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    • 1. 发明授权
    • Method of alkylating of triazine derivatives
    • 烷基化三嗪衍生物的方法
    • US5792867A
    • 1998-08-11
    • US571828
    • 1996-02-05
    • Norio TanakaMasataka HatanakaMakoto IshikawaYasuo FukueIsao HashibaYoshihisa Watanabe
    • Norio TanakaMasataka HatanakaMakoto IshikawaYasuo FukueIsao HashibaYoshihisa Watanabe
    • C07D251/16C07D251/18C07D251/52C07D251/70C07D251/54
    • C07D251/70C07D251/16C07D251/18C07D251/52
    • A method for alkylation of at least one or more amino groups or mono-substituted amino groups, each on a carbon atom of a triazine ring of 1,3,5-triazine derivatives (melamine, melamine derivatives and various kinds of guanamine derivatives and the like), which includes reacting the 1,3,5-triazine derivatives having at least one or more amino groups or mono-substituted amino groups with alcohols in the presence of a catalyst of a metal of group VII and/or group VIII in the periodic table. The object of the invention is to provide a method for alkylation of 1,3,5-triazine derivatives, which includes alkylating amino groups or mono-substituted amino groups in carbon atoms of a 1,3,5-triazine ring, whereby substituted 1,3,5-triazine derivatives which are a group of useful compounds and which are widely used as intermediates of fine chemicals such as agricultural chemicals, medications, dye-stuffs, paints and the like, as resin materials and as flame-retardant materials can be easily produced in high yields.
    • PCT No.PCT / JP94 / 01190 Sec。 371日期:1996年2月5日 102(e)日期1996年2月5日PCT提交1994年7月20日PCT公布。 出版物WO95 / 03287 日期1995年2月2日在1,3,5-三嗪衍生物(三聚氰胺,三聚氰胺衍生物等)的三嗪环的碳原子上烷基化至少一个以上的氨基或单取代氨基的方法 胍胺衍生物等),其包括使具有至少一个或多个氨基或单取代氨基的1,3,5-三嗪衍生物与醇在VII族金属和/ 或周期表中的VIII族。 本发明的目的是提供一种1,3,5-三嗪衍生物的烷基化方法,其包括在1,3,5-三嗪环的碳原子中烷基化氨基或单取代氨基,由此取代1 作为有用化合物的一组的3,5-三嗪衍生物,广泛用作农药,药物,染料,油漆等精细化学品的中间体作为树脂材料和阻燃材料, 容易以高产量生产。
    • 2. 发明授权
    • N-alkylation of heterocyclic, aromatic amines
    • 杂环芳族胺的N-烷基化
    • US5283341A
    • 1994-02-01
    • US880587
    • 1992-05-08
    • Norio TanakaMasataka HatanakaYoshihisa Watanabe
    • Norio TanakaMasataka HatanakaYoshihisa Watanabe
    • B01J27/13B01J31/24C07B61/00C07D231/12C07D231/20C07D231/22C07D231/38C07D233/54C07D233/58C07D249/04C07D249/06C07D249/08C07D249/18C07D249/20B01J23/46C07D249/22C07D403/02
    • C07D231/12
    • A process for producing a heterocyclic tertiary amine of the formula (III): ##STR1## wherein A is a nitrogen atom or C-R.sup.5, B is a nitrogen atom or C-R.sup.6, is a single bond or a double bond, and each of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 which may be the same or different, is a hydrogen atom, an acyl group, a halogen atom, a cyano group, etc., provided that two of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 may together form a 3-membered, 4-membered, 5-membered or 6-membered aliphatic ring, a heterocyclic rig or aromatic ring, and R.sup.7 is a C.sub.1-6 alkyl group which may be substituted, etc., which process comprises reacting a heterocyclic secondary amine of the formula (I): ##STR2## wherein A, B, , R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are as defined above, with an alkylating agent of the formula (II):R.sup.7 --X (II)wherein R.sup.7 is as defined above, and X is a hydroxyl group, a halogen atom, a OSO.sub.3 R.sup.7 group, a OSO.sub.2 R.sup.7 group, a OCO.sub.2 R.sup.7 group, a OCOR.sup.7 group, a OP(O)(OR.sup.7) group, a OP(O)O(R.sup.7).sub.2 group or an amino group, in the presence of a catalyst of Group VIII of the Periodic Table.
    • 制备式(III)的杂环叔胺的方法:(*化学结构*)(III)其中A为氮原子或C-R5,B为氮原子或C-R6,为单键或 双键,R 1,R 2,R 3,R 4,R 5和R 6可以相同或不同,为氢原子,酰基,卤素原子,氰基等,条件是两个 R 1,R 2,R 3和R 4可以一起形成3元,4元,5元或6元脂族环,杂环基或芳环,并且R 7为可被取代的C 1-6烷基, 等等,该方法包括使式(I)的杂环仲胺:其中A,B,,R 1,R 2,R 3和R 4如上所定义的式(I)化合物与 式(II):其中R7如上定义的R7-X(II),X是羟基,卤素原子,OSO3R7基,OSO2R7基,OCO2R7基,OCOR7基,OP(O )(OR 7)基,OP(O)O(R 7)2基或氨基, n元素周期表第VIII族催化剂的存在。
    • 3. 发明授权
    • Method of alkylating triazine derivatives
    • 烷基化三嗪衍生物的方法
    • US6130332A
    • 2000-10-10
    • US737712
    • 1997-02-07
    • Norio TanakaKenichi MizusawaMakoto IshikawaYasuo FukueIsao HashibaYoshihisa Watanabe
    • Norio TanakaKenichi MizusawaMakoto IshikawaYasuo FukueIsao HashibaYoshihisa Watanabe
    • C07D251/70C07D251/16C07D251/18C07D251/42C07D251/48
    • C07D251/70
    • The object of the present invention is to provide a method for producing substituted-1,3,5-triazine derivatives at high yield, in which at least one of carbon atoms in the ring thereof is substituted by a secondary amine group having at leat one of alkyl groups. The method of the present invention is a method for alkylation of 1,3,5-triazine derivatives, characterized by reacting 1,3,5-triazine derivatives (melamines, melamine derivatives, various kinds of guanaminde derivatives, etc.) which has at least one or more amino groups or mono-substituted amino groups on carbon atom of the ring thereof, with aldehydes or ketones alcohols in the presence of a catalyst of a metal of group VII and/or group VIII in the periodic table and a hydrogen-containing gas to alkylate said at least one of amino groups or mono-substituted amino groups. These derivatives are widely used as intermediates of fine chemicals such as agricultural chemicals, medications, dyestuffs, paints and the like and are widely used resin materials and as flame-retardant materials.
    • PCT No.PCT / JP95 / 00881 Sec。 371日期1997年2月7日 102(e)日期1997年2月7日PCT提交1995年5月9日PCT公布。 WO95 / 30662 PCT出版物 日期:1995年11月16日本发明的目的是提供以高产率制备取代-1,3,5-三嗪衍生物的方法,其中环中的至少一个碳原子被仲胺 具有烷基基团的基团。 本发明的方法是1,3,5-三嗪衍生物的烷基化方法,其特征在于使1,3,5-三嗪衍生物(三聚氰胺,三聚氰胺衍生物,各种胍胺衍生物等) 在环的碳原子上的至少一个或多个氨基或单取代的氨基与醛或酮醇在元素周期表中的第Ⅶ族和/或第Ⅷ族金属的催化剂存在下反应, 含有气体以烷基化所述至少一个氨基或单取代的氨基。 这些衍生物广泛用作农药,药物,染料,油漆等精细化学品的中间体,是广泛使用的树脂材料和阻燃材料。
    • 4. 发明授权
    • Resin product manufacturing system, manufacturing method, resin molding machine and mold
    • 树脂制品制造系统,制造方法,树脂成型机和模具
    • US09321193B2
    • 2016-04-26
    • US13061349
    • 2009-11-06
    • Norio TanakaYoshiyasu Horiuchi
    • Norio TanakaYoshiyasu Horiuchi
    • B29C43/40B29C37/02B29C45/00
    • B29C37/02B29C43/40B29C45/0055B29C2045/0077B29C2793/009
    • It is aimed to provide a resin product manufacturing system, a manufacturing method, a resin molding machine and a mold capable of easily manufacturing a burr-free finished product in injection molding or the like. In a resin product manufacturing system for forming an intermediate product by a resin molding machine and manufacturing a finished product by deburring the intermediate product by a deburring device, the resin molding machine is provided with a mold including a storing portion for storing an overflow resin (burr) formed at a site corresponding to the entire periphery of an intermediate product in a matching surface, the intermediate product having the overflow resin (burr) integrally formed over the entire periphery thereof is formed by the mold, and the deburring device cuts the overflow resin (burr) integrally formed over the entire periphery of the intermediate product together with the burr to manufacture a finished product.
    • 其目的在于提供一种能够容易地在注射成型等中制造无毛刺成品的树脂制品制造系统,制造方法,树脂成形机和模具。 在通过树脂成形机形成中间产品的树脂制品制造系统中,通过去毛刺装置对中间产品进行去毛刺来制造成品的树脂成型机设置有模具,该模具包括用于储存溢出树脂的储存部( 毛刺)形成在与匹配表面中的中间产品的整个周边相对应的位置处,具有通过模具整体形成的溢流树脂(毛刺)的中间产品由模具形成,并且去毛刺装置切割溢流 与毛刺一起形成在中间产品的整个周边上的树脂(毛刺),以制造成品。
    • 6. 发明授权
    • Ultrasonic trimming method
    • 超声波修整方法
    • US08632377B2
    • 2014-01-21
    • US13906141
    • 2013-05-30
    • Norio Tanaka
    • Norio Tanaka
    • B24B51/00
    • B26D7/086B26D3/10B26D7/12B26D7/2614B26D2007/2678B26F1/3806Y10T83/04Y10T83/0443Y10T83/263Y10T83/303Y10T83/313Y10T83/7493Y10T83/8798
    • An ultrasonic trimming method is composed of steps, driving a cutter blade having a flat plate shape and supported by an arm at an end of an articulated robot via an ultrasonic oscillator, the cutter blade being driven by the arm while the cutter blade is ultrasonically vibrated; cutting a workpiece secured by a workpiece securing portion; and during, operation for cutting, moving the cutter blade held attached to the articulated robot to the position at where the cutting edge is brought into contact with the grindstone, maintaining the cutter blades attitude such that a plane containing the cutting edge thereof contacts the grindstone, and grinding the cutter blade by pressing the cutter blade against a grinding member by the arm while the cutter blade is ultrasonically vibrated, the grinding member being disposed within a movable range of the cutter blade driven by the articulated robot.
    • 超声波修整方法由步骤构成,通过超声波振荡器驱动具有平板形状并由关节式机器人端部由臂支撑的切割刀片,刀片由臂驱动,同时刀片被超声波振动 ; 切割由工件固定部分固定的工件; 并且在切割操作期间,将附接到铰接式机器人的切割刀片移动到切割刃与磨石接触的位置处,保持切割刀片姿态使得包含其切割边缘的平面接触砂轮 并且通过在切割刀片被超声波振动的同时通过臂将切割刀片压靠在研磨部件上来研磨切割刀片,所述研磨部件设置在由关节式机器人驱动的切割刀片的可动范围内。
    • 7. 发明申请
    • WORKPIECE REMOVAL AND FINISHING DEVICE
    • 工作拆卸和修整设备
    • US20140017352A1
    • 2014-01-16
    • US14009472
    • 2012-04-02
    • Norio TanakaAtsushi IkedaTakaaki Hoshi
    • Norio TanakaAtsushi IkedaTakaaki Hoshi
    • B29C37/00
    • B29C37/0003B25J9/0084B25J9/0087B25J11/006B29C37/0007B29C37/02
    • There is provided a workpiece removal and finishing device that can easily, accurately, continuously and quickly perform a series of works for processing a workpiece of resin removed from a molding machine. The workpiece removal and finishing device for processing the workpiece of resin removed from the molding machine 41 has a workpiece removal robot 100 for directly or indirectly removing the workpiece from molds 2, 3, and a processing robot 200 for processing the workpiece. A processing tool which can profile the workpiece is secured to the arm tip of the processing robot 200 through a floating mechanism to be adaptable to thermal contraction of the workpiece, and the workpiece can processed by the profiling-capable processing tool provided to the arm tip 200A of the processing robot 200 while the workpiece removed by the workpiece removal robot 100 is positioned and held by the workpiece removal robot 100.
    • 提供了一种能够容易地,准确地连续地和快速地执行一系列用于处理从成型机去除的树脂的工件的工件的工件移除和整理装置。 用于处理从成型机41除去的树脂的工件的工件移除和整理装置具有用于直接或间接地从模具2,3移除工件的工件移除机器人100和用于处理工件的处理机器人200。 可以对工件进行轮廓化的加工工具通过浮动机构固定到加工机器人200的臂尖端,以适应于工件的热收缩,并且工件可以通过提供给臂尖的轮廓加工工具进行加工 在由被除去机器人100移除的工件被搬运机器人100定位和保持的同时,处理机器人200的200A。
    • 8. 发明授权
    • Optical deflection method and optical deflection apparatus
    • 光学偏转方法和光学偏转装置
    • US08208770B2
    • 2012-06-26
    • US12801300
    • 2010-06-02
    • Ichiro UenoNobutaka TanigakiNoritaka YamamotoToshiko MizokuroTakashi HiragaNorio TanakaHiroshi NagaedaNoriyasu Shiga
    • Ichiro UenoNobutaka TanigakiNoritaka YamamotoToshiko MizokuroTakashi HiragaNorio TanakaHiroshi NagaedaNoriyasu Shiga
    • G02B6/26G02F1/03
    • G02F1/0147G02F1/0126G02F1/293G02F1/31
    • An optical deflection apparatus includes a signal light source configured to emit signal light having one or more wavelengths, a control light source configured to emit control light having a wavelength different from the wavelength of the signal light, a thermal lens forming optical element including a light absorption layer configured to transmit the signal light and selectively absorb the control light, and a beam-condensing unit configured to cause beam-condensation of the control light and the signal light at different convergence points in the light absorption layer. The thermal lens forming optical element causes convergence and divergence of the control light and the signal light on an incidence plane of the light absorption layer or its vicinity in a light traveling direction, wherein a thermal lens is reversibly formed in the light absorption layer due to a temperature increase occurring in a region where the control light is absorbed and its peripheral region, and the thermal lens changes a refractive index to change a traveling direction of the signal light.
    • 一种光学偏转装置,包括配置为发射具有一个或多个波长的信号光的信号光源,被配置为发射具有与信号光的波长不同的波长的控制光的控制光源,包括光的热透镜形成光学元件 吸收层,被配置为透射信号光并选择性地吸收控制光;以及光束聚光单元,被配置为使得光吸收层中的控制光和信号光在不同会聚点处的光束冷凝。 热透镜形成光学元件引起控制光和信号光在光传播方向上的光吸收层或其附近的入射平面的会聚和发散,其中热透镜在光吸收层中可逆地形成,由于 发生在控制光被吸收的区域中的温度升高及其周边区域,并且热透镜改变折射率以改变信号光的行进方向。
    • 9. 发明申请
    • IMAGE FORMING APPARATUS AND A PAPER SHEET SUPPLY METHOD
    • 图像形成装置和纸张供应方法
    • US20120002223A1
    • 2012-01-05
    • US13171404
    • 2011-06-28
    • Norio Tanaka
    • Norio Tanaka
    • G06K15/02
    • G06K15/1809B41J11/00B41J11/009B41J11/485G03G15/00G03G15/6508G03G2215/0132G06K15/007G06K15/402G06K15/4065H04N1/00H04N1/00708H04N1/00729H04N1/00771H04N1/00779H04N2201/0082
    • An image forming apparatus, comprising: an input unit which designates the type of a sheet to be used in image formation; a sheet cassette which accommodates the sheets and in which the type of the accommodated sheets is set; a storage unit which stores the sheet type set in the sheet cassette if the sheet type set in the sheet cassette and the sheet type accommodated in the sheet cassette coincide with each other; and a control unit which, when the sheet type set in the sheet cassette is stored in the storage unit upon receiving a request of image formation, judges whether the sheet type designated by the input unit and the sheet type stored in the storage unit coincide with each other, if the sheet type designated by the input unit and the sheet type stored in the storage unit coincide with each other, said control unit instructs image formation, if the sheet type designated by the input unit and the sheet type stored in the storage unit do not coincide, said control unit notifies the judgment result to a user without instructing the image formation, and when the sheet type is not stored in the storage unit upon receiving the request of the image formation, said control unit instructs the image formation.
    • 一种图像形成装置,包括:输入单元,其指定要用于图像形成的片材的类型; 容纳片材并且容纳片材的类型被设置的片材盒; 存储单元,如果设置在纸盒中的纸张类型和容纳在纸张盒中的纸张类型彼此一致,则存储设置在纸张盒中的纸张类型; 以及控制单元,当接收到图像形成请求时,将设置在纸盒中的纸张类型存储在存储单元中时,判断由输入单元指定的纸张类型和存储在存储单元中的纸张类型是否与 如果由输入单元指定的纸张类型和存储在存储单元中的纸张类型彼此一致,则所述控制单元指示图像形成,如果由输入单元指定的纸张类型和存储在存储器中的纸张类型 所述控制单元在不指示图像形成的情况下向用户通知判断结果,并且当在接收到图像形成请求时片材类型未被存储在存储单元中时,所述控制单元指示图像形成。