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1. 发明授权

US06875826B1 High melt strength polypropylene 失效
标题翻译：高熔体强度聚丙烯
公开(公告)号：US06875826B1
公开(公告)日：2005-04-05
申请号：US09508405
申请日：1998-09-28
申请人： Päivi Huovinen , Ali Harlin , Pirjo Jääskeläinen , Amir Karbasi , Nina Manner
发明人： Päivi Huovinen , Ali Harlin , Pirjo Jääskeläinen , Amir Karbasi , Nina Manner
IPC分类号： C08J9/00 , C08F2/01 , C08F2/34 , C08F4/645 , C08F4/654 , C08F4/6592 , C08F10/06 , C08F110/06 , C08F210/06
CPC分类号： C08F110/06 , Y10S526/905 , C08F2/001 , C08F2500/12 , C08F2500/04 , C08F2500/17
摘要： The present invention concerns a high melt strength propylene polymer or copolymer suitable for manufacturing foams and thermoformed product exhibiting a melt strength of at least 3 g and comprising a high molar mass portion and a low or medium molar mass portion. The polymers are produced by subjecting propylene and optionally other olefins to polymerization in a plurality of polymerization reactors connected in series, employing different amounts of hydrogen as a molar mass modifier in at least two of the reactors, and carrying out the polymerization reaction in the presence of a catalyst system capable of catalyzing the formation of a high molar mass polymerization product having a MFR2 of less than 0.1 g/l0 min and a low or medium molar mass polymerization product having a MFR2 of more than 0.5 g/10 min.
摘要翻译：本发明涉及适用于制造泡沫和热成型产品的高熔体强度丙烯聚合物或共聚物，其具有至少3g的熔体强度并且包含高摩尔质量部分和低或中等摩尔质量部分。聚合物是通过使丙烯和任选的其它烯烃在串联连接的多个聚合反应器中进行聚合而制备的，其中在至少两个反应器中使用不同量的氢作为摩尔质量调节剂，并在存在下进行聚合反应的催化剂体系，其能够催化形成MFR 2小于0.1g / lmin的高摩尔质量聚合产物和具有大于0.5g / 10min的MFR 2的低或中等摩尔质量的聚合产物。

2. 发明授权

US07365136B2 High melt strength polypropylene 失效
标题翻译：高熔体强度聚丙烯
公开(公告)号：US07365136B2
公开(公告)日：2008-04-29
申请号：US11075488
申请日：2005-03-08
申请人： Paivi Huovinen , Ali Harlin , Pirjo Jaaskelainen , Amir Karbasi , Nina Manner
发明人： Paivi Huovinen , Ali Harlin , Pirjo Jaaskelainen , Amir Karbasi , Nina Manner
IPC分类号： C08F2/34 , C08F4/6592 , C08F4/614 , C08F210/06
CPC分类号： C08F110/06 , Y10S526/905 , C08F2/001 , C08F2500/12 , C08F2500/04 , C08F2500/17
摘要： The present invention concerns a high melt strength propylene polymer or copolymer suitable for manufacturing foams and thermoformed product exhibiting a melt strength of at least 3 g and comprising a high molar mass portion and a low or medium molar mass portion. The polymers are produced by subjecting propylene and optionally other olefins to polymerization in a plurality of polymerization reactors connected in series, employing different amounts of hydrogen as a molar mass modifier in at least two of the reactors, and carrying out the polymerization reaction in the presence of a catalyst system capable of catalyzing the formation of a high molar mass polymerization product having a MFR2 of less than 0.1 g/10 min and a low or medium molar mass polymerization product having a MFR2 of more than 0.5 g/10 min.
摘要翻译：本发明涉及适用于制造泡沫和热成型产品的高熔体强度丙烯聚合物或共聚物，其具有至少3g的熔体强度并且包含高摩尔质量部分和低或中等摩尔质量部分。聚合物是通过使丙烯和任选的其它烯烃在串联连接的多个聚合反应器中进行聚合而制备的，其中在至少两个反应器中使用不同量的氢作为摩尔质量调节剂，并在存在下进行聚合反应的催化剂体系，其能够催化形成具有小于0.1g / 10min的MFR 2的高摩尔质量聚合产物和具有小于0.1g / 10min的低摩尔质量或中等摩尔质量的聚合产物， 2 <0.5，大于0.5g / 10min。

3. 发明申请

US20050159564A1 High melt strength polypropylene 失效
标题翻译：高熔体强度聚丙烯
公开(公告)号：US20050159564A1
公开(公告)日：2005-07-21
申请号：US11075488
申请日：2005-03-08
申请人： Paivi Huovinen , Ali Harlin , Pirjo Jaaskelainen , Amir Karbasi , Nina Manner
发明人： Paivi Huovinen , Ali Harlin , Pirjo Jaaskelainen , Amir Karbasi , Nina Manner
IPC分类号： C08J9/00 , C08F2/01 , C08F2/34 , C08F4/645 , C08F4/654 , C08F4/6592 , C08F10/06 , C08F110/06 , C08L1/00 , C08F2/00
CPC分类号： C08F110/06 , Y10S526/905 , C08F2/001 , C08F2500/12 , C08F2500/04 , C08F2500/17
摘要： The present invention concerns a high melt strength propylene polymer or copolymer suitable for manufacturing foams and thermoformed product exhibiting a melt strength of at least 3 g and comprising a high molar mass portion and a low or medium molar mass portion. The polymers are produced by subjecting propylene and optionally other olefins to polymerization in a plurality of polymerization reactors connected in series, employing different amounts of hydrogen as a molar mass modifier in at least two of the reactors, and carrying out the polymerization reaction in the presence of a catalyst system capable of catalyzing the formation of a high molar mass polymerization product having a MFR2 of less than 0.1 g/10 min and a low or medium molar mass polymerization product having a MFR2 of more than 0.5 g/10 min.
摘要翻译：本发明涉及适用于制造泡沫和热成型产品的高熔体强度丙烯聚合物或共聚物，其具有至少3g的熔体强度并且包含高摩尔质量部分和低或中等摩尔质量部分。聚合物是通过使丙烯和任选的其它烯烃在串联连接的多个聚合反应器中进行聚合而制备的，其中在至少两个反应器中使用不同量的氢作为摩尔质量调节剂，并在存在下进行聚合反应的催化剂体系，其能够催化形成具有小于0.1g / 10min的MFR 2的高摩尔质量聚合产物和具有小于0.1g / 10min的低摩尔质量或中等摩尔质量的聚合产物， 2 <0.5，大于0.5g / 10min。

4. 发明申请

US20120160433A1 PROCESS FOR PRODUCING MICROFIBRILLATED CELLULOSE 有权
标题翻译：生产微晶纤维素的方法
公开(公告)号：US20120160433A1
公开(公告)日：2012-06-28
申请号：US13382573
申请日：2010-07-02
申请人： Marianna Vehvilainen , Taina Kamppuri , Maarit Peltola , Ali Harlin , Pertti Nousiainen
发明人： Marianna Vehvilainen , Taina Kamppuri , Maarit Peltola , Ali Harlin , Pertti Nousiainen
IPC分类号： D21B1/16
CPC分类号： D21H11/18 , D21C5/005 , D21C9/007 , D21H11/20 , D21H17/005
摘要： A process for treating cellulosic fibres comprises mechanically pre-treating the fibres followed by treating the fibres with an enzyme and thereafter mixing the fibres with a solution comprising an alkali metal hydroxide followed by mechanically treating the fibres to form microfibrillated cellulose. In this way it is possible to produce microfibrillated cellulose (MFC) in an improved and energy efficient way.
摘要翻译：用于处理纤维素纤维的方法包括机械预处理纤维，然后用酶处理纤维，然后将纤维与包含碱金属氢氧化物的溶液混合，然后机械处理纤维以形成微纤化纤维素。以这种方式，可以以改进和节能的方式生产微纤维化纤维素（MFC）。

5. 发明申请

US20110223401A1 FIBROUS PRODUCT HAVING A BARRIER LAYER AND METHOD OF PRODUCING THE SAME 审中-公开
标题翻译：具有障碍层的纤维制品及其生产方法
公开(公告)号：US20110223401A1
公开(公告)日：2011-09-15
申请号：US13122341
申请日：2009-10-01
申请人： Ali Harlin , Eero Iiskola , Mika Vähä-Nissi , Terhi Hirvikorpi , Tuomas Mustonen
发明人： Ali Harlin , Eero Iiskola , Mika Vähä-Nissi , Terhi Hirvikorpi , Tuomas Mustonen
IPC分类号： B32B7/02 , B32B5/00 , C23C16/44 , C23C16/513 , C23C16/06 , C23C16/22
CPC分类号： C23C16/45555 , C23C16/45525 , D21H19/18 , D21H19/20 , D21H19/52 , D21H19/54 , D21H23/50 , D21H25/04 , D21H27/10 , Y10T428/24975 , Y10T428/265
摘要： The invention relates to barrier products and a method for the manufacture thereof. The product comprises a fibrous substrate, a coating layer on at least one surface of the fibrous substrate, and a barrier applied on the coating layer, comprising a thin film with a thickness of less than about 1 micrometer and capable of providing barrier properties to the fibrous product. According to the invention, the coating layer comprises biopolymer, which have been found to be suitable for atomic layer deposition of thin barrier films comprising e.g. metal oxide. Improved oxygen, water vapour and aroma barrier properties can be achieved by the invention for papers and paperboards for packaging purposes.
摘要翻译：本发明涉及阻挡产品及其制造方法。该产品包括纤维基材，纤维基材的至少一个表面上的涂层和涂覆在涂层上的阻挡层，其包含厚度小于约1微米的薄膜，并能够提供阻挡性能纤维制品。根据本发明，涂层包括生物聚合物，其已被发现适合于薄膜阻挡膜的原子层沉积，所述薄阻挡膜包括例如金属氧化物。通过本发明，用于包装目的的纸和纸板可以实现改善的氧气，水蒸气和香气阻隔性能。

6. 发明授权

US5684097A Process for preparing polyethylene 失效
标题翻译：制备聚乙烯的方法
公开(公告)号：US5684097A
公开(公告)日：1997-11-04
申请号：US475842
申请日：1995-06-07
申请人： Ari Palmroos , Ali Harlin , Antero Ahvenainen , Jouni Takakarhu , Aimo Sahila
发明人： Ari Palmroos , Ali Harlin , Antero Ahvenainen , Jouni Takakarhu , Aimo Sahila
IPC分类号： C08F2/14 , B01J8/24 , B01J19/24 , C08F2/06 , C08F2/34 , C08F10/02 , C08F210/16
CPC分类号： C08F10/02 , B01J19/2435 , B01J19/245 , B01J8/24 , B01J2219/00051 , B01J2219/00166 , B01J2219/00173 , C08F210/16
摘要： A process for producing polyethylene compositions in the presence of a catalytic system of ethylene polymerizing catalyst and cocatalyst in a multistage continuous reaction sequence consisting of successive liquid phase and gas phase polymerizations is disclosed. In the first step of the process, ethylene and optionally hydrogen and comonomer are polymerized in a first loop reactor in a low boiling hydrocarbon medium in the presence of ethylene polymerizing catalyst and cocatalyst. The reaction mixture is then removed and then transferred to a second loop reactor where polymerization is continued by addiing ethylene, hydrogen and optionally inert hydrocarbon, comonomers and cocatalysts. Thereafter, the reaction mixture is removed from the second loop reactor along with an essential part of the reaction medium and transferred to a gas phase reactor where polymerizing is continued in the presence of added ethylene and optionally hydrogen, comonomers and cocatalysts to form an end product. The residence time and reaction temperature being such that the proportion of the ethylene polymer produced in the first loop reactor to the end product of the process is between 1-20%.
摘要翻译：在由连续液相和气相聚合组成的多级连续反应序列中，在乙烯聚合催化剂和助催化剂催化体系存在下生产聚乙烯组合物的方法。在该方法的第一步中，在乙烯聚合催化剂和助催化剂存在下，乙烯和任选的氢和共聚单体在第一回路反应器中在低沸点烃介质中聚合。然后除去反应混合物，然后转移到第二环管反应器中，其中通过加入乙烯，氢气和任选的惰性烃，共聚单体和助催化剂继续聚合。此后，将反应混合物与反应介质的主要部分一起从第二环管反应器中除去，并转移到气相反应器中，在气相反应器中，在加入的乙烯和任选的氢，共聚单体和助催化剂的存在下，继续聚合以形成最终产物。停留时间和反应温度使得在第一回路反应器中产生的乙烯聚合物与该方法的最终产物的比例为1-20％。

7. 发明申请

US20140088252A1 METHOD FOR MAKING SPECIFIC PRODUCTS FROM POLYSACCHARIDE MOLECULE 审中-公开
标题翻译：从多糖分子制备特定产品的方法
公开(公告)号：US20140088252A1
公开(公告)日：2014-03-27
申请号：US14006797
申请日：2012-03-22
申请人： Ali Harlin , Harri Setälä , Helinä Talja
发明人： Ali Harlin , Harri Setälä , Helinä Talja
IPC分类号： C08F8/00 , C08B15/00 , C08B37/00
CPC分类号： C08F8/00 , C08B11/187 , C08B11/193 , C08B11/20 , C08B15/005 , C08B15/10 , C08B37/00 , C08B37/0057 , C08F251/00 , C08G2210/00 , C08G2650/26 , C08H8/00 , C08J3/075 , C08J3/246 , C08J5/18 , C08J2301/02 , C08J2387/00 , C08L1/02 , C08L1/08 , C08L5/00 , D06M14/04 , D06M15/263 , D06M15/285 , D06M15/3562 , D06M2101/06 , D21C9/002
摘要： A method for preparing a specific product from a polysaccharide in which at least one hydroxyl of a saccharide unit is substituted with an ether or ester moiety. The ether or ester moiety is provided with ethenyl and/or epoxy functionality for preparing an activatable polysaccharide polymer and the activatable polysaccharide polymer with ethenyl and/or epoxy functionality is optionally reacted with an additional coupling reagent, having at least two coupling functionality for preparing polysaccharide polymer with additional activatable crosslinker. Thereafter, the activatable polysaccharide polymer or the polysaccharide polymer with an additional activatable crosslinker, is activated for crosslinking the polysaccharide polymer with another polysaccharide polymer by reacting the activatable polysaccharide polymer or polysaccharide polymer with an additional activatable crosslinker with a crosslinking initiator for crosslinking the polysaccharide polymer chains with each other, for preparing a product such as hydrogel, film, coating or membrane with polysaccharide backbone.
摘要翻译：一种由糖单元的至少一个羟基被醚或酯部分取代的多糖制备特定产品的方法。醚或酯部分具有用于制备可活化多糖聚合物的乙烯基和/或环氧官能团，并且具有乙烯基和/或环氧官能团的可活化多糖聚合物任选与另外的偶联试剂反应，其具有至少两个用于制备多糖的偶联官能团聚合物与另外的活化交联剂。此后，活化的多糖聚合物或具有另外的可活化交联剂的多糖聚合物被活化，以通过使可活化的多糖聚合物或多糖聚合物与另外的可活化的交联剂与交联引发剂反应来交联多糖聚合物与多糖聚合物，以交联多糖聚合物链条，用于制备具有多糖骨架的产品如水凝胶，膜，涂层或膜。

8. 发明申请

US20120053379A1 METHOD FOR PRODUCING OLEFINIC MONOMERS FROM BIO OIL 有权
标题翻译：从生物油生产烯烃单体的方法
公开(公告)号：US20120053379A1
公开(公告)日：2012-03-01
申请号：US13146857
申请日：2010-01-29
申请人： Ali Harlin , Tapani Penttinen , Jari Räsänen , Olli Aaltonen
发明人： Ali Harlin , Tapani Penttinen , Jari Räsänen , Olli Aaltonen
IPC分类号： C07C1/20
CPC分类号： C10G51/02 , C07C11/02 , C07C11/04 , C07C11/06 , C10G3/46 , C10G3/50 , C10G3/54 , C10G9/00 , C10G9/36 , C10G11/02 , C10G2300/1014 , C10G2300/807 , C10G2400/20 , Y02P30/42
摘要： The invention relates to a method of producing olefinic monomers for the production of a polymer. The invention particularly relates to the production of tall oil-based biopolymers, such as polyolefins. In the stages of the method bio oil, with a content of over 50% of fatty acids of tall oil and no more than 25% of resin acids of tall oil, and hydrogen gas are fed into a catalyst bed (7); the oil is catalytically deoxygenated in the bed by hydrogen; the flow exiting the bed is cooled down and divided into a hydrocarbon-bearing liquid phase (10) and a gas phase; and the hydrocarbon-bearing liquid (13) is subjected to steam cracking (4) to provide a product containing polymerizing olefins. The deoxygenation in the bed can be followed by a catalytic cracking or, with a suitable catalyst, the deoxygenation and cracking can be simultaneous. The separated hydrogen-bearing gas phase can be circulated in the process.
摘要翻译：本发明涉及生产用于生产聚合物的烯烃单体的方法。本发明特别涉及妥尔油基生物聚合物如聚烯烃的生产。在方法生物油的阶段，含量超过50％的妥尔油的脂肪酸和不超过25％的妥尔油的树脂酸，并将氢气进料到催化剂床（7）中; 油通过氢气在床中催化脱氧; 离开床的流被冷却并分成含烃液相（10）和气相; 并对含烃液体（13）进行蒸汽裂化（4）以提供含有聚合烯烃的产物。床中的脱氧可能是催化裂化，或者使用合适的催化剂，脱氧和裂解可以同时进行。分离的含氢气相可以在该过程中循环。

9. 发明申请

US20070292663A1 Fabric Structure For Use In Paper Machine And Manufacturing Method Thereof 有权
标题翻译：织物结构用于造纸机及其制造方法
公开(公告)号：US20070292663A1
公开(公告)日：2007-12-20
申请号：US11632777
申请日：2005-09-12
申请人： Hannu Martikainen , Pekka Kortelainen , Tania Rautio , Mari Seppanen , Ali Harlin , Tuula Wilenius-Jaakonaho
发明人： Hannu Martikainen , Pekka Kortelainen , Tania Rautio , Mari Seppanen , Ali Harlin , Tuula Wilenius-Jaakonaho
IPC分类号： D21F1/10 , D21F7/08
CPC分类号： D21F1/0027 , Y10S162/903 , Y10T428/24802 , Y10T428/2481
摘要： The invention relates to a flexible and porous fabric structure comprising a support structure (1) and a coating material for use in a paper machine. The coating material (2) is arranged solely on the surface of the support structure (1) at a predefined location(s) so that the coating material (2) does not substantially alter the permeability properties of the support structure (1). The invention also relates to a method for manufacturing a fabric structure.
摘要翻译：本发明涉及一种柔性和多孔织物结构，其包括支撑结构（1）和用于造纸机的涂层材料。涂层材料（2）仅在预定位置处布置在支撑结构（1）的表面上，使得涂层材料（2）基本上不改变支撑结构（1）的渗透性能。本发明还涉及一种用于制造织物结构的方法。

10. 发明授权

US06827568B2 Arrangement in connection with clamping tools 失效
标题翻译：与夹具相关的安排
公开(公告)号：US06827568B2
公开(公告)日：2004-12-07
申请号：US10220569
申请日：2002-11-29
申请人： Ali Harlin , Jyrki Pennala , Pekka Huotari
发明人： Ali Harlin , Jyrki Pennala , Pekka Huotari
IPC分类号： B29C4706
CPC分类号： B29C47/0822 , B29C47/0016 , B29C47/28
摘要： An arrangement in connection with clamping tools, which comprises a nozzle structure which consists of coaxially arranged nozzle elements and is arranged to form one or more layers which cover a flexible elongated element on the surface of the flexible elongated element, which passes through the innermost nozzle element, in which arrangement at least the head of the nozzle element, which controls the flexible elongated element, is a separate unit which is arranged to be pushed into its position in the direction of the flexible elongated element and provided with gripping means, which grip the innermost nozzle element of the nozzle structure as the unit arrives at the nozzle element. The joint between the separate unit and the nozzle element of the nozzle structure is arranged to be loosened by repulsive force acting on the separate unit in the direction of the flexible elongated element and the separate unit is arranged to exit from the nozzle structure in the direction of the flexible elongated element.
摘要翻译：与夹紧工具相关的装置，其包括由同轴布置的喷嘴元件组成的喷嘴结构，并且布置成形成一个或多个层，其覆盖柔性细长元件的表面上的柔性细长元件，其穿过最内部喷嘴元件，其中至少控制柔性细长元件的喷嘴元件的头部的布置是分离的单元，其被布置成沿着柔性细长元件的方向被推入其位置并且设置有夹持装置，该夹持装置作为单元的喷嘴结构的最内部喷嘴元件到达喷嘴元件。分离单元和喷嘴结构的喷嘴元件之间的接头被布置成通过沿着柔性细长元件的方向作用在单独单元上的排斥力而松开，并且分离单元被布置成沿喷嘴结构的方向的柔性细长元件。

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