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1. 发明授权

US06509508B2 Process for producing (meth)acrolein and (meth)acrylic acid 有权
标题翻译：制备（甲基）丙烯醛和（甲基）丙烯酸的方法
公开(公告)号：US06509508B2
公开(公告)日：2003-01-21
申请号：US10074035
申请日：2002-02-14
申请人： Naomasa Kimura , Michio Tanimoto , Hideo Onodera
发明人： Naomasa Kimura , Michio Tanimoto , Hideo Onodera
IPC分类号： C07C4535
CPC分类号： C07C51/235 , B01J23/002 , B01J23/31 , B01J23/8876 , B01J23/8885 , B01J2523/00 , C07C45/32 , C07C45/35 , C07C45/37 , C07C51/252 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/15 , B01J2523/3712 , B01J2523/847
摘要： A reaction for producing (metho)acrolein and (meth)acrylic acid by vaporn-phase oxidation of at least a compound selected from propyl-ene, isobytylene, t-bytanol and methyl-t-butyl ether. For the process Complex oxide catalysts represented by the formula, MoaWbBicFedAeBfCgDhEiOx (in which A is Ni or Co; B is Na, K, Rb, Cs or Tl; C is an alkaline earth metal; D is P, Te, Sb, Sn, Ce, Pb, Nb, Mn, As, B or Zn; E is Si, Al, Ti or Zr; and where a is 12, 0≦b≦10, 0
摘要翻译：通过至少选自丙基，异丁烯，叔丁醇和甲基叔丁基醚的化合物的蒸发相氧化制备（甲基）丙烯醛和（甲基）丙烯酸的反应。对于该方法，由式（其中A是Ni或Co; B是Na，K，Rb，Cs或Tl; C是碱土金属），D是P，Te，Sb，Sn，Ce ，Pb，Nb，Mn，As，B或Zn; E为Si，Al，Ti或Zr;其中a为12,0 <= b <= 10,0

2. 发明授权

US06383973B1 Complex oxide catalysts and process for producing (meth) acrolein and (meth) acrylic acid 有权
标题翻译：复合氧化物催化剂和（甲基）丙烯醛和（甲基）丙烯酸的制备方法
公开(公告)号：US06383973B1
公开(公告)日：2002-05-07
申请号：US09575454
申请日：2000-05-22
申请人： Naomasa Kimura , Michio Tanimoto , Hideo Onodera
发明人： Naomasa Kimura , Michio Tanimoto , Hideo Onodera
IPC分类号： B01J2714
CPC分类号： C07C51/235 , B01J23/002 , B01J23/31 , B01J23/8876 , B01J23/8885 , B01J2523/00 , C07C45/32 , C07C45/35 , C07C45/37 , C07C51/252 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/15 , B01J2523/3712 , B01J2523/847
摘要： Complex oxide catalysts represented by the formula, MoaWbBicFedAeBfCgDhEiOx (in which A is Ni or Co; B is Na, K, Rb, Cs or Tl; C is an alkaline earth metal; D is P, Te, Sb, Sn, Ce, Pb, Nb, Mn, As, B or Zn; E is Si, Al, Ti or Zr; and where a is 12, 0≦b≦10, 0
摘要翻译：由式（其中A为Ni或Co; B为Na，K，Rb，Cs或Tl; C为碱土金属; D为P，Te，Sb，Sn，Ce，Pb， Nb，Mn，As，B或Zn; E是Si，Al，Ti或Zr;其中a是12,0 <= b <= 10,0

3. 发明授权

US06632965B1 Process for producing acrolein and acrylic acid 有权
标题翻译：制备丙烯醛和丙烯酸的方法
公开(公告)号：US06632965B1
公开(公告)日：2003-10-14
申请号：US09633292
申请日：2000-08-04
申请人： Michio Tanimoto , Hiromi Yunoki , Hideyuki Hironaka , Naomasa Kimura
发明人： Michio Tanimoto , Hiromi Yunoki , Hideyuki Hironaka , Naomasa Kimura
IPC分类号： C07C5116
CPC分类号： C07C51/252 , B01J23/002 , B01J23/8876 , B01J23/8885 , B01J2523/00 , C07C45/35 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/847
摘要： The present invention provides a process for producing acrolein and acrylic acid by the vapor-phase oxidation of propylene in the presence of Mo—Bi—Fe-based compound oxide catalysts packed in a fixed-bed multitubular reactor wherein acrolein and acrylic acid can be stably produced in high yield for a long period of time. This process is characterized in that each reaction tube having two or more reaction zones disposed along the axis of the tube is packed with catalysts having different ratios of the Bi and/or Fe content to the Mo content in such a way that the ratio decreases from the gas inlet side toward the gas outlet side.
摘要翻译：本发明提供了一种在填充在固定床多管反应器中的Mo-Bi-Fe系复合氧化物催化剂存在下丙烯气相氧化制备丙烯醛和丙烯酸的方法，其中丙烯醛和丙烯酸可以稳定地长期以高产量生产。该方法的特征在于，具有沿着管轴设置的两个或更多反应区的每个反应管装填有具有不同比例的Bi和/或Fe含量与Mo含量的催化剂，使得该比例从气体入口侧朝向气体出口侧

4. 发明申请

US20100249455A1 Process for producing acrolein and acrylic acid 失效
标题翻译：制备丙烯醛和丙烯酸的方法
公开(公告)号：US20100249455A1
公开(公告)日：2010-09-30
申请号：US12662123
申请日：2010-03-31
申请人： Michio Tanimoto , Hideo Onodera
发明人： Michio Tanimoto , Hideo Onodera
IPC分类号： C07C51/25 , C07C45/35
CPC分类号： C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： The invention offers an improvement in a process for start-up in the occasion of producing acrolein and acrylic acid by catalytically oxidizing propylene at vapor phase under high load conditions, the start-up meaning the step of increasing the propylene supply rate (loading) from the non-reacting condition to the prescribed reaction conditions. This process is characterized in that the propylene supply rate is increased in the start-up stage of the reaction until the prescribed composition of starting reactant gas and the flow rate of the starting reactant gas are obtained, while adjusting at least one of the reaction temperature, the composition of the starting reactant gas and flow rate of the starting reactant gas, so as to maintain the propylene conversion at not lower than 90 mol %, the maximum peak temperature of the catalyst layer in each reaction zone at no higher than 450° C., and the sum of each ΔT (maximum peak temperature of a catalyst layer—reaction temperature) at the catalyst layer in each of the reaction zones to be no more than 180° C., respectively. According to this process, the reaction speedily reaches the steady state (standard operating conditions) and a high acrolein and acrylic acid yield is stably achieved from the start of the reaction.
摘要翻译：本发明提供了在高负载条件下通过在气相下催化氧化丙烯来生产丙烯醛和丙烯酸的情况下的启动方法的改进，启动意味着将丙烯供应速率（负载）从对规定的反应条件的非反应条件。该方法的特征在于，在反应的启动阶段，丙烯供给速率增加，直到获得规定的起始反应气体组成和起始反应气体的流量，同时调节至少一个反应温度，起始反应物气体的组成和起始反应气体的流速，以保持丙烯转化率不低于90mol％，各反应区中催化剂层的最高峰值温度不高于450° C，以及每个反应区域中的催化剂层的每个＆Dgr; T（催化剂层 - 反应温度的最大峰值温度）的总和分别不超过180℃。根据该方法，反应快速达到稳定状态（标准操作条件），从反应开始就可以稳定地获得高丙烯醛和丙烯酸的收率。

5. 发明申请

US20100249454A1 Process for producing acrylic acid 有权
标题翻译：丙烯酸生产工艺
公开(公告)号：US20100249454A1
公开(公告)日：2010-09-30
申请号：US12659994
申请日：2010-03-26
申请人： Michio Tanimoto , Hideo Onodera
发明人： Michio Tanimoto , Hideo Onodera
IPC分类号： C07C51/235
CPC分类号： C07C51/252 , C07C57/04
摘要： The invention offers an improvement in a process for start-up in the occasion of producing acrylic acid by catalytically oxidizing acrolein at vapor phase under high load conditions, the start-up meaning the step of increasing the acrolein supply rate (loading) from the non-reacting condition to the prescribed reaction conditions. This process is characterized in that the acrolein supply rate is increased in the start-up stage of the reaction until the prescribed composition of starting reactant gas and the flow rate of the starting reactant gas are obtained, while adjusting at least one of the reaction temperature, the composition of the starting reactant gas and the flow rate of the starting reactant gas, so as to maintain the acrolein conversion at not lower than 90 mol %, the maximum peak temperature of the catalyst layer in each reaction zone at no higher than 400° C., and the sum of each ΔT (maximum peak temperature of a catalyst layer-reaction temperature) at the catalyst layer in each of the reaction zones to be no more than 150° C., respectively. According to this process, the reaction speedily reaches the steady state (standard operating conditions) and a high acrylic acid yield is stably achieved from the start of the reaction.
摘要翻译：本发明提供了在高负载条件下通过在气相下催化氧化丙烯醛来生产丙烯酸的情况下的启动方法的改进，启动意味着提高丙烯醛供应速率（负载）反应条件达到规定的反应条件。该方法的特征在于，在反应开始阶段丙烯醛供应速率增加，直到获得规定的起始反应气体组成和起始反应气体的流量，同时调节至少一个反应温度，起始反应气体的组成和起始反应气体的流量，以使丙烯醛的转化率保持在不低于90mol％，催化剂层在每个反应区中的最大峰值温度不高于400℃ ℃，以及每个反应区域中的催化剂层的每个＆Dgr; T（催化剂层 - 反应温度的最大峰值温度）的总和分别不超过150℃。根据该方法，反应快速达到稳定状态（标准操作条件），从反应开始就稳定地得到高丙烯酸收率。

6. 发明授权

US06583316B1 Catalysts for production of unsaturated aldehyde and unsaturated carboxylic acid and a process for producing unsaturated aldehyde and unsaturated carboxylic acid using the catalysts 有权
标题翻译：用于生产不饱和醛和不饱和羧酸的催化剂和使用该催化剂生产不饱和醛和不饱和羧酸的方法
公开(公告)号：US06583316B1
公开(公告)日：2003-06-24
申请号：US09568975
申请日：2000-05-11
申请人： Hideo Onodera , Michio Tanimoto
发明人： Hideo Onodera , Michio Tanimoto
IPC分类号： C07C5116
CPC分类号： C07C51/25 , B01J21/06 , B01J23/002 , B01J23/10 , B01J23/8871 , B01J23/8876 , B01J35/0006 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/13 , B01J2523/3712 , B01J2523/41 , B01J2523/48 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/15 , B01J2523/36 , B01J2523/847
摘要： Improved catalysts for use in vapor phase oxidation of at least one compound selected from the group consisting of propylene, isobutylene, t-butanol and methyl-t-butyl ether with molecular oxygen or a molecular oxygen-containing gas to produce the corresponding unsaturated aldehyde and unsaturated carboxylic acid are provided. The improved catalysts are compositions comprising (A) a complex oxide containing as essential components molybdenum, bismuth and iron, which is known per se as a catalyst for said reaction and (B) a complex oxide containing cerium and zirconium as the essential components. When the improved catalysts are used, the production operation of unsaturated aldehyde and unsaturated carboxylic acid can be continued stably for over prolonged period.
摘要翻译：改进的催化剂用于至少一种选自丙烯，异丁烯，叔丁醇和甲基叔丁基醚与分子氧或含分子氧气体的化合物的气相氧化，以产生相应的不饱和醛和不饱和羧酸。改进的催化剂是包含（A）包含作为主要组分钼，铋和铁的复合氧化物的组合物，其本身已知作为所述反应的催化剂，（B）以铈和锆为主要成分的复合氧化物。当使用改进的催化剂时，不饱和醛和不饱和羧酸的生产操作可以长时间持续稳定。

7. 发明授权

US5981804A Catalyst for production of unsaturated aldehyde and unsaturated carboxylic acid and method for production of unsaturated aldehyde and unsaturated carboxylic acid by use of the catalyst 失效
标题翻译：用于生产不饱和醛和不饱和羧酸的催化剂以及通过使用催化剂生产不饱和醛和不饱和羧酸的方法
公开(公告)号：US5981804A
公开(公告)日：1999-11-09
申请号：US995642
申请日：1997-12-22
申请人： Ikuo Kurimoto , Tatsuya Kawajiri , Hideo Onodera , Michio Tanimoto , Yukio Aoki
发明人： Ikuo Kurimoto , Tatsuya Kawajiri , Hideo Onodera , Michio Tanimoto , Yukio Aoki
IPC分类号： B01J23/887 , B01J27/053 , B01J35/00 , C07C45/32 , C07C45/35 , C07C45/37 , C07C51/23 , C07C51/25 , C07C45/34 , B01J23/84
CPC分类号： C07C51/23 , B01J23/002 , B01J23/8876 , B01J27/053 , B01J35/0006 , C07C45/32 , C07C45/35 , C07C45/37 , C07C51/252 , B01J2523/00 , B01J35/002
摘要： A catalyst for the production of unsaturated aldehyde and unsaturated carboxylic acid by the vapor-phase catalytic oxidation of at least one compound selected from the group consisting of propylene, isobutylene, t-butanol and methyl-t-butyl ether and a method for the production of unsaturated aldehyde and unsaturated carboxylic acid by the use of this catalyst are provided. The catalyst of this invention comprises (A) a catalyst having Mo, Bi and Fe as essential components and used for the production of unsaturated aldehyde and unsaturated carboxylic acid by vapor-phase catalytic oxidation of propylene, isobutylene, t-butanol and/or methyl-t-butyl ether and (B) a solid acid having acid strength (Ho) of not more than -11.93. Since this catalyst excels in catalytic activity and service life, it allows unsaturated aldehyde and unsaturated carboxylic acid to be produced stably at a high yield for a long time.
摘要翻译：用于通过气相催化氧化至少一种选自丙烯，异丁烯，叔丁醇和甲基叔丁基醚的化合物来生产不饱和醛和不饱和羧酸的催化剂及其制备方法的不饱和醛和不饱和羧酸。本发明的催化剂包含（A）具有Mo，Bi和Fe作为必需组分的催化剂，用于通过丙烯，异丁烯，叔丁醇和/或甲基的气相催化氧化生产不饱和醛和不饱和羧酸叔丁基醚和（B）酸强度（Ho）不大于-11.93的固体酸。由于该催化剂在催化活性和使用寿命方面优异，因此可以长时间以高产率稳定地制备不饱和醛和不饱和羧酸。

8. 发明授权

US08404889B2 Process for producing acrolein and acrylic acid 失效
标题翻译：制备丙烯醛和丙烯酸的方法
公开(公告)号：US08404889B2
公开(公告)日：2013-03-26
申请号：US12662123
申请日：2010-03-31
申请人： Michio Tanimoto , Hideo Onodera
发明人： Michio Tanimoto , Hideo Onodera
IPC分类号： C07C51/16 , C07C45/00
CPC分类号： C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： The invention offers an improvement in a process for start-up in the occasion of producing acrolein and acrylic acid by catalytically oxidizing propylene at vapor phase under high load conditions, the start-up meaning the step of increasing the propylene supply rate (loading) from the non-reacting condition to the prescribed reaction conditions. This process is characterized in that the propylene supply rate is increased in the start-up stage of the reaction until the prescribed composition of starting reactant gas and the flow rate of the starting reactant gas are obtained, while adjusting at least one of the reaction temperature, the composition of the starting reactant gas and flow rate of the starting reactant gas, so as to maintain the propylene conversion at not lower than 90 mol %, the maximum peak temperature of the catalyst layer in each reaction zone at no higher than 450° C., and the sum of each ΔT (maximum peak temperature of a catalyst layer—reaction temperature) at the catalyst layer in each of the reaction zones to be no more than 180° C., respectively. According to this process, the reaction speedily reaches the steady state (standard operating conditions) and a high acrolein and acrylic acid yield is stably achieved from the start of the reaction.
摘要翻译：本发明提供了在高负载条件下通过在气相下催化氧化丙烯来生产丙烯醛和丙烯酸的情况下的启动方法的改进，启动意味着将丙烯供应速率（负载）从对规定的反应条件的非反应条件。该方法的特征在于，在反应的启动阶段，丙烯供给速率增加，直到获得规定的起始反应气体组成和起始反应气体的流量，同时调节至少一个反应温度，起始反应物气体的组成和起始反应气体的流速，以保持丙烯转化率不低于90mol％，各反应区中催化剂层的最高峰值温度不高于450° C，以及每个反应区域中的催化剂层的每个＆Dgr; T（催化剂层 - 反应温度的最大峰值温度）的总和分别不超过180℃。根据该方法，反应快速达到稳定状态（标准操作条件），从反应开始就可以稳定地获得高丙烯醛和丙烯酸的收率。

9. 发明授权

US08318978B2 Process for producing acrylic acid 有权
标题翻译：丙烯酸生产工艺
公开(公告)号：US08318978B2
公开(公告)日：2012-11-27
申请号：US12659994
申请日：2010-03-26
申请人： Michio Tanimoto , Hideo Onodera
发明人： Michio Tanimoto , Hideo Onodera
IPC分类号： C07C51/16 , C07C45/52
CPC分类号： C07C51/252 , C07C57/04
摘要： The invention offers an improvement in a process for start-up in the occasion of producing acrylic acid by catalytically oxidizing acrolein at vapor phase under high load conditions, the start-up meaning the step of increasing the acrolein supply rate (loading) from the non-reacting condition to the prescribed reaction conditions. This process is characterized in that the acrolein supply rate is increased in the start-up stage of the reaction until the prescribed composition of starting reactant gas and the flow rate of the starting reactant gas are obtained, while adjusting at least one of the reaction temperature, the composition of the starting reactant gas and the flow rate of the starting reactant gas, so as to maintain the acrolein conversion at not lower than 90 mol %, the maximum peak temperature of the catalyst layer in each reaction zone at no higher than 400° C., and the sum of each ΔT (maximum peak temperature of a catalyst layer-reaction temperature) at the catalyst layer in each of the reaction zones to be no more than 150° C., respectively. According to this process, the reaction speedily reaches the steady state (standard operating conditions) and a high acrylic acid yield is stably achieved from the start of the reaction.
摘要翻译：本发明提供了在高负载条件下通过在气相下催化氧化丙烯醛来生产丙烯酸的情况下的启动方法的改进，启动意味着提高丙烯醛供应速率（负载）反应条件达到规定的反应条件。该方法的特征在于，在反应开始阶段丙烯醛供应速率增加，直到获得规定的起始反应气体组成和起始反应气体的流量，同时调节至少一个反应温度，起始反应气体的组成和起始反应气体的流量，以使丙烯醛的转化率保持在不低于90mol％，催化剂层在每个反应区中的最大峰值温度不高于400℃ ℃，以及每个反应区域中的催化剂层的每个＆Dgr; T（催化剂层 - 反应温度的最大峰值温度）的总和分别不超过150℃。根据该方法，反应快速达到稳定状态（标准操作条件），从反应开始就稳定地得到高丙烯酸收率。

10. 发明授权

US5700752A Catalyst for production of unsaturated aldehyde and unsaturated carboxylic acid and method for production of unsaturated aldehyde and unsaturated carboxylic acid by the use of the catalyst 失效
标题翻译：用于生产不饱和醛和不饱和羧酸的催化剂以及通过使用催化剂生产不饱和醛和不饱和羧酸的方法
公开(公告)号：US5700752A
公开(公告)日：1997-12-23
申请号：US456062
申请日：1995-05-31
申请人： Ikuo Kurimoto , Tatsuya Kawajiri , Hideo Onodera , Michio Tanimoto , Yukio Aoki
发明人： Ikuo Kurimoto , Tatsuya Kawajiri , Hideo Onodera , Michio Tanimoto , Yukio Aoki
IPC分类号： B01J23/887 , B01J27/053 , B01J35/00 , C07C45/32 , C07C45/35 , C07C45/37 , C07C51/23 , C07C51/25 , B01J23/25 , B01J23/30 , B01J23/31
CPC分类号： C07C51/23 , B01J23/002 , B01J23/8876 , B01J27/053 , B01J35/0006 , C07C45/32 , C07C45/35 , C07C45/37 , C07C51/252 , B01J2523/00 , B01J35/002
摘要： A catalyst for the production of unsaturated aldehyde and unsaturated carboxylic acid by the vapor-phase catalytic oxidation of at least one compound selected from the group consisting of propylene, isobutylene, t-butanol and methyl-t-butyl ether and a method for the production of unsaturated aldehyde and unsaturated carboxylic acid by the use of this catalyst are provided. The catalyst of this invention comprises (A) a catalyst having Mo, Bi and Fe as essential components and used for the production of unsaturated aldehyde and unsaturated carboxylic acid by vapor-phase catalytic oxidation of propylene, isobutylene, t-butanol and/or methyl-t-butyl ether and (B) a solid acid having acid strength (Ho) of not more than -11.93. Since this catalyst excels in catalytic activity and service life, it allows unsaturated aldehyde and unsaturated carboxylic acid to be produced stably at a high yield for a long time.
摘要翻译：用于通过气相催化氧化至少一种选自丙烯，异丁烯，叔丁醇和甲基叔丁基醚的化合物来生产不饱和醛和不饱和羧酸的催化剂及其制备方法的不饱和醛和不饱和羧酸。本发明的催化剂包含（A）具有Mo，Bi和Fe作为必需组分的催化剂，用于通过丙烯，异丁烯，叔丁醇和/或甲基的气相催化氧化生产不饱和醛和不饱和羧酸叔丁基醚和（B）酸强度（Ho）不大于-11.93的固体酸。由于该催化剂在催化活性和使用寿命方面优异，因此可以长时间以高产率稳定地制备不饱和醛和不饱和羧酸。

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