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    • 1. 发明授权
    • Polyamide moulding material and use thereof for production of LED housing components
    • 聚酰胺成型材料及其用于生产LED外壳部件的用途
    • US08859662B2
    • 2014-10-14
    • US13096374
    • 2011-04-28
    • Nikolai LambertsAndreas BayerManfred HewelHeinz Hoff
    • Nikolai LambertsAndreas BayerManfred HewelHeinz Hoff
    • C08K3/26C08K3/22C08K7/14
    • C08K3/26C08K3/22C08K7/14C08L77/06
    • What is described is a polyamide molding material based on semicrystalline polyamides for production of LED housings or housing components with high strength, high long-term reflectivity and low blistering tendency. The polyamide moulding material proposed consists of the following components (A) 40 to 80% by weight of at least one semiaromatic polyamide based on at least 70 mol % of aromatic dicarboxylic acids and at least 70 mol % of aliphatic diamines having 4 to 18 carbon atoms and having a melting temperature in the range from 270° C. to 340° C. (B) 10 to 30% by weight of titanium dioxide particles (C) 5 to 20% by weight of glass fibres (D) 5-30% by weight of calcium carbonate. The percentages by weight of components (A) to (D) together add up to 100%, with the proviso that components (B), (C) and (D) meet the following conditions: (B)+(C)+(D)=20 to 60% by weight; weight ratio of (C)/(D) in the range from 0.25 to 1.5, where the polyamide molding material may optionally comprise customary additives (E) in addition to components (A) to (D), and where the amount thereof is in addition to the sum of components (A) to (D).
    • 描述的是用于生产具有高强度,高长期反射率和低起泡倾向的LED壳体或壳体部件的半结晶聚酰胺的聚酰胺模塑材料。 提出的聚酰胺成型材料由以下组分(A)40至80重量%的至少一种基于至少70摩尔%的芳族二羧酸和至少70摩尔%的具有4至18个碳原子的脂族二胺的半芳族聚酰胺 原子并且具有在270℃至340℃范围内的熔融温度。(B)10至30重量%的二氧化钛颗粒(C)5至20重量%的玻璃纤维(D)5-30 重量%的碳酸钙。 组分(A)至(D)的重量百分比一起加起来为100%,条件是组分(B),(C)和(D)满足以下条件:(B)+(C)+( D)= 20〜60重量% (C)/(D)的重量比在0.25至1.5的范围内,其中除了组分(A)至(D)之外,聚酰胺模塑材料可任选地包含常规添加剂(E),并且其量在 (A)至(D)的总和除外。
    • 2. 发明申请
    • TRANSPARENT POLYAMIDE ELASTOMERS
    • 透明聚酰胺弹性体
    • US20100203275A1
    • 2010-08-12
    • US12670306
    • 2008-07-17
    • Botho HoffmannHeinz Hoff
    • Botho HoffmannHeinz Hoff
    • C08G69/08B32B1/08B29C45/00
    • C08G69/26B29C39/006B29C45/0001B29C48/022C08G69/08C08G69/265C08G69/36C08G69/40C08G69/44Y10T428/139Y10T428/1397
    • A description is given, together with preferred applications, of a transparent polyamide elastomer of the general structure (I), where R1 is a polyamide segment formed from (a) 10-100 mol % of alkyl-substituted bis(aminocyclohexyl)methane and/or bis(aminocyclohexyl)propane and 0-90 mol % of other cycloaliphatic C6-C36 diamines and/or aliphatic C2-C36 diamines and/or aromatic C6-C36 diamines, the concentration figures being based on the total amount of diamine in the polyamide segment, and (b) aliphatic C4-C36 dicarboxylic acids and/or cycloaliphatic C8-C36 dicarboxylic acids and/or aromatic C8-C36 dicarboxylic acids, and (c) optionally lactams and/or aminocarboxylic acids C6-C12, R2 being selected from the group of the divalent radicals: linear or branched C2-C5 polyoxyalkylene, polyolefin, polysiloxane with a number-average molar mass in the range of 200-3000 g/mol, linear or branched, substituted or unsubstituted C2-C36 alkylene, C6-C36 cycloalkylene, C6-C20 aryl, polycaprolactone, polyesters based on aliphatic or cycloaliphatic dicarboxylic acids and diols, aliphatic polycarbonate, and also copolymers of or mixtures of these elements, and X1 and X2 independently of one another being amide (CONH) or ester (COO) bonds.
    • 连同一般结构(I)的透明聚酰胺弹性体一起被描述,其中R1是由(a)10-100摩尔%的烷基取代的双(氨基环己基)甲烷形成的聚酰胺链段和/ 或二(氨基环己基)丙烷和0-90摩尔%的其它脂环族C 6 -C 36二胺和/或脂肪族C 2 -C 36二胺和/或芳族C 6 -C 36二胺,其浓度图基于聚酰胺中二胺的总量 和(b)脂族C 4 -C 36二羧酸和/或脂环族C 8 -C 36二羧酸和/或芳族C 8 -C 36二羧酸,和(c)任选的内酰胺和/或氨基羧酸C6-C12,R2选自 二价基团:直链或支链C 2 -C 5聚氧化烯,聚烯烃,数均摩尔质量在200-3000g / mol范围内的聚硅氧烷,直链或支链的取代或未取代的C 2 -C 36亚烷基, C36亚环烷基,C6-C20芳基,聚己内酯,p 基于脂族或脂环族二羧酸和二醇的脂肪族聚酯,脂肪族聚碳酸酯,以及这些元素的共聚物或这些元素的混合物,X 1和X 2彼此独立地为酰胺(CONH)或酯(COO)键。
    • 5. 发明授权
    • Multi-cylinder hot-gas engine with automatic air and gas supply
    • 具有自动空气和气体供应的多缸热气发动机
    • US4327551A
    • 1982-05-04
    • US151883
    • 1980-05-21
    • Joachim GrossmannHeinz Hoff
    • Joachim GrossmannHeinz Hoff
    • F02G1/043F02G1/044F02G1/047F02G1/04
    • F02G1/047F02G1/044
    • The temperature of the working gas in the heating chamber of each of a number of cylinders is continuously measured. An electronic selection circuit selects the lowest measured temperature as a control parameter by which the speed of a blower in the common air supply is controlled for providing an air flow proportional to blower speed. A pressure-detecting device measures the air flow through a pressure converter provides an electrical signal that normally controls the valves of the respective fuel supplies for the combustion chambers of the cylinders, but a monitoring device for each cylinder compares the measured working gas temperature with a pre-set maximum value so that when the maximum value is exceeded, the fuel supply valve is changed over to control by the output of the monitoring device, to reduce the fuel supply until the maximum temperature is no longer exceeded in that cylinder. For still a higher temperature of the working gas in any cylinder, determined by another sensor, a general shutdown valve reduces the common fuel supply. An auxiliary air supply provides atomizing air for fuel injection.
    • 连续地测量多个气缸中的每一个的加热室中的工作气体的温度。 电子选择电路选择最低测量温度作为控制参数,通过该参数控制共用空气供应中的鼓风机的速度以提供与鼓风机速度成比例的空气流。 压力检测装置测量通过压力转换器的气流提供通常控制用于气缸的燃烧室的相应燃料供应的阀的电信号,但是每个气缸的监测装置将测得的工作气体温度与 预设最大值,使得当超过最大值时,通过监视装置的输出改变燃料供给阀以进行控制,以减少燃料供应,直到该气缸中不再超过最大温度。 对于由另一个传感器确定的任何气缸中的工作气体的较高温度,一般关闭阀减少了常见的燃料供应。 辅助空气源提供用于燃料喷射的雾化空气。
    • 8. 发明授权
    • Partially crystalline block copolyester-polyamides
    • 部分结晶嵌段共聚酯 - 聚酰胺
    • US5703177A
    • 1997-12-30
    • US573058
    • 1995-12-15
    • Heinz Hoff
    • Heinz Hoff
    • C08G69/44C08G81/00
    • C08G69/44
    • This invention relates to biologically degradable, partially crystalline block copolyester-polyamides comprising at least two chemically differently structured segments of which at least one is a polyester (PES) block or a copolyester (coPES) block, preferably with a number average molecular mass of 340 to 10,000 g/mole, and at least one is a polyamide (PA) block or a copolyamide (coPA) block, preferably with a number average molecular mass of 400 to 3,000 g/mole. In addition, copolyester-amide (coPEA) blocks can be employed, preferably with a number average molecular mass of 500 to 5,000 g/mole. The invention also relates to a polycondensation process for the manufacture of these partially crystalline block copolyester-polyamides. The block copolymers described are useful for the manufacture of fibers, foils, molded articles and hot melt-type adhesives. Molded components manufactured from the copolymers in accordance with the invention are biologically degradable and are capable of being composted.
    • 本发明涉及生物可降解的部分结晶的嵌段共聚酯 - 聚酰胺,其包含至少两个化学上不同的结构化部分,其中至少一个是聚酯(PES)嵌段或共聚酯(coPES)嵌段,优选数均分子量为340 至10,000g / mol,并且至少一种是聚酰胺(PA)嵌段或共聚酰胺(coPA)嵌段,优选数均分子量为400至3,000g / mol。 此外,可以使用共聚酯 - 酰胺(coPEA)嵌段,优选数均分子量为500-5,000g / mol。 本发明还涉及用于制造这些部分结晶嵌段共聚酯 - 聚酰胺的缩聚方法。 所述的嵌段共聚物可用于制造纤维,箔,模塑制品和热熔型粘合剂。 由本发明的共聚物制成的成型部件是生物可降解的并且能够被堆肥。
    • 10. 发明授权
    • Stain-resistant article and use thereof
    • 耐污渍制品及其用途
    • US09346952B2
    • 2016-05-24
    • US13861529
    • 2013-04-12
    • Etienne AepliMark PflegharBotho HoffmannHeinz Hoff
    • Etienne AepliMark PflegharBotho HoffmannHeinz Hoff
    • C08L77/06C08K3/30C08G69/14C08G69/26C08K7/14C08K3/22
    • C08L77/06C08G69/14C08G69/26C08K3/22C08K3/30C08K7/14C08K2003/2241C08K2003/3036C08L2205/02
    • What is described is the use of a polyamide moulding composition for the production of a stain-resistant article, the staining tendency (ST) of the article being at least 2. Here, the composition contains 30-100% by weight of a polyamide or a polyamide mixture, consisting of 50-100% by weight of at least one amorphous and/or microcrystalline polyamide having a glass transition temperature of at least 100° C., based on: 20-100 mol % of at least one cycloaliphatic diamine; and 0-80 mol % of at least one other aliphatic and/or aromatic diamine; and also aromatic and/or aliphatic dicarboxylic acids comprising at least 6 carbon atoms, and 0-50% by weight of at least one semi-aromatic polyamide. In addition, 0-70% by weight of fibrous fillers (B1) and/or particulate fillers (B2), 0-30% by weight of impact toughness modifier and/or polymers different from (A), 0-25% by weight of a flame retardant, and 0-3% by weight of additives may also be contained.
    • 描述的是使用聚酰胺模塑组合物来生产耐污渍制品,制品的染色趋势(ST)至少为2.这里,组合物含有30-100重量%的聚酰胺或 至少一种玻璃化转变温度至少为100℃的至少一种无定形和/或微晶聚酰胺组成的聚酰胺混合物,基于:20-100摩尔%的至少一种脂环族二胺; 和0-80摩尔%的至少一种其它脂族和/或芳族二胺; 以及包含至少6个碳原子的芳族和/或脂族二羧酸和0-50重量%的至少一种半芳族聚酰胺。 此外,0-70重量%的纤维填料(B1)和/或颗粒填料(B2),0-30重量%的冲击韧性改性剂和/或不同于(A)的聚合物,0-25重量% 的阻燃剂,并且还可以含有0-3重量%的添加剂。