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1. 发明授权

US4190717A Process for producing polymer from quaternized acrylate monomer 失效
标题翻译：由季铵化丙烯酸酯单体生产聚合物的方法
公开(公告)号：US4190717A
公开(公告)日：1980-02-26
申请号：US842157
申请日：1977-10-14
申请人： Naoyuki Suzuki , Yoji Wada , Akihisa Furuno , Masao Ishii
发明人： Naoyuki Suzuki , Yoji Wada , Akihisa Furuno , Masao Ishii
IPC分类号： C02F1/54 , C08F2/02 , C08F20/34 , C08F2/16
CPC分类号： C02F1/54 , C08F20/34
摘要： A process for producing a cationic polymer, which comprises polymerizing a vinyl monomer represented by the general formula, ##STR1## wherein R.sub.1 represents --H or --CH.sub.3, R.sub.2 represents --CH.sub.2 CH.sub.2 -- or ##STR2## R.sub.3 and R.sub.4 represent --CH.sub.3 or --CH.sub.2 CH.sub.3, R.sub.5 represents --C.sub.n H.sub.2n+1, in which n is an integer of 0 to 4, ##STR3## or --CH.sub.2 COOH, and X.sup.- represents Cl.sup.-, CH.sub.3 SO.sub.4.sup.-, CH.sub.3 SO.sub.3.sup.-, or 1/2 SO.sub.4.sup.--, either alone or in admixture with up to 25% by weight, based on the total weight of the monomers, of other copolymerizable vinyl monomers in the presence of 7 to 18% by weight, based on the weight of the polymerization system, of water and, if necessary, choline chloride by use of a polymerization initiator and elevating the temperature, in the final polymerization stage, to 110.degree. to 150.degree. C. to complete the polymerization, thereby obtaining the water-soluble cationic polymer in the form of a lump. The polymer in the lump form thus obtained may be easily ground with a high efficiency at room temperature. The powdered polymer is excellent as a cationic flocculant.
摘要翻译：一种阳离子聚合物的制造方法，其包括聚合由通式表示的乙烯基单体，其中R 1表示-H或-CH 3，R 2表示-CH 2 CH 2 - 或R 3，R 4表示-CH 3 或-CH 2 CH 3，R 5表示-C n H 2n + 1，其中n为0至4的整数，或者是-CH 2 COOH，X表示Cl - ，CH 3 SO 4 - ，CH 3 SO 3 - 或1/2 SO 4 - 在基于聚合体系的重量的7至18重量％的存在下，单独或以至多25重量％的混合物，基于单体的总重量，其它可共聚的乙烯基单体的混合物，以及如果需要，使用聚合引发剂进行氯化胆碱化，并在最终聚合阶段将温度升高至110℃至150℃以完成聚合，从而获得块状形式的水溶性阳离子聚合物。如此获得的块状聚合物可以容易地在室温下高效地研磨。粉末聚合物作为阳离子絮凝剂是优异的。

2. 发明授权

US4165419A Metal surfaces coated with aliphatic acids containing 12 carbon atoms or more to eliminate polymer build-up on reactor walls during the polymerization of water-soluble cationic polymers 失效
标题翻译：涂覆有12个碳原子或更多碳原子的脂肪酸的金属表面，以消除水溶性阳离子聚合物聚合过程中反应器壁上的聚合物积聚
公开(公告)号：US4165419A
公开(公告)日：1979-08-21
申请号：US912804
申请日：1978-06-05
申请人： Naoyuki Suzuki , Yoji Wada , Akihisa Furuno , Iwao Ohshima , Yukio Shibuya
发明人： Naoyuki Suzuki , Yoji Wada , Akihisa Furuno , Iwao Ohshima , Yukio Shibuya
IPC分类号： C08F2/00 , C08F2/10 , C08F2/44 , C08F20/00 , C08F20/34 , C08F18/00
CPC分类号： C08F20/34
摘要： A method for producing a water-soluble cationic polymer by polymerizing, in the presence of water, a high concentration of (a) at least one vinyl monomer represented by the following general formula (I)ch.sub.2 .dbd.cr.sub.1 coor.sub.2 n.sup..sym. r.sub.3 r.sub.4 r.sub.5 x.sup..crclbar. (i)wherein R.sub.1 is --H or --CH.sub.3 ; R.sub.2 is --CH.sub.2 CH.sub.2 -- or --CH.sub.2 CH(OH)CH.sub.2 --; R.sub.3 and R.sub.4, which may be the same or different, each is --CH.sub.3 or --CH.sub.2 CH.sub.3 ; R.sub.5 is --C.sub.n H.sub.2n+1 where n is 0 or an integer of 1 to 4, --CH.sub.2 C.sub.6 H.sub.5, or --CH.sub.2 COOH; and X is Cl.sup.-, Br.sup.-, 1/2SO.sub.4.sup.-- or CH.sub.3 SO.sub.4.sup.-,or (b) a mixture of (i) at least one vinyl monomer represented by the general formula (I) and (ii) at least one other vinyl monomer copolymerizable therewith, wherein the vinyl monomer represented by the general formula (I) is present in the mixture in a predominant amount, and obtaining a polymer in a lump form, the improvement comprising performing the polymerization in a polymerization zone defined by a metal surface or surfaces, in which the metal surface(s) contacted during the polymerization have been coated with a layer of at least one of a higher aliphatic acid having 12 or more carbon atoms, an ammonium salt of a higher aliphatic acid having 12 or more carbon atoms and/or an alkali metal salt of a higher aliphatic acid having 12 or more carbon atoms.
摘要翻译：一种水溶性阳离子聚合物的制备方法，该水溶性阳离子聚合物通过在水存在下聚合高浓度（a）至少一种由以下通式（I）表示的乙烯基单体：CH2 = CR1COOR2N（+）R3R4R5X（ - ）（I）其中R1是-H或-CH3; R2是-CH2CH2-或-CH2CH（OH）CH2-; R 3和R 4可以相同或不同，各自为-CH 3或-CH 2 CH 3; R5是-CnH2n + 1，其中n是0或1-4的整数，-CH2C6H5或-CH2COOH; 和（b）由通式（I）表示的至少一种乙烯基单体和（ⅱ）至少一种其它乙烯基单体的混合物，可共聚的单体，其中由通式（I）表示的乙烯基单体以主要的量存在于混合物中，并且获得块状聚合物，其改进包括在由金属表面限定的聚合区中进行聚合或其中金属表面在聚合过程中接触的表面已经涂覆有具有12个或更多个碳原子的高级脂族酸中的至少一种的层，具有12个或更多个碳的高级脂族酸的铵盐原子和/或具有12个或更多个碳原子的高级脂族酸的碱金属盐。

3. 发明授权

US4164612A Process for producing water-soluble cationic polymers 失效
标题翻译：生产水溶性阳离子聚合物的方法
公开(公告)号：US4164612A
公开(公告)日：1979-08-14
申请号：US847025
申请日：1977-10-31
申请人： Naoyuki Suzuki , Yoji Wada , Akihisa Furuno
发明人： Naoyuki Suzuki , Yoji Wada , Akihisa Furuno
IPC分类号： B01D21/01 , C08F2/00 , C08F2/04 , C08F2/10 , C08F2/44 , C08F20/00 , C08F20/34 , C08F18/22 , C08F126/06
CPC分类号： C08F20/34 , Y10S526/923
摘要： In a process for producing a water-soluble polymer in an easily grindable glassy state by subjecting to aqueous solution polymerization a mixture comprising a monomer composed mainly of a vinyl monomer represented by the general formula (I): ##STR1## and water in an amount of 7 to 18% by weight based on the total weight of the monomer and water, a water-soluble salt in a powdery form is added to and dispersed in the polymerization system and the polymerization is carried out in the state that the powdery salt is dispersed, whereby a water-soluble polymer excellent in flocculating action and dissolving workability is obtained.
摘要翻译：在通过对水溶液聚合制备水溶性聚合物的方法中，将包含主要由通式（I）表示的乙烯基单体组成的单体：水和水相对于单体和水的总重量为7〜18重量％，将粉末状的水溶性盐加入到聚合体系中并分散在聚合体系中，聚合反应在粉状盐分散，得到絮凝作用和溶解作业性优异的水溶性聚合物。

4. 发明授权

US4313863A Modification of acrylamide polymers 失效
标题翻译：丙烯酰胺聚合物的改性
公开(公告)号：US4313863A
公开(公告)日：1982-02-02
申请号：US211294
申请日：1980-11-28
申请人： Ryoji Handa , Norimasa Yoshida , Jun Hosoda , Akihisa Furuno
发明人： Ryoji Handa , Norimasa Yoshida , Jun Hosoda , Akihisa Furuno
IPC分类号： C08F8/00 , C08F8/12 , C08K5/06 , C08L33/00 , C08L33/24 , C08L33/26
CPC分类号： C08F8/12 , Y10S524/916
摘要： When an alkaline substance is added to and mixed with aggregates of the mutually adhering blobs of a hydrogel of an acrylamide polymer, (1) a mixing tank in which the portion to be contacted with the hydrogel of an acrylamide polymer is made of a chromium-plated material is used, and (2) to said hydrogel aggregates is added at least one compound represented by the general formulae: ##STR1## wherein R.sub.1 is a residue obtained by removing two OH groups from a saturated dihydric alcohol having 2 to 4 carbon atoms, and R.sub.2 is a residue obtained by removing three OH groups from a saturated trihydric alcohol having 3 to 6 carbon atoms, and having an average molecular weight of 500 to 5,000, whereby the hydrolysis of the acrylamide polymer can be achieved at a high efficiency while preventing the mutual adhesion of the hydrogel aggregates and also reducing the adhesion of the aggregates to the interior surface of the mixing tank to such an extent that there is substantially no problem of adhesion.
摘要翻译：当将碱性物质加入并与丙烯酰胺聚合物的水凝胶的相互粘合的团块的混合物混合时，（1）混合罐，其中与丙烯酰胺聚合物的水凝胶接触的部分由铬 - （2）对所述水凝胶聚集体加入至少一种由以下通式表示的化合物：HO [C 3 H 6 O] n H（I）其中R 1是残基通过从具有2〜4个碳原子的饱和二元醇中除去2个OH基而获得的R 2是通过从具有3〜6个碳原子的饱和三元醇除去3个OH基而得到的残基，平均分子量为500〜 5,000，从而可以高效率地实现丙烯酰胺聚合物的水解，同时防止水凝胶聚集体的相互粘附并且还降低聚集体到混合罐的内表面的粘附程度，使得存在s 基本上没有粘附问题。

5. 发明授权

US5352828A Process for stabilizing aqueous acrylamide solution 失效
标题翻译：稳定丙烯酰胺水溶液的方法
公开(公告)号：US5352828A
公开(公告)日：1994-10-04
申请号：US885358
申请日：1992-05-19
申请人： Susumu Seki , Akihisa Furuno
发明人： Susumu Seki , Akihisa Furuno
IPC分类号： C07C231/02 , C07C231/22 , C07C233/09 , C08F20/52 , C08F20/56 , C07C209/90
CPC分类号： C07C231/22
摘要： A process for the stabilization of an aqueous acrylamide solution is described which includes adding at least one compound selected from water-soluble monocarboxylic acid salts having at least two carbon atoms to an aqueous solution of acrylamide in an amount of from 20 to 5,000 ppm as acid per acrylamide. According to the present invention, a high purity aqueous acrylamide solution which is markedly stable, even under an iron surface-contacting condition, without causing problems such as the polymerization of acrylamide can be provided by adding a water-soluble monocarboxylic acid salt having at least two carbon atoms.
摘要翻译：描述了一种用于稳定丙烯酰胺水溶液的方法，该方法包括将至少一种选自具有至少两个碳原子的水溶性单羧酸盐的化合物加入至丙烯酰胺水溶液中，其量为20-5,000ppm作为酸每丙烯酰胺。根据本发明，即使在铁表面接触条件下，也不会引起丙烯酰胺聚合等问题，显着稳定的高纯度丙烯酰胺水溶液可以通过加入至少具有至少一种的水溶性一元羧酸盐两个碳原子。

6. 发明授权

US3968093A Process for producing partially hydrolyzed polyacrylamide in the presence of alkali metal hydroxide and boric acid 失效
标题翻译：在碱金属氢氧化物和硼酸存在下制备部分水解的聚丙烯酰胺的方法
公开(公告)号：US3968093A
公开(公告)日：1976-07-06
申请号：US469443
申请日：1974-05-13
申请人： Masao Hasegawa , Akihisa Furuno , Haruhiko Ishikawa , Yasuo Ogawa
发明人： Masao Hasegawa , Akihisa Furuno , Haruhiko Ishikawa , Yasuo Ogawa
IPC分类号： C08F120/56 , C08F120/52 , C02C1/02 , C08F120/70
CPC分类号： C08F120/56
摘要： A process for producing a partially hydrolyzed polyacrylamide which has a high molecular weight and high water solubility and can be suitably used as a flocculant for water treatment and a size for paper manufacture comprising polymerizing an aqueous solution of an acrylamide monomer in the presence of an alkali metal hydroxide such as sodium hydroxide and boric acid, whereby a partial hydrolysis of the polymer formed is also conducted substantially simultaneously with the polymerization. In an additional embodiment, a maturing of the polyacrylamide produced can be conducted by continuing to heat the polymer solution to increase the hydrolysis percentage.
摘要翻译：一种生产部分水解的聚丙烯酰胺的方法，其具有高分子量和高水溶性，并且可以适合用作水处理的絮凝剂和纸制造的尺寸，包括在碱的存在下聚合丙烯酰胺单体的水溶液金属氢氧化物如氢氧化钠和硼酸，由此在聚合过程中基本上同时进行形成的聚合物的部分水解。在另外的实施方案中，所生产的聚丙烯酰胺的成熟可以通过继续加热聚合物溶液以提高水解百分比来进行。

7. 发明授权

US5200464A Water-soluble radical-curing polyvinyl alcohol derivative 失效
标题翻译：水溶性自由基固化聚乙烯醇衍生物
公开(公告)号：US5200464A
公开(公告)日：1993-04-06
申请号：US631846
申请日：1990-12-21
申请人： Akihisa Furuno , Susumu Harashima
发明人： Akihisa Furuno , Susumu Harashima
IPC分类号： C08F8/14 , C08F16/02 , C08F216/00 , C08F216/06 , C08F220/04 , C08F290/00 , C08F299/00
CPC分类号： C08F8/14 , C08F2810/30
摘要： A radical-curing polyvinyl alcohol derivative is disclosed, which is obtained by reacting an anion-modified polyvinyl alcohol prepared by saponification of a copolymer comprising vinyl acetate and an unsaturated carboxylic acid and/or a derivative thereof with a glycidyl-containing vinyl compound in water or in a mixed solvent of water and a lower alcohol under acidic conditions, and which is useful as an image-forming material which is curable upon light irradiation and developable with water.

8. 发明授权

US4514551A Process for the preparation of cationic polymers 失效
标题翻译：阳离子聚合物的制备方法
公开(公告)号：US4514551A
公开(公告)日：1985-04-30
申请号：US572753
申请日：1984-01-23
申请人： Akihisa Furuno , Kenichi Inukai , Yasuo Ogawa
发明人： Akihisa Furuno , Kenichi Inukai , Yasuo Ogawa
IPC分类号： B01D21/01 , C08F2/00 , C08F2/10 , C08F2/38 , C08F20/00 , C08F20/34 , C08F20/52 , C08F220/56 , D21H17/36 , D21H17/45
CPC分类号： D21H17/455 , C08F220/56
摘要： A process for preparing a cationic polymer which comprises polymerizing a monomer mixture containing acrylamide and a cationic alkenyl monomer represented by the general formula: ##STR1## wherein R.sup.1 represents H or CH.sub.3 ; R.sup.2 and R.sup.3 represent independently CH.sub.3 or C.sub.2 H.sub.5 ; R.sup.4 represents H, CH.sub.3, C.sub.2 H.sub.5 or a benzyl group; A represents --OC.sub.n H.sub.2n -- (wherein n=2 or 3), ##STR2## or --NC.sub.n H.sub.2n -- (wherein n=2 or 3); and X.sup.- represents Cl.sup.-, Br.sup.-, I.sup.-, CH.sub.3 SO.sub.4.sup.-, C.sub.2 H.sub.5 SO.sub.4.sup.-, 1/2SO.sub.4.sup.-- or CH.sub.3 COO.sup.-, in the form of a sheet in an aqueous medium, characterized in that the composition ratio of acrylamide/cationic alkenyl monomer is within the range of 95/5 to 5/95, and the polymerization is carried out in the presence of a phosphite. The polymers obtained according to this process are free from insolubles produced under the influence of oxygen.
摘要翻译：一种制备阳离子聚合物的方法，其包括聚合含有丙烯酰胺和由以下通式表示的阳离子烯基单体的单体混合物：其中R 1表示H或CH 3; R2和R3独立地表示CH3或C2H5; R4代表H，CH3，C2H5或苄基; A表示-OC n H 2n - （其中n = 2或3），或者-NC n H 2n - （其中n = 2或3）; 和X-表示在水性介质中的片状形式的Cl-，Br-，I-，CH 3 SO 4 - ，C 2 H 5 SO 4 - ，1 / 2SO 4 - 或CH 3 COO-，其特征在于丙烯酰胺/阳离子烯基单体在95/5〜5/95的范围内，聚合在亚磷酸盐存在下进行。根据该方法获得的聚合物不含在氧气的影响下产生的不溶物。

9. 发明授权

US4734238A Process for producing powder of cationic polymer 失效
标题翻译：制备阳离子聚合物粉末的方法
公开(公告)号：US4734238A
公开(公告)日：1988-03-29
申请号：US841840
申请日：1986-03-20
申请人： Teruhiko Sugimori , Hideaki Habara , Ken-ichi Inukai , Akihisa Furuno
发明人： Teruhiko Sugimori , Hideaki Habara , Ken-ichi Inukai , Akihisa Furuno
IPC分类号： B29B9/04 , B29B9/06 , C08F2/00 , C08F2/02 , C08F2/10 , C08F220/00 , C08F220/02 , C08J3/12
CPC分类号： C08J3/12 , B29B9/04 , B29B9/06 , C08F2/10 , C08J2333/14
摘要： The invention relates to a process for producing a powder of a cationic polymer by spreading on a moveable carrier a layer of an aqueous solution of a vinyl monomer, carrying out continuous polymerization followed by peeling off hydrous polymer from the carrier in a hot state, and cutting said hydrous polymer in a hot state by a shearing stress.
摘要翻译：本发明涉及一种阳离子聚合物粉末的制造方法，其通过在可动载体上铺展乙烯基单体的水溶液层，进行连续聚合，然后在热态下从载体上剥离含水聚合物，以及通过剪切应力在热态切割含水聚合物。

10. 发明授权

US4306048A Method for preparing acrylamide polymers 失效
标题翻译：制备丙烯酰胺聚合物的方法
公开(公告)号：US4306048A
公开(公告)日：1981-12-15
申请号：US176031
申请日：1980-08-07
申请人： Norimasa Yoshida , Yasuo Ogawa , Ryoji Handa , Susumu Seki , Jun Hosoda , Nobuo Kurashige , Akihisa Furuno
发明人： Norimasa Yoshida , Yasuo Ogawa , Ryoji Handa , Susumu Seki , Jun Hosoda , Nobuo Kurashige , Akihisa Furuno
IPC分类号： C08K5/13 , C08F2/00 , C08F2/44 , C08F6/00 , C08F6/06 , C08F6/12 , C08F20/56 , C08K5/37 , C08K5/53 , C08L33/00 , C08L33/02 , C08L33/24 , C08L33/26 , C08L77/00 , C08J3/12
CPC分类号： C08F6/12
摘要： In the production of a dried acrylamide polymer by polymerizing, in an aqueous medium, acrylamide alone or a monomer mixture comprising 50 mole % or more of acrylamide and at least one monomer copolymerizable therewith with a radical initiator, and then drying the resulting hydrous acrylamide polymer, the allowing of at least one of the following compounds [I], [II] and [III] to be present in the drying step or a step prior thereto enables the dried acrylamide polymer having a high molecular weight and a good dissolvability in water to be obtained:[I] a non-polymerizable compound having in its molecule at least one group represented by the formula, ##STR1## wherein R.sub.1 is H or an alkyl group having up to 4 carbon atoms, [II] a compound represented by the formula, R.sub.2 --S--C.sub.n H.sub.2n X wherein n is an integer of 1 to 8, R.sub.2 is an alkyl group, an aryl group or --C.sub.n H.sub.2n X, in which X is --OH, --COOH (or its salt), --CN or --CONH.sub.2, and[III] a compound represented by the formula, ##STR2## wherein R.sub.3, R.sub.4 and R.sub.5 are H, alkali metals or alkyl or aryl groups.
摘要翻译：在水性介质中单独使用丙烯酰胺或含有50摩尔％以上丙烯酰胺的单体混合物和至少一种可与其自由基引发剂共聚的单体的聚合反应生产干燥的丙烯酰胺聚合物，然后干燥得到的含水丙烯酰胺聚合物，允许至少一种以下化合物[I]，[II]和[III]化合物存在于干燥步骤或之前的步骤中，使得干燥的丙烯酰胺聚合物具有高分子量和在水中的良好溶解性 [I]在其分子中具有至少一个由下式表示的基团的非聚合性化合物，其中R 1为H或具有至多4个碳原子的烷基，[II]表示的化合物其中n为1〜8的整数，R 2为烷基，芳基或-C n H 2n，其中X为-OH，-COOH（或其盐），-CN或 - CONH 2和[III]由下式表示的化合物，其中R 3，R 4和R 3 5是H，碱金属或烷基或芳基。

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