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    • 1. 发明授权
    • Chromoum heat-resistant steel excellent in toughness and having high
cracking resistance and high creep strength in welded joint
    • 耐腐蚀钢,韧性好,耐焊接性高,耐冲击强度高
    • US5116571A
    • 1992-05-26
    • US730013
    • 1991-07-12
    • Nakatsugu AbeHaruo SuzukiHiroaki TsukamotoSeishi TsuyamaMoriyasu Nagae
    • Nakatsugu AbeHaruo SuzukiHiroaki TsukamotoSeishi TsuyamaMoriyasu Nagae
    • C22C38/00C22C38/24C22C38/26C22C38/54
    • C22C38/24C22C38/26
    • A chromium heat-resistant steel excellent in toughness and having a high cracking resistance and a high creep strength when said steel is utilized to form a welded joint, said steel consisting essentially of:______________________________________ carbon: from 0.04 to 0.09 wt. %, silicon: from 0.01 to 0.50 wt. %, manganese: from 0.25 to 1.50 wt. %, chromium: from 7.0 to 9.2 wt. %, molybdenum: from 0.50 to 1.50 wt. %, soluble aluminum: from 0.005 to 0.060 wt. %, nitrogen: from 0.001 to 0.060 wt. %, ______________________________________ where, the total amount of nitrogen and carbon being up to 0.13 wt. %, at least one element selected from the group consisting of:______________________________________ vanadium: from 0.01 to 0.30 wt. %, and niobium: from 0.005 to 0.200 wt. %, ______________________________________ where, the total amount of vanadium and 1.5 times niobium being up to 0.30 wt. %, and the balance being iron and incidental impurities; and the amount of ferrite as represented by the ferrite number (.delta..sub.F) in the above-mentioned chromium heat-resistant steel being -5 or lower, as calculated by the following formula:.delta..sub.F=-104-555 (C+6/7N)+32.9Si-49.5Mn+12.1Cr+39.1Mo+46.1V+83.5Nb.
    • 当所述钢用于形成焊接接头时,韧性优异且具有高抗裂性和高蠕变强度的铬耐热钢,所述钢主要由以下组成: - 碳:0.04〜0.09重量% %, - 硅氧烷:0.01〜0.50wt。 %, - 锰:0.25至1.50wt。 %,-chromium:7.0〜9.2wt。 %, - 钼:0.50〜1.50wt。 %,可溶性铝:0.005〜0.060重量% %, - 氮:0.001〜0.060重量% %, - 其中,氮和碳的总量高达0.13wt。 %,选自以下的至少一种元素: - 钒:0.01〜0.30重量% %, - 和 - 铌:0.005〜0.200wt。 %, - 其中钒和1.5倍铌的总量高达0.30重量%。 %,余量为铁和杂质; 和由上述铬耐热钢中的铁素体数(ΔF)表示的铁素体的量为-5以下,通过下式计算:ΔF= -104-555(C + 6 / 7N)+ 32.9Si-49.5Mn + 12.1Cr + 39.1Mo + 46.1V + 83.5Nb。
    • 7. 发明授权
    • Girth-welding process for a pipe and a high cellulose type coated
electrode
    • 管和高纤维素涂层电极的环形焊接工艺
    • US5272305A
    • 1993-12-21
    • US938444
    • 1992-08-28
    • Shigeru EndoMoriyasu NagaeMotokiyo ItohTakeshi SuginoShouzou Naruse
    • Shigeru EndoMoriyasu NagaeMotokiyo ItohTakeshi SuginoShouzou Naruse
    • B23K35/30B23K35/365B23K35/22
    • B23K35/3053B23K35/365
    • Chemical compositions of a base metal and a high cellulose type welding electrode are regulated within predetermined ranges, so that the chemical composition of the weld metal obtained from the welding can be regulated within a predetermined range. Particularly, with respect to the weld metal, the Mo content (Mo)1 in the weld metal and the Mo content (Mo)2 in the base metal are regulated such that the difference between the both contents .DELTA.Mo (=(Mo)1-(Mo)2) is 0.03% or more, and PCM is 0.30% or less, where PCM is defined as follows: PCM=(C)+(Si)/30+(Mn)/20+(Cu)/20+(Ni)/60+(Cr)/20+(Mo)/15+(V)/10+5(B). Here, (M) denotes a content (weight %) of a component M in the weld metal.On the other hand, a coating flux of the high cellulose type coated electrode contains relative to the total amount of the coating flux, 0.1 to 7.0% of MgO, 7 to 25% of iron oxides (in FeO equivalent), 8 to 19% of TiO.sub.2, 10 to 30% of SiO.sub.2 and 5 to 27% of Mn, and a core wire and/or the coating flux includes 0.06 to 1.10% of Mo relative to the total amount of the welding electrode. A ratio of the weight of the coating flux to the weight of the welding electrode being 0.10 to 0.19. By this, preferential corrosion resistance, toughness and crack resistance can be improved in the weld metal of a girth weld zone of a pipe which might be exposed in a corrosion environment containing CO.sub.2.
    • 贱金属和高纤维素型焊接电极的化学组成被调节在预定范围内,从而可以将从焊接获得的焊接金属的化学组成调节在预定范围内。 特别地,对于焊接金属,焊接金属中的Mo含量(Mo)1和母材中的Mo含量(Mo)2调节为使得两种含量之间的差ΔTA(Mo(=(Mo)1 - (Mo)2)为0.03%以上,PCM为0.30%以下,PCM定义如下:PCM =(C)+(Si)/ 30 +(Mn)/ 20 +(Cu)/ 20 +(Ni)/ 60 +(Cr)/ 20 +(Mo)/ 15 +(V)/ 10 + 5(B)。 这里,(M)表示焊接金属中的成分M的含量(重量%)。 另一方面,高纤维素型涂布电极的涂层焊剂相对于涂层焊剂的总量,MgO的0.1〜7.0%,氧化铁的7〜25%(FeO当量),8〜19质量% 的TiO 2,10〜30%的SiO 2和5〜27%的Mn,并且芯线和/或涂层焊剂包含相对于焊接电极总量的0.06〜1.10%的Mo。 涂层焊剂的重量与焊接电极的重量的比率为0.10〜0.19。 由此,可以在可能暴露在含有CO 2的腐蚀环境中的管道的环形焊缝区域的焊接金属中改善耐腐蚀性,韧性和抗裂性。