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1. 发明授权

US5804650A Aqueous dispersion of vinylidene fluoride copolymer, aqueous dispersion of vinylidene fluoride seed polymer and processes for preparation of the same 失效
标题翻译：偏二氟乙烯共聚物的水分散体，偏二氟乙烯种子聚合物的水分散体及其制备方法
公开(公告)号：US5804650A
公开(公告)日：1998-09-08
申请号：US776528
申请日：1997-02-27
申请人： Nobuhiko Tsuda , Ryuzi Iwakiri , Yasushi Yonei , Katsuhiko Imoto , Yoshiki Shimizu , Takayuki Araki , Masahiro Kondo
发明人： Nobuhiko Tsuda , Ryuzi Iwakiri , Yasushi Yonei , Katsuhiko Imoto , Yoshiki Shimizu , Takayuki Araki , Masahiro Kondo
IPC分类号： C08L27/16 , C08F2/22 , C08F2/24 , C08F2/26 , C08F2/44 , C08F14/22 , C08F16/14 , C08F28/00 , C08F214/22 , C08F216/14 , C08F220/04 , C08F220/62 , C08F228/02 , C08L27/12 , C08L27/14 , C08L51/00 , C08L51/06
CPC分类号： C08L51/06 , C08F214/22 , C08L51/003 , C08L2201/50
摘要： To provide an aqueous dispersion of a vinylidene fluoride (VdF) copolymer which can be prepared by emulsion-polymerizing VdF monomer with a reactive emulsifying agent and is excellent in stability against sedimentation because an average particle size of the copolymer is as small as not more than 200 nm and a solid content is as high as from 30 to 60% by weight; an aqueous dispersion of a VdF seed polymer which can be prepared by seed-polymerizing an ethylenically unsaturated monomer in the presence of particles obtained by emulsion-polymerizing VdF monomer with a reactive emulsifying agent and is excellent in stability against sedimentation because an average particle size of the seed polymer is as small as not more than 250 nm and a solid content is as high as from 30 to 60% by weight; and processes for preparation thereof.
摘要翻译： PCT No.PCT / JP95 / 01679 Sec。 371日期1997年2月27日 102（e）日期1997年2月27日PCT提交1995年8月23日PCT公布。公开号WO96 / 06887 日期：1996年3月7日提供可通过将VdF单体与反应性乳化剂乳化聚合制备的偏二氟乙烯（VdF）共聚物的水分散体，并且由于共聚物的平均粒径为小至不超过200nm，固体含量高达30至60重量％; VdF种子聚合物的水分散体，其可以通过在通过使VdF单体与反应性乳化剂乳化聚合获得的颗粒的存在下使烯属不饱和单体进行种子聚合制备，并且由于平均粒径为种子聚合物小至不超过250nm，固体含量高达30至60重量％; 及其制备方法。

2. 发明授权

US5712335A Aqueous fluorine-containing polymer dispersion 失效
标题翻译：含氟聚合物水分散体
公开(公告)号：US5712335A
公开(公告)日：1998-01-27
申请号：US666356
申请日：1996-06-21
申请人： Nobuhiko Tsuda , Yasushi Yonei , Ryuzi Iwakiri , Katsuhiko Imoto
发明人： Nobuhiko Tsuda , Yasushi Yonei , Ryuzi Iwakiri , Katsuhiko Imoto
IPC分类号： C08K5/54 , C08F14/18 , C08F214/18 , C08F259/00 , C08F259/08 , C08K5/49 , C08K5/5419 , C08L27/12 , C08L83/04 , C09D127/12 , C08K9/06 , C08L27/16
CPC分类号： C08K5/5419 , C09D127/12 , C08L83/04
摘要： An aqueous dispersion of a fluorine-containing polymer, wherein 1 to 20 parts by weight of solids of an organosilicon compound is admixed on the basis of 100 parts by weight of solids in the fluorine-containing-polymer-dispersed aqueous composition and this aqueous dispersion is useful for a paint capable of forming a coating film which is excellent in adhesion to various base materials, film forming property, weatherability and soil resistance.
摘要翻译： PCT No.PCT / JP95 / 02152 Sec。 371日期：1996年6月21日 102（e）日期1996年6月21日PCT提交1995年10月19日PCT公布。 WO96 / 12773 PCT出版物日期1996年5月2日将含氟聚合物分散水性组合物中的固体100重量份混合在一起的含氟聚合物的水分散体，其中，将1〜20重量份固体的有机硅化合物并且该水分散体可用于能够形成对各种基材的粘合性，成膜性，耐候性和耐污性优异的涂膜的涂料。

3. 发明授权

US5646201A Aqueous dispersion of fluorine-containing copolymer 失效
标题翻译：含氟共聚物的水分散体
公开(公告)号：US5646201A
公开(公告)日：1997-07-08
申请号：US612866
申请日：1996-03-13
申请人： Takayuki Araki , Nobuhiko Tsuda , Yasushi Yonei
发明人： Takayuki Araki , Nobuhiko Tsuda , Yasushi Yonei
IPC分类号： C08F259/08 , C08L15/02 , C08L27/16
CPC分类号： C08F259/08 , Y10S525/902
摘要： Aqueous dispersion of a fluorine-containing copolymer which is prepared by, in an aqueous dispersion containing fluorine-containing copolymer particles which comprise 70 to 95% by mole of vinylidene fluoride and 5 to 30% by mole of chlorotrifluoroethylene, seed-polymerizing 20 to 100 parts by weight of an acrylic acid ester and/or a methacrylic acid ester in the presence of 100 parts by weight of the fluorine-containing copolymer particles. The aqueous dispersion assures excellent film forming property, and can provide a highly glossy coating excellent in mechanical properties, transparency at clear coating and weatherability.
摘要翻译： PCT No.PCT / JP94 / 01530 Sec。 371日期：1996年3月13日 102（e）1996年3月13日PCT 1994年9月16日PCT PCT。公开号WO95 / 08582 日期：1995年3月30日，含氟共聚物的水分散体，其含有含有70〜95摩尔％的偏二氟乙烯和5〜30摩尔％的三氟氯乙烯的含氟共聚物粒子的水分散体，种子在100重量份的含氟共聚物颗粒的存在下共聚20至100重量份的丙烯酸酯和/或甲基丙烯酸酯。水分散体确保了优异的成膜性，并且可以提供机械性能，透明度，透明涂层和耐候性优异的高光泽涂层。

4. 发明授权

US07700159B2 Hydrophilizing wax composition 失效
标题翻译：亲水蜡组合物
公开(公告)号：US07700159B2
公开(公告)日：2010-04-20
申请号：US10490455
申请日：2002-09-19
申请人： Yasushi Yonei , Tadao Shimizu , Eiji Kondoh
发明人： Yasushi Yonei , Tadao Shimizu , Eiji Kondoh
IPC分类号： B05D5/00
CPC分类号： C09G1/12 , C08K5/0008 , C09D191/06 , C09G1/10 , Y10T428/31641 , Y10T428/31801 , C08L91/06
摘要： There is provided a hydrophilizable wax composition which provides a wax coating layer having a hydrophilic surface and imparts a gloss and long-lasting stain-proofing property on a substrate. The hydrophilizable wax composition can form a hydrophilizable wax coating layer by applying the composition containing a hydrophilizing agent and wax component and wiping off the composition, in which the hydrophilizing agent has hydrolyzable groups which are converted into hydrophilic groups by hydrolysis in the presence of water and are condensed to enable the hydrophilizing agent to have a high molecular weight and is, for example, an organometallic compound having a releasable group by hydrolysis, its oligomer and/or a co-oligomer comprising two or more of the compounds.
摘要翻译：提供了一种可亲水化的蜡组合物，其提供具有亲水表面的蜡涂层，并在基材上赋予光泽和持久的防污性能。可亲水化的蜡组合物可以通过涂布含有亲水剂和蜡组分的组合物并且擦去组合物而形成可亲水化的蜡涂层，其中亲水剂具有通过在水存在下通过水解转化成亲水基团的可水解基团，被冷凝以使得亲水剂具有高分子量，并且例如是通过水解具有可释放基团的有机金属化合物，其低聚物和/或包含两种或更多种化合物的共低聚物。

5. 发明申请

US20050003219A1 Hydrophilizing wax composition 失效
标题翻译：亲水蜡组合物
公开(公告)号：US20050003219A1
公开(公告)日：2005-01-06
申请号：US10490455
申请日：2002-09-19
申请人： Yasushi Yonei , Tadao Shimizu , Eiji Kondoh
发明人： Yasushi Yonei , Tadao Shimizu , Eiji Kondoh
IPC分类号： C08K5/00 , C09D191/06 , C09G1/10 , C09G1/12 , B05D3/12 , C09F1/00
CPC分类号： C09G1/12 , C08K5/0008 , C09D191/06 , C09G1/10 , Y10T428/31641 , Y10T428/31801 , C08L91/06
摘要： There is provided a hydrophilizable wax composition which provides a wax coating layer having a hydrophilic surface and imparts a gloss and long-lasting stain-proofing property on a substrate. The hydrophilizable wax composition can form a hydrophilizable wax coating layer by applying the composition containing a hydrophilizing agent and wax component and wiping off the composition, in which the hydrophilizing agent has hydrolyzable groups which are converted into hydrophilic groups by hydrolysis in the presence of water and are condensed to enable the hydrophilizing agent to have a high molecular weight and is, for example, an organometallic compound having a releasable group by hydrolysis, its oligomer and/or a co-oligomer comprising two or more of the compounds.
摘要翻译：提供了一种可亲水化的蜡组合物，其提供具有亲水表面的蜡涂层，并在基材上赋予光泽和持久的防污性能。可亲水化的蜡组合物可以通过涂布含有亲水剂和蜡组分的组合物并且擦去组合物而形成可亲水化的蜡涂层，其中亲水剂具有通过在水存在下通过水解转化成亲水基团的可水解基团，被冷凝以使得亲水剂具有高分子量，并且例如是通过水解具有可释放基团的有机金属化合物，其低聚物和/或包含两种或更多种化合物的共低聚物。

6. 发明授权

US06309708B1 Stain-proofing agent for preventing adherence of stain and composition for paints 失效
标题翻译：用于防止污渍和组合物粘附的防污剂
公开(公告)号：US06309708B1
公开(公告)日：2001-10-30
申请号：US09043454
申请日：1998-03-23
申请人： Haruhiko Mohri , Yasushi Yonei
发明人： Haruhiko Mohri , Yasushi Yonei
IPC分类号： B05D302
CPC分类号： C09D5/1625 , C08K5/5415 , C08K5/56 , C09D5/00 , C09D7/63 , C09D7/65 , Y02A50/2327
摘要： A paint composition being capable of forming a coating film which is remarkably excellent in stain-proofing property whereby neither stains in the air nor stains marked due to rain water adhere to or are deposited on the coating film surface and a stain-proofing agent for adding to the composition are provided. The paint composition comprises a stain-proofing agent comprising an organometallic compound represented by XbM(OR1)aR2c, its oligomer or cooligomer comprising two or more of the organometallic compounds; a resin for paints; and a curing agent and/or a curing catalyst, provided that a stain-proofing agent comprising a compound represented by the formula (2): is excluded.
摘要翻译：一种能够形成涂膜的涂料组合物，其防污性能非常优异，既使空气中的污渍也不会由于雨水粘附或沉积在涂膜表面上而产生的污渍和用于添加的防污剂提供了组合物。涂料组合物包含防污剂，其包含由XbM（OR1）aR2c表示的有机金属化合物，其低聚物或共低聚物包含两种或更多种有机金属化合物; 油漆树脂; 和固化剂和/或固化催化剂，条件是排除包含由式（2）表示的化合物的防污剂。

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