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    • 5. 发明授权
    • Low modulus thermoplastic olefin compositions
    • 低模量热塑性烯烃组合物
    • US06207754B1
    • 2001-03-27
    • US08864954
    • 1997-05-29
    • Thomas Chen-Chi Yu
    • Thomas Chen-Chi Yu
    • C08F1002
    • C08L23/10C08L23/0815C08L23/16Y10T428/31938C08L2666/04
    • This invention relates to thermoplastic olefin compositions of a low modulus which are suitable for fabrication into flexible skins and liners for applications which heretofore have been serviced by skins and liners produced essentially only from plasticized polyvinyl chloride resin compositions. TPO compositions of this invention comprise an impact modified polypropylene resin and a “plastomer” resin intimately blended in proportions with respect of one to another to provide a blend composition having a 1% secant modulus of less than 40,000 psi, and preferably less than 30,000 psi. Optionally, and preferably, the blend also comprises as a discrete component apart from the impact modified polypropylene an olefin copolymer elastomer or a cross-linked elastomer concentrate. Optionally the blend may contain other polyolefin components to alter its stiffness in desirable ways. In addition to the olefin based polymer components, the blend may further comprise, and preferably does comprise, a coupling agent and activator compound which, during melt compounding of the blend components causes the plastomer to extend to its dimer form and, when a discrete OCE component is present to couple the plastomer thereto.
    • 本发明涉及低模量的热塑性烯烃组合物,其适于制造用于迄今为止仅由增塑的聚氯乙烯树脂组合物生产的表皮和衬里所提供的应用的柔性表皮和衬里。 本发明的TPO组合物包含冲击改性的聚丙烯树脂和“塑性体”树脂,其按相对于彼此的比例密切混合,以提供具有小于40,000psi,优选小于30,000psi的1%割线模量的共混组合物 。 并且优选地,并且优选地,共混物还包括作为分散组分,除了抗冲改性聚丙烯之外,烯烃共聚物弹性体或交联的弹性体浓缩物。 任选地,共混物可以含有其它聚烯烃组分以以期望的方式改变其刚度。 除了基于烯烃的聚合物组分之外,共混物可以进一步包含并且优选地包含偶联剂和活化剂化合物,其在共混组分的熔融混合期间使塑性体延伸至其二聚体形式,并且当离散的OCE 存在组分以将塑性体连接到其上。