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1. 发明授权

US08664337B2 Thick blown films 有权
标题翻译：厚膜
公开(公告)号：US08664337B2
公开(公告)日：2014-03-04
申请号：US13515828
申请日：2011-01-11
申请人： Nicolas Mazzola , Jorge Gomes , Maria Pollard , Michael Turner
发明人： Nicolas Mazzola , Jorge Gomes , Maria Pollard , Michael Turner
IPC分类号： C08F8/00 , C08F10/02 , C08K5/32 , C08L23/26 , C08L23/04 , C08J5/18 , C08F8/30 , C08K5/3435 , C08F210/16 , C08F110/02 , C08J3/22
CPC分类号： C08L23/0815 , C08F8/30 , C08F110/02 , C08J5/18 , C08J2323/36 , C08K5/3435 , C08L2205/025 , Y10T428/139 , C08L23/36 , C08L2023/44 , C08L2666/04 , C08F2500/03 , C08F2500/11 , C08F2500/12 , C08F2500/17
摘要： The present invention is a film having a thickness greater than 100 microns comprising from 10 to 100 percent by weight of a polyethylene polymer made by the process of a) selecting a target polyethylene resin having a density, as determined according to ASTM D792, in the range of from 0.90 g/cm3 to 0.955 g/cm3, and a melt index, as determined according to ASTM D1238(2.16 kg, 190 C), in the range of from 0.01 g/10 min to 10 g/10 min; b) reacting said target polyethylene with an alkoxy amine derivative in an amount less than 900 parts derivative per million parts by weight of total polyethylene resin under conditions sufficient to increase the melt strength of the target polyethylene resin; and c) forming a thick film from the modified target resin. The present films include those which can achieve similar processability as those containing unmodified linear polyethylene despite having at least 10% less LDPE resins in the formulation.
摘要翻译：本发明是一种厚度大于100微米的薄膜，其包含10-100％重量的聚乙烯聚合物，该聚乙烯聚合物是通过以下方法制备的：a）选择具有根据ASTM D792测定的密度的目标聚乙烯树脂范围为0.90g / cm 3至0.955g / cm 3，根据ASTM D1238（2.16kg，190℃）测定的熔体指数为0.01g / 10min至10g / 10min; b）在足以增加目标聚乙烯树脂的熔体强度的条件下，使所述目标聚乙烯与总聚乙烯树脂的百万分之一重量份衍生物的量小于900份的衍生物反应所述目标聚乙烯; 和c）从改性目标树脂形成厚膜。本发明的膜包括那些可以实现与含有未改性的线性聚乙烯相似的加工性的那些，尽管配方中LDPE树脂的含量至少降低10％。

2. 发明申请

US20130022804A1 THICK BLOWN FILMS 有权
标题翻译：厚薄膜
公开(公告)号：US20130022804A1
公开(公告)日：2013-01-24
申请号：US13515828
申请日：2011-01-11
申请人： Nicolas Mazzola , Jorge Gomes , Maria Pollard , Michael Turner
发明人： Nicolas Mazzola , Jorge Gomes , Maria Pollard , Michael Turner
IPC分类号： C08L23/06
CPC分类号： C08L23/0815 , C08F8/30 , C08F110/02 , C08J5/18 , C08J2323/36 , C08K5/3435 , C08L2205/025 , Y10T428/139 , C08L23/36 , C08L2023/44 , C08L2666/04 , C08F2500/03 , C08F2500/11 , C08F2500/12 , C08F2500/17
摘要： The present invention is a film having a thickness greater than 100 microns comprising from 10 to 100 percent by weight of a polyethylene polymer made by the process of a) selecting a target polyethylene resin having a density, as determined according to ASTM D792, in the range of from 0.90 g/cm3 to 0.955 g/cm3, and a melt index, as determined according to ASTM D1238(2.16 kg, 190 C), in the range of from 0.01 g/10 min to 10 g/10 min; b) reacting said target polyethylene with an alkoxy amine derivative in an amount less than 900 parts derivative per million parts by weight of total polyethylene resin under conditions sufficient to increase the melt strength of the target polyethylene resin; and c) forming a thick film from the modified target resin. The present films include those which can achieve similar processability as those containing unmodified linear polyethylene despite having at least 10% less LDPE resins in the formulation.
摘要翻译：本发明是一种厚度大于100微米的薄膜，其包含10-100％重量的聚乙烯聚合物，该聚乙烯聚合物是通过以下方法制备的：a）选择具有根据ASTM D792测定的密度的目标聚乙烯树脂范围为0.90g / cm 3至0.955g / cm 3，根据ASTM D1238（2.16kg，190℃）测定的熔体指数为0.01g / 10min至10g / 10min; b）在足以增加目标聚乙烯树脂的熔体强度的条件下，使所述目标聚乙烯与总聚乙烯树脂的百万分之一重量份衍生物的量小于900份的衍生物反应所述目标聚乙烯; 和c）从改性目标树脂形成厚膜。本发明的膜包括那些可以实现与含有未改性的线性聚乙烯相似的加工性的那些，尽管配方中LDPE树脂的含量至少降低10％。

3. 发明授权

US08987382B2 High melt strength polyethylene compositions and methods for making the same 有权
标题翻译：高熔体强度聚乙烯组合物及其制备方法
公开(公告)号：US08987382B2
公开(公告)日：2015-03-24
申请号：US13515841
申请日：2011-01-11
申请人： Mehmet Demirors , Teresa Karjala , Nicolas Mazzola
发明人： Mehmet Demirors , Teresa Karjala , Nicolas Mazzola
IPC分类号： C08F8/00 , C08L23/10 , C08L23/08 , C08J5/18 , C08F110/02 , C08K5/3435
CPC分类号： C08L23/0815 , C08F8/30 , C08F110/02 , C08J5/18 , C08J2323/36 , C08K5/3435 , C08L2205/025 , Y10T428/139 , C08L23/36 , C08L2023/44 , C08L2666/04 , C08F2500/03 , C08F2500/11 , C08F2500/12 , C08F2500/17
摘要： The present invention is a method for increasing the melt strength of a polyethylene resin comprising reacting the polyethylene resin with a free radical generator with a decomposition energy in between −50 kJoule/mole and −250 kJoules/mole and a peak decomposition temperature of less than 280 degree C. The resulting resin has increased melt strength with higher ratio of elongational viscosities at 0.1 to 100 rad/s when compared to substantially similar polyethylene resins which have not been reacted with a free radical generator such as an alkoxy amine derivative.
摘要翻译：本发明是提高聚乙烯树脂的熔融强度的方法，其包括使聚乙烯树脂与自由基发生剂反应，其分解能在-50kJoule / mol和-250kJo / mol之间，峰分解温度小于当与未与诸如烷氧基胺衍生物的自由基发生剂反应的基本相似的聚乙烯树脂相比时，所得树脂具有增加的熔体强度，并且在0.1-100prad / s时具有较高的伸长粘度比。

4. 发明申请

US20120283390A1 HIGH MELT STRENGTH POLYETHYLENE COMPOSITIONS AND METHODS FOR MAKING THE SAME 有权
标题翻译：高熔点强度聚乙烯组合物及其制备方法
公开(公告)号：US20120283390A1
公开(公告)日：2012-11-08
申请号：US13515841
申请日：2011-01-11
申请人： Mehmet Demirors , Teresa Karjala , Nicolas Mazzola
发明人： Mehmet Demirors , Teresa Karjala , Nicolas Mazzola
IPC分类号： C08F10/02 , C08F8/32
CPC分类号： C08L23/0815 , C08F8/30 , C08F110/02 , C08J5/18 , C08J2323/36 , C08K5/3435 , C08L2205/025 , Y10T428/139 , C08L23/36 , C08L2023/44 , C08L2666/04 , C08F2500/03 , C08F2500/11 , C08F2500/12 , C08F2500/17
摘要： The present invention is a method for increasing the melt strength of a polyethylene resin comprising reacting the polyethylene resin with a free radical generator with a decomposition energy in between −50 kJoule/mole and −250 kJoules/mole and a peak decomposition temperature of less than 280 degree C. The resulting resin has increased melt strength with higher ratio of elongational viscosities at 0.1 to 100 rad/s when compared to substantially similar polyethylene resins which have not been reacted with a free radical generator such as an alkoxy amine derivative.
摘要翻译：本发明是提高聚乙烯树脂的熔融强度的方法，其包括使聚乙烯树脂与自由基发生剂反应，其分解能在-50kJoule / mol和-250kJo / mol之间，峰分解温度小于当与未与诸如烷氧基胺衍生物的自由基发生剂反应的基本相似的聚乙烯树脂相比时，所得树脂具有增加的熔体强度，并且在0.1-100prad / s时具有较高的伸长粘度比。

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