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1. 发明申请

US20100120983A1 STYRENE/ANHYDRIDE POLYMERIC MATERIAL AND GRAFT HAVING ENHANCED PROPERTIES 有权
标题翻译：苯乙烯/无水聚合材料和具有增强性能的树脂
公开(公告)号：US20100120983A1
公开(公告)日：2010-05-13
申请号：US12526102
申请日：2008-02-01
申请人： Nicolas Dufaure , Sandra Grimaldi , Manuel Hidalgo , Ludwik Leibler , Francois-Genes Tournilhac
发明人： Nicolas Dufaure , Sandra Grimaldi , Manuel Hidalgo , Ludwik Leibler , Francois-Genes Tournilhac
IPC分类号： C08F222/06
CPC分类号： C08F8/34 , C08F8/14 , C08F8/32 , C08F222/06 , C08F2800/20 , C08F2810/10 , C08L51/06 , C08L2205/08 , C08F212/08
摘要： A polymeric material from the styrene family, consisting of macromolecular chains grafted by nitrogen-containing heterocyclic groups; wherein the macromolecular chains consist of a polymeric backbone to which a grafted agent is attached by at least one covalent bond, the grafting agent comprises, in a single molecule, one or more associative groups capable of being bound by hydrogen bonds, and one or more reactive groups capable of forming covalent bonds with the polymeric backbone, at least one of the associative groups of the modifier is an imidazolidone heterocyclic ring. The mean number of imidazolidone groups to be inserted into the macromolecular chains is dependent both on the mean mass of said chains and on the final properties to be imparted to the material. The polymeric material of the invention can be extruded, coextruded, injected, blow-moulded, moulded, overmoulded, calendered or thermoformed. Objects such as tubes, films, plates, stiffenerss, bottles and containers can be made. The polymeric material of the invention can also be blended with other materials such as other polymers, and can thus be modified by elastomeric phases that enhance the impact strength thereof. The polymeric material of the invention can be a component of masterbatches of additives such as pigments and fillers. The present invention further relates to the use of said polymeric material as a compatibilization agent in a composition including, inter alia, at least two polymers belonging to different polymeric classes.”
摘要翻译：来自苯乙烯家族的聚合物材料，由含氮杂环基团接枝的大分子链组成; 其中所述大分子链由接枝剂通过至少一个共价键连接的聚合物主链组成，所述接枝剂在单个分子中包含一个或多个能够被氢键结合的缔合基团，以及一个或多个能够与聚合物主链形成共价键的反应性基团，改性剂的至少一个缔合基团是咪唑烷酮杂环。插入大分子链中的咪唑烷酮基团的平均数目取决于所述链的平均质量和赋予材料的最终性能。本发明的聚合物材料可以挤出，共挤出，注塑，吹塑，模制，包覆成型，压延或热成型。可以制造诸如管，膜，板，扶强材，瓶和容器的物体。本发明的聚合物材料还可以与其它材料如其它聚合物共混，并且因此可以通过增强其冲击强度的弹性体相改性。本发明的聚合物材料可以是颜料和填料等添加剂母料的成分。本发明还涉及所述聚合物材料在组合物中的相容剂的用途，所述组合物尤其包括属于不同聚合物类别的至少两种聚合物。

2. 发明授权

US08609765B2 Styrene/anhydride polymeric material and graft having enhanced properties 有权
标题翻译：具有增强性能的苯乙烯/酸酐聚合物材料和接枝物
公开(公告)号：US08609765B2
公开(公告)日：2013-12-17
申请号：US13541064
申请日：2012-07-03
申请人： Nicolas Dufaure , Sandra Grimaldi , Manuel Hidalgo , Ludwik Leibler , Francois-Genes Tournilhac
发明人： Nicolas Dufaure , Sandra Grimaldi , Manuel Hidalgo , Ludwik Leibler , Francois-Genes Tournilhac
IPC分类号： C08L51/00 , C08F20/08
CPC分类号： C08F8/34 , C08F8/14 , C08F8/32 , C08F222/06 , C08F2800/20 , C08F2810/10 , C08L51/06 , C08L2205/08 , C08F212/08
摘要： A polymeric material from the styrene family comprises macromolecular chains grafted by nitrogen-containing heterocyclic groups; wherein the macromolecular chains comprise a polymeric backbone to which a grafted agent is attached by at least one covalent bond, the grafting agent comprises, in a single molecule, one or more associative groups capable of being bound by hydrogen bonds, and one or more reactive groups capable of forming covalent bonds with the polymeric backbone, at least one of the associative groups of the modifier is an imidazolidone heterocyclic ring. The mean number of imidazolidone groups to be inserted into the macromolecular chains is dependent both on the mean mass of said chains and on the final properties to be imparted to the material. Objects such as tubes, films, plates, stiffeners, bottles and containers can be made.
摘要翻译：来自苯乙烯系的聚合物材料包括由含氮杂环基团接枝的大分子链; 其中所述大分子链包含通过至少一个共价键连接的接枝剂的聚合物主链，所述接枝剂在单一分子中包含一个或多个能够被氢键结合的缔合基团，以及一个或多个反应性能够与聚合物主链形成共价键的基团，改性剂的至少一个缔合基团是咪唑啉酮杂环。插入大分子链中的咪唑烷酮基团的平均数目取决于所述链的平均质量和赋予材料的最终性能。可以制造诸如管，膜，板，加强件，瓶和容器的物体。

3. 发明授权

US08242207B2 Styrene/anhydride polymeric material and graft having enhanced properties 有权
标题翻译：具有增强性能的苯乙烯/酸酐聚合物材料和接枝物
公开(公告)号：US08242207B2
公开(公告)日：2012-08-14
申请号：US12526102
申请日：2008-02-01
申请人： Nicolas Dufaure , Sandra Grimaldi , Manuel Hidalgo , Ludwik Leibler , Francois-Genes Tournilhac
发明人： Nicolas Dufaure , Sandra Grimaldi , Manuel Hidalgo , Ludwik Leibler , Francois-Genes Tournilhac
IPC分类号： C08L51/00 , C08K3/00
CPC分类号： C08F8/34 , C08F8/14 , C08F8/32 , C08F222/06 , C08F2800/20 , C08F2810/10 , C08L51/06 , C08L2205/08 , C08F212/08
摘要： A polymeric material from the styrene family, consisting of macromolecular chains grafted by nitrogen-containing heterocyclic groups; wherein the macromolecular chains consist of a polymeric backbone to which a grafted agent is attached by at least one covalent bond, the grafting agent comprises, in a single molecule, one or more associative groups capable of being bound by hydrogen bonds, and one or more reactive groups capable of forming covalent bonds with the polymeric backbone, at least one of the associative groups of the modifier is an imidazolidone heterocyclic ring. The polymeric material of the invention can also be blended with other materials such as other polymers, and can thus be modified by elastomeric phases that enhance the impact strength thereof.
摘要翻译：来自苯乙烯家族的聚合物材料，由含氮杂环基团接枝的大分子链组成; 其中所述大分子链由接枝剂通过至少一个共价键连接的聚合物主链组成，所述接枝剂在单个分子中包含一个或多个能够被氢键结合的缔合基团，以及一个或多个能够与聚合物主链形成共价键的反应性基团，改性剂的至少一个缔合基团是咪唑烷酮杂环。本发明的聚合物材料还可以与其它材料如其它聚合物共混，并且因此可以通过增强其冲击强度的弹性体相改性。

4. 发明申请

US20120029139A1 BLOCK COPOLYMERS HAVING ASSOCIATIVE GROUPS, AND ADHESIVE CONTAINING SAME 审中-公开
标题翻译：具有相关组合的嵌段共聚物，和包含它们的粘合剂
公开(公告)号：US20120029139A1
公开(公告)日：2012-02-02
申请号：US13147228
申请日：2010-01-29
申请人： Nicolas Dufaure , Manuel Hidalgo , Aurelie Grange , Francois-Genes Tournilhac , Ludwik Leibler
发明人： Nicolas Dufaure , Manuel Hidalgo , Aurelie Grange , Francois-Genes Tournilhac , Ludwik Leibler
IPC分类号： C09J153/00
CPC分类号： C09J153/00 , C08F293/005 , C08F2438/02
摘要： The present invention relates to a hot-melt adhesive that comprises a block copolymer having associative groups containing a nitrogen heterocyclic compound. The invention also relates to block copolymers having associative groups specifically adapted for implementation in a hot-melt adhesive
摘要翻译：本发明涉及包含具有含有氮杂环化合物的缔合基团的嵌段共聚物的热熔性粘合剂。本发明还涉及具有特别适用于在热熔粘合剂中实施的缔合基团的嵌段共聚物

5. 发明申请

US20100135940A1 SEMI-CRYSTALLINE SUPRAMOLECULAR POLYMERS 有权
标题翻译：半结晶分子聚合物
公开(公告)号：US20100135940A1
公开(公告)日：2010-06-03
申请号：US12440308
申请日：2007-09-07
申请人： Sandra Grimaldi , Jean-Philippe Gillet , Manuel Hidalgo , Francois-Genes Tournilhac , Philippe Cordier , Ludwik Leibler
发明人： Sandra Grimaldi , Jean-Philippe Gillet , Manuel Hidalgo , Francois-Genes Tournilhac , Philippe Cordier , Ludwik Leibler
IPC分类号： C08G69/14 , C08L77/00 , A61K8/84 , A61Q19/02 , C09J179/04 , C08L95/00 , C09D11/10
CPC分类号： A61K8/84 , A61K2800/54 , A61Q19/00 , C08G69/00 , C09D177/00
摘要： The invention relates to a supramolecular polymer derived from the reaction between (i) an amine bearing a nitrogen-containing heterocyclic group: imidazolidone, trimethyleneurea or triazine, capable of joining together via hydrogen bonds with (ii) at least one fatty acid monomer comprising at least one reactive functional group, a dimer of identical or different fatty acids and/or a trimer of identical or different fatty acids, or a derivative of said fatty acid(s) chosen from a fatty acid ester, and a fatty acid chloride.
摘要翻译：本发明涉及一种超分子聚合物，其衍生自（i）带有含氮杂环基的胺：咪唑烷酮，三亚甲基脲或三嗪，其能够通过氢键与（ii）至少一种含有至少一个反应性官能团，相同或不同脂肪酸的二聚物和/或相同或不同脂肪酸的三聚体，或所述脂肪酸的衍生物，选自脂肪酸酯和脂肪酰氯。

6. 发明授权

US08916142B2 Semi-crystalline supramolecular polymers 有权
标题翻译：半结晶超分子聚合物
公开(公告)号：US08916142B2
公开(公告)日：2014-12-23
申请号：US12440308
申请日：2007-09-07
申请人： Sandra Grimaldi , Jean-Philippe Gillet , Manuel Hidalgo , Francois-Genes Tournilhac , Philippe Cordier , Ludwik Leibler
发明人： Sandra Grimaldi , Jean-Philippe Gillet , Manuel Hidalgo , Francois-Genes Tournilhac , Philippe Cordier , Ludwik Leibler
IPC分类号： A61K31/785 , A61K8/84 , A61Q19/00 , C09D177/00 , C08G69/00
CPC分类号： A61K8/84 , A61K2800/54 , A61Q19/00 , C08G69/00 , C09D177/00
摘要： The invention relates to a supramolecular polymer obtained from the reaction of (i) an amine bearing a nitrogen-containing heterocyclic group: imidazolidone, trimethyleneurea or triazine, which is capable of associating by means of hydrogen bonds and (ii) at least one fatty acid monomer comprising at least one reactive function, a dimer of identical or different fatty acids and/or a trimer of identical or different fatty acids, or a derivative of said fatty acid(s) which is selected from a fatty acid ester, and a fatty acid chloride.
摘要翻译：本发明涉及从（i）带有含氮杂环基的胺：咪唑烷酮，三亚甲基脲或三嗪的反应得到的超分子聚合物，其能够通过氢键缔合，和（ii）至少一种脂肪酸包含至少一种反应性官能团的单体，相同或不同脂肪酸的二聚体和/或相同或不同脂肪酸的三聚体或所述脂肪酸的衍生物，其选自脂肪酸酯和脂肪酸酰氯。

7. 发明授权

US08252872B2 Polymer material containing chains bearing imidazolidone functions 有权
标题翻译：含有咪唑烷酮功能的链的聚合物材料
公开(公告)号：US08252872B2
公开(公告)日：2012-08-28
申请号：US12878383
申请日：2010-09-09
申请人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
发明人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
IPC分类号： C08F8/30 , C08F8/32 , C08G69/48 , C08L77/00
CPC分类号： C08F8/30 , C08F8/32 , C08F8/34 , C08G69/48 , Y10T428/1352 , Y10T428/139 , C08F220/14 , C08F210/02
摘要： The invention concerns a polymer material consisting of macromolecular chains bound by hydrogen bonds, wherein: the macromolecular chains consist of a polymer skeleton whereon is fixed by at least one covalent bond a modifying agent, the modifying agent comprising, assembled in a common molecule, one or more associative groups capable of being bound by hydrogen bonds and one or more reactive groups capable of forming covalent bonds with the polymer skeleton, at least one of the associative groups of the modifying agent is an imidazolidone heterocycle, the macromolecular chains bear on average, 1 to 10 imidazolidone groups per chain. The average number of imidazolidone groups to be introduced into the macromolecular chains depends both on the average mass of said chains and the final properties desired for the material.
摘要翻译：本发明涉及由氢键结合的大分子链组成的聚合物材料，其中：大分子链由其中通过至少一个共价键固定的聚合物骨架修饰剂组成，改性剂包含组装在共同分子中的一种，一种或更多的能够被氢键结合的缔合基团和一个或多个能够与聚合物骨架形成共价键的反应性基团，改性剂的至少一个缔合基团是咪唑啉酮杂环，大分子链平均负载，每链1至10个咪唑烷酮基。引入大分子链中的咪唑烷酮基团的平均数量取决于所述链的平均质量和材料所需的最终性能。

8. 发明申请

US20080221272A1 Polymer Material Comprising Chains Bearing Imidazolidone Functions 审中-公开
标题翻译：包含咪唑啉酮功能的链条的聚合物材料
公开(公告)号：US20080221272A1
公开(公告)日：2008-09-11
申请号：US11631690
申请日：2005-07-06
申请人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
发明人： Francois-Genes Tournilhac , Ludwik Leibler , Philippe Cordier , Corinne Soulie-Ziakovic , Annett Linemann , Manuel Hidalgo
IPC分类号： C08F8/30 , C08G63/91
CPC分类号： C08F8/30 , C08F8/32 , C08F8/34 , C08G69/48 , Y10T428/1352 , Y10T428/139 , C08F220/14 , C08F210/02
摘要： The invention concerns a polymer material consisting of macromolecular chains bound by hydrogen bonds wherein: the macromolecular chains consist of a polymer skeleton whereon is fixed by at least one covalent bond a modifying agent, the modifying agent comprising, assembled in a common molecule, one or more associative groups capable of being bound by hydrogen bonds and one or more reactive groups capable of forming covalent bonds with the polymer skeleton, at least one of the associative groups of the modifying agent is an imidazolidone heterocycle, the macromolecular chains bear on average 1 to 10 imidazolidone groups per chain. The average number of imidazolidone groups to be introduced into the macromolecular chains depends both on the average mass of said chains and the final properties desired for the material. The inventive polymer material can be extruded, co-extruded, injected, blown, moulded, overmoulded, calandered, thermoformed. It can be used to produce articles such as tubes, films, plates, extruded strings, bottles, containers. The inventive polymer material can also be mixed with other materials such as other polymers, thus it is used for example as impact modifier or rheology regulator. The invention further concerns the use of said polymer material as compatibility agent in a composition comprising among others at least two polymers belonging to different classes of polymers.
摘要翻译：本发明涉及由氢键结合的大分子链组成的聚合物材料，其中：大分子链由其中通过至少一个共价键固定的聚合物骨架修饰剂组成，改性剂包含组装在共同分子中的一种或多种能够被氢键和一个或多个能够与聚合物骨架形成共价键的反应性基团结合的更多缔合基团，改性剂的至少一个缔合基团是咪唑啉酮杂环，大分子链平均为1〜 10个咪唑烷酮基团。引入大分子链中的咪唑烷酮基团的平均数量取决于所述链的平均质量和材料所需的最终性能。本发明的聚合物材料可以挤出，共挤出，注射，吹塑，模塑，包覆成型，压延，热成型。它可用于生产诸如管，薄膜，板，挤压线，瓶，容器等物品。本发明的聚合物材料也可以与其它材料如其它聚合物混合，因此其用作例如抗冲改性剂或流变调节剂。本发明还涉及所述聚合物材料作为相容剂在包含至少两种属于不同类型聚合物的聚合物的组合物中的用途。

9. 发明授权

US10093770B2 Supramolecular initiator for latent cationic epoxy polymerization 有权
公开(公告)号：US10093770B2
公开(公告)日：2018-10-09
申请号：US13964878
申请日：2013-08-12
申请人： Thomas Vidil , Francois-Genes Tournilhac , Ludwik Leibler
发明人： Thomas Vidil , Francois-Genes Tournilhac , Ludwik Leibler
IPC分类号： C08G59/72 , C08K5/06 , C08G59/68 , C08L63/00 , C08L101/00 , B01J31/00
摘要： A mixture may include at least one polymerizable species and at least one thermoresponsive supramolecular initiator complex involving a host-guest interaction. Processes for making resins may include mixing at least one polymerizable species with at least one thermoresponsive supramolecular initiator complex involving a host-guest interaction; subjecting the mixture to a temperature above about 30° C. thereby promoting the dissociation of the at least one thermoresponsive supramolecular initiator; and allowing the mixture to cure at the temperature for a period of time.

10. 发明申请

US20070123694A1 Supramolecular polymers 有权
标题翻译：超分子聚合物
公开(公告)号：US20070123694A1
公开(公告)日：2007-05-31
申请号：US11598931
申请日：2006-11-14
申请人： Francois-Genes Tournilhac , Corinne Soulie-Ziakovic , Ludwik Leibler , Laurent Lachaize
发明人： Francois-Genes Tournilhac , Corinne Soulie-Ziakovic , Ludwik Leibler , Laurent Lachaize
IPC分类号： C08G73/00
CPC分类号： C08G61/123 , C08F8/30 , C08F8/34 , C08G73/028 , C08K5/0025 , C08L65/00 , C08L79/02
摘要： The invention relates to a supramolecular polymer containing units which are linked by hydrogen bonds, said units being monomers of prepolymers comprising at least one functional group selected from the functional groups (1) and (3) and a second functional group (5) wherein A denotes oxygen, sulphur or NH and X is any unit; the hydrogen bonds in the supramolecular polymer being formed between two identical or different functional groups chosen from the functional groups (1) to (5). The inventive polymers can be used alone, i.e. in the form of a composition which is essentially made from said polymers and, optionally, stabilizers, antioxidants, etc. or in the form of a mixture with other polymers or other products.
摘要翻译：本发明涉及含有通过氢键连接的单元的超分子聚合物，所述单元是包含至少一种选自官能团（1）和（3）的官能团和第二官能团（5）的预聚物的单体，其中A 表示氧，硫或NH，X是任何单元; 超分子聚合物中的氢键形成在选自官能团（1）至（5）的两个相同或不同的官能团之间。本发明的聚合物可以单独使用，即以基本上由所述聚合物和任选的稳定剂，抗氧化剂等制成或与其它聚合物或其它产品混合形式的组合物的形式使用。

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