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    • 4. 发明申请
    • LITHIUM SECONDARY BATTERY
    • 锂二次电池
    • US20120141846A1
    • 2012-06-07
    • US13313039
    • 2011-12-07
    • Norio IWAYASUJinbao ZhaoHidetoshi Honbo
    • Norio IWAYASUJinbao ZhaoHidetoshi Honbo
    • H01M10/42
    • H01M2/345H01M2/022H01M4/62H01M10/052H01M10/0587H01M10/4235H01M2300/004Y02T10/7011
    • In a lithium secondary battery which contains an electrode group including a positive electrode, a negative electrode and a separator interposed between the positive electrode and the negative electrode, and an electrolytic solution, a current shut-off portion which is activated by an increase in an internal pressure is provided, a polymerizable compound having an aromatic functional group and a polymerizable functional group, or a polymer having an aromatic functional group and a residue of a polymerizable functional group is contained, and a carbon dioxide generating agent which produces carbon dioxide by a neutralization reaction is contained in at least one of the positive electrode and the separator. Thereby, the current shut-off valve is activated in an early stage of overcharge to increase the safety of the battery when overcharged.
    • 在包含正极,负极和夹在正极和负极之间的隔膜的电极组和电解液的锂二次电池中,电流切断部分通过增加激活 提供内部压力,包含具有芳香族官能团和聚合性官能团的聚合性化合物,或具有芳香族官能团的聚合物和可聚合官能团的残基,以及二氧化碳发生剂,其通过 中和反应包含在正极和隔膜中的至少一个中。 因此,电流截止阀在过充电的早期阶段被激活,以增加当过充电时电池的安全性。
    • 7. 发明授权
    • Nonaqueous electrolytic solution and nonaqueous electrolyte secondary battery using the same
    • 非水电解液和使用其的非水电解质二次电池
    • US08765310B2
    • 2014-07-01
    • US13094902
    • 2011-04-27
    • Jinbao ZhaoNorio IwayasuYuuki OkudaHidetoshi Honbo
    • Jinbao ZhaoNorio IwayasuYuuki OkudaHidetoshi Honbo
    • H01M6/04H01M6/16H01M10/056
    • H01M10/052H01M10/0567H01M2300/0022Y02T10/7011
    • A nonaqueous electrolytic solution which may suppress the overcharge of a battery and a nonaqueous electrolyte secondary battery using the solution are provided. The overcharge of the battery is suppressed by undergoing the electrolytic polymerization in the solution when the battery is overcharged, and simultaneously more effectively suppressed by increasing the internal resistance of the battery. The nonaqueous electrolytic solution comprises a polymer which undergoes the electrolytic polymerization in the range of 4.3V or more to 5.5V or less at the lithium metal standard voltage, having a repeating unit represented by the formula (1), an electrolytic salt and a nonaqueous solvent. [where, A is a functional group which undergoes the electrolytic polymerization in the range of 4.3V or more to 5.5V or less at the lithium metal standard voltage, R and R′ are each independently an hydrogen atom or a methyl group]
    • 提供了可以抑制电池的过充电的非水电解液和使用该溶液的非水电解质二次电池。 当电池过充电时,通过在溶液中进行电解聚合来抑制电池的过充电,并且通过增加电池的内阻同时更有效地抑制电池的过充电。 非水电解液包含在锂金属标准电压下进行4.3V以上且5.5V以下的电解聚合的聚合物,具有式(1)表示的重复单元,电解质盐和非水性 溶剂。 [其中,A是以锂金属标准电压在4.3V以上至5.5V以下的范围内进行电解聚合的官能团,R和R'各自独立地为氢原子或甲基]