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    • 1. 发明授权
    • Impact modifier and molding material containing it
    • 抗冲改性剂和含有它的成型材料
    • US5336718A
    • 1994-08-09
    • US996410
    • 1992-12-23
    • Norbert NiessnerWolfgang FischerNorbert GuentherbergKarl RuppmichFriedrich Seitz
    • Norbert NiessnerWolfgang FischerNorbert GuentherbergKarl RuppmichFriedrich Seitz
    • C08F285/00C08L25/12C08L27/06C08L51/00C08L69/00C08F257/02C08F265/04
    • C08F285/00C08L25/12C08L27/06C08L69/00C08L51/003Y10S525/902
    • A graft consisting of from 5 to 90% of a core A1 having a glass transition temperature above 25.degree. C. made up of, from 50 to 99.9% of a vinylaromatic monomer and from 0.1 to 10% of a polyfunctional crosslinking and/or graft-linking monomer optionally up to 49.9% of one or more copolymerizable monomers; from 5 to 90% of a first shell A2 of elastomeric material made up of from 50 to 99.8% of an alkyl acrylate and/or of a diene, from 0.1 to 10% of a polyfunctional graft-linking monomer, up to 49.8% of one or more copolymerizable unsaturated monomers and from 0.1 to 10% of one or more monomers containing acidic groups; from 5 to 90% of a second shell A3 of rigid material made up of from 50 to 99.9% of a vinylaromatic monomer, up to 10% of a polyfunctional cross-linking and/or graft-linking monomer, up to 49.9% of one or more copolymerizable monomers and from 0.1 to 20% of a monomer containing one or more basic groups; and optionally up to 85% of a third shell A4 of a copolymer of, from 1 to 99% of one or more vinylaromatic monomers and from 1 to 99% of one or more copolymerizable monomers. The percentages are by weight and based, in the case of the monomers, on the core or shells to which they belong and, in the case of the core and shells A1-A4, on the sum of A1 to A4.
    • 由50至99.9%的乙烯基芳族单体和0.1至10%的多官能交联和/或接枝组成的具有玻璃化转变温度高于25℃的核心A1的5-90%的移植物 连接单体,任选地高达49.9%的一种或多种可共聚单体; 由50至99.8%的丙烯酸烷基酯和/或二烯,0.1至10%的多官能接枝单体组成的弹性体材料的第一壳A2的5至90%,高达49.8%的多官能接枝单体 一种或多种可共聚的不饱和单体和0.1至10%的一种或多种含酸性基团的单体; 由50至99.9%的乙烯基芳族单体组成的刚性材料的第二壳A3的5至90%,多至10%的多官能交联和/或接枝单体,高达49.9%的一种 或更多的可共聚单体和0.1至20%的含有一个或多个碱性基团的单体; 和至多85%的共聚物的第三壳A4,1至99%的一种或多种乙烯基芳族单体和1至99%的一种或多种可共聚单体。 百分比是重量百分比,在单体的情况下,它们属于它们的核心或壳,并且在核心和壳A1-A4的情况下,基于A1至A4的总和。
    • 2. 发明授权
    • Molding composition having a matt surface
    • 具有无光泽表面的成型组合物
    • US5475053A
    • 1995-12-12
    • US259165
    • 1994-06-13
    • Norbert NiessnerFriedrich SeitzWolfgang FischerNorbert GuentherbergKarl RuppmichRainer MoorsRobert Weiss
    • Norbert NiessnerFriedrich SeitzWolfgang FischerNorbert GuentherbergKarl RuppmichRainer MoorsRobert Weiss
    • C08L51/00C08L51/04C08L51/06C08L55/02C08L101/00
    • C08L101/00C08L51/04C08L55/02C08L2555/40
    • A molding composition based on an impact-modified thermoplastic A selected from ABS, ASA, impact-resistant polystyrene (HIPS) impact resistant polymethyl methacrylate, impact resistant PVC, polycarbonate, polyester carbonate, polyester, polyamide, polyphenylene ether, polyether ketone, polyether sulfone, polysulfone, polyoxyalkylene, polyarylene sulfide and also mixtures thereof containing a matting agent B composed of 30 to 80% by weight of an elastomeric grafting base B1 of 75 to 99.8% by weight of an alkyl acrylate having 1 to 8 carbon atoms in the alkyl radical (B11), 0.1 to 5% by weight of a polyfunctional, crosslinking monomer (B12) and 0.1 to 20% by weight of a monomer containing one or more acidic groups, or 49.9 to 99.9% by weight of one or more dienes (B111), up to 50% by weight of a further ethylenically unsaturated monomer (B112) and 0.1 to 20% by weight of a monomer containing one or more acidic groups (B113), and 20 to 70% by weight of a graft sheath B2 composed of 40 to 99.9% by weight of an aromatic vinyl monomer (B21), up to 49.9% by weight of a polar, copolymerizable, ethylenically unsaturated monomer (B22) and 0.1 to 20% by weight of a monomer containing one or more basic groups (B23), and also a molding composition whose constituents B13 and B113 and B23 are interchanged.
    • 基于抗冲击改性热塑性塑料A的成型组合物,其选自ABS,ASA,耐冲击聚苯乙烯(HIPS)耐冲击聚甲基丙烯酸甲酯,耐冲击PVC,聚碳酸酯,聚酯碳酸酯,聚酯,聚酰胺,聚苯醚,聚醚酮,聚醚砜 ,聚砜,聚氧化烯,聚芳硫醚以及它们的混合物,其含有消光剂B,其由30至80重量%的弹性体接枝基料B1为75至99.8重量%的烷基中具有1至8个碳原子的丙烯酸烷基酯 (B11),0.1〜5重量%的多官能交联单体(B12)和0.1〜20重量%的含有一个或多个酸性基团的单体,或49.9-99.9重量%的一种或多种二烯( B111),至多50重量%的另外的烯属不饱和单体(B112)和0.1〜20重量%的含有一个或多个酸性基团(B113)的单体和20〜70重量%的接枝鞘B2 由40组成 99.9重量%的芳族乙烯基单体(B21),最多49.9重量%的极性,可共聚的烯属不饱和单体(B22)和0.1-20重量%的含有一个或多个碱性基团(B23)的单体, ,以及其组分B13和B113和B23互换的成型组合物。
    • 3. 发明授权
    • Thermoplastic molding material
    • 热塑性成型材料
    • US5367029A
    • 1994-11-22
    • US136932
    • 1993-10-18
    • Wolfgang FischerNorbert GuentherbergNorbert Niessner
    • Wolfgang FischerNorbert GuentherbergNorbert Niessner
    • C08F265/04C08F279/02C08F265/06
    • C08F265/04C08F279/02
    • Particulate graft copolymers for matt thermoplastic molding materials contain a base and a graft sheath. The base contains 75 to 99.8% of at least one alkyl acrylate, from 0.1 to 5% of at least one polyfunctional, crosslinking monomer having at least two ethylenic double bonds which are not conjugated in the 1,3-position, and from 0.1 to 20% of at least one ethylenically unsaturated monomer having one or more acidic groups. Alternatively, the base may contain at least 50% of one or more dienes, up to 50% of at least one further ethylenically unsaturated monomer, and up to 15% of at least one ethylenically unsaturated monomer having one or more acidic groups. The sheath contains from 0 to 99.8% of at least one aromatic vinyl monomer, from 0 to 99.8% of at least one polar, copolymerizable, ethylenically unsaturated monomer, from 0.1 to 20% of at least one ethylenically unsaturated monomer having one or more basic groups, and from 0.1 to 10% of at least one hydroxyalkyl (meth)acrylate. All percentages are by weight.
    • 用于无光热塑性成型材料的颗粒接枝共聚物含有基体和移植鞘。 该碱含有75-99.8%的至少一种丙烯酸烷基酯,0.1-5%的至少一种具有至少两个在1,3-位上不共轭的烯键式双键的多官能交联单体,和0.1至 20%至少一种具有一个或多个酸性基团的烯属不饱和单体。 或者,碱可以包含至少50%的一种或多种二烯,至多50%的至少一种其它烯键式不饱和单体和至多一种具有一个或多个酸性基团的至少一种烯属不饱和单体的至少15%。 鞘含有0至99.8%的至少一种芳族乙烯基单体,0至99.8%的至少一种极性,可共聚的烯键式不饱和单体,0.1-20%的至少一种烯属不饱和单体,其具有一个或多个碱 和至少一种(甲基)丙烯酸羟烷基酯的0.1至10%。 所有百分比均以重量计。
    • 4. 发明授权
    • Particulate graft copolymer
    • 颗粒接枝共聚物
    • US5373060A
    • 1994-12-13
    • US85907
    • 1993-07-06
    • Norbert GuentherbergWolfgang FischerNorbert Niessner
    • Norbert GuentherbergWolfgang FischerNorbert Niessner
    • C08F285/00C08L51/00C08F265/02C08F265/04C08F279/02C08L51/04
    • C08L51/003C08F285/00
    • A particulate graft polymer A ofA1: a grafting base based on a polydiene rubber A1 of, based on A1,A11: 70 to 100% by weight of a polymerizable diene, andA12: up to 30% by weight of a copolymerizable, ethylenically unsaturated monomer having a first graft sheath A2 of, based on A2,A21: 75 to 99.8% of at least one C.sub.1 -C.sub.8 alkyl acrylate A21,A22: 0.1 to 5% by weight of at least one polyfunctional, crosslinking monomer A22,A23: 0.1 to 20% by weight of at least one monomer A23 containing one or more acidic or basic groups, and a second graft sheath A3 comprising, based on A3,A31: 40 to 89.9% by weight of at least one aromatic vinyl monomer A31,A32: 10 to 49.9% by weight of at least one polar, ethylenically unsaturated monomer A32,A33: 0.1 to 20% by weight of at least one monomer A33 containing one or more basic or acidic groups, andA34: up to 5% by weight of at least one polyfunctional, crosslinking monomer A34,A23 and A33 in each case being different groups.
    • A1的颗粒接枝聚合物A:基于基于Al,A11:70至100重量%的可聚合二烯的聚二烯橡胶A1和A12:至多30重量%的可共聚的烯键式 不饱和单体,具有基于A2的第一接枝鞘A2,A21:75至99.8%的至少一种丙烯酸C 1 -C 8烷基酯A 21,A 22:0.1至5重量%的至少一种多官能交联单体A22,A23: 0.1至20重量%的至少一种含有一个或多个酸性或碱性基团的单体A23和第二接枝鞘A3,其基于A3,A31:40至89.9重量%的至少一种芳族乙烯基单体A31, A32:10至49.9重量%的至少一种极性,烯属不饱和单体A32,A33:0.1至20重量%的至少一种含有一个或多个碱性或酸性基团的单体A33,以及A34:至多5% 至少一种多官能交联单体A34,A23和A33的重量在每种情况下都是不同的基团。
    • 6. 发明授权
    • Particulate graft copolymer and thermoplastic molding materials obtained
therefrom
    • 从其获得的颗粒接枝共聚物和热塑性成型材料
    • US5438099A
    • 1995-08-01
    • US165465
    • 1993-12-13
    • Wolfgang FischerNorbert Guentherberg
    • Wolfgang FischerNorbert Guentherberg
    • C08F2/22C08F265/04C08F279/02C08F291/08C08L25/12C08L51/00C08L51/04C08L55/02C08L69/00C08L71/12C08F291/02
    • C08L51/04C08F265/04C08F279/02C08F291/08C08L25/12C08L51/003C08L55/02C08L69/00C08L71/123
    • Abstract of the disclosure: A particulate graft copolymer comprises 30 to 90% by weight of at least one elastomeric grafting base A having a weight average particle size of from 30 to 1,000 nm comprising, based on A, 85 to 99.8% by weight of at least one alkyl acrylate A11 having 1 to 8 carbon atoms in the alkyl radical, 0.1 to 5% by weight of at least one polyfunctional, crosslinking monomer A12, and 0.1 to 10% by weight of at least one hydroxyalkyl acrylate or hydroxyalkyl methacrylate A13 or at least 50% by weight of one or more dienes A111, up to 50% by weight of one or more ethylenically unsaturated monomers A112, and 0.1 to 10% by weight of at least one hydroxyalkyl acrylate or hydroxyalkyl methacrylate A113 and10 to 70% by weight of a graft sheath B comprising, based on B, up to 99.9% by weight of at least one aromatic vinyl monomer B1, up to 99.9% by weight of at least one polar, copolymerizable, ethylenically unsaturated monomer B2, and 0.1 to 20% by weight of at least one monomer B3 containing one or more basic or acid groups.
    • 本发明摘要:一种颗粒状接枝共聚物包含30-90%重量的至少一种重均粒径为30至1,000nm的弹性体接枝基体A,其基于A为85-99.8%(重量),基于A 烷基中具有1至8个碳原子的丙烯酸烷基酯A11和0.1至5重量%的至少一种多官能交联单体A12和0.1至10重量%的至少一种丙烯酸羟烷基酯或甲基丙烯酸羟烷基酯A13或 至少50重量%的一种或多种二烯A111,至多50重量%的一种或多种烯属不饱和单体A112和0.1至10重量%的至少一种丙烯酸羟烷基酯或甲基丙烯酸羟烷基酯A113和10至70重量% 的移植鞘B,其包含基于B的至多一种芳族乙烯基单体B1至多99.9重量%的至多99.9重量%的至少一种极性,可共聚的烯键式不饱和单体B2和0.1至 20重量%的至少一个mo 含有一个或多个碱性或酸性基团的聚合物B3。
    • 7. 发明授权
    • Three stage graft copolymers and weathering-stable, dull thermoplastic
molding materials containing said copolymers and having good
low-temperature toughness
    • 含有所述共聚物并且具有良好的低温韧性的三阶段接枝共聚物和风化稳定的无光热塑性成型材料
    • US5652307A
    • 1997-07-29
    • US730808
    • 1996-10-17
    • Norbert NiessnerWolfgang Fischer
    • Norbert NiessnerWolfgang Fischer
    • C08F285/00C08L25/12C08L51/00C08L51/06C08L101/00C08F283/12
    • C08L25/12C08F285/00C08L101/00C08L51/00C08L51/003Y10S525/902
    • Graft copolymers obtained by(A) polymerizing 10 to 89 wt % of a mixture consisting essentially of either(a1) from 70 to 99.89 wt % of a C.sub.1 -C.sub.18 -alkyl ester of acrylic acid,(a2) from 0.1 to 10 wt % of a polyfunctional monomer,(a3) from 0 to 29.89 wt % of an ethylenically unsaturated monomer which differs from (a1) and (a2), is copolymerizable therewith and carries no acid group and(a4) from 0.01 to 10 wt % of a copolymerizable monomer containing at least one acid groupor(a5) from 49.99 to 99.99 wt % of at least one diene,(a6) from 0 to 50 wt % of a monomer which is copolymerizable therewith and carries no acid group and(a7) from 0.01 to 10 wt % of a copolymerizable monomer containing at least one acid groupin the presence of from 1 to 80 wt % of a cross-linked silicone rubber to form a copolymer A,and(B) polymerizing 10 to 89 wt % of a mixture consisting essentially of(b1) from 50 to 99.99 wt % of a styrene compound of the formula (I) ##STR1## where R.sup.1 and R.sup.2 independently of one another are each hydrogen, C.sub.1 -C.sub.8 -alkyl, etc.(b2) from 0 to 50 wt % of a methacrylonitrile, acrylonitrile, methacrylic acid, acrylic acid, maleic anhydride, etc. monomerand(b3) from 0.01 to 20 wt % of a copolymerizable monomer containing at least one basic groupin the presence of the graft copolymer (A) and used to prepare thermoplastic molding materials.
    • 通过(A)聚合10〜89重量%的基本上由(a1)70〜99.89重量%的丙烯酸的C1-C18烷基酯,(a2)0.1〜10重量% 的多官能单体(a3)0〜29.89重量%与(a1)和(a2)不同的烯键式不饱和单体可共聚,不含酸基,(a4)为0.01〜10重量% 含有至少一个酸基团的可共聚单体或(a5)至少一种二烯的49.99至99.99重量%的(a6)0至50重量%的可与其共聚的单体,(a7)不含酸基团 0.01〜10重量%的可共聚单体,在1〜80重量%的交联硅橡胶的存在下,含有至少1个酸基,形成共聚物A,(B)使10〜89重量% 混合物主要由(b1)50至99.99wt%的式(I)苯乙烯化合物组成,其中R1和R2独立地为 各自为氢,C 1 -C 8烷基等(b2)0〜50重量%的甲基丙烯腈,丙烯腈,甲基丙烯酸,丙烯酸,马来酸酐等单体,(b3)为0.01〜20 wt%的在接枝共聚物(A)存在下含有至少一个碱性基团的可共聚单体,并用于制备热塑性模塑材料。
    • 8. 发明授权
    • Three-stage silicone rubber based graft copolymers
    • 三阶段硅橡胶基接枝共聚物
    • US5585436A
    • 1996-12-17
    • US352750
    • 1994-12-02
    • Norbert NiessnerWolfgang Fischer
    • Norbert NiessnerWolfgang Fischer
    • C08F285/00C08L25/12C08L51/00C08L51/06C08L101/00C08F283/12
    • C08L25/12C08F285/00C08L101/00C08L51/00C08L51/003Y10S525/902
    • Graft copolymers obtained by(A) polymerization of from 10 to 89% by weight of a mixture consisting essentially of either(a1) from 70 to 99.89% by weight of a C.sub.1 -C.sub.18 -alkyl ester of acrylic acid,(a2) from 0.1 to 10% by weight of a polyfunctional monomer,(a3) from 0 to 29.89% by weight of an ethylenically unsaturated monomer which differs from (a1) and (a2), is copolymerizable therewith and carries no acid group and(a4) from 0.01 to 10% by weight of a copolymerizable monomer containing at least one acid group or(a5) from 49.99 to 99.99% by weight of at least one diene,(a6) from 0 to 50% by weight of a monomer which is copolymerizable therewith and carries no acid group and(a7) from 0.01 to 10% by weight of a copolymerizable monomer containing at least one acid group in the presence of from 1 to 80% by weight of a crosslinked silicone rubberand to form a graft copolymer A,(B) polymerization of from 10 to 89% by weight of a mixture consisting essentially of(b1) from 50 to 99.99% by weight of a styrene compound of the formula (I) ##STR1## where R.sup.1 and R.sup.2 independently of one another are each hydrogen, C.sub.1 -C.sub.8 -alkyl, etc.,(b2) from 0 to 50% by weight of a methacrylonitrile, acrylonitrile, methacrylic acid, acrylic acid, maleic anhydride, etc. monomer and(b3) from 0.01 to 20% by weight of a copolymerizable monomer containing at least one basic group in the presence of the graft copolymer (A).
    • 通过(A)聚合10至89重量%的基本上由(a1)70至99.89重量%的丙烯酸的C 1 -C 18烷基酯,(a2)0.1重量%混合而获得的接枝共聚物 -10重量%的多官能单体(a3)0〜29.89重量%的与(a1)和(a2)不同的烯属不饱和单体可共聚,不含酸基,(a4)为0.01 至10重量%的含有至少一个酸基的可共聚单体或(a5)49.99至99.99重量%的至少一种二烯,(a6)0至50重量%的可与其共聚的单体,和 不含酸基和(a7)0.01〜10重量%的含有至少一个酸基的可共聚单体,在1〜80重量%交联硅橡胶的存在下,形成接枝共聚物A( B)基本上由(b1)50至99.99%的混合物组成的混合物的10至89重量% 重量的式(I)的苯乙烯化合物其中R 1和R 2彼此独立地为氢,C 1 -C 8烷基等,(b2)0至50重量%的甲基丙烯腈 ,丙烯腈,甲基丙烯酸,丙烯酸,马来酸酐等单体,(b3)在接枝共聚物(A)的存在下,含有至少一个碱性基团的可共聚单体的0.01〜20重量%。
    • 9. 发明授权
    • Thermoplastic elastomeric block copolymers
    • 热塑性弹性体嵌段共聚物
    • US06197889B1
    • 2001-03-06
    • US08981051
    • 1997-12-11
    • Konrad KnollHermann GausepohlNorbert NiessnerPaul NaegeleWolfgang Fischer
    • Konrad KnollHermann GausepohlNorbert NiessnerPaul NaegeleWolfgang Fischer
    • C08F29300
    • C08F297/04
    • Elastomeric block copolymers comprising at least one hard block A composed of styrene monomers and at least one elastomeric block (B/A) composed of styrene monomers and dienes, the glass transition temperature Tg of the block A being more than 25° C. and that of block (B/A) being less than 25° C. and the phase volume ratio of block A to block (B/A) being chosen so that the proportion of the hard phase in the total block copolymer is from 1 to 40% by volume and the amount by weight of the diene is less than 50% by weight, and the relative proportion of 1,2 linkages of the polydiene, based on the sum of 1,2- and 1,4-cis/trans linkages, being below 15%, are prepared by anionic polymerization by means of a lithium alkyl in a nonpolar solvent in the presence of a soluble potassium salt and are used for the production of shaped articles.
    • 弹性体嵌段共聚物包含至少一个由苯乙烯单体组成的硬嵌段A和至少一个由苯乙烯单体和二烯构成的弹性嵌段(B / A),嵌段A的玻璃化转变温度Tg高于25℃, (B / A)小于25℃,并且选择块A与嵌段(B / A)的相体积比,使得总嵌段共聚物中硬相的比例为1〜40% 并且二烯的重量百分比小于50重量%,并且基于1,2-和1,4-顺/反键的总和的聚二烯的1,2-键的相对比例, 低于15%,通过在非极性溶剂中在可溶性钾盐的存在下通过烷基锂进行阴离子聚合制备,并用于生产成型制品。