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    • 3. 发明申请
    • Composition capable of free radical polymerization resulting in shockproof organic glass materials
    • 能够进行自由基聚合的组合物,从而产生防震有机玻璃材料
    • US20050107537A1
    • 2005-05-19
    • US10496743
    • 2002-11-26
    • Gilles RichardOdile PrimelLeanirith Yean
    • Gilles RichardOdile PrimelLeanirith Yean
    • G02C7/02C08F290/06G02B1/04C08L33/02
    • C08F290/061C08F290/06C08F290/062
    • A radically polymerizable composition comprising: a first component A comprising at least an oligomer having at least two radically polymerizable functions and the homopolymer of which has a glass transition temperature (Tg) lower than 50° C., such a component being able to result through polymerization in a (co)polymer having a glass transition temperature (Tg) equal to or lower than 50° C., preferably equal to or lower than 0° C. and more preferably ranging from −50° C. to −10C, said oligomer accounting for more than 15%, preferably at least 20% of the total weight of the polymerizable monomers present in the composition; and a second component B comprising at least a (meth)acrylic monomer having at least one H link promoting group, such a (meth)acrylic monomer accounting for at least 15% of the total weight of the polymerizable monomers and oligomers present in the composition when such a monomer is a methacrylic monomer and at least 35% of the total weight of such polymerizable monomers and oligomers present in the composition when such a monomer is an acrylic monomer.
    • 一种可自由基聚合的组合物,其包含:第一组分A,其包含至少一种具有至少两个可自由基聚合的功能的低聚物,其均聚物的玻璃化转变温度(T g)低于50℃, 这种组分能够通过在等于或低于50℃,优选等于或低于0℃的玻璃化转变温度(T℃)的(共)聚合物中聚合而得到。 更优选为-50℃至-10℃,所述低聚物占组合物中存在的可聚合单体的总重量的15重量%,优选至少20重量%。 和包含至少一种具有至少一个H链段促进基团的(甲基)丙烯酸单体的第二组分B,所述(甲基)丙烯酸单体占组合物中存在的可聚合单体和低聚物的总重量的至少15% 当这样的单体是甲基丙烯酸单体时,当这种单体是丙烯酸单体时,组合物中存在的这些可聚合单体和低聚物的总重量的至少35%。
    • 6. 发明授权
    • Radically polymerizable composition resulting in shock resistant organic lenses
    • 可自由基聚合的组合物产生抗冲击有机透镜
    • US07393880B2
    • 2008-07-01
    • US10496743
    • 2002-11-26
    • Gilles RichardOdile PrimelLeanirith Yean
    • Gilles RichardOdile PrimelLeanirith Yean
    • C08F2/46C08F2/50
    • C08F290/061C08F290/06C08F290/062
    • A radically polymerizable composition comprising: a first component A comprising at least an oligomer having at least two radically polymerizable functions and the homopolymer of which has a glass transition temperature (Tg) lower than 50° C., such a component being able to result through polymerization in a (co)polymer having a glass transition temperature (Tg) equal to or lower than 50° C., preferably equal to or lower than 0° C. and more preferably ranging from −50° C. to −10 C., said oligomer accounting for more than 15%, preferably at least 20% of the total weight of the polymerizable monomers present in the composition; and a second component B comprising at least a (meth)acrylic monomer having at least one H link promoting group, such a (meth)acrylic monomer accounting for at least 15% of the total weight of the polymerizable monomers and oligomers present in the composition when such a monomer is a methacrylic monomer and at least 35% of the total weight of such polymerizable monomers and oligomers present in the composition when such a monomer is an acrylic monomer.
    • 一种可自由基聚合的组合物,其包含:第一组分A,其包含至少一种具有至少两个可自由基聚合的功能的低聚物,其均聚物的玻璃化转变温度(T g)低于50℃, 这种组分能够通过在等于或低于50℃,优选等于或低于0℃的玻璃化转变温度(T℃)的(共)聚合物中聚合而得到。 更优选为-50℃至-10℃,所述低聚物占组合物中存在的可聚合单体的总重量的15重量%,优选至少20重量%。 和包含至少一种具有至少一个H链段促进基团的(甲基)丙烯酸单体的第二组分B,所述(甲基)丙烯酸单体占组合物中存在的可聚合单体和低聚物的总重量的至少15% 当这样的单体是甲基丙烯酸单体时,当这种单体是丙烯酸单体时,组合物中存在的这些可聚合单体和低聚物的总重量的至少35%。