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1. 发明授权

US4583638A Pressure-tight vessel for the storage of hydrogen in a metal matrix body 失效
标题翻译：用于在金属基质体中储存氢的耐压容器
公开(公告)号：US4583638A
公开(公告)日：1986-04-22
申请号：US661430
申请日：1984-10-16
申请人： Otto Bernauer , Robert Wagner
发明人： Otto Bernauer , Robert Wagner
IPC分类号： F17C11/00
CPC分类号： F17C11/005 , Y02E60/321
摘要： A pressure-tight vessel for the storage of hydrogen in a metal matrix body and in which a matrix body is arranged in a tube preferably made of aluminum, the outside diameter of the matrix body before activation is less than the inside diameter of the vessel, and in which discs are provided filling the tube cross-section, which discs rest against the end faces of the matrix body and are displaceable axially outwards against resistance within the tube, as a result of which it becomes possible for the matrix body to expand in the axial direction. For a faster absorption and emission of hydrogen, the matrix body is preferably provided with a central extraction tube which is guided through the discs. Any deformation of the vessel as a result of changes in volume of the matrix body is avoided by this construction.
摘要翻译：一种压力容器，用于在金属基质体中储存氢，并且其中基质体布置在优选由铝制成的管中，活化前的基体的外径小于容器的内径，并且其中设置有填充管横截面的盘，该盘支撑在基体的端面上，并且能够抵抗管内的阻力向轴向移动，结果使得基体能够在轴向。为了更快的吸收和释放氢，基质体优选地设置有引导通过盘的中心抽取管。通过这种结构避免了由于基体的体积变化导致的容器的任何变形。

2. 发明授权

US4457891A Hydrogen storage alloy 失效
标题翻译：储氢合金
公开(公告)号：US4457891A
公开(公告)日：1984-07-03
申请号：US475367
申请日：1983-03-14
申请人： Otto Bernauer , Klaus Ziegler
发明人： Otto Bernauer , Klaus Ziegler
IPC分类号： C22C22/00 , C01B3/00 , C22C30/00 , C01B6/02
CPC分类号： C01B3/0052 , C01B3/0031 , C01B3/0057 , Y02E60/327 , Y02P20/129 , Y10S420/90
摘要： A hydrogen storage material is described which comprises an alloy of the composition of 25 to 30.9% by weight of Ti, about 10 to about 42% by weight of V and about 27.1 to about 65.1% by weight of Mn. The proviso is that more than 2 up to at most 2.2 atoms are present per titanium atom. Up to about 40%, preferably about 10 to about 40%, of the vanadium atoms can be replaced by iron atoms and up to about 10%, preferably about 3 to about 10%, can be replaced by aluminum atoms, but not more than about 40% of the vanadium atoms in total are replaced. Moreover, in place of titanium, a mixture can be used in which up to about 20% of the titanium fraction are replaced by Ca, Y, La, misch metal, or mixtures thereof. Up to about 0.2 atom of Cr per the titanium atom, up to about 0.1 atom of Ni per titanium atom and up to about 0.05 atom of Cu per titanium atom can also be present, but not more than about 0.1 atom of Ni plus Cu, these atoms replacing the same number of vanadium atoms.
摘要翻译：描述了一种储氢材料，其包含组合物为25至30.9重量％的Ti，约10至约42重量％的V和约27.1至约65.1重量％的Mn的合金。条件是每个钛原子存在多于2个至多2.2个原子。高达约40％，优选约10％至约40％的钒原子可以被铁原子代替，最多约10％，优选约3％至约10％可被铝原子代替，但不能超过总共约40％的钒原子被替换。此外，代替钛，可以使用其中高达约20％的钛部分被Ca，Y，La，混合稀土或其混合物代替的混合物。每钛原子高达约0.2原子的Cr，每钛原子高达约0.1原子的Ni，每钛原子最多为约0.05原子的Cu，但Ni不超过约0.1原子的Cu，这些原子代替相同数量的钒原子。

3. 发明授权

US4385726A Method of preheating motor vehicles with internal combustion engines 失效
标题翻译：用内燃机预热机动车辆的方法
公开(公告)号：US4385726A
公开(公告)日：1983-05-31
申请号：US150291
申请日：1980-05-16
申请人： Otto Bernauer , Helmut Buchner
发明人： Otto Bernauer , Helmut Buchner
IPC分类号： F28F23/00 , B60H1/22 , B60K3/00 , F02B43/10 , F02G5/00 , F02N19/02 , F28D20/00 , B60H1/02
CPC分类号： F02N19/02 , F02B43/10 , F28D20/003 , Y02E60/142 , Y02E70/30 , Y02T10/32 , Y02T90/42 , Y10S123/12
摘要： A method of preheating vehicles equipped with internal combustion engines involves the utilization of the heat released when hydrogen is combined with a high-temperature hydride-forming material contained within a high-temperature reservoir. The high-temperature reservoir contains a sufficient quantity of low-temperature reservoir hydride-forming material that when hydrogen is added from a low-temperature reservoir to the high-temperature reservoir, the quantity of heat which is initially released by the low-temperature hydride-forming material is sufficient to raise the high-temperature reservoir hydride-forming material also contained in the high-temperature reservoir to the reaction temperatures required for absorption of hydrogen and the release of heat. The amount of heat released in the high-temperature reservoir is used to preheat the vehicle by heat exchange with the vehicle passenger compartment and/or engine and the exhaust heat released by the engine during operation is used to desorb the hydrogen from the hydride-forming material in the high-temperature reservoir and transfer the hydrogen back to a low-temperature reservoir.
摘要翻译：预热配备有内燃机的车辆的方法涉及利用当氢气与包含在高温储存器中的高温氢化物形成材料组合时释放的热量。高温储层含有足够量的低温储层氢化物形成材料，当从低温储层向高温储层添加氢时，最初由低温氢化物释放的热量足以将高温储存器中所含的高温储层氢化物形成材料升高至吸收氢气和释放热所需的反应温度。高温储存器中释放的热量用于通过与车辆乘客舱和/或发动机的热交换来预热车辆，并且在操作期间由发动机释放的排气热用于从氢化物形成中解吸氢材料在高温储层中并将氢转移回低温储层。

4. 发明授权

US5182089A Chemisorptive metal alloy and method of using the same 失效
标题翻译：化学金属合金及其使用方法
公开(公告)号：US5182089A
公开(公告)日：1993-01-26
申请号：US658034
申请日：1991-02-20
申请人： Otto Bernauer
发明人： Otto Bernauer
IPC分类号： B01D53/04 , B01D53/34 , B01D53/81 , C01B3/00 , C22C9/00 , C22C14/00 , C22C16/00
CPC分类号： C01B3/0031 , C22C14/00 , C22C9/00 , Y02E60/327
摘要： A chemisorptive metal alloy includes from about 30% to about 70% by weight of Ti and/or Zr and from about 30% to about 70% by weight of Cu. Optionally, the alloy may also contain from 0% to about 5% by weight of Fe; from 0% to about 10% by weight of Ni; from 0% to about 5% of V; and from 0% to about 5% of Cr.A method of purifying a reactive gas and removing foreign impurities therefrom includes conducting the impurities containing reactive gas, such as chlorine, hydrogen chloride, silane and dichlorosilane, through a bed of the above described pulverized metal alloy and removing the impurities from the gas by chemisorption on the alloy.
摘要翻译：化学吸收金属合金包括约30重量％至约70重量％的Ti和/或Zr和约30重量％至约70重量％的Cu。任选地，合金还可以含有0重量％至约5重量％的Fe; 0％至约10％的Ni; 从0％到约5％的V; 和0％至约5％的Cr。一种纯化反应性气体并除去杂质的方法包括通过上述粉碎金属合金床将含有反应性气体如氯，氯化氢，硅烷和二氯硅烷的杂质导入，并通过化学吸附法从气体中除去杂质在合金上。

5. 发明授权

US4973227A Method of producing a vacuum 失效
标题翻译：制造真空的方法
公开(公告)号：US4973227A
公开(公告)日：1990-11-27
申请号：US367025
申请日：1989-06-16
申请人： Otto Bernauer , Clemens Halene , Manfred Keller
发明人： Otto Bernauer , Clemens Halene , Manfred Keller
IPC分类号： B01J3/00 , C01B3/00 , F04B37/02
CPC分类号： F04B37/02
摘要： A method of producing a vacuum in a volume of a hollow body which has at least one outlet opening for the gaseous atmosphere present therein, the method includes the following steps: introducing at least about 3 g/dm.sup.3 of evacuation volume of a metal hydride into the hollow body so as to take up less than about 5% of the volume 3. The metal hydride comprises a hydride forming alloy of the formulaTi(V.sub.1-a-b Fe.sub.a Al.sub.b).sub.xy Mn.sub.z,wherein1
摘要翻译：一种在具有至少一个气体气氛出口的中空体的体积中产生真空的方法，该方法包括以下步骤：将至少约3g / dm 3的金属氢化物排空体积引入空心体以便占据体积3的小于约5％。金属氢化物包括式Ti（V1-ab FeaAlb）xyMnz的氢化物形成合金，其中1 = = 0 0 z 。将金属氢化物加热到使氢化物中释放大量气态氢的温度，进行加热步骤，使中空体的加热温度不超过约500℃。用从氢化物释放的气态氢冲洗体积，从而在释放之前更换体积中存在的气体气氛; 关闭中空体的出口; 冷却空心体; 并用氢化物形成合金吸收气态氢。

6. 发明授权

US4330084A Method for operating a heating power plant and heating power plant for carrying out the method 失效
标题翻译：用于操作加热发电厂和加热发电厂以执行该方法的方法
公开(公告)号：US4330084A
公开(公告)日：1982-05-18
申请号：US8260
申请日：1979-02-01
申请人： Helmut Buchner , Otto Bernauer
发明人： Helmut Buchner , Otto Bernauer
IPC分类号： F02G5/04 , F01K3/00 , F01K27/02 , F02G5/02 , F25B17/12 , F24D1/00
CPC分类号： F01K27/02 , F01K3/00 , F02G5/02 , F25B17/12 , Y02B30/52 , Y02B30/625 , Y02E20/14 , Y02P80/15 , Y02T10/166
摘要： A heating power plant and a process for operating the power plant with the power plant containing a thermal power installation for producing mechanical motive energy for driving an energy supply device as well as waste heat which may be utlized for heating purposes in the power plant. The thermal power installation may be shut down or operated at slight partial loads during periods of low energy needs with hydrogen being introduced into a metal hydride storage device which is capable of absorbing hydrogen. At times of higher energy need the thermal power installation is kept in operation under greater load conditions and hydrogen is removed from a metal hydride storage device which is capable of releasing such hydrogen. The release enthalpy required for releasing the hydrogen is provided by waste heat from the thermal power installation or by ambient air.
摘要翻译：一个加热发电厂和一个使用发电厂运行发电厂的过程，该发电厂包含用于驱动能量供应装置的机械动力的火力发电装置，以及用于在发电厂中用于加热目的的废热。在能够吸收氢气的金属氢化物储存装置中引入氢气的时候，可以在低能量需求期间以轻微的部分负荷关闭或运行火力发电装置。在更高能量的时候，火力发电装置在更大的负载条件下保持运行，并且从能够释放这种氢的金属氢化物储存装置中除去氢。释放氢气所需的释放焓由来自火力发电设备的废热或环境空气提供。

7. 发明授权

US5080875A Process and apparatus for the purification of hydrogen gas 失效
标题翻译：用于净化氢气的方法和装置
公开(公告)号：US5080875A
公开(公告)日：1992-01-14
申请号：US473674
申请日：1990-02-01
申请人： Otto Bernauer
发明人： Otto Bernauer
IPC分类号： C01B3/00 , C01B3/50 , C01B3/56 , F17C11/00
CPC分类号： C01B3/0005 , C01B3/508 , Y02E60/321 , Y02E60/327
摘要： A process for the purification of contaminated hydrogen gas which involves, first, subjecting the hydrogen gas to a preliminary purification with a hydride-forming material which has a low hydrogen storage capacity to remove substantially all of the contaminants, followed by a primary purification of the hydrogen gas with a hydride-forming material which has a high hydrogen storage capacity, thereby extending the useful life of the hydride-forming material which has the high hydrogen storage capacity.
摘要翻译：一种用于净化污染氢气的方法，其中首先使用具有低储氢能力的氢化物形成材料对氢气进行初步纯化，以除去基本上所有的污染物，然后初步纯化具有氢存储能力高的氢化物形成材料的氢气，从而延长了具有高储氢能力的氢化物形成材料的使用寿命。

8. 发明授权

US4736779A Process and apparatus for using a hydride-forming alloy to store hydrogen 失效
标题翻译：使用氢化物形成合金来储存氢气的方法和装置
公开(公告)号：US4736779A
公开(公告)日：1988-04-12
申请号：US854529
申请日：1986-04-22
申请人： Otto Bernauer
发明人： Otto Bernauer
IPC分类号： C01B3/00 , C01B3/50 , F17C11/00 , B65B3/04
CPC分类号： F17C11/005 , C01B3/0005 , C01B3/508 , Y02E60/321 , Y02E60/327 , Y10S220/901
摘要： A process is provided for optimizing the storage capacity, based on weight, of a hydrogen storage device containing a hydride-forming alloy. A corresponding hydrogen storage device is also provided wherein the storage device is designed to operate under a pressure of 100 to 300 bars, and the weight of hydride-forming alloy contained within the device is about 0.8 to 2 kg of hydride-forming alloy per liter of internal volume. As an added benefit attendant this process and device, the hydrogen gas stored in the device is purified thereby.
摘要翻译：提供了一种基于重量来优化包含氢化物形成合金的储氢装置的存储容量的方法。还提供了相应的氢存储装置，其中存储装置设计成在100至300巴的压力下操作，并且装置内所含的氢化物形成合金的重量为每升约0.8至2kg氢化物形成合金的内部音量。作为该方法和装置的附加效益，由此净化存储在装置中的氢气。

9. 发明授权

US4717551A Titanium-based alloy used as a gettering material 失效
标题翻译：钛基合金用作吸气材料
公开(公告)号：US4717551A
公开(公告)日：1988-01-05
申请号：US751972
申请日：1985-07-05
申请人： Otto Bernauer , Klaus Ziegler
发明人： Otto Bernauer , Klaus Ziegler
IPC分类号： C22C27/02 , H01J7/18 , B01D53/34
CPC分类号： H01J7/183 , C22C27/02
摘要： The use of an alloy of the formulaTi(V.sub.l-a-b Fe.sub.a Al.sub.b).sub.x Cr.sub.y Mn.sub.zwherex=greater than 1. to 2y=0 to 0.2x+y=at most 2a=0 to 0.4b=0 to 0.2a+b=at most 0.5(l-a-b).x=at least 1Z=0 to (2-x-y)as a getter material. The alloy is distinguished by a low activation temperature, favorable mechanical properties and inexpensiveness.
摘要翻译：使用式Ti（VI-a-bFeaAlb）xCryMnz的合金，其中x =大于1至2 y = 0至0.2 x + y =至多2 a = 0至0.4 b = 0至0.2 a + b =至多0.5（实验室）.x =至少1 Z = 0至（2-xy）作为吸气剂材料。合金的特征在于活化温度低，机械性能好，成本低廉。

10. 发明授权

US4446101A Storage material for hydrogen 失效
标题翻译：储氢材料
公开(公告)号：US4446101A
公开(公告)日：1984-05-01
申请号：US426932
申请日：1982-09-29
申请人： Otto Bernauer , Klaus Ziegler
发明人： Otto Bernauer , Klaus Ziegler
IPC分类号： C01B3/00 , C22C30/00
CPC分类号： C01B3/0031 , Y02E60/327 , Y10S420/90
摘要： A storage material for hydrogen comprising an alloy with the following composition:______________________________________ Ti(V.sub.1-a-b Fe.sub.a Al.sub.b).sub.x Cr.sub.y Mn.sub.2-x-y, ______________________________________ wherein: x = greater than 1, less than 2 y = 0 to approximately 0.2 x + y = not greater than 2 a = 0 to approximately 0.25 b = 0 to approximately 0.33 a + b = not greater than approximately 0.35 (1 - a - b) .multidot. x = not less than 1 ______________________________________ This storage material for hydrogen can, in the cold state, absorb a maximum of 3.2% by weight of H.sub.2 and already possesses, at low temperatures, a high reaction speed for the absorption of hydrogen. During the absorption of hydrogen, the storage material exhibits self-heating to high temperatures. Thus, in addition to its use for storing hydrogen, it is also particularly suitable for use in preheating systems for hydride-type storage units of motor vehicles.
摘要翻译：用于氢的储存材料包括具有以下组成的合金：-Ti（V1-a-bFeaAlb）xCryMn2-xy，其中：-x =大于1，小于2 -y = 0至约0.2-x + y = 不大于2 -a = 0至约0.25 -b = 0至约0.33 -a + b =不大于约0.35 - （1-a-b）xx =不小于1 - 在冷态下，最多吸收3.2重量％的H 2，并且在低温下已经具有吸收氢的高反应速度。在吸收氢气的过程中，储存材料会自发加热到高温。因此，除了用于储存氢的用途之外，它还特别适用于机动车辆的氢化物型存储单元的预热系统。

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