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1. 发明授权

US08697757B2 Hydrophobic organic solvent-dispersed sol of anhydrous zinc antimonate colloidal particles and method for producing the same 有权
标题翻译：无水锑酸锌胶体颗粒的疏水性有机溶剂分散溶胶及其制备方法
公开(公告)号：US08697757B2
公开(公告)日：2014-04-15
申请号：US13054202
申请日：2009-07-16
申请人： Yoshinari Koyama , Tomonari Shinji , Osamu Fujimoto
发明人： Yoshinari Koyama , Tomonari Shinji , Osamu Fujimoto
IPC分类号： B01J13/00 , C09K5/00 , F21V9/06 , C08K3/22 , C09D1/00
CPC分类号： C01G30/02 , B01J13/003 , B01J13/0034 , B82Y30/00 , C01G33/00 , C01P2002/52 , C01P2004/62 , C01P2004/64 , C01P2006/22
摘要： A hydrophobic organic solvent-dispersed sol of anhydrous zinc antimonate colloidal particles and a method for producing the same. The hydrophobic organic solvent-dispersed sol includes surface-modified anhydrous zinc antimonate colloidal particles dispersed in a hydrophobic organic solvent having a water solubility of 0.002 to 12% by mass. The surface-modified anhydrous zinc antimonate colloidal particles are formed by: coating outer surfaces of anhydrous zinc antimonate colloidal particles (A) serving as cores with at least one substance (B) of colloidal particles of a composite oxide containing silica and stannic oxide or silica and antimony pentoxide at a silica/stannic oxide or silica/antimony pentoxide ratio of 0.1 to 10, an oligomer of the colloidal particles, or a mixture of the colloidal particles and the oligomer to form modified anhydrous zinc antimonate colloidal particles (C); and bonding an organosilicon compound and an amine compound to surfaces of the colloidal particles (C).
摘要翻译：无水锑酸锌胶体粒子的疏水性有机溶剂分散溶胶及其制造方法。疏水性有机溶剂分散溶胶包含分散在水溶性为0.002〜12质量％的疏水性有机溶剂中的表面改性无水锑酸锌胶体粒子。表面改性的无水锑酸锌胶体粒子通过以下方法形成：用至少一种含有二氧化硅和氧化锡或二氧化硅的复合氧化物的胶体粒子的物质（B）作为核心的无水锑酸锌胶体粒子（A）的外表面二氧化硅/氧化锡/二氧化硅/五氧化二锑比为0.1〜10的五氧化二锑，胶体粒子的低聚物或胶体粒子与低聚物的混合物形成改性的无水锑酸锌胶体粒子（C）。并将有机硅化合物和胺化合物键合到胶体粒子（C）的表面。

2. 发明申请

US20130143035A1 HYDROPHOBIC-ORGANIC-SOLVENT DISPERSION OF SURFACE-MODIFIED COLLOIDAL PARTICLES OF ANHYDROUS ZINC ANTIMONATE, COATING COMPOSITION CONTAINING THE SAME, AND COATED MEMBER 审中-公开
标题翻译：非离子型抗氧化剂表面改性胶体颗粒的疏水有机溶剂分散体，含有它们的涂料组合物和涂层组分
公开(公告)号：US20130143035A1
公开(公告)日：2013-06-06
申请号：US13817270
申请日：2011-08-25
申请人： Osamu Fujimoto , Tomonari Shinji , Yoshinari Koyama
发明人： Osamu Fujimoto , Tomonari Shinji , Yoshinari Koyama
IPC分类号： C09D7/12
CPC分类号： C09D7/67 , B82Y30/00 , C01G9/00 , C01G30/02 , C01P2004/62 , C01P2004/64 , C08L1/00 , C08L25/08 , C08L29/00 , C08L33/00 , C09D5/24 , C09D7/60 , C09D7/61 , C09D7/68 , Y10T428/256
摘要： There is provided a hydrophobic-organic-solvent dispersion containing colloidal particles of anhydrous zinc antimonate having high transparency which has not been attained hitherto, a coating composition containing the hydrophobic-organic-solvent dispersion and a member coated with the coating composition. A hydrophobic-organic-solvent dispersion comprising colloidal particles of anhydrous zinc antimonate having a primary particle diameter of 5 to 500 nm, which are surface-modified with azi alkylamine and a surfactant having an acid group is used. The surfactant has a carboxylic acid group, a sulfonic acid group, or a phosphoric acid group.
摘要翻译：提供了含有迄今为止尚未获得的具有高透明度的无水锑酸锌的胶体颗粒的疏水 - 有机 - 溶剂分散体，包含疏水 - 有机溶剂分散体的涂料组合物和涂覆有涂料组合物的构件。使用包含具有5〜500nm的一次粒径的无水锑酸锌的胶体粒子的疏水性有机溶剂分散体，其用氮杂烷基胺表面改性，并具有酸性基团的表面活性剂。表面活性剂具有羧酸基，磺酸基或磷酸基。

3. 发明申请

US20110114871A1 HYDROPHOBIC ORGANIC SOLVENT-DISPERSED SOL OF ANHYDROUS ZINC ANTIMONATE COLLOIDAL PARTICLES AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：非离子型锌离子型胶体颗粒的疏水性有机溶剂分散溶液及其制造方法
公开(公告)号：US20110114871A1
公开(公告)日：2011-05-19
申请号：US13054202
申请日：2009-07-16
申请人： Yoshinari Koyama , Tomonari Shinji , Osamu Fujimoto
发明人： Yoshinari Koyama , Tomonari Shinji , Osamu Fujimoto
IPC分类号： C09K5/00 , F21V9/06 , C09K3/00 , C09D1/00
CPC分类号： C01G30/02 , B01J13/003 , B01J13/0034 , B82Y30/00 , C01G33/00 , C01P2002/52 , C01P2004/62 , C01P2004/64 , C01P2006/22
摘要： There is provided a hydrophobic organic solvent-dispersed sol of anhydrous zinc antimonate colloidal particles and a method for producing the same. A hydrophobic organic solvent-dispersed sol of anhydrous zinc antimonate colloidal particles, wherein surface-modified anhydrous zinc antimonate colloidal particles are dispersed in a hydrophobic organic solvent having a water solubility of 0.002 to 12% by mass, the surface-modified anhydrous zinc antimonate colloidal particles being formed by coating outer surfaces of anhydrous zinc antimonate colloidal particles (A) serving as cores with at least one substance (B) of colloidal particles of a composite oxide containing silica and stannic oxide or silica and antimony pentoxide at a silica/stannic oxide or silica/antimony pentoxide mass ratio of 0.1 to 10, an oligomer of the colloidal particles, and a mixture of the colloidal particles and the oligomer to form modified anhydrous zinc antimonate colloidal particles (C), and by bonding an organosilicon compound and an amine compound to surfaces of the colloidal particles (C). A method for producing the hydrophobic organic solvent-dispersed sol.
摘要翻译：提供了无水锑酸锌胶体粒子的疏水性有机溶剂分散溶胶及其制造方法。将表面改性的无水锑酸锌胶体粒子分散在水溶性为0.002〜12质量％的疏水性有机溶剂中的无水锑酸锌胶体粒子的疏水性有机溶剂分散溶胶，表面改性无水锑酸锌胶体通过在二氧化硅/氧化锡上涂覆含有二氧化硅和氧化锡或二氧化硅和五氧化二锑的复合氧化物的至少一种物质（B）的作为芯的无水锑酸锌胶体粒子（A）的外表面形成的粒子或二氧化硅/五氧化二锑质量比为0.1〜10，胶体粒子的低聚物和胶体粒子与低聚物的混合物形成改性的无水锑酸锌胶体粒子（C），通过键合有机硅化合物和胺与胶体颗粒（C）的表面化合物。疏水性有机溶剂分散溶胶的制造方法。

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