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    • 3. 发明授权
    • Colored film-coated glass article
    • 彩色镀膜玻璃制品
    • US5942331A
    • 1999-08-24
    • US898365
    • 1997-07-22
    • Taro MiyauchiMitsuhiro KawazuKoichi Maeda
    • Taro MiyauchiMitsuhiro KawazuKoichi Maeda
    • C03C17/25C03C17/00B32B17/00
    • C03C17/007C03C17/008C03C2217/475C03C2217/479Y10T428/256Y10T428/257
    • A sunligh absorbing colored film-coated glass article which can freely control color tint, infrared transmittance, UV light transmittance, and visible light transmittance. The colored film-coated glass article which comprises a glass substrate and a colored film formed on one surface thereof, the colored film comprising, in % by weight:5-30% at least one coloring fine particle selected from the group consisting of gold, silver, platinum, palladium, cadmium sulfide, and cadmium selenide;0-50% silicon oxide;0-70% titanium oxide;0-20% cerium oxide; and5-95% at least one coloring metal oxide selected from the group consisting of cobalt oxide, chromium oxide, copper oxide, manganese oxide, nickel oxide, and iron oxide, with the proviso that the total amount of silicon oxide, titanium oxide, and iron oxide is 10 to 95 wt %.
    • 可以自由控制彩色,红外透射率,紫外光透射率和可见光透射率的日光浴吸收彩色薄膜玻璃制品。 所述彩色薄膜包覆玻璃制品包括玻璃基底和在其一个表面上形成的着色膜,所述着色膜以重量%计含有5-30%至少一种选自金, 银,铂,钯,硫化镉和硒化镉; 0-50%氧化硅; 0-70%氧化钛; 0-20%氧化铈; 和选自氧化钴,氧化铬,氧化铜,氧化锰,氧化镍和氧化铁中的至少一种着色金属氧化物的5-95%,条件是氧化硅,氧化钛, 氧化铁为10〜95重量%。
    • 4. 发明申请
    • LIQUID CRYSTAL LIGHT CONTROL DEVICE AND METHOD FOR PRODUCING THE SAME
    • 液晶灯控制装置及其制造方法
    • US20100302476A1
    • 2010-12-02
    • US12744659
    • 2008-11-13
    • Masaatsu KidoMitsuhiro KawazuYuichi YanoDaisuke ShinikeHitoshi Shinike
    • Masaatsu KidoMitsuhiro KawazuYuichi YanoDaisuke ShinikeHitoshi Shinike
    • G02F1/1335B32B37/02
    • C09K19/544G02F1/1334Y10T156/10
    • In the production method of the present invention, an emulsion including a copolymer with a glass transition temperature (Tg) of −50 to 20° C. is obtained by the emulsion polymerization of a monomer group including a monomer A that is a (meth)acrylic acid alkyl ester (where the alkyl group is an open chain group with 1 to 20 carbon atoms or a cyclic group with 5 to 20 carbon atoms) as the main monomer and a monomer B having a carbon-carbon double bond and a nonionic hydrophilic group such as a polyoxyalkylene group, an amide group, and a hydroxyl group. Liquid crystals are dispersed in this emulsion, which is applied onto a conductive film-coated substrate. Another conductive film-coated substrate is laminated thereto, and thus a liquid crystal light control device is obtained. A monomer C having a carboxyl group and/or an amino group and a carbon-carbon double bond may be used in combination with a crosslinking agent so that a crosslinked structure is introduced into the copolymer. The present invention provides a liquid crystal light control device in which the transparency with a voltage applied and the shielding property with no voltage applied are compatible at high level.
    • 在本发明的制造方法中,通过包含单体A(甲基)丙烯酸酯单体的乳液聚合,得到玻璃化转变温度(Tg)为-50〜20℃的共聚物的乳液, 丙烯酸烷基酯(其中烷基是具有1至20个碳原子的开链基团或具有5至20个碳原子的环状基团)作为主要单体和具有碳 - 碳双键的单体B和非离子亲水性 例如聚氧化烯基,酰胺基和羟基。 将液晶分散在该乳液中,将其施加到导电膜涂覆的基底上。 将另一个导电膜涂覆的基板层压,从而获得液晶光控制装置。 具有羧基和/或氨基的单体C和碳 - 碳双键可以与交联剂组合使用,使得交联结构被引入到共聚物中。 本发明提供了一种液晶光控制装置,其中施加电压的透明度和没有施加电压的屏蔽性能在高水平上是兼容的。
    • 5. 发明授权
    • Ultraviolet/infrared absorbent glass
    • 紫外/红外吸收玻璃
    • US06468934B2
    • 2002-10-22
    • US09785406
    • 2001-02-20
    • Yukihito NagashimaMitsuhiro KawazuToshifumi Tsujino
    • Yukihito NagashimaMitsuhiro KawazuToshifumi Tsujino
    • C03C3095
    • C03C4/085C03C3/095C03C4/082C03C17/007C03C17/008C03C2217/45C03C2217/479Y10T428/252Y10T428/256
    • An ultraviolet/infrared absorbent glass is formed of base glass, and colorants. The base glass includes 65 to 80 wt. % SiO2; 0 to 5 wt. % Al2O3; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO; 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O; 5 to 15 wt. % a total amount of MgO and CaO; 10 to 20 wt. % a total amount of Na2O and K2O; 0.05 to 0.3 wt. % SO3; and 0 to 5 wt. % B2O3. The colorants are formed of 0.35 to 0.55 wt. % the total iron oxide (T-Fe2O3) expressed as Fe2O3; 0.08 to 0.15 wt. % FeO; 0.8 to 1.5 wt. % CeO2 and 0 to 1.5 wt. % TiO2. FeO expressed as Fe2O3 is equal to or more than 20 wt.% and less than 27 wt. % of T-Fe2O3. The glass has high visible light transmittance and light greensih color shade so that it is useful for a window of a vehicle and a building.
    • 紫外/红外吸收玻璃由基底玻璃和着色剂形成。 基础玻璃包括65至80wt。 %SiO2; 0至5wt。 %Al2O3; 0〜10重量% %MgO; 5至15wt。 %CaO; 10至18wt。 %Na2O; 0至5wt。 %K2O; 5至15wt。 MgO和CaO的总量%; 10〜20重量% Na2O和K2O的总量% 0.05〜0.3重量% %SO3; 和0-5重量% %B2O3。 着色剂由0.35〜0.55重量% 以Fe2O3表示的总氧化铁(T-Fe2O3)的百分比; 0.08〜0.15wt %FeO; 0.8〜1.5wt。 %CeO 2和0〜1.5重量% %TiO2。 以Fe 2 O 3表示的FeO等于或大于20重量%且小于27重量% %的T-Fe2O3。 玻璃具有高可见光透光率和浅绿色色调,因此它对于车辆和建筑物的窗户是有用的。
    • 6. 发明授权
    • Colored film-coated ultraviolet/infrared absorbent glass plate and window glass of vehicle
    • 彩色涂膜紫外线/红外线吸收玻璃板和车窗玻璃
    • US06340646B1
    • 2002-01-22
    • US09437229
    • 1999-11-10
    • Yukihito NagashimaMitsuhiro KawazuToshifumi Tsujino
    • Yukihito NagashimaMitsuhiro KawazuToshifumi Tsujino
    • C03C3095
    • C03C4/085C03C3/095C03C4/082C03C17/007C03C17/008C03C2217/45C03C2217/479Y10T428/252Y10T428/256
    • A colored film-coated ultraviolet/infrared absorbent glass plate is formed of base glass, colorants, and a colored film. The base glass includes 65 to 80 wt. % SiO2; 0 to 5 wt. % Al2O3; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO; 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O; 5 to 15 wt. % total amount of MgO and CaO; 10 to 20 wt. % total amount of Na2O and K2O; 0.05 to 0.3 wt. % of SO3; and 0 to 5 wt. % B2O3. The colorants includes 0.35 to 0.55 wt. % total iron oxide (T-Fe2O3) expressed as Fe2O3; 0.08 to 0.15 wt. % FeO; 0.8 to 1.5 wt. % CeO2; and 0 to 0.5 wt. % TiO2. FeO expressed as Fe2O3 is equal to or more than 20 wt. % and less than 27 wt. % of T-Fe2O3. The colored film has a red color shade with a thickness between 30 nm and 300 nm and includes fine particles of gold and silicon oxide of more than 50 wt. % and equal to or less than 95 wt. %. The colored film is applied onto a surface of the ultraviolet/infrared absorbent glass plate.
    • 彩色薄膜紫外/红外线吸收玻璃板由基底玻璃,着色剂和着色膜形成。 基础玻璃包括65至80wt。 %SiO2; 0至5wt。 %Al2O3; 0〜10重量% %MgO; 5至15wt。 %CaO; 10至18wt。 %Na2O; 0至5wt。 %K2O; 5至15wt。 MgO和CaO的总量% 10〜20重量% Na2O和K2O的总量% 0.05〜0.3重量% SO3% 和0-5重量% %B2O3。 着色剂包括0.35至0.55wt。 以Fe2O3表示的总氧化铁(T-Fe2O3)%; 0.08〜0.15wt %FeO; 0.8〜1.5wt。 %CeO2; 和0〜0.5wt。 %TiO2。 以Fe2O3表示的FeO等于或大于20wt。 %且小于27wt。 %的T-Fe2O3。 着色膜具有厚度在30nm和300nm之间的红色色调,并且包括大于50重量%的金和氧化硅的细颗粒。 %且等于或小于95wt。 %。 将着色膜施加到紫外/红外线吸收玻璃板的表面上。
    • 9. 发明授权
    • Cover glass for photoelectric conversion devices and method for producing the same
    • 光电转换装置用盖玻璃及其制造方法
    • US09188705B2
    • 2015-11-17
    • US13513972
    • 2010-11-05
    • Mizuho KoyoToru YamamotoMitsuhiro KawazuMasaatsu Kido
    • Mizuho KoyoToru YamamotoMitsuhiro KawazuMasaatsu Kido
    • B32B5/16B05D1/02G02B1/113G02B1/115H01L31/0216
    • G02B1/113G02B1/115H01L31/02168Y02E10/50Y10T428/24421
    • In order to eliminate non-uniformity in the appearance of a cover glass for photoelectric conversion devices, the reflectance curve of the cover glass is extremely flattened. Provided is a cover glass for photoelectric conversion devices that includes a glass sheet having an uneven surface such as a figured glass, and a reflection-reducing film formed on the uneven surface. The reflection-reducing film includes silica fine particles and a binder for the silica fine particles. The silica fine particles are arranged in a single layer on the top portion of the uneven surface of the glass sheet, while the silica fine particles are arranged in stacks to a thickness equivalent to at least three layers on the bottom portion of the uneven surface. The uneven surface of the glass sheet has an average spacing Sm of at least 0.4 mm but not more than 2.5 mm and an arithmetic average roughness Ra of 0.5 μm to 5 μm. The cover glass has a reflectance of at least 1.5% but not more than 3% over the entire wavelength range of 380 nm to 780 nm for incident light from the side on which the reflection-reducing film is formed.
    • 为了消除用于光电转换装置的玻璃罩外观的不均匀性,盖玻璃的反射率曲线非常扁平化。 提供一种用于光电转换装置的玻璃罩,其包括具有不平坦表面的玻璃板,例如图案玻璃,以及形成在不平坦表面上的反射减少膜。 减反射膜包括二氧化硅微粒和二氧化硅微粒的粘合剂。 二氧化硅微粒在玻璃板的不平坦表面的顶部上排列成单层,而二氧化硅微粒以不均匀表面的底部相当于三层的厚度排列。 玻璃板的不平坦表面的平均间隔Sm为至少0.4mm但不大于2.5mm,算术平均粗糙度Ra为0.5μm至5μm。 对于从形成有减反射膜的一侧的入射光,玻璃罩在380nm〜780nm的整个波长范围内具有至少1.5%且不大于3%的反射率。