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1. 发明授权

US07838587B2 Polymer materials containing dispersed carbon nanotubes 失效
标题翻译：含有分散碳纳米管的聚合物材料
公开(公告)号：US07838587B2
公开(公告)日：2010-11-23
申请号：US11910565
申请日：2006-03-31
申请人： Nour Eddine El Bounia , Ludwik Leibler , Sylvie Tence-Girault , Corinne Soulie-Ziakovic
发明人： Nour Eddine El Bounia , Ludwik Leibler , Sylvie Tence-Girault , Corinne Soulie-Ziakovic
IPC分类号： B60C1/00 , B29C47/00 , B32B3/10 , G11B5/64 , H01B1/00 , H01B1/06 , B32B27/00 , B29D22/00
CPC分类号： C08L51/003 , C08L53/00 , Y10T428/1352 , Y10T428/139 , Y10T428/24322 , Y10T428/24355 , Y10T428/3154 , C08L2666/04 , C08L2666/02
摘要： The invention relates to a polymer material comprising 99 to 20 parts by weight of polymer(s), 0.1 to 80 parts by weight of carbon nanotubes, and 0.05 to 80 parts by weight of at least one type of dispersant selected from A-B-C, B-C and/or C-B-C block copolymers, wherein each block is bonded to the other by means of a covalent bond, C is a chemical and/or physical interaction with the polymer material and in preferably is miscible therwith, B is not miscible with the polymer material and with the block B and the glass transition temperature thereof. Tg is less than the polymer material use temperature, A is not miscible with the polymer material and with the blocks B and the block C and the Tg or the fusion temperature Tf is greater than the Tg of B.
摘要翻译：本发明涉及一种包含99至20重量份聚合物，0.1-80重量份碳纳米管和0.05-80重量份选自ABC，BC和 /或CBC嵌段共聚物，其中每个嵌段通过共价键结合到另一个嵌段，C是与聚合物材料的化学和/或物理相互作用，并且优选是可混溶的，B不与聚合物材料混溶，具有块B及其玻璃化转变温度。 Tg小于聚合物材料的使用温度，A与聚合物材料和块B和块C不混溶，Tg或熔融温度Tf大于B的Tg。

2. 发明申请

US20070123694A1 Supramolecular polymers 有权
标题翻译：超分子聚合物
公开(公告)号：US20070123694A1
公开(公告)日：2007-05-31
申请号：US11598931
申请日：2006-11-14
申请人： Francois-Genes Tournilhac , Corinne Soulie-Ziakovic , Ludwik Leibler , Laurent Lachaize
发明人： Francois-Genes Tournilhac , Corinne Soulie-Ziakovic , Ludwik Leibler , Laurent Lachaize
IPC分类号： C08G73/00
CPC分类号： C08G61/123 , C08F8/30 , C08F8/34 , C08G73/028 , C08K5/0025 , C08L65/00 , C08L79/02
摘要： The invention relates to a supramolecular polymer containing units which are linked by hydrogen bonds, said units being monomers of prepolymers comprising at least one functional group selected from the functional groups (1) and (3) and a second functional group (5) wherein A denotes oxygen, sulphur or NH and X is any unit; the hydrogen bonds in the supramolecular polymer being formed between two identical or different functional groups chosen from the functional groups (1) to (5). The inventive polymers can be used alone, i.e. in the form of a composition which is essentially made from said polymers and, optionally, stabilizers, antioxidants, etc. or in the form of a mixture with other polymers or other products.
摘要翻译：本发明涉及含有通过氢键连接的单元的超分子聚合物，所述单元是包含至少一种选自官能团（1）和（3）的官能团和第二官能团（5）的预聚物的单体，其中A 表示氧，硫或NH，X是任何单元; 超分子聚合物中的氢键形成在选自官能团（1）至（5）的两个相同或不同的官能团之间。本发明的聚合物可以单独使用，即以基本上由所述聚合物和任选的稳定剂，抗氧化剂等制成或与其它聚合物或其它产品混合形式的组合物的形式使用。

3. 发明申请

US20050148760A1 Supramolecular polymers 有权
标题翻译：超分子聚合物
公开(公告)号：US20050148760A1
公开(公告)日：2005-07-07
申请号：US10503610
申请日：2003-01-15
申请人： Francois-Genes Tournilhac , Corinne Soulie-Ziakovic , Ludwik Leibler , Laurent Lachaize
发明人： Francois-Genes Tournilhac , Corinne Soulie-Ziakovic , Ludwik Leibler , Laurent Lachaize
IPC分类号： C10M149/22 , C08F8/30 , C08F8/34 , C08G61/12 , C08G73/00 , C08G73/02 , C08K5/00 , C08L65/00 , C08L79/02 , C09D5/03 , C09D7/12 , C09D163/00 , C09D179/04 , C09D187/00 , C09J11/08 , C09J179/04 , C10M151/04 , C08L77/00
CPC分类号： C08G61/123 , C08F8/30 , C08F8/34 , C08G73/028 , C08K5/0025 , C08L65/00 , C08L79/02
摘要： The invention relates to a supramolecular polymer containing units which are linked by hydrogen bonds, said units being monomers of prepolymers comprising at least one functional group selected from the functional groups (1) and (3) and a second functional group chosen from functional groups (1) to (5) wherein A denotes oxygen, sulphur or NH and X is any unit; the hydrogen bonds in the supramolecular polymer being formed between two identical or different functional groups chosen from the functional groups (1) to (5). The inventive polymers can be used alone, i.e. in the form of a composiiotn which is essentially made from said polymers and, optionally, stabilizers, antioxidants, etc. or in the form of a mixture with other polymers or other products.
摘要翻译：本发明涉及含有通过氢键连接的单元的超分子聚合物，所述单元是包含至少一个选自官能团（1）和（3）的官能团的预聚物的单体和选自官能团的第二官能团（ 1）至（5）其中A表示氧，硫或NH，X表示任何单元; 超分子聚合物中的氢键形成在选自官能团（1）至（5）的两个相同或不同的官能团之间。本发明的聚合物可以单独使用，即基本上由所述聚合物和任选的稳定剂，抗氧化剂等制成或与其它聚合物或其它产品混合形式的组合物的形式使用。

4. 发明授权

US07348397B2 Supramolecular polymers 有权
标题翻译：超分子聚合物
公开(公告)号：US07348397B2
公开(公告)日：2008-03-25
申请号：US11598931
申请日：2006-11-14
申请人： Francois-Genes Tournilhac , Corinne Soulie-Ziakovic , Ludwik Leibler , Laurent Lachaize
发明人： Francois-Genes Tournilhac , Corinne Soulie-Ziakovic , Ludwik Leibler , Laurent Lachaize
IPC分类号： C08G73/06 , C08G73/08
CPC分类号： C08G61/123 , C08F8/30 , C08F8/34 , C08G73/028 , C08K5/0025 , C08L65/00 , C08L79/02
摘要： The invention relates to a supramolecular polymer containing units which are linked by hydrogen bonds, said units being monomers of prepolymers comprising at least one functional group selected from the functional groups (1) and (3) and a second functional group (5) wherein A denotes oxygen, sulphur or NH and X is any unit; the hydrogen bonds in the supramolecular polymer being formed between two identical or different functional groups chosen from the functional groups (1) to (5). The inventive polymers can be used alone, i.e. in the form of a composition which is essentially made from said polymers and, optionally, stabilizers, antioxidants, etc. or in the form of a mixture with other polymers or other products.
摘要翻译：本发明涉及包含通过氢键连接的单元的超分子聚合物，所述单元是包含至少一种选自官能团（1）和（3）的官能团和第二官能团（5）的预聚物的单体，其中A 表示氧，硫或NH，X是任何单元; 超分子聚合物中的氢键形成在选自官能团（1）至（5）的两个相同或不同的官能团之间。本发明的聚合物可以单独使用，即以基本上由所述聚合物和任选的稳定剂，抗氧化剂等制成或与其它聚合物或其它产品混合形式的组合物的形式使用。

5. 发明授权

US08252872B2 Polymer material containing chains bearing imidazolidone functions 有权
标题翻译：含有咪唑烷酮功能的链的聚合物材料
公开(公告)号：US08252872B2
公开(公告)日：2012-08-28
申请号：US12878383
申请日：2010-09-09
申请人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
发明人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
IPC分类号： C08F8/30 , C08F8/32 , C08G69/48 , C08L77/00
CPC分类号： C08F8/30 , C08F8/32 , C08F8/34 , C08G69/48 , Y10T428/1352 , Y10T428/139 , C08F220/14 , C08F210/02
摘要： The invention concerns a polymer material consisting of macromolecular chains bound by hydrogen bonds, wherein: the macromolecular chains consist of a polymer skeleton whereon is fixed by at least one covalent bond a modifying agent, the modifying agent comprising, assembled in a common molecule, one or more associative groups capable of being bound by hydrogen bonds and one or more reactive groups capable of forming covalent bonds with the polymer skeleton, at least one of the associative groups of the modifying agent is an imidazolidone heterocycle, the macromolecular chains bear on average, 1 to 10 imidazolidone groups per chain. The average number of imidazolidone groups to be introduced into the macromolecular chains depends both on the average mass of said chains and the final properties desired for the material.
摘要翻译：本发明涉及由氢键结合的大分子链组成的聚合物材料，其中：大分子链由其中通过至少一个共价键固定的聚合物骨架修饰剂组成，改性剂包含组装在共同分子中的一种，一种或更多的能够被氢键结合的缔合基团和一个或多个能够与聚合物骨架形成共价键的反应性基团，改性剂的至少一个缔合基团是咪唑啉酮杂环，大分子链平均负载，每链1至10个咪唑烷酮基。引入大分子链中的咪唑烷酮基团的平均数量取决于所述链的平均质量和材料所需的最终性能。

6. 发明授权

US08188293B2 Elastic materials 有权
标题翻译：弹性材料
公开(公告)号：US08188293B2
公开(公告)日：2012-05-29
申请号：US11815982
申请日：2006-02-14
申请人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic
发明人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic
IPC分类号： C07D403/12
CPC分类号： C08L101/025 , C08F8/30 , C08F8/34 , C08G83/008
摘要： The present invention relates to materials exhibiting the property of rubbery elasticity, consisting of molecules with a mass of between 9 and 9000 g/mol, all or some of the molecules having at least three groups (also referred to as “associative groups”) capable of associating via non-covalent interactions.Although consisting of small non-polymerized molecules that are not chemically crosslinked, this material exhibits properties of rubbery elasticity. According to an embodiment of the invention, this material exhibits rubbery elasticity at ambient temperature. Above a certain temperature, the material flows like a simple liquid. The material is thermoreversible, i.e. after cooling, the material again exhibits the property of rubbery elasticity. This material is self-repairing and potentially recyclable, which is never the case with a chemically crosslinked elastomer.According to an embodiment of the invention, the molecules constituting the material of the invention bear associative groups of formula (1) below: in which A denotes oxygen, sulphur or NH; the carbon atoms of formula (1) can be substituted. Preferably, A denotes oxygen. Advantageously, the material comprises (i) molecules having at least 3 associative groups, and (ii) molecules having a single associative group. Advantageously, the molecules are obtained from fatty acid derivatives.
摘要翻译：本发明涉及具有弹性弹性的材料，由质量介于9至9000g / mol的分子组成，全部或部分分子具有至少三个基团（也称为“缔合基团”），其能够通过非共价相互作用关联。虽然由不是化学交联的小的非聚合分子组成，但是该材料表现出橡胶弹性的性质。根据本发明的一个实施方案，该材料在环境温度下表现出橡胶弹性。在一定温度以上，材料就像液体一样流动。材料是热可逆的，即在冷却之后，材料再次表现出橡胶弹性的性质。这种材料是自修复和潜在可循环利用的，化学交联的弹性体永远不会这样。根据本发明的一个实施方案，构成本发明材料的分子具有下式（1）的缔合基团：其中A表示氧，硫或NH; 式（1）的碳原子可以被取代。优选地，A表示氧。有利地，该材料包含（i）具有至少3个缔合基团的分子，和（ii）具有单个缔合基团的分子。有利地，分子从脂肪酸衍生物获得。

7. 发明申请

US20110135859A1 POLYMER MATERIAL CONTAINING CHAINS BEARING IMIDAZOLIDONE FUNCTIONS 有权
标题翻译：含有IMIDAZOLIDONE功能的聚合物材料
公开(公告)号：US20110135859A1
公开(公告)日：2011-06-09
申请号：US12878383
申请日：2010-09-09
申请人： Francois-Genes TOURNILHAC , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
发明人： Francois-Genes TOURNILHAC , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
IPC分类号： B32B1/08 , C08G69/48 , C08L77/00 , B32B1/02
CPC分类号： C08F8/30 , C08F8/32 , C08F8/34 , C08G69/48 , Y10T428/1352 , Y10T428/139 , C08F220/14 , C08F210/02
摘要： The invention concerns a polymer material consisting of macromolecular chains bound by hydrogen bonds, wherein: the macromolecular chains consist of a polymer skeleton whereon is fixed by at least one covalent bond a modifying agent, the modifying agent comprising, assembled in a common molecule, one or more associative groups capable of being bound by hydrogen bonds and one or more reactive groups capable of forming covalent bonds with the polymer skeleton, at least one of the associative groups of the modifying agent is an imidazolidone heterocycle, the macromolecular chains bear on average, 1 to 10 imidazolidone groups per chain. The average number of imidazolidone groups to be introduced into the macromolecular chains depends both on the average mass of said chains and the final properties desired for the material.
摘要翻译：本发明涉及由氢键结合的大分子链组成的聚合物材料，其中：大分子链由其中通过至少一个共价键固定的聚合物骨架修饰剂组成，改性剂包含组装在共同分子中的一种，一种或更多的能够被氢键结合的缔合基团和一个或多个能够与聚合物骨架形成共价键的反应性基团，改性剂的至少一个缔合基团是咪唑啉酮杂环，大分子链平均负载，每链1至10个咪唑烷酮基。引入大分子链中的咪唑烷酮基团的平均数量取决于所述链的平均质量和材料所需的最终性能。

8. 发明授权

US07750113B2 Supramolecular polymers 有权
标题翻译：超分子聚合物
公开(公告)号：US07750113B2
公开(公告)日：2010-07-06
申请号：US12051278
申请日：2008-03-19
申请人： Francois-Genes Tournilhac , Corinne Soulie-Ziakovic , Ludwik Leibler , Laurent Lachaize
发明人： Francois-Genes Tournilhac , Corinne Soulie-Ziakovic , Ludwik Leibler , Laurent Lachaize
IPC分类号： C08G73/06 , C08G73/08 , C08G73/00
CPC分类号： C08G61/123 , C08F8/30 , C08F8/34 , C08G73/028 , C08K5/0025 , C08L65/00 , C08L79/02
摘要： The invention relates to a supramolecular polymer containing units which are linked by hydrogen bonds, said units being monomers of prepolymers comprising at least one functional group selected from the functional groups (1) and (3) and a second functional group (5) wherein A denotes oxygen, sulphur or NH and X is any unit; the hydrogen bonds in the supramolecular polymer being formed between two identical or different functional groups chosen from the functional groups (1) to (5). The inventive polymers can be used alone, i.e. in the form of a composition which is essentially made from said polymers and, optionally, stabilizers, antioxidants, etc. or in the form of a mixture with other polymers or other products.
摘要翻译：本发明涉及包含通过氢键连接的单元的超分子聚合物，所述单元是包含至少一种选自官能团（1）和（3）的官能团和第二官能团（5）的预聚物的单体，其中A 表示氧，硫或NH，X是任何单元; 超分子聚合物中的氢键形成在选自官能团（1）至（5）的两个相同或不同的官能团之间。本发明的聚合物可以单独使用，即以基本上由所述聚合物和任选的稳定剂，抗氧化剂等制成或与其它聚合物或其它产品混合形式的组合物的形式使用。

9. 发明申请

US20090062551A1 ELASTIC MATERIALS 有权
标题翻译：弹性材料
公开(公告)号：US20090062551A1
公开(公告)日：2009-03-05
申请号：US11815982
申请日：2006-02-14
申请人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic
发明人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic
IPC分类号： C07D403/12
CPC分类号： C08L101/025 , C08F8/30 , C08F8/34 , C08G83/008
摘要： The present invention relates to materials exhibiting the property of rubbery elasticity, consisting of molecules with a mass of between 9 and 9000 g/mol, all or some of the molecules having at least three groups (also referred to as “associative groups”) capable of associating via non-covalent interactions.Although consisting of small non-polymerized molecules that are not chemically crosslinked, this material exhibits properties of rubbery elasticity. According to an embodiment of the invention, this material exhibits rubbery elasticity at ambient temperature. Above a certain temperature, the material flows like a simple liquid. The material is thermoreversible, i.e. after cooling, the material again exhibits the property of rubbery elasticity. This material is self-repairing and potentially recyclable, which is never the case with a chemically crosslinked elastomer.According to an embodiment of the invention, the molecules constituting the material of the invention bear associative groups of formula (1) below: in which A denotes oxygen, sulphur or NH; the carbon atoms of formula (1) can be substituted. Preferably, A denotes oxygen. Advantageously, the material comprises (i) molecules having at least 3 associative groups, and (ii) molecules having a single associative group.Advantageously, the molecules are obtained from fatty acid derivatives.
摘要翻译：本发明涉及具有弹性弹性的材料，由质量介于9至9000g / mol的分子组成，全部或部分分子具有至少三个基团（也称为“缔合基团”），其能够通过非共价相互作用关联。虽然由不是化学交联的小的非聚合分子组成，但是该材料表现出橡胶弹性的性质。根据本发明的一个实施方案，该材料在环境温度下表现出橡胶弹性。在一定温度以上，材料就像液体一样流动。材料是热可逆的，即在冷却之后，材料再次表现出橡胶弹性的性质。这种材料是自修复和潜在可循环利用的，化学交联的弹性体永远不会这样。根据本发明的一个实施方案，构成本发明材料的分子具有下式（1）的缔合基团：其中A表示氧，硫或NH; 式（1）的碳原子可以被取代。优选地，A表示氧。有利地，该材料包含（i）具有至少3个缔合基团的分子，和（ii）具有单个缔合基团的分子。有利地，分子从脂肪酸衍生物获得。

10. 发明申请

US20080221272A1 Polymer Material Comprising Chains Bearing Imidazolidone Functions 审中-公开
标题翻译：包含咪唑啉酮功能的链条的聚合物材料
公开(公告)号：US20080221272A1
公开(公告)日：2008-09-11
申请号：US11631690
申请日：2005-07-06
申请人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
发明人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
IPC分类号： C08F8/30 , C08G63/91
CPC分类号： C08F8/30 , C08F8/32 , C08F8/34 , C08G69/48 , Y10T428/1352 , Y10T428/139 , C08F220/14 , C08F210/02
摘要： The invention concerns a polymer material consisting of macromolecular chains bound by hydrogen bonds wherein: the macromolecular chains consist of a polymer skeleton whereon is fixed by at least one covalent bond a modifying agent, the modifying agent comprising, assembled in a common molecule, one or more associative groups capable of being bound by hydrogen bonds and one or more reactive groups capable of forming covalent bonds with the polymer skeleton, at least one of the associative groups of the modifying agent is an imidazolidone heterocycle, the macromolecular chains bear on average 1 to 10 imidazolidone groups per chain. The average number of imidazolidone groups to be introduced into the macromolecular chains depends both on the average mass of said chains and the final properties desired for the material. The inventive polymer material can be extruded, co-extruded, injected, blown, moulded, overmoulded, calandered, thermoformed. It can be used to produce articles such as tubes, films, plates, extruded strings, bottles, containers. The inventive polymer material can also be mixed with other materials such as other polymers, thus it is used for example as impact modifier or rheology regulator. The invention further concerns the use of said polymer material as compatibility agent in a composition comprising among others at least two polymers belonging to different classes of polymers.
摘要翻译：本发明涉及由氢键结合的大分子链组成的聚合物材料，其中：大分子链由其中通过至少一个共价键固定的聚合物骨架修饰剂组成，改性剂包含组装在共同分子中的一种或多种能够被氢键和一个或多个能够与聚合物骨架形成共价键的反应性基团结合的更多缔合基团，改性剂的至少一个缔合基团是咪唑啉酮杂环，大分子链平均为1〜 10个咪唑烷酮基团。引入大分子链中的咪唑烷酮基团的平均数量取决于所述链的平均质量和材料所需的最终性能。本发明的聚合物材料可以挤出，共挤出，注射，吹塑，模塑，包覆成型，压延，热成型。它可用于生产诸如管，薄膜，板，挤压线，瓶，容器等物品。本发明的聚合物材料也可以与其它材料如其它聚合物混合，因此其用作例如抗冲改性剂或流变调节剂。本发明还涉及所述聚合物材料作为相容剂在包含至少两种属于不同类型聚合物的聚合物的组合物中的用途。

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