095
    • The present invention relates generally to glass compositions incorporating rare earth oxides (RE2O3). In one embodiment, a glass composition suitable for fiber forming comprises 51-70 wt. % SiO2, 12.5-22 wt. % Al2O3, 0-20 wt. % CaO, 0-11 wt. % MgO, 0.2-1 wt. % Fe2O3, 0.05 or greater wt. % RE2O3, and greater than 1 wt. % MnOx. In another embodiment, a glass composition suitable for fiber forming comprises 51-70 wt. % SiO2, 12.5-22 wt. % Al2O3, 0-20 wt. % CaO, 0-11 wt. % MgO, 0.2-1 wt. % Fe2O3, 0.05 or greater wt. % RE2O3, 0-4 wt. % BaO, 0-4 wt. % SrO, and 0-5.5 wt. % ZnO, wherein the sum of BaO+SrO+ZnO is greater than about 2 wt. %. In another embodiment, a glass composition suitable for fiber forming comprises 51-70 wt. % SiO2, 12.5-22 wt. % Al2O3, 0-20 wt. % CaO, 0-11 wt. % MgO, 0.2-1 wt. % Fe2O3, 0.05 or greater wt. % RE2O3, and from greater than 0 to 2.5 wt. % Cu2O. In another embodiment, a glass composition suitable for fiber forming comprises 51-70 wt. % SiO2, 12.5-22 wt. % Al2O3, 0-20 wt. % CaO, 0-12.5 wt. % MgO, 0.2-1 wt. % Fe2O3, 0.05 or greater wt. % RE2O3, and at least one additional feature selected from the group consisting of: La2O3 is present in an amount greater than about 2 weight percent, CaO is present in an amount less than about 2 weight percent, a MgO/CaO ratio less than about 1, and a SiO2/Al2O3 ratio greater than about 4. The glass compositions can be used to form glass fibers which can be incorporated into a variety of other fiber glass products (e.g., strands, rovings, fabrics, etc.) and incorporated into various composites.
    • 7. 发明申请
    • GLASS COMPOSITIONS, FIBERIZABLE GLASS COMPOSITIONS, AND GLASS FIBERS MADE THEREFROM
    • US20170101338A1
    • 2017-04-13
    • US15385083
    • 2016-12-20
    • PPG Industries Ohio, Inc.
    • Hong LiPaul A. Westbrook
    • C03C13/00C08K7/14C03C3/095
    • C03C13/00C03C3/095C08K7/14
    • The present invention relates generally to glass compositions incorporating rare earth oxides (RE2O3). In one embodiment, a glass composition suitable for fiber forming comprises 51-70 wt. % SiO2, 12.5-22 wt. % Al2O3, 0-20 wt. % CaO, 0-11 wt. % MgO, 0.2-1 wt. % Fe2O3, 0.05 or greater wt. % RE2O3, and greater than 1 wt. % MnOx. In another embodiment, a glass composition suitable for fiber forming comprises 51-70 wt. % SiO2, 12.5-22 wt. % Al2O3, 0-20 wt. % CaO, 0-11 wt. % MgO, 0.2-1 wt. % Fe2O3, 0.05 or greater wt. % RE2O3, 0-4 wt. % BaO, 0-4 wt. % SrO, and 0-5.5 wt. % ZnO, wherein the sum of BaO+SrO+ZnO is greater than about 2 wt. %. In another embodiment, a glass composition suitable for fiber forming comprises 51-70 wt. % SiO2, 12.5-22 wt. % Al2O3, 0-20 wt. % CaO, 0-11 wt. % MgO, 0.2-1 wt. % Fe2O3, 0.05 or greater wt. % RE2O3, and from greater than 0 to 2.5 wt. % Cu2O. In another embodiment, a glass composition suitable for fiber forming comprises 51-70 wt. % SiO2, 12.5-22 wt. % Al2O3, 0-20 wt. % CaO, 0-12.5 wt. % MgO, 0.2-1 wt. % Fe2O3, 0.05 or greater wt. % RE2O3, and at least one additional feature selected from the group consisting of: La2O3 is present in an amount greater than about 2 weight percent, CaO is present in an amount less than about 2 weight percent, a MgO/CaO ratio less than about 1, and a SiO2/Al2O3 ratio greater than about 4. The glass compositions can be used to form glass fibers which can be incorporated into a variety of other fiber glass products (e.g., strands, rovings, fabrics, etc.) and incorporated into various composites.