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1. 发明授权

US09862653B2 Use of a catalyst comprising a phosphorous modified zeolite in an alcohol dehydration process 有权
公开(公告)号：US09862653B2
公开(公告)日：2018-01-09
申请号：US14236726
申请日：2012-07-25
申请人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath , Joseph Lopez , Patrick Euzen
发明人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath , Joseph Lopez , Patrick Euzen
IPC分类号： C07C1/24 , B01J37/10 , B01J37/28 , B01J29/40 , B01J29/85
CPC分类号： C07C1/24 , B01J29/40 , B01J29/85 , B01J37/10 , B01J37/28 , C07C2527/14 , C07C2529/06 , C07C2529/40 , Y02P20/52 , Y02P30/42 , C07C11/04
摘要： A catalyst can be used to convert an alcohol in a dehydration process into an olefin having the same number of carbon atoms as the alcohol. The catalyst can include a phosphorus modified zeolite made by providing a zeolite with at least one ten member ring in the structure, steaming the zeolite, mixing the zeolite with binders and shaping additives, and shaping the zeolite. An ion-exchange step can be performed, and the shaped catalyst can be steamed. Phosphorus can be introduced on the catalyst at an amount of at least 0.1 wt %, such as by dry impregnation or chemical vapor deposition. A metal can be introduced. The catalyst can be washed and/or calcinated, and steamed in an equilibration step. The steaming severity (X) can be at least about 2. The catalyst can be steamed at a temperature above 625° C., such as a temperature ranging from 700 to 800° C.

2. 发明授权

US09790142B2 Catalyst comprising a phosphorous modified zeolite and having partly an ALPO structure 有权
公开(公告)号：US09790142B2
公开(公告)日：2017-10-17
申请号：US14236765
申请日：2012-07-25
申请人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath
发明人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath
IPC分类号： B01J29/06 , B01J27/18 , C07C2/66 , B01J29/40 , B01J29/70 , B01J37/10 , B01J37/28 , B01J29/85 , C07C1/24 , C07C2/86 , C07C4/06 , B01J35/10 , B01J37/00
CPC分类号： C07C2/66 , B01J29/40 , B01J29/405 , B01J29/7049 , B01J29/85 , B01J35/1038 , B01J35/1061 , B01J35/1066 , B01J37/0009 , B01J37/10 , B01J37/28 , B01J2229/16 , B01J2229/183 , B01J2229/186 , B01J2229/36 , B01J2229/37 , B01J2229/40 , B01J2229/42 , C07C1/24 , C07C2/864 , C07C4/06 , C07C2529/40 , C07C2529/70 , C07C2529/80 , C07C2529/83 , C07C2529/85 , Y02P20/52 , Y02P30/42 , C07C11/04
摘要： A catalyst can include a phosphorus modified zeolite having partly an ALPO structure. The ALPO structure can be determined by a signal between 35-45 ppm in 27Al MAS NMR spectrum. The zeolite can include at least one ten member ring in the structure thereof. The catalyst can also include a binder and one or more metal oxides. The catalyst can be used in processes in the presence of steam at high temperatures, such as temperatures that are above 300° C. and up to 800° C. The catalyst can be used in alcohol dehydration, olefin cracking, MTO processes, and alkylation of aromatic compounds with olefins and/or alcohols.

3. 发明授权

US09249066B2 Dehydration of alcohols on acidic catalysts 有权
标题翻译：醇在酸性催化剂上脱水
公开(公告)号：US09249066B2
公开(公告)日：2016-02-02
申请号：US13701774
申请日：2011-06-20
申请人： Delphine Minoux , Cindy Adam , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath , Walter Vermeiren
发明人： Delphine Minoux , Cindy Adam , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath , Walter Vermeiren
IPC分类号： C07C1/24
CPC分类号： C07C1/24 , C07C2521/04 , C07C2521/06 , C07C2521/12 , C07C2529/40 , C07C2529/65 , C07C2529/82 , C07C2529/83 , C07C2529/85 , Y02P20/52 , C07C11/04
摘要： A dehydration process may include introducing in a reactor an alcohol, and contacting the alcohol with an acidic catalyst to dehydrate the alcohol to make a corresponding olefin. The process may include recovering from the reactor the olefin and water. In the process, an effective amount of a component capable to neutralize a part of the catalyst active site may be introduced. The component may include ammonia, organic ammonium salts, hydrazine, nitriles, amines, amides, imines, di-imines, imides, cyanates, isocyanates, nitrites and nitroso compounds, aldehydes, ketones, carboxylic esters, and their corresponding thio-compounds.
摘要翻译：脱水方法可以包括在反应器中引入醇，并将醇与酸性催化剂接触以使醇脱水以制备相应的烯烃。该方法可以包括从反应器中回收烯烃和水。在该方法中，可以引入有效量的能够中和一部分催化剂活性部位的成分。该组分可包括氨，有机铵盐，肼，腈，胺，酰胺，亚胺，二亚胺，酰亚胺，氰酸酯，异氰酸酯，亚硝酸酯和亚硝基化合物，醛，酮，羧酸酯及其相应的硫代化合物。

4. 发明授权

US09233886B2 Simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts 有权
标题翻译：酸催化剂上异丁醇的同时脱水和骨架异构化
公开(公告)号：US09233886B2
公开(公告)日：2016-01-12
申请号：US13582759
申请日：2011-03-15
申请人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
发明人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/24 , B01J29/85 , C07C5/27 , C07C11/08 , C07C11/09 , C07C5/25
CPC分类号： C07C1/24 , B01J29/85 , C07C5/2518 , C07C5/2775 , C07C11/08 , C07C11/09 , C07C2521/04 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/127
摘要： The present invention (in a first embodiment) relates to a process for the simultaneous dehydration and skeletal isomerization of isobutanol to make substantially corresponding olefins, having the same number of carbons and consisting essentially of a mixture of n-butenes and iso-butene, said process comprising: a) introducing in a reactor a stream (A) comprising isobutanol, optionally water, optionally an inert component, b) contacting said stream with a catalyst in said reactor at conditions effective to dehydrate and skeletal isomerize at least a portion of the isobutanol to make a mixture of n-butenes and iso-butene, c) recovering from said reactor a stream (B), removing water, the inert component if any and unconverted isobutanol if any to get a mixture of n-butenes and iso-butene, Wherein, the WHSV of the isobutanol is at least 1 h−1 or the temperature is from 200° C. to 600° C. and the catalyst is capable to make simultaneously the dehydration and skeletal isomerization of butene. The catalyst is a crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL or TON having Si/Al higher than 10, or a dealuminated crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL or TON having Si/Al higher than 10, or a phosphorus modified crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL or TON having Si/Al higher than 10, or a silicoaluminaphosphate molecular sieve of the group AEL, or a silicated, zirconated or titanated or fluorinated alumina. Advantageously the stream (B) is fractionated in a step d) to produce a n-butenes stream (N) and to remove the essential part of isobutene optionally recycled with stream (A) to the dehydration/isomerization reactor of step b).
摘要翻译：本发明（在第一实施方案中）涉及同时脱水和骨架异构化异丁醇以制备具有相同数目的碳并基本上由正丁烯和异丁烯组成的基本相应的烯烃的方法，所述方法方法包括：a）在反应器中引入包含异丁醇，任选的水，任选的惰性组分的物流（A），b）在所述反应器中使所述物流与催化剂接触，所述条件有效脱水并骨架异构化至少一部分异丁醇以制备正丁烯和异丁烯的混合物，c）从所述反应器回收流（B），除去水，惰性组分（如果有的话）和未转化的异丁醇，以获得正丁烯和异丁烯的混合物，丁烯，其中异丁醇的WHSV为至少1h-1或温度为200℃至600℃，催化剂能够同时进行b的脱水和骨架异构化 utene。该催化剂是具有Si / Al大于10的FER，MWW，EUO，MFS，ZSM-48，MTT，MFI，MEL或TON的结晶硅酸盐，或FER，MWW，EUO等的脱铝结晶硅酸盐，具有Si / Al大于10的MFS，ZSM-48，MTT，MFI，MEL或TON，或FER，MWW，EUO，MFS，ZSM-48，MTT，MFI，MEL或TON的磷改性结晶硅酸盐，其具有 Si / Al高于10，或AEL的硅铝磷酸盐分子筛，或硅化，锆酸化或钛酸化或氟化氧化铝。有利地，在步骤d）中将流（B）分馏以产生正丁烯料流（N），并除去任选与料流（A）一起循环的异丁烯的主要部分至步骤b）的脱水/异构化反应器。

5. 发明授权

US09079813B2 Process to make propylene from isobutanol by dehydration and subsequent cracking 有权
标题翻译：通过脱水和随后开裂从异丁醇制备丙烯的方法
公开(公告)号：US09079813B2
公开(公告)日：2015-07-14
申请号：US13813107
申请日：2011-07-08
申请人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
发明人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/22 , C07C1/24 , C07C4/06 , C10G3/00 , C12P5/02 , C12P7/16 , B01J21/04 , B01J29/40 , B01J29/65
CPC分类号： C07C1/24 , B01J21/04 , B01J29/40 , B01J29/65 , C07C4/06 , C07C2521/04 , C07C2529/40 , C07C2529/65 , C07C2529/85 , C10G3/44 , C10G3/49 , C10G2300/1014 , C10G2300/201 , C10G2300/4081 , C10G2400/20 , C10G2400/22 , C12P5/026 , C12P7/16 , Y02E50/10 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/08 , C07C11/06
摘要： A process for conversion of isobutanol to make propylene can include dehydrating the isobutanol to produce butenes. The process can include cracking the butenes to produce propylene.
摘要翻译：异丁醇转化成丙烯的方法可以包括使异丁醇脱水以制备丁烯。该方法可以包括裂解丁烯以产生丙烯。

6. 发明申请

US20130217935A1 PROCESS TO MAKE OLEFINS FROM METHANOL AND ISOBUTANOL 审中-公开
标题翻译：从甲醇和异丁醇制备油脂的方法
公开(公告)号：US20130217935A1
公开(公告)日：2013-08-22
申请号：US13813170
申请日：2011-07-08
申请人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
发明人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/22
CPC分类号： C07C1/22 , B01J29/40 , B01J2229/42 , C07C1/20 , C07C1/24 , C07C4/06 , C07C2529/40 , C10G3/44 , C10G3/49 , C10G3/62 , C10G2300/1014 , C10G2300/1022 , C10G2300/201 , C10G2300/4081 , C10G2400/20 , C12P5/026 , C12P7/16 , Y02E50/10 , Y02P20/52 , Y02P30/42 , C07C11/02 , C07C11/06 , C07C11/08 , C07C11/04
摘要： The present invention relates to a process for making essentially ethylene and propylene comprising: a) providing an alcohol mixture (A) comprising about 20 w % to 100% isobutanol, b) introducing in a reactor (A) a stream comprising the mixture (A) mixed with methanol or dimethyl ether or mixture thereof, optionally water, optionally an inert component, c) contacting said stream with a catalyst (A1) in said reactor (A), the MTO reactor, at conditions effective to convert at least a part of the alcohol mixture (A) and at least a part of the methanol and/or dimethyl ether to olefins, d) recovering from said reactor (A) an effluent comprising: ethylene, propylene, butene, water, optionally unconverted alcohols, various hydrocarbons, and the optional inert component of step b), e) fractionating said effluent of step d) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).
摘要翻译：本发明涉及一种基本上制备乙烯和丙烯的方法，包括：a）提供包含约20重量％至100重量％异丁醇的醇混合物（A），b）在反应器（A）中引入包含混合物（A ）与甲醇或二甲醚或其混合物，任选的水，任选的惰性组分混合，c）使所述流与所述反应器（A）中的催化剂（A1），所述MTO反应器在有效地转化至少一部分的醇混合物（A）和至少一部分甲醇和/或二甲醚至烯烃，d）从所述反应器（A）回收包含乙烯，丙烯，丁烯，水，任选未转化的醇，各种烃和步骤b）的任选的惰性组分，e）将步骤d）的所述流出物分馏以产生至少一种乙烯流，丙烯料流，基本上由具有4个或更多个碳原子的烃组成的馏分，水和任选的惰性 com 步骤a）的方法，任选地在反应器（A）的入口处全部或部分地回收乙烯，任选地在反应器（A）的入口处循环基本上由具有4个或更多个碳原子的烃组成的馏分。

7. 发明授权

US09056807B2 Process to make olefins from isobutanol 有权
标题翻译：从异丁醇制备烯烃的方法
公开(公告)号：US09056807B2
公开(公告)日：2015-06-16
申请号：US13813168
申请日：2011-07-08
申请人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
发明人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/22 , C07C1/24 , C07C4/06 , C07C6/04 , C10G3/00 , C12P5/02 , C12P7/16 , B01J29/40
CPC分类号： C07C1/24 , B01J29/40 , B01J2229/42 , C07C1/22 , C07C4/06 , C07C6/04 , C07C2529/40 , C08F10/02 , C10G3/42 , C10G3/44 , C10G3/49 , C10G2300/1014 , C10G2300/1022 , C10G2300/201 , C10G2300/4081 , C10G2400/20 , C10G2400/22 , C12P5/026 , C12P7/16 , Y02E50/10 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/08 , C07C11/06
摘要： The present invention relates to a process for the conversion of an alcohol mixture (A) comprising about 20 w % to 100% isobutanol to make essentially propylene, comprising: a) introducing in a reactor (A) a stream comprising the mixture (A), optionally water, optionally an inert component, b) contacting said stream with a catalyst (A1) at a temperature above 450° C. in said reactor (A) at conditions effective to dehydrate at least a part of the isobutanol and other alcohols, if any, and make a cracking, c) recovering from said reactor (A) an effluent comprising: ethylene, propylene, water, optionally unconverted alcohols of the mixture (A), various hydrocarbons, and the optional inert component of step a), d) fractionating said effluent of step c) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).
摘要翻译：本发明涉及一种将包含约20％至100％异丁醇的醇混合物（A）转化成基本上丙烯的方法，其包括：a）在反应器（A）中引入包含混合物（A）的料流，任选的水，任选的惰性组分，b）在有效使至少一部分异丁醇和其它醇脱水的条件下，使所述物流与催化剂（A1）在高于450℃的温度下在所述反应器（A）中接触， c）从所述反应器（A）回收包含乙烯，丙烯，水，任选未转化的混合物（A）的醇，各种烃和步骤a）的任选的惰性组分的流出物， d）将步骤c）的所述流出物分馏以产生至少一种乙烯流，丙烯流，基本上由具有4个碳原子或更多的烃组成的级分，水和步骤a）的任选的惰性组分，任选地将乙烯全部回收或在par 在反应器（A）的入口处，任选地在反应器（A）的入口处循环基本上由具有4个或更多个碳原子的烃组成的馏分。

8. 发明申请

US20130204059A1 PROCESS TO MAKE OLEFINS FROM ISOBUTANOL 有权
标题翻译：从ISOBUTANOL制造OLEFINS的过程
公开(公告)号：US20130204059A1
公开(公告)日：2013-08-08
申请号：US13813115
申请日：2011-07-08
申请人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
发明人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/22 , C07C2/12
CPC分类号： C07C1/24 , C07C1/20 , C07C1/22 , C07C2/12 , C07C4/06 , C07C11/06 , C07C29/00 , C07C2529/40 , C07C2529/85 , C08F210/02 , C08F210/06 , C12P7/16 , Y02P30/42
摘要： The present invention relates to a process for the conversion of an alcohols mixture (A) comprising about 20 w % to 100% isobutanol to make essentially propylene, comprising: a) introducing in a reactor (A) a stream comprising the mixture (A), mixed with a stream (D1) comprising olefins having 4 carbon atoms or more (C4+ olefins), optionally water, optionally an inert component, b) contacting said stream with a catalyst (A1) at a temperature above 500° C. in said reactor (A) at conditions effective to dehydrate at least a part of the isobutanol and other alcohols, if any, and make a cracking, c) recovering from said reactor (A) an effluent comprising: ethylene, propylene, water, optionally unconverted alcohols of the mixture (A), various hydrocarbons, and the optional inert component of step a), d) fractionating said effluent of step c) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).
摘要翻译：本发明涉及一种将包含约20％至100％异丁醇的醇混合物（A）转化成基本上丙烯的方法，其包括：a）在反应器（A）中引入包含混合物（A）的料流，与包含具有4个或更多碳原子的烯烃（C 4 +烯烃），任选的水，任选的惰性组分的流（D1）混合，b）在所述的温度高于500℃的温度下使所述料流与催化剂（A1）接触反应器（A）在有效使至少一部分异丁醇和其它醇脱水的条件下（如果有的话）并且产生裂化，c）从所述反应器（A）回收包含乙烯，丙烯，水，任选未转化的醇混合物（A），各种烃和步骤a）的任选的惰性组分，d）将步骤c）的所述流出物分馏以产生至少一种乙烯流，丙烯料流，基本上由具有4碳原子的烃组成的馏分原子或更多，水和步骤a）的任选的惰性组分，任选地在反应器（A）的入口处全部或部分地循环乙烯，任选地在反应器（A）的入口处循环基本上由具有4个或更多碳原子的烃组成的馏分，。

9. 发明申请

US20130204057A1 SIMULTANEOUS DEHYDRATION AND SKELETAL ISOMERISATION OF ISOBUTANOL ON ACID CATALYSTS 有权
标题翻译： ISOBUTANOL在酸性催化剂上的同时脱水和同位素同位素
公开(公告)号：US20130204057A1
公开(公告)日：2013-08-08
申请号：US13582759
申请日：2011-03-15
申请人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
发明人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/24 , C07C5/25
CPC分类号： C07C1/24 , B01J29/85 , C07C5/2518 , C07C5/2775 , C07C11/08 , C07C11/09 , C07C2521/04 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/127
摘要： The present invention (in a first embodiment) relates to a process for the simultaneous dehydration and skeletal isomerisation of isobutanol to make substantially corresponding olefins, having the same number of carbons and consisting essentially of a mixture of n-butenes and iso-butene, said process comprising: a) introducing in a reactor a stream (A) comprising isobutanol, optionally water, optionally an inert component, b) contacting said stream with a catalyst in said reactor at conditions effective to dehydrate and skeletal isomerise at least a portion of the isobutanol to make a mixture of n- butenes and iso-butene, c) recovering from said reactor a stream (B), removing water, the inert component if any and unconverted isobutanol if any to get a mixture of n-butenes and iso-butene, Wherein, the WHSV of the isobutanol is at least 1 h−1 or the temperature is from 200° C. to 600° C. and the catalyst is capable to make simultaneously the dehydration and skeletal isomerization of butene. The catalyst is a crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL or TON having Si/Al higher than 10, or a dealuminated crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL or TON having Si/Al higher than 10, or a phosphorus modified crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL or TON having Si/Al higher than 10, or a silicoaluminaphosphate molecular sieve of the group AEL, or a silicated, zirconated or titanated or fluorinated alumina. Advantageously the stream (B) is fractionated in a step d) to produce a n-butenes stream (N) and to remove the essential part of isobutene optionally recycled with stream (A) to the dehydration/isomerization reactor of step b).
摘要翻译：本发明（在第一个实施方案中）涉及同时脱水和骨架异构化异丁醇以制备具有相同数目的碳并基本上由正丁烯和异丁烯组成的基本相应的烯烃的方法，所述方法方法包括：a）在反应器中引入包含异丁醇，任选的水，任选的惰性组分的物流（A），b）在所述反应器中使所述物流与催化剂接触，所述条件有效地脱水和骨架异构化至少部分异丁醇以制备正丁烯和异丁烯的混合物，c）从所述反应器回收流（B），除去水，惰性组分（如果有的话）和未转化的异丁醇（如果有的话）以得到正丁烯和异丁烯的混合物，丁烯，其中异丁醇的WHSV为至少1h-1或温度为200℃至600℃，并且催化剂能够同时进行bu的脱水和骨架异构化泰恩该催化剂是具有Si / Al大于10的FER，MWW，EUO，MFS，ZSM-48，MTT，MFI，MEL或TON的结晶硅酸盐，或FER，MWW，EUO等的脱铝结晶硅酸盐，具有Si / Al大于10的MFS，ZSM-48，MTT，MFI，MEL或TON，或FER，MWW，EUO，MFS，ZSM-48，MTT，MFI，MEL或TON的磷改性结晶硅酸盐，其具有 Si / Al高于10，或AEL的硅铝磷酸盐分子筛，或硅化，锆酸化或钛酸化或氟化氧化铝。有利地，在步骤d）中将流（B）分馏以产生正丁烯料流（N），并除去任选与料流（A）一起循环的异丁烯的主要部分至步骤b）的脱水/异构化反应器。

10. 发明授权

US10464053B2 Method for making a catalyst comprising a phosphorous modified zeolite and use of said zeolite 有权
公开(公告)号：US10464053B2
公开(公告)日：2019-11-05
申请号：US14236750
申请日：2012-07-25
申请人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath
发明人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath
IPC分类号： B01J29/06 , B01J29/85 , B01J29/40 , B01J37/02 , B01J29/70 , B01J29/65 , B01J37/10 , B01J37/28 , C07C1/20 , C07C1/24 , C07C2/66 , C07C2/86 , C07C4/06 , C10G29/20 , C10G29/22 , C10G3/00 , B01J37/00 , C07C1/22 , C07C2/08
摘要： A method to make a phosphorus modified zeolite can include providing a zeolite having at least one ten member ring, making an ion-exchange, steaming the zeolite, and introducing phosphorus on the zeolite. The zeolite can be mixed with one or more binders and shaping additives, and then shaped. A metal can be introduced, and the catalyst can be washed, calcined, and steamed in an equilibration step. The steaming can be at performed at a steam severity (X) of at least about 2. The steaming can be performed at a temperature above 625° C. The catalyst can be used in alcohol dehydration, olefin cracking, MTO processes, and alkylation of aromatics by alcohols with olefins and/or alcohols.

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