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    • 3. 发明授权
    • Rubber compositions comprising organosilicon coupling agents and inorganic fillers
    • 包含有机硅偶联剂和无机填料的橡胶组合物
    • US08524823B2
    • 2013-09-03
    • US11921013
    • 2006-05-19
    • Laurent GuyMichel FernandezSébastien Sterin
    • Laurent GuyMichel FernandezSébastien Sterin
    • C08K3/36
    • C08F290/148C08F290/00C08L51/08C08L51/10
    • Elastomeric isoprene rubber compositions contain an effective amount of a coupling agent (A) comprising an organosilicon compound with coupling agent functions for inorganic/elastomeric fillers and include (B) at least one natural or synthetic rubber elastomer, (C) an inorganic filler as reinforcement filler, (D) other conventional constituents or additives comprising vulcanization agents; the coupling agent (A) being a functionalized organosilicon compound, including the following two compounds (i) and (2i), (i) being at least one functionalized siloxane corresponding to the formula (I): [(G0)3SiO1/2]m [(G0)2SiO2/2]n [G0SiO3/2]o [SiO4/2]p [(G2)a(G1)a′(Z—CO—N═N—CO-A)SiO(3-a-a′)/2]q and (2i) being a mixture of at least one functionalized siloxane (i) with (3i) at least one functionalized organosilane also corresponding to formula (I) where m=n=o=p=0 (zero), q=1, a=0, 1, 2 or 3 and the sum a+a′=3.
    • 弹性异戊二烯橡胶组合物包含有效量的偶联剂(A),其包含具有偶合剂功能的有机硅化合物,用于无机/弹性体填料,并且包括(B)至少一种天然或合成橡胶弹性体,(C)无机填料作为增强剂 填料,(D)其它常规组分或包含硫化剂的添加剂; 偶联剂(A)是官能化的有机硅化合物,包括以下两种化合物(i)和(2i),(i)是至少一种对应于式(I)的官能化硅氧烷:[(G0)3SiO1 / 2] m [(G0)2SiO2 / 2] n [G0SiO3 / 2] o [SiO4 / 2] p [(G2)a(G1)a'(Z-CO-N = N-CO-A) -a')/ 2] q和(2i)是至少一种官能化硅氧烷(i)与(3i)至少一种也对应于式(I)的官能化有机硅烷的混合物,其中m = n = o = p = 0 (零),q = 1,a = 0,1,2或3,和a + a'= 3。
    • 7. 发明授权
    • Rubber compositions comprising coupling agents and coating agents and also inorganic fillers
    • 包含偶联剂和包衣剂以及无机填料的橡胶组合物
    • US08530562B2
    • 2013-09-10
    • US11921011
    • 2006-05-19
    • Laurent GuyMichel FernandezSébastien Sterin
    • Laurent GuyMichel FernandezSébastien Sterin
    • C08K3/36
    • C08K5/5455C08K5/5465C08K5/548C08L21/00
    • Elastomeric isoprene rubber compositions contain an effective amount of a coupling system (A) as an inorganic filler/elastomer coupling agent, and (B) at least one natural or synthetic rubber elastomer, (C) an inorganic filler as reinforcing filler, (D) other conventional constituents or additives comprising (a) vulcanization agent(s), the coupling system (A) being a particular mixture of the following combination of constituents (A1) and (A2): (A1) is at least one coupling agent selected from among the following functionalized organosilicon compounds of formula (I):[(G0)3SiO1/2]m[(G0)2SiO2/2]n[G0SiO3/2]o[SiO4/2]p[(G2)a(G1)a′(Z—CO—N═N—CO-A)SiO(3-a-a′)/2]g and (A2) is at least one coating agent for the reinforcing filler including one compound with the single function Y in the structure thereof which is capable of bonding physically and chemically to the inorganic filler and resulting in an increase in dispersion of the charge within the rubber matrix and a reduction in viscosity of the composition.
    • 弹性异戊二烯橡胶组合物含有有效量的作为无机填料/弹性体偶联剂的偶联体系(A),和(B)至少一种天然或合成橡胶弹性体,(C)作为增强填料的无机填料,(D) 其它常规成分或添加剂包括(a)硫化剂,偶联体系(A)是组分(A1)和(A2)的以下组合的特定混合物:(A1)是至少一种选自 在以下式(I)的官能化有机硅化合物中:[(G0)3SiO1 / 2] m [(G0)2SiO2 / 2] n [G0SiO3 / 2] o [SiO4 / 2] p [(G2) a'(Z-CO-N = N-CO-A)SiO(3-a-a')/ 2] g和(A2)是至少一种用于增强填料的涂料,其包括一种单一官能化合物Y 在其结构中能够物理和化学地与无机填料结合,并导致电荷在橡胶基质内的分散性增加,并且粘度降低 组成。