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    • 3. 发明授权
    • Process for the fluidized bed oxidation of ethane to acetic acid
    • 将乙烷流化床氧化成乙酸的方法
    • US5300684A
    • 1994-04-05
    • US803882
    • 1991-12-09
    • Nancy C. BenkalowyczPatricia R. BlumDavid R. Wagner
    • Nancy C. BenkalowyczPatricia R. BlumDavid R. Wagner
    • B01J23/36B01J27/195C07B61/00C07C51/215C07C53/08C07C51/16
    • C07C53/08C07C51/215
    • Disclosed is a process for oxidizing ethane to acetic acid which comprises feeding ethane and a recycle gas to a fluidized bed reaction zone containing fluidized particulate solid oxidation catalyst, feeding a molecular oxygen-containing gas separately from said ethane to said reaction zone so that said molecular oxygen-containing gas first mixes with the major portion of the combustible hydrocarbon feed gases within the fluidized bed, said process including the steps of (1) cooling the gaseous effluent from the reaction zone, (2) separating most of the acetic acid in liquid form from the effluent gases, leaving a gaseous stream containing nearly all of the carbon oxides contained in said effluent, (3) purging a small portion of said gaseous stream and recycling most of said gaseous stream as part of the feed to said reaction zone,wherein said purging serves to prevent build-up of carbon oxides in the reaction zone, and said recycling serves to maintain a high proportion of carbon oxides in said reaction zone gases, thus aiding in moderating the temperature elevating effect of the highly exothermic oxidation reaction in said reaction zone.
    • 公开了一种将乙烷氧化成乙酸的方法,该方法包括将乙烷和循环气体进料到含有流化的颗粒状固体氧化催化剂的流化床反应区,将含有分子的含氧气体与所述乙烷分开供给所述反应区,使得所述分子 首先将含氧气体与流化床内的可燃烃进料气体的主要部分混合,所述方法包括以下步骤:(1)冷却来自反应区的气态流出物,(2)将大部分乙酸分离成液体 从流出气体中形成,留下含有所述流出物中所含的几乎所有碳氧化物的气流,(3)吹扫所述气流的一小部分并将大部分所述气流作为进料的一部分再循环到所述反应区, 其中所述清洗用于防止反应区中碳氧化物的累积,并且所述循环用于维持高比例的碳氧化物 在所述反应区气体中,从而有助于缓和所述反应区中高放热氧化反应的温度升高作用。
    • 7. 发明申请
    • FLUID INJECTION DEVICE
    • 流体注射装置
    • US20110009848A1
    • 2011-01-13
    • US12498867
    • 2009-07-07
    • Bryan WoodardJames D. PurdyDavid R. WagnerRichard B. SiskenSteven J. CharleboisGregory A. FranklandScott K. Philhower
    • Bryan WoodardJames D. PurdyDavid R. WagnerRichard B. SiskenSteven J. CharleboisGregory A. FranklandScott K. Philhower
    • A61M5/32
    • A61B17/3478A61B2017/00805A61M2025/0008A61M2025/0087A61M2210/1092
    • A medical device is provided. The device includes a cannula with a lumen defined therethrough and an upper portion, a right side portion, a bottom portion, and a left side portion each substantially equally spaced from their respective neighboring portion around the circumferential surface of the cannula. The cannula additionally includes a plurality of apertures disposed through the distal end portion to provide communication from the lumen and a visually perceptible indicator that is configured to allow the cannula to be positioned at an appropriate rotational position within the patient. A plurality of injection needles are disposed within the lumen and a first handle is fixed with respect to the cannula and a second handle is disposed in conjunction with the first handle and fixed to the proximal portion of each of the plurality of needles, the first handle is translatable with respect to the second handle to translate the plurality of needles from a first position where the distal portions of each of the plurality of needles are disposed within the lumen of the cannula, and a second position where the distal portion of each of the plurality of needles extends out of the lumen through their respective aperture.
    • 提供医疗设备。 该装置包括具有限定穿过其中的内腔的套管,以及上部,右侧部分,底部部分和左侧部分,所述上部部分,右侧部分,底部部分和左侧部分各自与其相应的相邻部分围绕套管的周面。 套管还包括穿过远端部分设置的多个孔,以提供来自内腔的通信和视觉上可察觉的指示器,其被配置为允许套管定位在患者体内的适当旋转位置。 多个注射针设置在内腔内,并且第一手柄相对于套管固定,第二手柄与第一手柄结合设置并固定到多个针中的每一个的近端部分,第一手柄 可相对于第二手柄平移,以将多个针从多个针的每个的远端部分设置在套管的内腔内的第一位置平移,以及第二位置,其中每个的远端部分 多个针通过其相应的孔从管腔延伸出来。
    • 8. 发明授权
    • Extraction process for recovery of acrylic acid
    • 萃取法回收丙烯酸
    • US06737546B2
    • 2004-05-18
    • US10008641
    • 2001-11-13
    • David R. WagnerSteve J. Miko
    • David R. WagnerSteve J. Miko
    • C07C5142
    • C07C51/44C07C51/48C07C57/04
    • Economical processes are disclosed for recovery and refining of at least acrylic acid from a gaseous mixture such as is obtainable by gas-phase catalytic oxidation of propylene. Processes of the invention include quenching the gaseous mixture with an aqueous quench liquid to obtain an aqueous solution comprising the acid values; contacting the aqueous solution with an immiscible extraction solvent; and an integrated sequence of distillations and phase separations to recover for recycle organic components of the extraction solvent, and obtain valuable acrylic acid and acetic acid products. Advantageously, the immiscible extraction solvent is substantially free of aromatic compounds such as benzene and toluene.
    • 公开的经济方法用于从诸如可通过丙烯的气相催化氧化获得的气体混合物中回收和精炼至少丙烯酸。 本发明的方法包括用水性骤冷液淬火气体混合物以获得包含酸值的水溶液; 使所述水溶液与不混溶的萃取溶剂接触; 以及蒸馏和相分离的一体化顺序,以回收提取溶剂的循环有机组分,并获得有价值的丙烯酸和乙酸产物。 有利地,不混溶的萃取溶剂基本上不含芳族化合物如苯和甲苯。