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    • 5. 发明申请
      US20060178469A1 Polymerizable cyclopropyl acrylates 有权
    • Polymerizable cyclopropyl acrylates
    • US20060178469A1
    • 2006-08-10
    • US11200488
    • 2005-08-09
    • Norbert Moszner , Frank Zeuner , Urs-Karl Fischer , Volker Rheinberger , Armin de Meijere , Viktor Bahutski
    • Norbert Moszner , Frank Zeuner , Urs-Karl Fischer , Volker Rheinberger , Armin de Meijere , Viktor Bahutski
    • C08L31/00 , C07C69/74
    • A61K6/083 , A61K6/0017 , A61K6/0023 , C07C69/753 , C07C69/757 , C07C2602/18 , C07C2603/66 , C08L33/00
    • Cyclopropyl acrylate of general formula (1), constitutional and stereoisomers thereof and their mixtures in which A is selected from: Y for A=A1 is absent, CH2 or 0, and for A=A2=CH2 or 0; n for Y is absent=0, 1, 2 or 3, and for Y=CH2 or 0=1; m for Y is absent=0, 1, 2 or 3, and for Y=CH2 or 0=1; r=1, 2, 3 or 4; R1=H, a C1 to C10 alkyl, C6 to C12 aryl, C1 to C10 arylalkyl or bicyclic C5-C12 radical or —R10—X—; R2=an aliphatic C1-C20 hydrocarbon radical, substituted r times by the expression in brackets, which can be interrupted by O or S, cycloaliphatic C4-C12 radical, bicyclic C5-C12 radical, a C6-C14 aryl or C7-C20 alkylaryl radical; R3=—CO—OR9, —CO—R9, —S(O)R9, SO2R9, —SO2(OR9), —PO(OR9)2, —CN, —H, —R9; R4=—CO—OR9, —CO—R9, —S(O)R9, —SO2R9, —SO2(OR9), —PO(OR9)2, —CN or —R11—R10—X—; R5-R8=independently of one another H, —CO—OR9, —CO—NHR9, —CO—NR92, —CO—R9, —CN, a C1-C20 alkyl radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C5-C12 radical, a C6-C14 aryl, C7-C20 alkylaryl radical, or at least two of the radicals form together with the carbon atoms to which they are bonded a 5- to 8-membered ring system; R9=a C1-C20 alkyl radical which can be interrupted by O or S, a cycloaliphatic C4-C12 radical, a bicyclic C5-C12 radical, a C6-C14 aryl or C7-C20 alkylaryl radical; R10=is absent or a C1-C20 alkylene radical which can be interrupted by O or S, a cycloaliphatic or bicyclic C5-C12 radical, a C6-C14 arylene or C7-C20 alkylenearylene radical; R11=—COO—, —CO—, —SO—, —SO2—, —SO2(O—), —PO(OR9)(O—); X=is absent, —O—CO—, —CO—O—, —NH—CO—, —CO—NH—, —NH—CO—O— or —O—CO—NH—, wherein X has the meaning “is absent” if R10 is absent, wherein the radicals R2 and R5-9 can be substituted or unsubstituted, either R4=—R11—R10—X— or R1=—R10—X— and the expression in brackets is bonded to R2 via X and wherein several radicals of one type can be identical or different.
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