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1. 发明授权

US09708425B2 Routes to polyacrylates 有权
公开(公告)号：US09708425B2
公开(公告)日：2017-07-18
申请号：US13885030
申请日：2011-11-11
申请人： Niels Joergen Madsen , Christian B. Nielsen , Petr Sehnel , David George Anderson
发明人： Niels Joergen Madsen , Christian B. Nielsen , Petr Sehnel , David George Anderson
IPC分类号： C08F120/18 , C08F2/50 , C08G18/73 , C08G18/66 , C08G18/75 , C08G18/32
CPC分类号： C08F120/18 , C08F2/50 , C08G18/3275 , C08G18/667 , C08G18/6688 , C08G18/73 , C08G18/758
摘要： A polyacrylate is obtained by radical polymerization of at least one acrylate monomer (Ac) in the presence of a polymeric photoinitiator. The polymeric photoinitiator is a co-polymer of at least one photoinitiator monomer (A) with at least one monomer (B), and optional additional monomers (C). Rapid polymerization of the acrylate monomer is provided. A method produces a polyacrylate using the polymeric photoinitiator as described, and a polymeric photoinitiator is used as the photoinitiator of radical polymerization of acrylate monomers.

2. 发明申请

US20130296577A1 NOVEL PHOTOINITIATORS 有权
标题翻译：新光子
公开(公告)号：US20130296577A1
公开(公告)日：2013-11-07
申请号：US13885015
申请日：2011-11-11
申请人： Niels Joergen Madsen , Petr Sehnal , Christian B. Nielsen , David George Anderson
发明人： Niels Joergen Madsen , Petr Sehnal , Christian B. Nielsen , David George Anderson
IPC分类号： C07C225/22 , C07C213/02 , C07C221/00 , C07C217/22 , C07D335/16
CPC分类号： C07D335/16 , C07C213/02 , C07C217/22 , C07C217/62 , C07C221/00 , C07C225/16 , C07C225/22 , C07D207/416 , C08F2/50 , C08G18/3275 , C08G18/4833 , C08G18/5024 , C08G18/5072 , C08G18/73 , C08G18/758 , C08J3/24 , C08J3/28 , C08J2375/00 , C09D175/12
摘要： Novel photoinitiators provide for polyurethane formation, in which a photoinitiator moiety and a tertiary amine are incorporated into the photoinitiator structure, and thus the polyurethane polymer.
摘要翻译：新型光引发剂提供聚氨酯形成，其中将光引发剂部分和叔胺引入光引发剂结构中，从而聚氨酯聚合物。

3. 发明申请

US20130289155A1 NOVEL POLYMERIC PHOTOINITIATORS 有权
标题翻译：新型聚合物光敏剂
公开(公告)号：US20130289155A1
公开(公告)日：2013-10-31
申请号：US13885007
申请日：2011-11-11
申请人： Niels Joergen Madsen , Petr Sehnal , Christian B. Nielsen , David George Anderson
发明人： Niels Joergen Madsen , Petr Sehnal , Christian B. Nielsen , David George Anderson
IPC分类号： C09D175/12
CPC分类号： C07D335/16 , C07C213/02 , C07C217/22 , C07C217/62 , C07C221/00 , C07C225/16 , C07C225/22 , C07D207/416 , C08F2/50 , C08G18/3275 , C08G18/4833 , C08G18/5024 , C08G18/5072 , C08G18/73 , C08G18/758 , C08J3/24 , C08J3/28 , C08J2375/00 , C09D175/12
摘要： A polymeric photoinitiator, most suitably a polyurethane photoinitiator, is obtained by step-growth co-polymerization of at least one monomer (A) with at least one monomer (B). Monomer (A) includes a photoinitiator moiety, while monomer (B) is a monomer reactive with monomer (A) to form a polymer. A method produces the polymeric photoinitiator, a method cross-links the polymeric photoinitiator, and the polymeric photoinitiator is used as a photoinitiator of radical polymerization.
摘要翻译：聚合物光引发剂，最合适的是聚氨酯光引发剂，通过至少一种单体（A）与至少一种单体（B）的步进生长共聚获得。单体（A）包括光引发剂部分，而单体（B）是与单体（A）反应形成聚合物的单体。一种方法产生聚合物光引发剂，一种交联聚合物光引发剂的方法，聚合物光引发剂用作自由基聚合的光引发剂。

4. 发明授权

US09034941B2 Hydrophilic gels from polyurethane-based photoinitiators 有权
标题翻译：聚氨酯类光引发剂的亲水性凝胶
公开(公告)号：US09034941B2
公开(公告)日：2015-05-19
申请号：US13805134
申请日：2011-06-22
申请人： Christian B. Nielsen , Niels Joergen Madsen , David George Anderson , Petr Sehnal
发明人： Christian B. Nielsen , Niels Joergen Madsen , David George Anderson , Petr Sehnal
IPC分类号： C08G18/67 , C08G65/18 , A61K9/00 , C08L75/12 , A61L27/34 , A61L27/52 , A61L29/08 , A61L29/14 , A61L31/10 , A61L31/14 , C08F2/50 , C08G18/32 , C08G18/50 , C08G18/66 , C08G18/75 , C08G73/02 , C08J3/075 , C08J3/24
CPC分类号： C08L75/12 , A61L27/34 , A61L27/52 , A61L29/085 , A61L29/145 , A61L31/10 , A61L31/145 , C08F2/50 , C08G18/329 , C08G18/5024 , C08G18/6688 , C08G18/758 , C08G73/028 , C08G2210/00 , C08J3/075 , C08J3/24 , C08J2375/12
摘要： The present invention relates to the use of polymeric photoinitiators based on polyalkyletherurethane backbones in the production of hydrophilic gels, in particular hydrogels. The invention relates to methods for manufacturing hydrophilic gels using said polymeric photoinitiators, and the hydrophilic gels thus obtained.
摘要翻译：本发明涉及基于聚烷基醚聚氨酯主链的聚合物光引发剂在亲水性凝胶，特别是水凝胶的生产中的用途。本发明涉及使用所述聚合物光引发剂制备亲水性凝胶的方法和由此获得的亲水性凝胶。

5. 发明授权

US09670373B2 Polymers comprising photoinitiator moieties and dye moieties 有权
公开(公告)号：US09670373B2
公开(公告)日：2017-06-06
申请号：US14240704
申请日：2012-08-24
申请人： Niels Joergen Madsen , Christian B. Nielsen , Petr Sehnal , David George Anderson
发明人： Niels Joergen Madsen , Christian B. Nielsen , Petr Sehnal , David George Anderson
IPC分类号： C09D11/328 , C09B62/00 , C09D11/101 , C08F2/50 , C08F2/48 , C09D11/023 , C08F2/46
CPC分类号： C09D11/328 , C08F2/46 , C08F2/48 , C08F2/50 , C08G2261/1642 , C09B62/00 , C09D11/023 , C09D11/101
摘要： The invention relates to a polymer (P) comprising at least one photoinitiator moiety (PI) and at least one dye moiety (DYE), wherein said at least one photoinitiator moiety (PI) and at least one dye moiety (DYE) are covalently linked to said polymer (P). Additionally, the invention relates to said polymer (P) being end-functionalized with optionally substituted acryloyi groups. The fact that both of these moieties are tightly bonded within the polymer, and the cross-linked polymer, means that the opportunities for leaching/migration of these components is reduced or even eliminated. Inks comprising at least one of said polymers are also provided. Methods for the manufacture of the polymers, and for printing are provided.

6. 发明授权

US09371308B2 Polymeric photoinitiators 有权
标题翻译：聚合物光引发剂
公开(公告)号：US09371308B2
公开(公告)日：2016-06-21
申请号：US13885007
申请日：2011-11-11
申请人： Niels Joergen Madsen , Petr Sehnal , Christian B. Nielsen , David George Anderson
发明人： Niels Joergen Madsen , Petr Sehnal , Christian B. Nielsen , David George Anderson
IPC分类号： C07D213/02 , C07D221/00 , C07D207/416 , C07D335/16 , C08F2/50 , C08G18/32 , C08G18/48 , C08G18/50 , C08G18/73 , C08G18/75 , C07C217/22 , C07C225/16 , C07C225/22 , C08J3/24 , C08J3/28 , C09D175/12 , C07C213/02 , C07C221/00 , C07C217/62
CPC分类号： C07D335/16 , C07C213/02 , C07C217/22 , C07C217/62 , C07C221/00 , C07C225/16 , C07C225/22 , C07D207/416 , C08F2/50 , C08G18/3275 , C08G18/4833 , C08G18/5024 , C08G18/5072 , C08G18/73 , C08G18/758 , C08J3/24 , C08J3/28 , C08J2375/00 , C09D175/12
摘要： A polymeric photoinitiator, most suitably a polyurethane photoinitiator, is obtained by step-growth co-polymerization of at least one monomer (A) with at least one monomer (B). Monomer (A) includes a photoinitiator moiety, while monomer (B) is a monomer reactive with monomer (A) to form a polymer. A method produces the polymeric photoinitiator, a method cross-links the polymeric photoinitiator, and the polymeric photoinitiator is used as a photoinitiator of radical polymerization.
摘要翻译：聚合物光引发剂，最合适的是聚氨酯光引发剂，通过至少一种单体（A）与至少一种单体（B）的步进生长共聚获得。单体（A）包括光引发剂部分，而单体（B）是与单体（A）反应形成聚合物的单体。一种方法产生聚合物光引发剂，一种交联聚合物光引发剂的方法，聚合物光引发剂用作自由基聚合的光引发剂。

7. 发明申请

US20130296454A1 ROUTES TO POLYACRYLATES 有权
标题翻译：路线聚丙烯酸酯
公开(公告)号：US20130296454A1
公开(公告)日：2013-11-07
申请号：US13885030
申请日：2011-11-11
申请人： Niels Jørgen Madsen , Petr Sehnel , David George Anderson , Christian B. Nielsen
发明人： Niels Jørgen Madsen , Petr Sehnel , David George Anderson , Christian B. Nielsen
IPC分类号： C08F120/18 , C08G18/66
CPC分类号： C08F120/18 , C08F2/50 , C08G18/3275 , C08G18/667 , C08G18/6688 , C08G18/73 , C08G18/758
摘要： A polyacrylate is obtained by radical polymerization of at least one acrylate monomer (Ac) in the presence of a polymeric photoinitiator. The polymeric photoinitiator is a co-polymer of at least one photoinitiator monomer (A) with at least one monomer (B), and optional additional monomers (C). Rapid polymerization of the acrylate monomer is provided. A method produces a polyacrylate using the polymeric photoinitiator as described, and a polymeric photoinitiator is used as the photoinitiator of radical polymerization of acrylate monomers.
摘要翻译：在聚合物光引发剂的存在下，通过至少一种丙烯酸酯单体（Ac）的自由基聚合获得聚丙烯酸酯。聚合物光引发剂是至少一种光引发剂单体（A）与至少一种单体（B）和任选的另外的单体（C）的共聚物。提供丙烯酸酯单体的快速聚合。一种方法使用如所述的聚合物光引发剂生产聚丙烯酸酯，并且使用聚合物光引发剂作为丙烯酸酯单体的自由基聚合的光引发剂。

8. 发明授权

US08946449B2 Photoinitiators 有权
标题翻译：光引发剂
公开(公告)号：US08946449B2
公开(公告)日：2015-02-03
申请号：US13885015
申请日：2011-11-11
申请人： Niels Jørgen Madsen , Petr Sehnal , David George Anderson , Christian B. Nielsen
发明人： Niels Jørgen Madsen , Petr Sehnal , David George Anderson , Christian B. Nielsen
IPC分类号： C07D207/416 , C07C213/02 , C07D335/16 , C08F2/50 , C08G18/32 , C08G18/48 , C08G18/50 , C08G18/73 , C08G18/75 , C07C217/22 , C07C225/16 , C07C225/22 , C08J3/24 , C08J3/28 , C09D175/12 , C07C221/00
CPC分类号： C07D335/16 , C07C213/02 , C07C217/22 , C07C217/62 , C07C221/00 , C07C225/16 , C07C225/22 , C07D207/416 , C08F2/50 , C08G18/3275 , C08G18/4833 , C08G18/5024 , C08G18/5072 , C08G18/73 , C08G18/758 , C08J3/24 , C08J3/28 , C08J2375/00 , C09D175/12
摘要： Novel photoinitiators provide for polyurethane formation, in which a photoinitiator moiety and a tertiary amine are incorporated into the photoinitiator structure, and thus the polyurethane polymer.
摘要翻译：新型光引发剂提供聚氨酯形成，其中将光引发剂部分和叔胺引入光引发剂结构中，从而聚氨酯聚合物。

9. 发明授权

US5905164A Polyalkylene polyol esters of dialkylaminobenzoic acid and their use in photoinitiated curing processes 失效
标题翻译：二烷基氨基苯甲酸的聚亚烷基多元醇酯及其在光引发固化过程中的用途
公开(公告)号：US5905164A
公开(公告)日：1999-05-18
申请号：US930581
申请日：1998-02-27
申请人： David George Anderson , Robert Stephen Davidson , Neil Richard Cullum , Elizabeth Sands
发明人： David George Anderson , Robert Stephen Davidson , Neil Richard Cullum , Elizabeth Sands
IPC分类号： C07C229/60 , C07C229/00 , C07C205/00
CPC分类号： C07C229/60
摘要： Amine compounds of general formula (I), ##STR1## wherein: each R.sup.1 independently represents an alkyl group; each R.sup.2 independently represents an alkyl group; each group X independently represents a polyalkylene polyol moiety wherein hydroxyl groups of the polyol moiety are optionally alkylated but not including a group X which includes an ethyleneoxy or di(ethyleneoxy) moiety; n and m independently represent 1, 2 or 3; and each Q is independently selected from hydrogen or halogen atoms, and alkyl, acyl, nitro, cyano, alkoxy, hydroxy, amino, alkylamino, sulphinyl, alkylsulphinyl, sulphonyl, alkylsulphonyl, sulphonate, amido, alkylamido, alkoxycarbonyl, halocarbonyl and haloalkyl groups, processes for their preparation and intermediate compounds are described. Compounds of general formula (I) are useful as radiation curing agents in polymerisation processes.
摘要翻译： PCT No.PCT / GB96 / 00910 Sec。 371日期1998年2月27日 102（e）1998年2月27日PCT PCT 1996年4月17日PCT公布。出版物WO96 / 33157 日期：1996年10月24日通式（I）的化合物，其中：各个R1独立地表示烷基; 每个R 2独立地表示烷基; 每个基团X独立地表示多亚烷基多元醇部分，其中多元醇部分的羟基任选被烷基化，但不包括包含乙烯氧基或二（乙烯氧基）部分的基团X; n和m独立地表示1,2或3; 烷基，酰基，硝基，氰基，烷氧基，羟基，氨基，烷基氨基，亚磺酰基，烷基亚磺酰基，磺酰基，烷基磺酰基，磺酸酯，酰胺基，烷基酰氨基，烷氧基羰基，卤代羰基和卤代烷基，描述了它们的制备方法和中间体化合物。通式（I）的化合物在聚合过程中可用作辐射固化剂。

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