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    • 8. 发明授权
    • Method of preparing bismuth oxide superconducting wire
    • 制备氧化铋超导线的方法
    • US06536096B2
    • 2003-03-25
    • US08167581
    • 1993-12-15
    • Kenichi SatoNobuhiro ShibutaHidehito MukaiTakeshi HikataMunetsugu UeyamaTakeshi Kato
    • Kenichi SatoNobuhiro ShibutaHidehito MukaiTakeshi HikataMunetsugu UeyamaTakeshi Kato
    • H01L3924
    • H01L39/248C04B35/4521C04B35/4525Y10T29/49014
    • Powder of not more than 1 &mgr;m in mean particle diameter is prepared to contain a mixture of superconducting phases mainly composed of 2212 phases of Bi—Sr—Ca—Cu or (Bi, Pb)—Sr—Ca—Cu and non-superconducting phases which is obtained by calcining and pulverizing raw material powder at least once, this powder is heat treated at a high temperature and thereafter coated with a metal to prepare a round wire by deformation processing, thereafter a tape type or flat type wire is prepared by deformation processing, then the wire is heat treated under conditions for allowing phase transformation of the 2212 phases of main superconducting phases to 2223 phases with facilitation of grain growth, thereafter the as-formed 2223 phases are highly densified by deformation processing or pressurization, and the wire is again heat treated so that the 2223 phases are strongly bonded with each other and the non-superconducting phases are finely dispersed. Thus, a bismuth oxide superconducting wire having a high critical current density is obtained.
    • 制备平均粒径不超过1um的粉末,其含有主要由2212相的Bi-Sr-Ca-Cu或(Bi,Pb)-Sr-Ca-Cu和非超导相的超导相的混合物 其通过将原料粉末煅烧和粉碎至少一次而获得,该粉末在高温下进行热处理,然后用金属涂覆以通过变形处理制备圆形线,然后通过变形来制备带状或扁平型线 然后在使主要超导相的2212相相变到2223相的条件下进行热处理,促进晶粒生长,此后形成的2223相通过变形加工或加压而高度致密化,并且导线 再次热处理使得2223相彼此牢固地结合,并且非超导相被细分散。 因此,获得具有高临界电流密度的氧化铋超导线。