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2. 发明授权

US4158003A Metallized bis-formazans 失效
标题翻译：金属化双甲烷
公开(公告)号：US4158003A
公开(公告)日：1979-06-12
申请号：US741017
申请日：1976-11-11
申请人： Otto Bitterlin , Paul Dussy
发明人： Otto Bitterlin , Paul Dussy
IPC分类号： C09B50/06 , C09B45/48
CPC分类号： C09B50/06
摘要： Heavy-metal-containing bisformazan dyestuffs of the formula ##STR1## WHEREIN A.sub.1, A.sub.2, B.sub.1 and B.sub.2 are the same or different and each represents an unsubstituted or substituted o-phenylene radical or an o-naphthylene radical,R.sub.1 and R.sub.2 are the same or different and each represent a monovalent organic radical,Me.sub.1 and Me.sub.2 each represent nickel or copper,X.sub.1 and X.sub.2 are the same or different and each represents a metal-binding substituent connected to A.sub.1, B.sub.1, A.sub.2 or B.sub.2 in a position ortho to that to which the nitrogen is linked,Y represents the radical of a dibasic carboxylic acid or a radical which is derived from an, at least, bifunctional heterocyclic compound,Z represents a salt-forming water-solubilizing group, dissociating acid in water, selected from --SO.sub.3.sup..crclbar. M.sym. and --COO.sup..crclbar. M.sup..sym.wherein M.sup..sym. represents a cation,N represents a number from 2 to 6, andWherein aromatic radicals present may contain further substituents known per se for use in azo dyestuffs, and wherein the grouping --NH--Y--HN-- is bound directly or via a bridging member to a ring carbon atom of A.sub.1, A.sub.2, B.sub.1, B.sub.2, R.sub.1 or R.sub.2 ,which bis-formazans are substantive dyestuffs suitable for the dyeing or printing of textile material made from natural or regenerated cellulose. The aforesaid bis-formazan dyestuffs are distinguished by high coloring strength and substantivity to cellulose textile material. The dyeings obtained therewith are of a pure shade of color and have good fastness properties, especially to light and wet.
摘要翻译：具有下式的重金属的双甲缩醛染料，其中A1，A2，B1和B2相同或不同，并且各自表示未取代或取代的邻亚苯基或邻亚萘基， R1和R2相同或不同，各自表示一价有机基团，Me1和Me2各自表示镍或铜，X1和X2相同或不同，表示与A1，B1，A2或B2连接的金属结合取代基在与氮连接的位置的邻位，Y表示二元羧酸或至少由双官能的杂环化合物衍生的基团的基团，Z表示形成盐的水溶性基团，离解的其中M（+）表示阳离子，N代表从2到6的数目，以及存在于本文中的AROMATIC RADICALS可能含有的在AZO DYESTUFFS和本集团所使用的更多替代品 ING -NH-Y-HN-直接键合或通过桥连构件结合到A1，A2，B1，B2，R1或R2的环碳原子上，双甲烷是适合纺织材料的染色或印花的实质性染料由天然或再生纤维素制成。上述双甲an染料的特征在于高着色强度和对纤维素纺织材料的亲和性。由此获得的染色具有纯色的色泽，并且具有良好的牢度性能，特别是对于光和湿。

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