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    • 2. 发明申请
    • HYBRID PHOTOINITIATORS
    • 混合摄影机
    • US20160168279A1
    • 2016-06-16
    • US14436694
    • 2013-10-16
    • PETER NESVADBAJean-Luc BIRBAUMYvonne PILAKBrun SPONYFlorian ZIEGLER
    • PETER NESVADBAJean-Luc BIRBAUMYvonne PILAKBrun SPONYFlorian ZIEGLER
    • C08F2/50C09D4/00C07C67/14C07C69/716C07C69/003
    • C08F2/50C07C67/14C07C69/003C07C69/616C07C69/716C07C69/738C09D4/00
    • Compounds of the formula I wherein m is 1 or 2; R1, R2, R4 and R5 independently of one another are hydrogen, C1-C4alkyl, C5-C7 cycloalkyl, phenyl, C1-C4alkoxy, C5-C7cycloalkoxy or phenoxy; R3, if m is 1, has one of the meanings as given above for R1, R2, R4 and R5; R3, if m is 2, is a divalent group; R6 is hydrogen or C1-C4alkyl; R7 is hydrogen, and if R6 is hydrogen then R7 may additionally be C1-C4alkyl; R8 is group A or B X is O, O—CH2— or —O(CHR14)—; n is 0-10; provided that (i) if n is 0, and X is O, then R8 is a group A; (ii) if n is other than 0, then X is O and R8 is the group A; R9 and R10 independently of one another are hydrogen or C1-C4alkyl; R11 and R12 independently of one another are C1-C4alkyl or form together with the C atom to which they are attached a 5 to 7 membered saturated carbocyclic ring; R13 is hydrogen, C1-C4alkyl, C5-C7cycloalkyl, 2-tetrahydropyranyl or Si(C1-C4alkyl)3; R14 is a group A′ and R′13 has one of the meanings as given for R13 or is the group C are effective photoinitiator compounds.
    • 式I化合物,其中m为1或2; R 1,R 2,R 4和R 5彼此独立地是氢,C 1 -C 4烷基,C 5 -C 7环烷基,苯基,C 1 -C 4烷氧基,C 5 -C 7环烷氧基或苯氧基; R3如果m为1,具有如上对R1,R2,R4和R5所给出的含义之一; R3如果m为2,则为二价基团; R6是氢或C1-C4烷基; R7是氢,如果R6是氢,则R7可以另外是C 1 -C 4烷基; R8是A或B X是O,O-CH 2 - 或-O(CHR 14) - ; n为0-10; 条件是(i)如果n为0,X为O,则R8为A基团; (ii)如果n不为0,则X为O,R8为A组; R 9和R 10彼此独立地是氢或C 1 -C 4烷基; R 11和R 12彼此独立地是C 1 -C 4烷基或与它们所连接的C原子一起形成5至7元饱和碳环; R 13是氢,C 1 -C 4烷基,C 5 -C 7环烷基,2-四氢吡喃基或Si(C 1 -C 4烷基)3; R14是基团A',R'13具有R 13给出的含义之一,或者C是有效的光引发剂化合物。