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1. 发明授权

US06376695B1 Organosilicon-modified charge transporting compound and curable composition containing the compound and having charge transporting ability 失效
标题翻译：有机硅改性电荷输送化合物和含有化合物并具有电荷输送能力的固化性组合物
公开(公告)号：US06376695B1
公开(公告)日：2002-04-23
申请号：US08744192
申请日：1996-11-05
申请人： Nobuo Kushibiki , Kikuko Takeuchi , Hideki Kobayashi , Toru Masatomi , Kazuo Yoshinaga , Yuichi Hashimoto , Shunichiro Nishida
发明人： Nobuo Kushibiki , Kikuko Takeuchi , Hideki Kobayashi , Toru Masatomi , Kazuo Yoshinaga , Yuichi Hashimoto , Shunichiro Nishida
IPC分类号： C07F710
CPC分类号： G03G5/078 , C07F7/1804 , C08G77/18 , C08G77/20 , C08G77/70 , C08K9/06 , C08L83/04 , G03G5/0578 , G03G5/0614 , G03G5/0616 , G03G5/0629 , G03G5/0631 , G03G5/0633 , G03G5/0637 , G03G5/0642 , C08L2666/44
摘要： An organosilicon-modified charge transporting compound having a structure represented by the following Formula (I): wherein A represents a charge transporting group, Q represents a hydrolytic group or a hydroxyl group, R2 represents a monovalent hydrocarbon group or a halogen-substituted monovalent hydrocarbon group having 1 to 15 carbon atoms, n is 1 to 18, m is 1 to 3, and 1 is 1 to 5; and a curable composition containing the organosilicon-modified charge transporting compound and a cure type resin chiefly composed of an organosilicon high polymer.
摘要翻译：具有由下式（I）表示的结构的有机硅改性的电荷输送化合物：其中A表示电荷输送基团，Q表示水解基团或羟基，R2表示一价烃基或卤素取代的一价烃具有1至15个碳原子的基团，n为1至18，m为1至3，1为1至5; 以及含有有机硅改性的电荷输送性化合物和主要由有机硅高分子构成的固化型树脂的固化性组合物。

2. 发明授权

US5910386A Electrophotographic photosensitive member, and electrophotographic apparatus and process cartridge employing the same 失效
标题翻译：电子照相感光构件和使用其的电子照相设备和处理盒
公开(公告)号：US5910386A
公开(公告)日：1999-06-08
申请号：US890649
申请日：1997-07-09
申请人： Kazuo Yoshinaga , Shunichiro Nishida , Masataka Kawahara , Keiko Hiraoka , Nobuo Kushibiki , Hideki Kobayashi , Kikuko Takeuchi , Toru Masatomi
发明人： Kazuo Yoshinaga , Shunichiro Nishida , Masataka Kawahara , Keiko Hiraoka , Nobuo Kushibiki , Hideki Kobayashi , Kikuko Takeuchi , Toru Masatomi
IPC分类号： G03G5/147 , G03G5/14
CPC分类号： G03G5/147 , G03G5/14704 , G03G5/14773
摘要： An electrophotographic photosensitive member is disclosed which has a photosensitive layer and a protection layer. The protection layer contains a particulate colloidal silica and a siloxane resin to have a contact angle of water of not less than 90.degree.. The photosensitive member has a lowered surface energy and excellent mechanical and electrical durability.
摘要翻译：公开了一种具有感光层和保护层的电子照相感光构件。保护层含有胶体二氧化硅和硅氧烷树脂，其接触角不小于90°。感光构件具有降低的表面能和优异的机械和电气耐久性。

3. 发明授权

US06149979A Process for the preparation of photosensitive body surface coating material 失效
标题翻译：感光体表面涂料的制备方法
公开(公告)号：US06149979A
公开(公告)日：2000-11-21
申请号：US40888
申请日：1998-03-18
申请人： Nobuo Kushibiki , Kikuko Takeuchi , Hideki Kobayashi , Toru Masatomi
发明人： Nobuo Kushibiki , Kikuko Takeuchi , Hideki Kobayashi , Toru Masatomi
IPC分类号： C08G77/24 , C09D183/08 , G03G5/147 , B05D3/02
CPC分类号： G03G5/14773
摘要： A process for the preparation of a photosensitive body surface coating material comprises hydrolytically condensing an alkoxysilane in a mixed solvent comprising an alcohol and water in the presence of finely divided silica. A polysiloxane resin is produced by heat curing the silane after its hydrolytic condensation. The polysiloxane resin has the formula: R.sup.1 SiO.sub.3/2, and R.sup.1 comprises fluorohydrocarbon groups. The photosensitive body surface coating material is not detrimental to the functionality required of the electrophotographic photosensitive bodies, has superior optical uniformity, has low surface energy, and has superior surface hardness.
摘要翻译：用于制备感光体表面涂层材料的方法包括在细碎二氧化硅存在下，在包含醇和水的混合溶剂中水解缩合烷氧基硅烷。通过在其水解缩合后热固化硅烷来制备聚硅氧烷树脂。聚硅氧烷树脂具有下式：R1SiO3 / 2，R1包含氟代烃基。感光体表面涂层材料不影响电子照相感光体所需的功能，具有优异的光学均匀性，低表面能，并具有优异的表面硬度。

4. 发明授权

US5840816A Method of manufacturing a polysiloxane charge transporting material 失效
标题翻译：聚硅氧烷电荷输送材料的制造方法
公开(公告)号：US5840816A
公开(公告)日：1998-11-24
申请号：US743600
申请日：1996-11-04
申请人： Hideki Kobayashi , Nobuo Kushibiki , Tohru Masatomi , Kikuko Takeuchi
发明人： Hideki Kobayashi , Nobuo Kushibiki , Tohru Masatomi , Kikuko Takeuchi
IPC分类号： C07F7/10 , C07F7/18 , C08G77/26 , C08K5/544 , C08L83/04 , C08L83/06 , G03G5/05 , G03G5/06 , G03G5/07
CPC分类号： G03G5/078 , C08L83/04 , G03G5/0578 , G03G5/0614 , C08G77/16 , C08G77/18 , Y10S526/941
摘要： The invention provides a method for manufacturing a polysiloxane resin with charge transporting property by uniformly dissolving a charge transporting material to a practical concentration in a polysiloxane resin. The charge transporting material that is dissolved in the polysiloxane resin is an aromatically substituted tertiary amine which has been modified by substitution of one or more of the aromatic groups with a hydrocarbon group containing a silyl group with hydrolyzable substituents.
摘要翻译：本发明提供了一种通过均匀地将电荷输送材料溶解在聚硅氧烷树脂中的实际浓度来制造具有电荷输送性的聚硅氧烷树脂的方法。溶解在聚硅氧烷树脂中的电荷输送材料是芳族取代的叔胺，其通过用含有可水解取代基的含有甲硅烷基的烃基取代一个或多个芳族基团而被改性。

5. 发明授权

US06592945B2 Nanoparticle dispersed structure and laminate thereof 有权
标题翻译：纳米粒子分散结构及其层压体
公开(公告)号：US06592945B2
公开(公告)日：2003-07-15
申请号：US09798123
申请日：2001-03-02
申请人： Masaaki Suzuki , Maria Teresa de los Arcos de Pedro , Yoshinori Nakata , Yoshiho Imai , Munehiro Yamaguchi , Nobuo Kushibiki , Kikuko Takeuchi
发明人： Masaaki Suzuki , Maria Teresa de los Arcos de Pedro , Yoshinori Nakata , Yoshiho Imai , Munehiro Yamaguchi , Nobuo Kushibiki , Kikuko Takeuchi
IPC分类号： B05D302
CPC分类号： C08L83/04 , B82Y30/00 , C08G77/06 , C08J3/203 , C08J2383/04 , C08K3/01 , C08K3/08 , C08K2201/011 , C09D183/04 , Y10T428/31663 , C08L2666/54
摘要： The present invention provides a nanoparticle dispersed structure featuring a polymer having a crosslinked structure that is chemically inert with respect to the nanoparticles and that is effective in suppressing diffusion, and provides a method for manufacturing this nanoparticle dispersion.
摘要翻译：本发明提供一种纳米颗粒分散结构，其特征在于具有相对于纳米颗粒具有化学惰性的交联结构的聚合物，并且有效抑制扩散，并提供了制造该纳米颗粒分散体的方法。

6. 发明授权

US5708099A Polysiloxane resin containing optically-functional constituents and transparent optically-functional element obtained therefrom 失效
标题翻译：含有光学功能成分的聚硅氧烷树脂和由其获得的透明光学功能元件
公开(公告)号：US5708099A
公开(公告)日：1998-01-13
申请号：US743599
申请日：1996-11-04
申请人： Nobuo Kushibiki , Kikuko Takeuchi
发明人： Nobuo Kushibiki , Kikuko Takeuchi
IPC分类号： C08G77/42 , C08K5/54 , C08L83/04 , C08L83/10 , G02B1/04 , C08G77/26
CPC分类号： G02B1/04 , C08K5/54
摘要： The invention is an optically transparent organopolysiloxane resin with a large amount of a uniformly dissolved and dispersed optically-functional organic material. The compatibility of the optically functional material is achieved by modifying it by addition of alkoxysilylalkyl groups to aromatic groups of optically-functional organic compounds such phthalocyanines, porphyrins, tetraphenylbutadienes, axobenzenes, bis(4-dimethylaminodithiobenzyl)nickel and anthracenes. The compositions contain 20 to 200 parts by weight of the modified optically-functional organic compounds per 100 parts by weight of the organopolysiloxane resin. The composition may be formed into a specified shape, solvents evaporated, and cured by heat.
摘要翻译：本发明是具有大量均匀溶解和分散的光学功能有机材料的光学透明的有机聚硅氧烷树脂。光学功能材料的相容性通过将烷氧基甲硅烷基烷基加成到光学官能的有机化合物如酞菁，卟啉，四苯基丁二烯，轴对苯二甲酸，双（4-二甲基氨基二硫代苄基）镍和蒽的芳族基团进行改性来实现。该组合物每100重量份有机聚硅氧烷树脂含有20至200重量份的改性光学官能的有机化合物。可以将组合物形成为特定形状，蒸发溶剂，并通过加热固化。

7. 发明申请

US20070025678A1 Curable organopolysiloxane resin composition for optical transmission components, optical transmission components, and fabrication process thereof 审中-公开
标题翻译：用于光传输部件的可固化有机聚硅氧烷树脂组合物，光传输部件及其制造方法
公开(公告)号：US20070025678A1
公开(公告)日：2007-02-01
申请号：US10552191
申请日：2004-04-07
申请人： Nobuo Kushibiki , Takuya Ogawa , Kikuko Takeuchi
发明人： Nobuo Kushibiki , Takuya Ogawa , Kikuko Takeuchi
IPC分类号： G02B6/00
CPC分类号： C08L83/04 , C08G77/045 , C08G77/12 , C08G77/20 , C08G77/70 , C08L83/00 , C08L2666/52
摘要： The present invention relates to a hydrosilation-curable organopolysiloxane resin composition comprising (A) an organopolysiloxane resin having three or more monovalent unsaturated aliphatic hydrocarbon groups and aromatic hydrocarbon carbon groups, (B) an organosilicon compound having two or more silicon-bonded hydrogen atoms and aromatic hydrocarbon groups, (C) a hydrosilation catalyst, and optionally (D) (d1) a solvent or (d2) a hydrosilation-reactive organosiloxane-based diluent, for optical transmission components, especially for optical transmission components serving as optical communication elements, relates to optical transmission components, represented by optical waveguides, comprisiong a hydrosilation-cured product of the aforementioned organopolysiloxane resin and organosilicon compound, and relates to a process for fabricatiing optical transmission components.
摘要翻译：本发明涉及一种含硅氢化的有机聚硅氧烷树脂组合物，其包含（A）具有三个或更多个一价不饱和脂族烃基和芳族烃碳基的有机聚硅氧烷树脂，（B）具有两个或更多个与硅键合的氢原子的有机硅化合物和芳族烃基，（C）氢化硅烷化催化剂和任选的（D）（d1）溶剂或（d2）氢化硅烷化反应性有机硅氧烷基稀释剂，用于光传输部件，特别是用作光通信元件的光传输部件，涉及由光波导表示的光传输部件，包括上述有机聚硅氧烷树脂和有机硅化合物的硅氢化固化产物，涉及制造光传输部件的方法。

8. 发明授权

US5688961A Method of manufacturing a silicon-type charge transporting material 失效
标题翻译：硅型电荷输送材料的制造方法
公开(公告)号：US5688961A
公开(公告)日：1997-11-18
申请号：US740738
申请日：1996-11-04
申请人： Nobuo Kushibiki , Kikuko Takeuchi
发明人： Nobuo Kushibiki , Kikuko Takeuchi
IPC分类号： C07F7/18 , C08G77/26 , C08L83/04 , G03G5/05 , G03G5/06 , G03G5/07 , C07F7/08 , C07F7/10 , G03G13/05
CPC分类号： G03G5/0614 , C07F7/1876 , G03G5/0578 , G03G5/078
摘要： A method of manufacturing charge transporting materials which impart a charge transporting property to a polysiloxane resin, and which is soluble in the resin. The charge transporting material is an aromatic substituted tertiary amine with a plurality of aromatic groups, and a silyl group introduced via a hydrocarbon group, into at least one of the aromatic groups. The method is characterized by using an unsaturated aliphatic group bonded to an aromatic group which makes up the silicon-type charge transporting compound, or using a newly bonded unsaturated aliphatic group which is bonded to a silane in which the substituent for silicon is hydrogen or a hydrolyzable group. This is conducted in the presence of a platinum compound as catalyst by means of hydrosilylation. The silicon-type charge transporting material is then brought into contact with an adsorbent for the platinum compound, causing the platinum compound to be adsorbed onto the adsorbent. The platinum compound is removed along with the adsorbent, so that the concentration of residual platinum compound is less than 10 ppm.
摘要翻译：制造赋予聚硅氧烷树脂电荷输送性且可溶于树脂的电荷输送材料的方法。电荷传输材料是具有多个芳族基团的芳族取代的叔胺和经由烃基引入的甲硅烷基，至少一个芳族基团。该方法的特征在于使用与构成硅型电荷输送性化合物的芳香族基团键合的不饱和脂肪族基团，或者使用与硅取代基键合的新键合的不饱和脂肪族基团，可水解组。这是通过氢化硅烷化在铂化合物作为催化剂的存在下进行的。然后使硅型电荷输送材料与铂化合物的吸附剂接触，使铂化合物吸附在吸附剂上。铂化合物与吸附剂一起除去，使得残余铂化合物的浓度小于10ppm。

9. 发明授权

US06045962A Method for forming low surface energy coating 失效
标题翻译：低表面能涂层的形成方法
公开(公告)号：US06045962A
公开(公告)日：2000-04-04
申请号：US40890
申请日：1998-03-18
申请人： Nobuo Kushibiki , Kikuko Takeuchi
发明人： Nobuo Kushibiki , Kikuko Takeuchi
IPC分类号： G03G5/00 , B05D5/00 , B05D7/24 , C09D5/00 , C09D183/08 , G03G5/05 , G03G5/147
CPC分类号： G03G5/14773 , G03G5/147 , G03G5/14704 , G03G5/14726
摘要： A method for forming a low surface energy coating for electrophotographic photosensitive body substrates does not require performing a physical surface reforming treatment such as corona discharge, plasma treatment, and the like. The process comprises: forming on the substrate at least one polysiloxane coating material, (B), that has a water contact angle greater than the water contact angle of the substrate; and thereafter forming an outermost surface coating material, (A), on top of coating material (B). The water contact angle of coating material (B) is smaller than the water contact angle of coating material (A). Coating material (A) comprises finely divided silica and a resin of the formula RSiO.sub.3/2, wherein not less than 1 mol % and not more than 80 mol % of the R groups are fluorohydrocarbon groups of 3 to 12 carbon atoms.
摘要翻译：用于形成电子照相感光体基材的低表面能涂层的方法不需要进行诸如电晕放电，等离子体处理等的物理表面重整处理。该方法包括：在基底上形成至少一种聚硅氧烷涂层材料（B），其具有大于基底的水接触角的水接触角; 然后在涂层材料（B）的顶部上形成最外表面涂层材料（A）。涂料（B）的水接触角小于涂料（A）的水接触角。涂料（A）包含细碎的二氧化硅和式RSiO 3/2的树脂，其中不小于1摩尔％且不大于80摩尔％的R基团是3至12个碳原子的氟代烃基。

10. 发明授权

US5910272A Process for the preparation of an electrically conductive coating material 失效
标题翻译：制备导电涂料的方法
公开(公告)号：US5910272A
公开(公告)日：1999-06-08
申请号：US40889
申请日：1998-03-18
申请人： Nobuo Kushibiki , Kikuko Takeuchi
发明人： Nobuo Kushibiki , Kikuko Takeuchi
IPC分类号： H01B1/12 , H01B1/04
CPC分类号： H01B1/12
摘要： A process for the preparation of an electrically conductive coating material for use in electrophotography applications comprises subjecting an epoxy-functional silane to hydrolytic condensation in a mixed solvent of alcohol and water in the presence of silica. The hydrolyzed material is then heat cured to form a resin coating comprising (R.sup.1 SiO).sub.3/2 units, where R.sup.1 comprises epoxy-functional groups. The coating has superior optical homogeneity and electrical conductivity without being detrimental to the functionality required of electrophotographic photosensitive bodies.
摘要翻译：用于制备用于电子照相应用的导电涂料的方法包括在二氧化硅存在下使环氧官能的硅烷在醇和水的混合溶剂中进行水解缩合。然后将水解的材料热固化以形成包含（R 1 SiO）3/2单元的树脂涂层，其中R1包含环氧官能团。该涂层具有优异的光学均匀性和导电性，而不会影响电子照相感光体所需的功能。

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