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    • 2. 发明申请
    • Organophotoreceptor with charge transport material having fluorenone hydrazone groups
    • 具有芴酮腙基团的电荷传输材料的有机光感受器
    • US20050069794A1
    • 2005-03-31
    • US10671172
    • 2003-09-25
    • Nusrallah JubranZbigniew TokarskiKam Law
    • Nusrallah JubranZbigniew TokarskiKam Law
    • C07C251/84C07C317/22C07C327/26C07C327/30C07D285/12C07D285/125G03G5/06G03G9/12G03G5/05
    • G03G5/0616C07C251/84C07C317/22C07C327/26C07C2603/18C07D285/125G03G5/0603G03G5/0607G03G5/0609G03G5/0614G03G5/0618G03G5/062G03G5/0633
    • Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where n is an integer between 2 and 6, inclusive; R1 and R2 are, independently, an alkyl group, an alkaryl group, or an aryl group with the proviso that neither R1 nor R2 is a naphthyl group, a stilbenyl group, alkylsulfonylphenyl group or a (9H-fluoren-9-ylidene)benzyl group; R3 and R4 are, independently, H, halogen, carboxyl, hydroxyl, thiol, cyano, nitro, aldehyde group, ketone group, an ether group, an ester group, a carbonyl group, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups can be optionally replaced by O, S, C═O, O=S=O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR5 group, a CHR6 group, or a CR7R8 group where R5, R6, R7, and R8 are, independently, H, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; and Y comprises a bond, C, N, O, S, a branched or linear —(CH2)p— group where p is an integer between 0 and 10, an aromatic group, a cycloalkyl group, a heterocyclic group, or a NR9 group where R9 is hydrogen atom, an alkyl group, or aryl group, wherein Y has a structure selected to form n bonds with the corresponding X groups; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
    • 改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件,光电导元件包括:(a)具有下式的电荷传输材料,其中n是2和6之间的整数,包括端值; R1和R2独立地是烷基,烷芳基或芳基,条件是R1和R2都不是萘基,茋基,烷基磺酰基苯基或(9H-芴-9-亚基)苄基 组; R 3和R 4独立地是H,卤素,羧基,羟基,硫醇,氰基,硝基,醛基,酮基,醚基,酯基,羰基,烷基,烷芳基或芳基 组; X是具有式 - (CH2)m-,分支或直链的连接基团,其中m是0和20之间的整数,包括1和20个,并且一个或多个亚甲基可以任选地被O,S,C = O,O = S = O,杂环基,芳基,氨基甲酸酯,脲,酯基,NR5基,CHR6基或CR7R8基,其中R5,R6,R7和R8独立地为H ,烷基,烷芳基,杂环基或芳基; 并且Y包含键,C,N,O,S,支链或线性 - (CH 2)p基团,其中p是0和10之间的整数,芳族基团,环烷基,杂环基或NR 9 基团,其中R9是氢原子,烷基或芳基,其中Y具有选择与相应的X基团形成n键的结构; 和(b)电荷产生化合物。 描述相应的电子照相设备和成像方法。
    • 3. 发明申请
    • Organophotoreceptor with charge transport material with fluorenone azine groups
    • US20050069793A1
    • 2005-03-31
    • US10670483
    • 2003-09-25
    • Nusrallah JubranZbigniew TokarskiKam Law
    • Nusrallah JubranZbigniew TokarskiKam Law
    • C07C251/88C07C327/26G03G5/06G03G9/12G03G5/05C07C251/54
    • G03G5/0633G03G5/0616G03G5/0618G03G5/062
    • Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where n is an integer between 2 and 6, inclusive; R1 and R2 are, independently, H, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; R3 and R4 are, independently, H, halogen, carboxyl, hydroxyl, thiol, cyano, nitro, aldehyde group, ketone group, an ether group, an ester group, a carbonyl group, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups can be optionally replaced by O, S, C═O, O═S═O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR5 group, a CHR6 group, or a CR7R8 group where R5, R6, R7, and R8 are, independently, H, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; and Y is a bond, C, N, O, S, a branched or linear —(CH2)p— group where p is an integer between 0 and 10 and where one or more of the hydrogen atoms in the —(CH2)p— may be optionally removed to provide bond positions to enable n to have a higher value than 2, an aromatic group, a cycloalkyl group, a heterocyclic group, or a NR9 group where R9 is hydrogen atom, an alkyl group, or aryl group Y comprises a bond, C, N, O, S, a branched or linear —(CH2)p— group where p is an integer between 0 and 10, an aromatic group, a cycloalkyl group, a heterocyclic group, or a NR9 group where R9 is hydrogen atom, an alkyl group, or aryl group, wherein Y has a structure selected to form n bonds with the corresponding X groups; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
    • 4. 发明申请
    • Electrophotographic organophotoreceptors with novel charge transport materials
    • 具有新型电荷传输材料的电子照相有机光感受器
    • US20050058917A1
    • 2005-03-17
    • US10982320
    • 2004-11-04
    • Kam LawNusrallah JubranZbigniew Tokarski
    • Kam LawNusrallah JubranZbigniew Tokarski
    • C07D209/86C07D403/12C07D403/14C07D409/14G03G5/047G03G5/06
    • C07D403/14C07D209/86C07D403/12C07D409/14G03G5/047G03G5/0616G03G5/0629G03G5/0642G03G5/0648G03G5/0651G03G5/0661
    • An organophotoreceptor that includes: (a) a charge transport compound having the formula where n is an integer between 2 and 6, inclusive; R1 is an aryl group; R2 is a sulfolanyl group; a pyrrolyl group; a tetrazolyl group; a benzotriazolyl group; a 4-(9H-fluoren-9-ylidene)benzyl group; a stilbenyl group; an alkylsulfonylphenyl group, an arylsulfonylphenyl; or a pyrazolyl group, with the proviso that when R2 is an alkylsulfonylphenyl group or an arylsulfonylphenyl, R1 may be hydrogen, an alkyl group, or an aryl group; X is an alkylene linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 0 and 20, inclusive; and Y is a bond, C, N, O, S, a branched or linear —(CH2)p— group where p is an integer between 0 and 10, an aryl group, a cycloalkyl group, a cyclosiloxyl, a heterocyclic group, or a CR7 group where R7 is H, an alkyl group, or aryl group; (b) a charge generating compound; and (c) an electrically conductive substrate.
    • 一种有机光感受器,其包括:(a)具有下式的电荷传输化合物,其中n是2和6之间的整数,包括端值在内; R1是芳基; R2是环丁砜基; 吡咯基; 四唑基; 苯并三唑基; 4-(9H-芴-9-亚基)苄基; 茋基; 烷基磺酰基苯基,芳基磺酰基苯基; 或吡唑基,条件是当R 2是烷基磺酰基苯基或芳基磺酰基苯基时,R 1可以是氢,烷基或芳基; X是具有式 - (CH2)m-,分支或直链的亚烷基连接基团,其中m是0和20之间的整数,包括0和20; 并且Y是键,C,N,O,S,分支或线性 - (CH 2)p - 基团,其中p是0和10之间的整数,芳基,环烷基,环甲硅烷氧基,杂环基, 或R 7为H,烷基或芳基的CR 7基团; (b)电荷产生化合物; 和(c)导电基板。
    • 7. 发明申请
    • Organophotoreceptor with a hydrazone polymer charge transport material
    • 有机光感受器与腙聚合物电荷传输材料
    • US20050089783A1
    • 2005-04-28
    • US10695044
    • 2003-10-28
    • Zbigniew TokarskiNusrallah JubranKam Law
    • Zbigniew TokarskiNusrallah JubranKam Law
    • C07D209/86G03G5/05G03G5/06
    • C07D209/86G03G5/0603G03G5/0607G03G5/0614G03G5/0616G03G5/0618G03G5/062G03G5/0625G03G5/0629
    • An organophotoreceptor comprises an electrically conductive substrate and photoconductive element on the electrically conductive substrate, the photoconductive element having a) a charge transport material with the formula where X is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups is optionally replaced by O, S, C═O, O═S═O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R5, and R6 are, independently, H, hydroxyl group, thiol group, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; R1 and R2 are independently a hydrogen, a halogen, an alkyl group, an aryl group, an alkaryl group, an aromatic group or a heterocyclic group; Y is an aromatic group; and n is a distribution of integer values greater than 2; and (b) a charge generating compound. The charge transport material can be crosslinked with a polymer binder either directly or through a crosslinking agent.
    • 有机光感受器包括导电衬底上的导电衬底和光电导元件,光电导元件具有a)具有下式的电荷传输材料,其中X是具有下式的连接基团 - (CH 2 CH 2) 其中m是0至20的整数,包括端值,并且一个或多个亚甲基任选被O,S,CO,OSO,杂环基取代, 芳族基团,氨基甲酸酯,尿素,酯基,NR 3基团,CHR 4 N基团或CR 5 R 其中R 3,R 4,R 5和R 6均为, 独立地是H,羟基,硫醇基,烷基,烷芳基,杂环基或芳基; R 1和R 2分别独立地为氢,卤素,烷基,芳基,烷芳基,芳族基或杂环基; Y是芳族基团; 并且n是大于2的整数值的分布; 和(b)电荷产生化合物。 电荷输送材料可以直接或通过交联剂与聚合物粘合剂交联。
    • 8. 发明申请
    • Organophotoreceptor with charge transport material having bis(9-fluorenone) azine groups
    • 具有双(9-芴酮)吖嗪基的电荷传输材料的有机光感受器
    • US20050069795A1
    • 2005-03-31
    • US10671255
    • 2003-09-25
    • Nusrallah JubranZbigniew TokarskiKam Law
    • Nusrallah JubranZbigniew TokarskiKam Law
    • C07C251/20C07C251/88C07C317/22C07C327/16C07C327/30C07D285/125G03G5/06G03G15/06C07C251/84G03G9/08
    • G03G5/0633C07D285/125G03G5/0616G03G5/0618G03G5/062
    • Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where n is an integer between 2 and 6, inclusive; R1 and R2 are, independently, H, halogen, carboxyl, hydroxyl, thiol, cyano, nitro, aldehyde group, ketone group, an ether group, an ester group, a carbonyl group, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups can be optionally replaced by O, S, C═O, O═S═O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R5, and R6 are, independently, H, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; Y comprises a bond, C, N, O, S, a branched or linear —(CH2)p— group where p is an integer between 0 and 10, an aromatic group, a cycloalkyl group, a heterocyclic group, or a NR9 group where R9 is hydrogen atom, an alkyl group, or aryl group, wherein Y has a structure selected to form n bonds with the corresponding X groups; and Z is a fluorenylidene group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
    • 改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件,光电导元件包括:(a)具有下式的电荷传输材料,其中n是2和6之间的整数,包括端值; R 1和R 2独立地是H,卤素,羧基,羟基,硫醇,氰基,硝基,醛基,酮基,醚基,酯基,羰基,烷基,烷芳基或芳基 组; X是具有式 - (CH2)m-,分支或直链的连接基团,其中m是0和20之间的整数,包括1和20个,并且一个或多个亚甲基可以任选地被O,S,C = O,O = S = O,杂环基,芳基,氨基甲酸酯,脲,酯基,NR 3基,CHR 4基或CR 5 R 6基,其中R 3,R 4,R 5和R 6独立地为H ,烷基,烷芳基,杂环基或芳基; Y包括键,C,N,O,S,分支或线性 - (CH 2)p基团,其中p是0和10之间的整数,芳族基团,环烷基,杂环基或NR 9基团 其中R9是氢原子,烷基或芳基,其中Y具有选择与相应X基团形成n键的结构; Z为亚芴基; 和(b)电荷产生化合物。 描述相应的电子照相设备和成像方法。
    • 10. 发明申请
    • Sulfonyldiphenylene based charge transport compositions
    • 基于磺酰基二亚苯基的电荷输送组合物
    • US20050123848A1
    • 2005-06-09
    • US10954454
    • 2004-09-30
    • Kam LawNusrallah JubranZbigniew Tokarski
    • Kam LawNusrallah JubranZbigniew Tokarski
    • G03G5/06C07C317/36G03G15/10
    • C07C317/36C07C2603/18G03G5/0605G03G5/0607G03G5/0612G03G5/0614G03G5/0616
    • This invention relates to a novel electrophotographic imaging process that includes: (a) applying an electrical charge to a surface of an organophotoreceptor comprising: (i) a charge transport composition comprising molecules having the formula where the average n is between 1 and 1000; R1 and R2 are, independently, hydrogen, alkyl, unsaturated hydrocarbon, ether, cycloalkyl, or aryl; X is a bis(fluorene-4-carboxyl)alkane group; Y is a sulfonyldiphenylene; Z is X=O or two hydrogens; and Q is O or N—N(R1)—Y—N(R2)—NH2; (ii) a charge generating compound; and (iii) an electrically conductive substrate over which said charge transport composition and said charge generating compound are located; (b) imagewise exposing said surface of said organophotoreceptor to radiation to dissipate charge in selected areas and thereby form a pattern of charged and uncharged areas on said surface; (c) contacting said surface with a toner to create a toned image; and (d) transferring said toned image to a substrate.
    • 本发明涉及一种新颖的电子照相成像方法,其包括:(a)将电荷施加到有机光感受器的表面,包括:(i)电荷传输组合物,其包含具有下式的分子,其中平均n在1和1000之间; R 1和R 2分别独立地为氢,烷基,不饱和烃,醚,环烷基或芳基; X是双(芴-4-羧基)烷烃基团; Y是磺酰基二亚苯基; Z是X = O或两个氢; 并且Q是O或N-N(R 1 H 2)-Y-N(R 2 H 2)-NH 2; (ii)电荷产生化合物; 和(iii)所述电荷输送组合物和所述电荷产生化合物所在的导电基底; (b)将所述有机光感受器的所述表面成像曝光于辐射以在选定区域中散发电荷,从而在所述表面上形成带电和不带电区域的图案; (c)使所述表面与调色剂接触以产生调色图像; 和(d)将所述调色图像转印到基底上。