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    • 5. 发明授权
    • Insecticides
    • 杀虫剂
    • US07812170B2
    • 2010-10-12
    • US10598041
    • 2005-03-02
    • David John HughesJames Edward PeaceSuzanna RileySally RussellJoseph John SwanboroughRoger Graham HallAndré JeanguenatOlivier LoiseleurPeter RenoldStephan TrahJean Wenger
    • David John HughesJames Edward PeaceSuzanna RileySally RussellJoseph John SwanboroughRoger Graham HallAndré JeanguenatOlivier LoiseleurPeter RenoldStephan TrahJean Wenger
    • C07D401/00
    • C07D401/04A01N37/46A01N43/40A01N43/56C07D401/14C07D405/14C07D409/14C07D413/14C07D417/14C07D491/04C07D493/08C07D495/04C07D513/04
    • Compounds of the formula (I) in which Z, is an oxygen atom; or a sulfur atom; Z2 is an oxygen atom; or a sulfur atom; R, is an aryl or heteroaryl group, which is unsubstituted or substituted; R2 is hydrogen; or an organic substituent; R3 is hydrogen; or an organic substituent; R4 is hydrogen; or an organic substituent; or R3 and R4, taken together, form, together with the nitrogen atom, to which they are attached, a ring, which is unsubstituted or substituted; R5 is hydrogen; or an unsubstituted or substituted alkyl group; or forms, taken together with R8 or with a monovalent substituent attached to that atom of R6, via which atom R6 is directly connected with the carbon atom, shown in the formula I, which carries R5, one additional bond; R6 and R7, taken together, form, together with the two carbon atoms, shown in the formula I, to which atoms they are attached, a bicyclic ring system, which ring system is carbocyclic or heterocyclic, which ring system is substituted, in the manner shown in the formula I, by the four substituents —N(R2)-C(═Z1)-R, —C(═Z2)-N(R3)-R4, R5 and R8, and which ring system is optionally further substituted; and R8 is hydrogen; or an unsubstituted or substituted alkyl group; or forms, taken together with R5 or with a monovalent substituent attached to that atom of R7, via which atom R7 is directly connected with the carbon atom, shown in the formula I, which carries R8, one additional bond, and, where appropriate, tautomers thereof, in each case in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.
    • 其中Z为氧原子的式(I)化合物; 或硫原子; Z2是氧原子; 或硫原子; R 1是未取代或取代的芳基或杂芳基; R2是氢; 或有机取代基; R3是氢; 或有机取代基; R4是氢; 或有机取代基; 或者R 3和R 4一起与它们所连接的氮原子一起形成未被取代或被取代的环, R5是氢; 或未取代或取代的烷基; 或其形式,与R8一起或与R6的该原子连接的一价取代基,其中原子R6直接与碳原子连接,如式I所示,其携带R5,另外一个键; R6和R7一起与式I中所示的两个碳原子一起形成,其中它们连接的原子是双环系统,该环系是碳环或杂环的,该环系被取代,在 式(I)所示的四种取代基-N(R 2)-C(= Z 1)-R,-C(= Z 2)-N(R 3)-R 4,R 5和R 8, 取代 R8是氢; 或未取代或取代的烷基; 或其形式与R5一起或与R7的原子连接的一价取代基,其中原子R7与碳原子直接连接,如式I所示,其携带R8,一个附加键,并且在适当的情况下, 互变异构体,以游离形式或盐形式,可以用作农业化学活性成分,并且可以以本身已知的方式制备。
    • 6. 发明授权
    • Pesticidal triazine-derivatives
    • 杀虫三嗪衍生物
    • US06723720B2
    • 2004-04-20
    • US10006954
    • 2001-11-05
    • Arthur SteigerWerner ZambachAndré JeanguenatMartin EberleStephan TrahSaleem Farooq
    • Arthur SteigerWerner ZambachAndré JeanguenatMartin EberleStephan TrahSaleem Farooq
    • C07D253065
    • A01N57/22A01N43/707C07D253/07
    • A compound of formula wherein R1 is unsubstituted or substituted aryl or heteroaryl, the substituents of the aryl and heteroaryl rings being selected, for example, from the group consisting of OH, halogen, CN, NO2, C1-C6alkyl, C3-C8cycloalkyl, C1-C6alkyl-C3-C8cycloalkyl, C3-C8cycloalkyl-C1-C6alkyl, C1-C6haloalkyl, C3-C8halocycloalkyl, C1-C6alkoxy and phenyl; phenoxy; phenylthio; phenylamino; and phenyl-(C1-C6alkyl)-amino; the substituents of the phenoxy, phenylthio, phenylamino and phenyl-(C1-C6alkyl)-amino groups being selected from the group consisting of halogen, CN, NO2, C1-C6alkyl, C3-C8cycloalkyl, C1-C6haloalkyl, C3-C8halocycloalkyl, C1-C6alkoxy, C3-C8cycloalkoxy, C1-C6alkylthio, C3-C8cycloalkylthio, C1-C6haloalkylthio and C3-C8halocycloalkylthio; R2 is, for example, H, OH, halogen, CN, NO2, C1-C6alkyl or C1-C6alkoxy; A is, for example, a single bond, C1-C12alkylene, O or O(C1-C12alkylene); R4 is H, C1-C6alkyl, C3-C8cycloalkyl, C1-C6haloalkyl, C1-C6alkoxy, N(R5)2 or C1-C6alkoxy-C2-C6alkyl; R5 is H, C1-C6alkyl, C3-C8cycloalkyl, C1-C6haloalkyl or aryl-C1-C6alkyl; X1 is R10; X2 and X3 are each independently of the other H or R10; R10 is, for example, halogen, CN, NO2, C1-C6alkyl or C3-C8cycloalkyl; and n is 0, 1 or 2, and to their physiologically tolerable and agrochemically acceptable addition compounds, and where appropriate to E/Z isomers, to mixtures of E/Z isomers and/or to tautomers, in each case in free form or in salt form. The compounds, in free form or in agrochemically acceptable salt form, exhibit advantageous pesticidal properties. They are suitable especially in the control of pests in agriculture and stored goods and also in the keeping of domestic animals.
    • 化合物R1是未取代或取代的芳基或杂芳基,芳基和杂芳基环的取代基选自例如由OH,卤素,CN,NO 2,C 1 -C 6烷基,C 3 -C 8环烷基,C 1 -C 6烷基 - C 3 -C 8环烷基,C 3 -C 8环烷基-C 1 -C 6烷基,C 1 -C 6卤代烷基,C 3 -C 8卤代环烷基,C 1 -C 6烷氧基和苯基; 苯氧基 苯硫基 苯基氨基; 苯基 - (C 1 -C 6烷基) - 氨基;苯氧基,苯硫基,苯基氨基和苯基 - (C 1 -C 6烷基) - 氨基的取代基选自卤素,CN,NO 2,C 1 -C 6烷基, C 3 -C 8卤代烷基,C 1 -C 6卤代烷基,C 3 -C 8卤代环烷基,C 1 -C 6烷氧基,C 3 -C 8环烷氧基,C 1 -C 6烷硫基,C 3 -C 8环烷硫基,C 1 -C 6卤代烷硫基和C 3 -C 8卤代环烷硫基; R 2为例如H,OH,卤素,CN, C1-C6烷基或C1-C6烷氧基; A是例如单键,C1-C12亚烷基,O或O(C1-C12亚烷基); R4是H,C1-C6烷基,C3-C8环烷基,C1-C6卤代烷基,C1-C6烷氧基 ,N(R 5)2或C 1 -C 6烷氧基-C 2 -C 6烷基; R 5是H,C 1 -C 6烷基,C 3 -C 8环烷基,C 1 -C 6卤代烷基或芳基-C 1 -C 6烷基; X 1是R 10; X 2和X 3各自独立地为H或R 10; R 10为例如卤素,CN,NO 2,C 1 -C 6烷基或C 3 -C 8环烷基; 和n为0,1或2,以及其生理上可耐受和农业化学上可接受的加成化合物,以及适用于E / Z异构体的E / Z异构体和/或互变异构体的混合物,在每种情况下为游离形式或 游离形式或农业化学上可接受的盐形式的化合物表现出有利的杀虫性质。 它们特别适用于控制农业和储存物中的害虫以及保存家畜。
    • 8. 发明授权
    • N-substituted tetrahydropyridines and their use as pesticides
    • N-取代四氢吡啶类及其作为农药的用途
    • US06953811B2
    • 2005-10-11
    • US10470790
    • 2002-02-04
    • Stephan TrahJosef EhrenfreundPeter MaienfischAndré JeanguenatSaleem Farooq
    • Stephan TrahJosef EhrenfreundPeter MaienfischAndré JeanguenatSaleem Farooq
    • A01N43/40C07D211/70C07D211/94C07D401/06
    • C07D401/06C07D211/70C07D211/94
    • A description is given of compounds of the formula in which R1 and R2 independently of one another are halogen, C1-C6alkyl, halo-C1-C6alkyl, C1-C6alkoxy, halo-C1-C6alkoxy, or SF5, R3 is hydrogen, OH, halogen, C1-C6alkoxy or —O—C(═O)—C1-C6alkyl, R4 is for example hydrogen, halogen, C1-C6alkyl, halo-C1-C6alkyl, C1-C6alkoxy, halo-C1-C6alkoxy or SCN; R5 and R6 independently of one another are for example hydrogen, C1-C12alkyl, halo-C1-C12alkyl, C2-C12alkenyl, halo-C2-C12alkenyl or C2-C12alkynyl; and q is 0 or 1; and, where appropriate, E/Z isomers, E/Z isomer mixtures and/or tautomers, each in free form or in salt form; a process for the preparation of these compounds and their use, pesticide compositions whose active ingredient is selected from these compounds, or an agrochemically useable salt thereof, a process for preparing these compositions, and their use, plant propagation material treated with these compositions, and a method of combating pests.
    • 给出下式的化合物,其中R 1和R 2彼此独立地是卤素,C 1 -C 3 C 6 -C 6烷基,卤代C 1 -C 6烷基,C 1 -C 6烷基,C 1 -C 6烷基,C 1 -C 6烷基, 烷氧基,卤代-C 1 -C 6烷氧基或SF 5,R 3是氢,OH, 卤素,C 1 -C 6烷氧基或-OC(-O)-C 1 -C 6 -C 6烷基 R 4是例如氢,卤素,C 1 -C 6烷基,卤代C 1 -C 4烷基, C 1 -C 6烷基,C 1 -C 6烷氧基,卤代C 1 -C 6烷基,C 1 -C 6烷氧基,C 1 -C 6烷基, 烷氧基或SCN; R 5和R 6彼此独立地是例如氢,C 1 -C 12 - 烷基,卤代 C 1 -C 12烷基,C 2 -C 12链烯基,卤代-C 2烷基,C 1 -C 12烷基,C 2 -C 12 - C 12 -C 12链烯基或C 2 -C 12 - 炔基; q为0或1; 和/或互变异构体,各自为游离形式或盐形式的E / Z异构体,E / Z异构体混合物和/或互变异构体; 制备这些化合物及其用途的方法,其活性成分选自这些化合物的农药组合物或其农业上可用的盐,这些组合物的制备方法及其用途,用这些组合物处理的植物繁殖材料,以及 一种防治害虫的方法。