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    • 4. 发明申请
    • Liquid crystal composition and liquid crystal display element
    • US20050230661A1
    • 2005-10-20
    • US11108002
    • 2005-04-14
    • Norikatsu HattoriHitoshi Yamamoto
    • Norikatsu HattoriHitoshi Yamamoto
    • G02F1/13C09K19/12C09K19/30C09K19/42
    • C09K19/3066C09K19/3001Y10T428/10Y10T428/1005
    • An advantage of the present invention is to provide a liquid crystal composition, which satisfies two or more of characteristics such as a wide nematic phase temperature range, a small viscosity, a suitable optical anisotropy, a large negative dielectric anisotropy, and a large specific resistance. One aspect of the invention is to provide a liquid crystal composition having properly balanced characteristics. Another aspect of the invention is to provide a liquid crystal display element, which includes such a composition to have a large voltage holding ratio. A further aspect of the invention is to provide an AM element, which includes a composition having characteristics such as a small viscosity, an optical anisotropy of 0.05 to 0.11, and a dielectric anisotropy of −6.5 to −2.0, and is suitable for a VA mode, an IPS mode, etc. A liquid crystal composition with a negative dielectric anisotropy, comprising at least one compound selected from the group of compounds represented by the following formula (1) as a first component, and at least one compound selected from the group of compounds represented by the following formulas (2-1) to (2-3) and (3-1) to (3-4) as a second component: wherein R1 is alkyl or alkenyl; R2is alkyl, alkenyl, or alkoxy; R3 is alkyl, alkenyl, alkoxy, or —COO—R4, in which R4 is alkyl; R5 is alkyl, alkenyl, alkoxy, or alkoxymethyl; Z1 and Z2 are independently a single bond, —CH2O—, —OCH2—, —(CH2)2—, —(CH2)4—, —CF2O—, —OCF2—, —C2H4CF2O—, —C2H4OCF2—, —CF2OC2H4—, or —OCF2C2H4—, Z3 is a single bond or —COO—; A1 is 1,4-cyclohexylene or 1,4-phenylene; A2 and A3 are independently 1,4-cyclohexylene, 1,4-phenylene, 1,4-phenylene in which any hydrogen may be replaced by fluorine, or 2-difluoromethyl-3-fluoro-1,4-phenylene; A4 is 1,4-cyclohexylene, 1,4-phenylene, or 1,4-phenylene in which a hydrogen is replaced by a fluorine; A5 is 1,4-phenylene or 1,4-phenylene in which a hydrogen is replaced by a fluorine; A6is 2-fluoro-1,4-phenylene; n is 0 or 1; in the formula (1), when n is 0, A2 is 2-difluoromethyl-3-fluoro-1,4-phenylene, and Z2 is a single bond; and in the formula (1), when n is 1, one of A2 and A3 is 2-difluoromethyl-3-fluoro-1,4-phenylene, and one of Z1 and Z2 is a single bond.
    • 9. 发明申请
    • ORGANIC LIGHT EMITTING DEVICE AND MATERIALS FOR USE IN SAME
    • US20130306961A1
    • 2013-11-21
    • US13995216
    • 2011-02-11
    • Hitoshi YamamotoMichael S. WeaverJulia J. BrownKazuki NishimuraToshihiro IwakumaTomoki KatoMitsunori Ito
    • Hitoshi YamamotoMichael S. WeaverJulia J. BrownKazuki NishimuraToshihiro IwakumaTomoki KatoMitsunori Ito
    • H01L51/50
    • H01L51/5028H01L51/0059H01L51/0067H01L51/0072H01L51/0085H01L51/5016
    • The present invention provides an OLED in which an organic thin film emissive layer comprising a single layer or plural layers between a cathode and an anode, wherein the organic thin film layer comprises at least one organic light emitting layer, wherein at least one light emitting layer comprises at least one host material and at least one phosphorescent emitter material, wherein the host material comprises a substituted or unsubstituted hydrocarbon compound having the chemical structure represented by the following formula: wherein at least one of Ar1 to Ar3 is represented by the following formula: wherein at least X1 to X3 are independently a nitrogen atom or CR2, provided that two of X1 to X3 are a nitrogen atom, R1 is a linear or branched alkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 3 to 10 ring carbon atoms, a substituted or unsubstituted silyl group, an aryl group having 6 to 50 ring carbon atoms, a heteroaryl group having 5 to 50 ring atoms, a halogen atom or a cyano group, R2 is a hydrogen atom or a group represented by R1, a is an integer of 1 to 2 and n is an integer of 0 to 3, L1 is a substituted or unsubstituted arylene group having 6 to 50 ring carbon atoms, L2 is a substituted or unsubstituted arylene group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heteroarylene group having 5 to 50 ring atoms, at most two of Ar1 to Ar3 that are not the group of formula (2) are independently a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, when L1, L2 and/or at most two of Ar1 to Ar3 that are not the group of formula (2) are a substituted group, the substitutes are independently a linear or branched alkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 3 to 10 ring carbon atoms, a substituted or unsubstituted silyl group, an aryl group having 6 to 14 ring carbon atoms, a heteroaryl group having 5 to 20 ring atoms, a halogen atom or a cyano group, when two or more of Ar1 to Ar3 are the groups of formula (2), the groups of formula (2) may be the same or different, when a is 2, R1s may be the same or different, and when n is 2 or more, L2s may be the same or different; and the phosphorescent emitter material comprises a phosphorescent organometallic complex having a substituted chemical structure represented by one of the following partial chemical structures represented by the following formulas: wherein each R is independently selected from the group consisting of H, alkyl, alkenyl, alkynyl, CN, CF3, CnF2n+1, trifluorovinyl, CO2R, C(O)R, NR2, NO2, OR, halo, aryl, heteroaryl, substituted heteroaryl or a heterocyclic group.
    • 10. 发明申请
    • ORGANIC LIGHT EMITTING DEVICE AND MATERIALS FOR USE IN SAME
    • US20130306960A1
    • 2013-11-21
    • US13995193
    • 2011-02-11
    • Hitoshi YamamotoMichael S. WeaverJulia J. BrownKazuki NishimuraToshihiro IwakumaMitsunori Ito
    • Hitoshi YamamotoMichael S. WeaverJulia J. BrownKazuki NishimuraToshihiro IwakumaMitsunori Ito
    • H01L51/50
    • H01L51/5028H01L51/0054H01L51/0058H01L51/0059H01L51/0072H01L51/0085H01L51/5012
    • The present invention provides an OLED in which an organic thin film emissive layer comprising a single layer or plural layers between a cathode and an anode, wherein the organic thin film layer comprises at least one organic light emitting layer, wherein at least one light emitting layer comprises at least one host material and at least one phosphorescent emitter material, wherein the host material comprises a substituted or unsubstituted hydrocarbon compound having the chemical structure represented by the following formula (1): wherein R2 represents a hydrogen atom, a benzene ring, a condensed aromatic hydrocarbon ring, a dibenzofuran ring or a group represented by Ar3—R3; Ar1 to Ar3 each independently represent a benzene ring, a condensed aromatic hydrocarbon ring or a dibenzofuran ring; R1 and R3 each independently represent a hydrogen atom, a benzene ring, a condensed aromatic hydrocarbon ring, or a dibenzofuran ring; the condensed aromatic hydrocarbon ring represented by R1 to R3 and Ar1 to Ar3 is selected from the group consisting of a naphthalene ring, a chrysene ring, a fluoranthene ring, a triphenylene ring, a phenanthrene ring, a benzophenanthrene ring, a dibenzophenanthrene ring, a benzotriphenylene ring, a benzochrysene ring, and a benzo[b]fluoranthene ring; and R1 to R3, Ar1 to Ar3 and 2,7-disubstituted naphthalene ring each independently may have one or more substituents; with the proviso that when Ar1 and Ar2 each represents a condensed aromatic hydrocarbon constituted by four or more-membered ring, Ar1 and Ar2 are different from each other; wherein when Ar1 and Ar2 each represents a benzene ring, R1 and R2 cannot both be a hydrogen atom or a naphthalene ring at the same time; and when R1 and R2 each represents a hydrogen atom, Ar1 and Ar2 cannot both be a naphthalene ring at the same time or a combination of a naphthalene ring and a benzene ring; and the phosphorescent emitter material comprises a phosphorescent organometallic complex having a substituted chemical structure represented by one of the following partial chemical structures represented by the following formulas: wherein each R is independently selected from the group consisting of H, alkyl, alkenyl, alkynyl, CN, CF3, CnF2n+1, trifluorovinyl, CO2R, C(O)R, NR2, NO2, OR, halo, aryl, heteroaryl, substituted heteroaryl or a heterocyclic group.