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1. 发明申请

US20060110592A1 Acrylic film and laminates comprising the same 有权
标题翻译：丙烯酸膜和包含其的层压制品
公开(公告)号：US20060110592A1
公开(公告)日：2006-05-25
申请号：US10531282
申请日：2002-12-19
申请人： Norito Doi , Takao Shibata , Yoichi Matsumura , Shigemi Matsumoto
发明人： Norito Doi , Takao Shibata , Yoichi Matsumura , Shigemi Matsumoto
IPC分类号： B32B27/30 , C08L51/00
CPC分类号： C08L33/10 , C08J5/18 , C08J2333/10 , C08J2351/04 , C08L33/12 , C08L51/04 , Y10T428/254 , Y10T428/31935 , C08L2666/24
摘要： To provide an acrylic film, composed of a resin composition (C) that includes an acrylic graft copolymer (A) containing an acrylic ester rubber-like polymer and a methacrylic polymer (B) containing 80% by weight or more of methyl methacrylate, wherein (1) the content of the acrylic ester rubber-like polymer in the resin composition (C) is 5% by weight or more and 30% by weight or less, (2) the average particle size of the acrylic ester rubber-like polymer is 500 to 2000 Å, (3) the relationship between the average particle size d (Å) of the acrylic ester rubber-like polymer and the amount w (% by weight) of crosslinking agent used in the acrylic ester rubber-like polymer satisfies the following equation: 0.002d≦w≦0.005d, (4) the graft ratio of the acrylic graft copolymer (A) is 30% or more and 200% or less, and (5) the reduced viscosity of methyl ethyl ketone soluble matter in the resin composition (C) is 0.2 to 0.8 dl/g.
摘要翻译：为了提供一种由含有丙烯酸酯类橡胶状聚合物的丙烯酸接枝共聚物（A）和含有80重量％以上的甲基丙烯酸甲酯的甲基丙烯酸系聚合物（B）的树脂组合物（C）构成的丙烯酸系膜，其中，（1）树脂组合物（C）中丙烯酸酯类橡胶状聚合物的含量为5重量％以上且30重量％以下，（2）丙烯酸酯类橡胶状聚合物的平均粒径为500〜2000埃，（3）丙烯酸酯类橡胶状聚合物的平均粒径d（）与丙烯酸酯类橡胶状聚合物中使用的交联剂的w（重量％）的量之间的关系满足以下等式：0.002d <= w <= 0.005d，（4）丙烯酸接枝共聚物（A）的接枝率为30％以上且200％以下，（5）甲基乙基酮的比浓粘度树脂组合物（C）中的可溶物质为0.2〜0.8dl / g。

2. 发明授权

US07195816B2 Acrylic film and laminates comprising the same 有权
标题翻译：丙烯酸膜和包含其的层压制品
公开(公告)号：US07195816B2
公开(公告)日：2007-03-27
申请号：US10531282
申请日：2002-12-19
申请人： Norito Doi , Takao Shibata , Yoichi Matsumura , Shigemi Matsumoto
发明人： Norito Doi , Takao Shibata , Yoichi Matsumura , Shigemi Matsumoto
IPC分类号： B32B5/16 , B32B27/30 , C08G63/48 , C08L31/02 , C08L33/06
CPC分类号： C08L33/10 , C08J5/18 , C08J2333/10 , C08J2351/04 , C08L33/12 , C08L51/04 , Y10T428/254 , Y10T428/31935 , C08L2666/24
摘要： To provide an acrylic film, composed of a resin composition (C) that includes an acrylic graft copolymer (A) containing an acrylic ester rubber-like polymer and a methacrylic polymer (B) containing 80% by weight or more of methyl methacrylate, wherein (1) the content of the acrylic ester rubber-like polymer in the resin composition (C) is 5% by weight or more and 30% by weight or less, (2) the average particle size of the acrylic ester rubber-like polymer is 500 to 2000 Å, (3) the relationship between the average particle size d (Å) of the acrylic ester rubber-like polymer and the amount w (% by weight) of crosslinking agent used in the acrylic ester rubber-like polymer satisfies the following equation: 0.002d≦w≦0.005d, (4) the graft ratio of the acrylic graft copolymer (A) is 30% or more and 200% or less, and (5) the reduced viscosity of methyl ethyl ketone soluble matter in the resin composition (C) is 0.2 to 0.8 dl/g.
摘要翻译：为了提供一种由含有丙烯酸酯类橡胶状聚合物的丙烯酸接枝共聚物（A）和含有80重量％以上的甲基丙烯酸甲酯的甲基丙烯酸系聚合物（B）的树脂组合物（C）构成的丙烯酸系膜，其中，（1）树脂组合物（C）中丙烯酸酯类橡胶状聚合物的含量为5重量％以上且30重量％以下，（2）丙烯酸酯类橡胶状聚合物的平均粒径为500〜2000埃，（3）丙烯酸酯类橡胶状聚合物的平均粒径d（）与丙烯酸酯类橡胶状聚合物中使用的交联剂的w（重量％）的量之间的关系满足以下等式：0.002d <= w <= 0.005d，（4）丙烯酸接枝共聚物（A）的接枝率为30％以上且200％以下，（5）甲基乙基酮的比浓粘度树脂组合物（C）中的可溶物质为0.2〜0.8dl / g。

3. 发明授权

US6136918A Rubber latexes, graft copolymers, and thermoplastic resin compositions 失效
标题翻译：橡胶胶乳，接枝共聚物和热塑性树脂组合物
公开(公告)号：US6136918A
公开(公告)日：2000-10-24
申请号：US68014
申请日：1998-04-30
申请人： Ikuhiro Mishima , Norito Doi , Youichi Matsumura , Shigemi Matsumoto , Shinobu Ochikoshi , Kazuhito Wada , Hiroki Yoshino
发明人： Ikuhiro Mishima , Norito Doi , Youichi Matsumura , Shigemi Matsumoto , Shinobu Ochikoshi , Kazuhito Wada , Hiroki Yoshino
IPC分类号： C08C1/07 , C08F265/04 , C08F279/02 , C08L21/02 , C08L51/04 , C08F291/02 , C08L33/06
CPC分类号： C08L21/02 , C08C1/07 , C08F265/04 , C08F279/02 , C08L51/04
摘要： A rubber latex with its particles grown through cohesion by adding 100 weight parts of (B) a rubber latex (solid), 0.1-15 weight parts (solid) of (A) an acid group-containing latex having an average particle size of 50-500 nm prepared by polymerizing a monomer mixture comprising (a), (b), (c) and (d) [wherein (a)+(b)+(c)+(d)=100 weight %]: (a) 5-25 weight % of at least one of unsaturated acids selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid and crotonic acid, (b) 20-95 weight % of at least one of alkyl methacrylates with its alkyl group 1-12 in carbon number, (c) 0-30 weight % of at least one of alkyl acrylates with its alkyl group 1-12 in carbon number, (d) 0-40 weight % of at least one selected from the group consisting of aromatic vinyls, compounds having at least two polymerizable functional groups in a molecule and vinyl cyanides, copolymerizable with the aforementioned (a), (b) and (c) is provided. The rubber latex and a graft copolymer containing it and thermoplastic resins incorporating said graft copolymer are excellent in impact strength, heat resistance and workability.
摘要翻译： PCT No.PCT / JP95 / 02548 Sec。 371日期：1998年4月30日 102（e）1998年4月30日PCT 1995年12月13日PCT PCT。出版物WO97 / 21770 日期：1996年6月19日通过加入100重量份（B）橡胶胶乳（固体），0.1-15重量份（固体）（A）含酸基胶乳的胶乳（其具有通过聚合包含（a），（b），（c）和（d）[其中（a）+（b）+（c）+（d））= 100重量的单体混合物制备的平均粒径为50-500nm ％）：（a）5-25重量％的选自丙烯酸，甲基丙烯酸，衣康酸和巴豆酸的不饱和酸中的至少一种，（b）20-95重量％的至少一种烷基其碳原子数为1-12的甲基丙烯酸酯，（c）0-30重量％的碳原子数为1-12的烷基丙烯酸烷基酯中的至少一种，（d）0-40重量％的至少一种选自芳族乙烯基，分子中具有至少两个可聚合官能团的化合物和可与上述（a），（b）和（c）共聚的乙烯基氰化物）。橡胶胶乳和含有它的接枝共聚物和结合所说接枝共聚物的热塑性树脂具有优异的冲击强度，耐热性和可加工性。

4. 发明授权

US5798414A Resin composition excellent in impact strength 失效
标题翻译：树脂成分冲击强度优异
公开(公告)号：US5798414A
公开(公告)日：1998-08-25
申请号：US656295
申请日：1996-06-13
申请人： Ikuhiro Mishima , Norito Doi , Youichi Matsumura , Shigemi Matsumoto
发明人： Ikuhiro Mishima , Norito Doi , Youichi Matsumura , Shigemi Matsumoto
IPC分类号： C08L25/02 , C08L25/08 , C08L51/04
CPC分类号： C08L25/08 , C08L25/02 , C08L51/04 , C08L2205/02
摘要： A resin composition is disclosed, which comprizes (I) a graft copolymer using a medium-size rubber particles grown by an acid-group-containing latex, (II) a graft copolymer using small-size rubber particles, (III) a styrene-acrylonitrile copolymer, and/or (IV) a styrene-maleimide copolymer, said resin composition containing 5-40 weight % of rubber. The resin composition is not only superior in impact strength, planar impact strength in particular and gloss, but is favorable in moldability and heat resistance.
摘要翻译： PCT No.PCT / JP95 / 02243 Sec。 371日期：1996年6月13日 102（e）1996年6月13日PCT 1996年11月2日PCT PCT。公开号WO96 / 15188 日期1996年5月23日公开了一种树脂组合物，其包括（I）使用由含酸基的胶乳生长的中等尺寸的橡胶颗粒的接枝共聚物，（II）使用小尺寸橡胶颗粒的接枝共聚物（III ）苯乙烯 - 丙烯腈共聚物和/或（IV）苯乙烯 - 马来酰亚胺共聚物，所述树脂组合物含有5-40重量％的橡胶。该树脂组合物的冲击强度，平面冲击强度，光泽度均不但优异，而且成型性和耐热性也良好。

5. 发明授权

US4518742A Thermoplastic resin composition having toughness and high heat distortion resistance 失效
标题翻译：具有韧性和耐热变形性高的热塑性树脂组合物
公开(公告)号：US4518742A
公开(公告)日：1985-05-21
申请号：US546596
申请日：1983-10-28
申请人： Eiichi Muramatsu , Shigemi Matsumoto , Fumiya Nagoshi
发明人： Eiichi Muramatsu , Shigemi Matsumoto , Fumiya Nagoshi
IPC分类号： C08F285/00 , C08L51/00 , C08L51/04 , C08L69/00
CPC分类号： C08L51/00 , C08L69/00
摘要： A thermoplastic resin composition having excellent impact resistance, heat distortion resistance and processability which comprises an aromatic polycarbonate and a thermoplastic resin prepared by polymerizing a monomer mixture containing mainly acrylonitrile and styrene in the presence of a diene rubber, adding .alpha.-methylstyrene or a monomer mixture containing mainly .alpha.-methylstyrene to the system, and continuing the polymerization, while gradually adding acrylonitrile or a monomer mixture containing mainly acrylonitrile.
摘要翻译：一种具有优异的耐冲击性，耐热变形性和加工性的热塑性树脂组合物，其包含芳族聚碳酸酯和通过在二烯橡胶的存在下主要包含丙烯腈和苯乙烯的单体混合物聚合制备的热塑性树脂，加入α-甲基苯乙烯或单体混合物其中主要含有α-甲基苯乙烯，并继续聚合，同时逐渐加入丙烯腈或主要是丙烯腈的单体混合物。

6. 发明授权

US5990240A Rubber-containing resin composition and styrene resin composition containing the same 失效
标题翻译：含有橡胶的树脂组合物和含有它的苯乙烯树脂组合物
公开(公告)号：US5990240A
公开(公告)日：1999-11-23
申请号：US893556
申请日：1997-07-11
申请人： Ikuhiro Mishima , Yo-ichi Matsumura , Yoshihiko Hashimoto , Shigemi Matsumoto
发明人： Ikuhiro Mishima , Yo-ichi Matsumura , Yoshihiko Hashimoto , Shigemi Matsumoto
IPC分类号： C08L15/00 , C08F2/22 , C08L21/02 , C08L25/00 , C08L25/12 , C08L51/04 , C08L55/00 , C08L55/02 , C08L9/00
CPC分类号： C08L25/12 , C08L55/02
摘要： A rubber-containing resin composition suitable as an impact modifier for styrene resins (such as styrene homopolymer and copolymers and polymer alloys thereof with other thermoplastic resins), which comprises (A) a graft copolymer having a graft ratio of 10 to 80% by weight wherein a graft component comprising 15 to 60% by mole of at least one vinyl cyanide compound, 40 to 85% by mole of at least one aromatic vinyl compound and 0 to 30% by mole of at least one other monomer copolymerizable with them is graft-copolymerized onto a diene rubber having a volume average particle size of 100 to 1,000 nm by an emulsion polymerization method, and (B) an emulsion-polymerized copolymer of 15 to 60% by mole of at least one vinyl cyanide compound, 40 to 85% by mole of at least one aromatic vinyl compound and 0 to 30% by mole of at least one other monomer copolymerizable with them, which has a weight average molecular weight of 5,000 to 90,000 and a ratio of weight average molecular weight to number average molecular weight of 1.5 to 4.5, in which the ratio of the graft copolymer (A) to the copolymer (B) is from 50/50 to 95/5 by weight. A styrene resin composition comprising the rubber-containing resin composition and a styrene resin provides molded articles having excellent properties such as impact resistance, mechanical property, heat resistance and surface appearance with good processability.
摘要翻译：适合作为苯乙烯类树脂（例如苯乙烯均聚物及其与其它热塑性树脂的共聚物及其聚合物合金）的抗冲改性剂的含橡胶的树脂组合物，其包含（A）接枝率为10〜80重量％其中，含有15〜60摩尔％的至少一种乙烯基氰化合物，40〜85摩尔％的至少一种芳族乙烯基化合物和0〜30摩尔％的与其共聚的至少一种其他单体的接枝成分是接枝通过乳液聚合法共聚到体积平均粒径为100〜1000nm的二烯系橡胶上，（B）15〜60摩尔％的至少一种乙烯基氰化合物的乳液聚合共聚物，40〜85 摩尔％的至少一种芳族乙烯基化合物和0至30摩尔％的至少一种可与其共聚的其它单体，其重均分子量为5,000至90,000，重均分子量与数量的比率平均分子量为1.5至4.5，其中接枝共聚物（A）与共聚物（B）的比例为50/50至95/5重量比。包含含橡胶的树脂组合物和苯乙烯树脂的苯乙烯树脂组合物提供了具有优异的性能如耐冲击性，机械性能，耐热性和表面外观的加工性能优异的模制品。

7. 发明授权

US5741860A Thermoplastic resin composition and trim parts for interior decoration of automobile 失效
标题翻译：汽车室内装饰用热塑性树脂组合物及装饰件
公开(公告)号：US5741860A
公开(公告)日：1998-04-21
申请号：US652476
申请日：1996-06-18
申请人： Shigemi Matsumoto , Akinaga Goda
发明人： Shigemi Matsumoto , Akinaga Goda
IPC分类号： C08L23/08 , C08L33/06 , C08L55/02
CPC分类号： C08L23/08 , C08L33/062 , C08L55/02
摘要： A thermoplastic resin composition is disclosed, which comprizes 5-55 weight % of a copolymer (A) whose glass transition temperature is not more than 0.degree. C., and 95-45 weight % of a high .alpha.-methylstyrene-content ABS resin (B) and/or a maleimide-type ABS resin (C), both (B) and (C) being not less than 100.degree. C. in thermal deformation temperature (load 18.6 kg/cm.sup.2), and said resin composition being not less than 10 kg.cm/cm in Izod impact strength (23.degree. C.). The resin composition provides molded articles less deformable at high temperatures, low in impact-induced stress, i.e, high in impact energy absorptivity, and thus is suitable for trim parts for use in interior decoration of automobiles.
摘要翻译： PCT No.PCT / JP95 / 02237 Sec。 371日期1996年6月18日 102（e）1996年6月18日PCT 1995年11月1日PCT PCT。出版物WO96 / 15190 日期：1996年5月23日公开了一种热塑性树脂组合物，其含有5-55重量％的玻璃化转变温度不高于0℃的共聚物（A）和95-45重量％的高α-甲基苯乙烯 - 含量ABS树脂（B）和/或马来酰亚胺型ABS树脂（C），（B）和（C）在热变形温度（负荷18.6kg / cm 2）下不低于100℃，所述树脂组合物的悬臂梁式冲击强度（23℃）不小于10kg·cm / cm。树脂组合物提供在高温下变形较小，冲击诱发应力低的冲击能量吸收性的模塑制品，因此适合用于汽车的室内装饰的装饰部件。

8. 发明授权

US4761463A Thermoplastic resin composition having a matte appearance 失效
标题翻译：具有无光泽外观的热塑性树脂组合物
公开(公告)号：US4761463A
公开(公告)日：1988-08-02
申请号：US843358
申请日：1986-03-24
申请人： Shigemi Matsumoto , Fumiya Nagoshi
发明人： Shigemi Matsumoto , Fumiya Nagoshi
IPC分类号： C08L25/00 , C08F279/02 , C08L7/00 , C08L21/00 , C08L25/02 , C08L25/12 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/04 , C08L37/00
CPC分类号： C08L25/12 , C08F279/02 , C08L51/04
摘要： A thermoplastic resin composition having a matte appearance comprising:(A) 80-5 parts by weight of a graft copolymer obtained by grafting 40-95 parts by weight of diene rubber with 60-5 parts by weight of vinyl compounds consisting of0.1-40 weight % of at least one glycidyl ester of an .alpha.- and .beta.-unsaturated acid as an essential component,10-40 weight % of at least one vinyl cyanide compound,60-90 weight % of at least one aromatic vinyl compound, and0-30 weight % of other copolymerizable vinyl compounds, and(B) 20-95 parts by weight of a copolymer obtained through reaction of10-40 weight % of at least one vinyl cyanide compound,60-90 weight % of at least one aromatic vinyl compound, and0-30 weight % of other copolymerizable vinyl compounds, the intrinsic viscosity of the resin composition in terms of its components which are soluble in methyl ethyl ketone being 0.25-1.5 dl/g (N,N'-dimethyl formamide solution, 30.degree. C.).
摘要翻译：具有无光泽外观的热塑性树脂组合物包含：（A）80-5重量份通过将40-95重量份二烯橡胶与60-5重量份由0.1-40重量份组成的乙烯基化合物接枝而获得的接枝共聚物至少一种作为必需组分的α-和β-不饱和酸的缩水甘油酯的重量％，10-40重量％的至少一种乙烯基氰化合物，60-90重量％的至少一种芳族乙烯基化合物和0 -30重量％的其它可共聚的乙烯基化合物，和（B）20-95重量份通过将10-40重量％的至少一种乙烯基氰化合物，60-90重量％的至少一种芳族化合物乙烯基化合物和0-30重量％的其它可共聚乙烯基化合物，根据可溶于甲基乙基酮的组分，树脂组合物的特性粘度为0.25-1.5dl / g（N，N'-二甲基甲酰胺溶液，30℃）。

9. 发明授权

US06482456B1 Method for producing low acid beverage 有权
标题翻译：生产低酸饮料的方法
公开(公告)号：US06482456B1
公开(公告)日：2002-11-19
申请号：US09596201
申请日：2000-06-16
申请人： Yoshiaki Yokoo , Shigemi Matsumoto , Yoshiko Hino , Nobuya Matsumoto
发明人： Yoshiaki Yokoo , Shigemi Matsumoto , Yoshiko Hino , Nobuya Matsumoto
IPC分类号： A23B420
CPC分类号： A23L2/44 , A23C9/1542 , A23C9/1544 , A23V2002/00 , A23V2250/511
摘要： A method for producing a low acid beverage in which a deterioration in quality associated with a pH decrease during heat sterilization or long-term storage in a heated condition is eliminated or minimized, and which is characterized by adding at least one of chitosan, chitosan oligosaccharide and glucosamine.
摘要翻译：一种生产低酸饮料的方法，其中消除或最小化在加热灭菌或加热条件下的长期保存中与pH降低相关的质量劣化，其特征在于，将至少一种壳聚糖，壳聚糖寡糖和葡糖胺。

10. 发明授权

US5367016A Reinforced resin composition 失效
标题翻译：增强树脂组合物
公开(公告)号：US5367016A
公开(公告)日：1994-11-22
申请号：US980008
申请日：1992-11-23
申请人： Osamu Miyama , Katsutoyo Fujita , Hayato Nishimura , Shigemi Matsumoto , Satoshi Tonoki
发明人： Osamu Miyama , Katsutoyo Fujita , Hayato Nishimura , Shigemi Matsumoto , Satoshi Tonoki
IPC分类号： C08L23/06 , C08L23/12 , C08L51/04 , C08L67/02 , C08L69/00
CPC分类号： C08L67/02 , C08L69/00 , C08L23/06 , C08L23/12 , C08L51/04 , C08L67/025
摘要： A reinforced resin composition comprising 100 parts by weight of a resin component comprising a polycarbonate resin, a thermoplastic polyester resin and an impact modifier in a ratio, by weight, of 90-10:10-90:0-40 and 0.5 to 100 parts by weight of kaolin with a mean particle diameter of 0.1 to 4.0 .mu.m. The composition can be molded by conventional techniques such as injection molding and extrusion molding into automotive parts, electrical or electronic parts and other products excellent in heat resistance, impact resistance, rigidity, dimensional stability, chemical resistance, moldability, weather resistance and thermal stability with a low linear coefficient of expansion and excellent surface gloss and appearance.
摘要翻译：一种增强树脂组合物，其包含100重量份的树脂组分，其包含聚碳酸酯树脂，热塑性聚酯树脂和抗冲改性剂，其重量比为90-10：10-90：0-40和0.5至100份的平均粒径为0.1〜4.0μm的高岭土。组合物可以通过常规技术如注射成型和挤出成型成型为汽车部件，电气或电子部件以及耐热性，耐冲击性，刚性，尺寸稳定性，耐化学性，成型性，耐候性和热稳定性优异的其它产品线性膨胀系数低，表面光泽和外观优异。

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