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1. 发明授权

US4231899A Method of producing a steam stable aluminosilicate zeolite catalyst 失效
标题翻译：制备蒸汽稳定的硅铝酸盐沸石催化剂的方法
公开(公告)号：US4231899A
公开(公告)日：1980-11-04
申请号：US5279
申请日：1979-01-22
申请人： Nai Y. Chen , Joseph N. Miale , William J. Reagan
发明人： Nai Y. Chen , Joseph N. Miale , William J. Reagan
IPC分类号： B01J29/40 , B01J29/46 , B01J29/65 , B01J29/70 , B01J37/08 , B01J29/04 , B01J29/28
CPC分类号： B01J29/7034 , B01J29/40 , B01J29/46 , B01J29/65 , B01J37/084 , B01J2229/14 , B01J2229/24 , B01J2229/34 , B01J2229/36 , B01J2229/40
摘要： Steam stable aluminosilicate zeolite catalysts are prepared by calcining said zeolites at an elevated temperature below about 1100.degree. F. in a closed system having a limited amount of oxygen wherein said zeolite contains organic cations and/or is in intimate contact with a charring agent thereby converting a portion of said organic cations or charring agent to a carbonaceous deposit within the pores of said zeolite in an amount from about 1.5-15 wt. % based on the total weight of the catalyst. Such catalysts are highly useful in the conversion of oxygenates, e.g., methanol to hydrocarbon products.
摘要翻译：蒸汽稳定的硅铝酸盐沸石催化剂是通过在低于约1100°F的高温下煅烧所述沸石而制备的，所述沸石具有有限量的氧气，其中所述沸石含有有机阳离子和/或与炭化剂紧密接触从而转化所述有机阳离子或炭化剂的一部分以约1.5-15重量％的量存在于所述沸石的孔内的碳质沉积物中。％，基于催化剂的总重量。这种催化剂在将含氧化合物例如甲醇转化为烃产物中非常有用。

2. 发明授权

US4197214A Crystalline zeolite catalysts of chemical reactions 失效
标题翻译：结晶沸石催化剂的化学反应
公开(公告)号：US4197214A
公开(公告)日：1980-04-08
申请号：US949703
申请日：1978-10-10
申请人： Nai Y. Chen , William J. Reagan , Vern W. Weekman, Jr.
发明人： Nai Y. Chen , William J. Reagan , Vern W. Weekman, Jr.
IPC分类号： C10G11/00 , B01J29/06 , B01J29/90 , B01J38/12 , C01B39/20 , C01B39/26 , C01B39/30 , C01B39/36 , C01B39/38 , C01B39/42 , C01B39/44 , C10G2/00 , C10G3/00 , B01J29/38 , C07C15/00 , C10G35/06
CPC分类号： B01J29/90 , C10G3/49 , C10G3/62 , C10G2300/4006 , C10G2300/807 , C10G2400/02 , Y02P30/20
摘要： Crystalline zeolite catalysts are stabilized against reducing and moisture containing atmospheres by providing and maintaining substantial metal cationic sites in the zeolite during use in chemical reactions encountering reducing and/or moisture rich atmospheres at high temperature.
摘要翻译：结晶沸石催化剂通过在使用期间在沸石中提供和维持大量的金属阳离子位点而稳定，以减少和含水气氛。在化学反应中遇到在高温下还原和/或富含水分的气氛。

3. 发明授权

US4101595A Conversion of ethyl benzene to para xylene 失效
标题翻译：乙苯转化成对二甲苯
公开(公告)号：US4101595A
公开(公告)日：1978-07-18
申请号：US793017
申请日：1977-05-02
申请人： Nai Y. Chen , William J. Reagan
发明人： Nai Y. Chen , William J. Reagan
IPC分类号： B01J29/00 , B01J29/44 , C07B61/00 , C07C1/00 , C07C5/13 , C07C5/27 , C07C7/00 , C07C7/13 , C07C15/02 , C07C15/08 , C07C67/00 , C07C5/24 , C07C3/62 , C07C7/01
CPC分类号： C07C15/08 , B01J29/44 , C07C5/2791 , C07C7/005 , Y02P20/52
摘要： Monoalkyl benzene having a side chain of at least two carbon atoms is converted to dialkyl benzene having side chains of shorter length than the charge and containing a proportion of para dialkyl benzene in excess of the thermodynamic equilibrium value by reaction over a dual function catalyst comprising a noble metal from Group VIII of the Periodic Table and a crystalline aluminosilicate zeolite of high silica/alumina ratio above 12, a constraint index of 1 to 12, which aluminosilicate is in a state to restrict diffusion of ortho xylene.
摘要翻译：具有至少两个碳原子的侧链的单烷基苯被转化为具有比电荷短的侧链的二烷基苯，并且通过在包含一种或多种的双官能催化剂的反应中反应，含有一定比例的对二烷基苯超过热力学平衡值元素周期表第VIII族的贵金属和12以上二氧化硅/氧化铝比高的结晶硅铝酸盐沸石，其约束指数为1〜12，铝硅酸盐处于限制邻二甲苯扩散的状态。

4. 发明授权

US4278565A Hydrocarbon manufacture from alcohols 失效
标题翻译：醇制烃
公开(公告)号：US4278565A
公开(公告)日：1981-07-14
申请号：US152878
申请日：1980-05-23
申请人： Nai Y. Chen , William J. Reagan
发明人： Nai Y. Chen , William J. Reagan
IPC分类号： B01J29/40 , B01J29/44 , B01J29/72 , B01J29/74 , C10G3/00 , B01J29/28
CPC分类号： B01J29/44 , B01J29/068 , B01J29/405 , B01J29/67 , B01J29/7469 , C10G3/47 , C10G3/49 , B01J2229/26 , B01J2229/42 , Y02P30/20
摘要： A catalytic process is provided for converting a feed containing a C.sub.1 -C.sub.4 monohydric alcohol by contact of said alcohol, under conversion conditions, with a catalyst comprising a crystalline aluminosilicate zeolite having a crystal size of at least about 1 micron, a silica to alumina ratio of at least about 12 and a constraint index, as hereinafter defined, within the approximate range of 1 to 12. The zeolite contains a Group 2B and a Group 8 metal or metal compound plus magnesium, either per se or in compound form.
摘要翻译：提供了一种催化方法，用于在转化条件下通过所述醇的接触将含有C 1 -C 4一元醇的进料与包含结晶尺寸至少约1微米的结晶硅铝酸盐沸石，二氧化硅与氧化铝比至少约12，约束指数（如下文所定义）在大约1至12的范围内。该沸石本身或以化合物形式含有第2B族和第8族金属或金属化合物加镁。

5. 发明授权

US4148835A Hydrocarbon manufacture from alcohols 失效
标题翻译：醇制烃
公开(公告)号：US4148835A
公开(公告)日：1979-04-10
申请号：US896267
申请日：1978-04-14
申请人： Nai Y. Chen , William J. Reagan
发明人： Nai Y. Chen , William J. Reagan
IPC分类号： B01J29/40 , C07C1/20 , C07C9/04 , C07C11/02
CPC分类号： C07C1/20 , B01J29/405 , C07C2529/44 , Y02P30/42
摘要： A catalytic process is provided for converting a feed containing a C.sub.1 -C.sub.4 monohydric alcohol by contact of said alcohol, under conversion conditions, with a catalyst comprising a crystalline aluminosilicate zeolite having a crystal size of at least about 1 micron, a silica to alumina ratio of at least about 12 and a constraint index, as hereinafter defined, within the approximate range of 1 to 12. The zeolite contains a Group 2B and a Group 8 metal or metal compound plus magnesium, either per se or in compound form.
摘要翻译：提供了一种催化方法，用于在转化条件下通过所述醇的接触将含有C 1 -C 4一元醇的进料与包含结晶尺寸至少约1微米的结晶硅铝酸盐沸石，二氧化硅与氧化铝比至少约12，约束指数（如下文所定义）在大约1至12的范围内。该沸石本身或以化合物形式含有第2B族和第8族金属或金属化合物加镁。

6. 发明授权

US4049578A Hydrocarbon conversion catalyst 失效
标题翻译：烃转化催化剂
公开(公告)号：US4049578A
公开(公告)日：1977-09-20
申请号：US695230
申请日：1976-06-11
申请人： William J. Reagan , Nai Y. Chen
发明人： William J. Reagan , Nai Y. Chen
IPC分类号： B01J23/46 , B01J23/56 , B01J23/66 , B01J23/89 , B01J37/02 , C10G35/09 , B01J21/04 , B01J23/42 , B01J23/72
CPC分类号： B01J23/8926 , B01J23/468 , B01J23/56 , B01J23/66 , B01J37/0203 , C10G35/09
摘要： A metallic reforming catalyst, consisting of platinum and iridium or platinum, iridium and copper on a porous carrier provides excellent conversion of naphtha to C.sub.5.sup.+ product. A method of incorporating the metals or metal compounds on the carrier and preparing the finished catalyst using dimethyl sulfoxide is a novel procedure and provides unexpected catalytic properties. Novel reforming operations using these catalysts under moderate or severe conditions do not drastically alter the product yield.
摘要翻译：在多孔载体上由铂和铱或铂，铱和铜组成的金属重整催化剂提供石脑油到C5 +产物的极好的转化。将金属或金属化合物并入载体上并使用二甲基亚砜制备最终催化剂的方法是一种新的方法，并提供了意想不到的催化性能。在中等或严重条件下使用这些催化剂的新型重整操作不会显着改变产物产率。

7. 发明授权

US3981825A Hydrocarbon conversion catalyst 失效
标题翻译：烃转化催化剂
公开(公告)号：US3981825A
公开(公告)日：1976-09-21
申请号：US477240
申请日：1974-06-07
申请人： William J. Reagan , Nai Y. Chen
发明人： William J. Reagan , Nai Y. Chen
IPC分类号： B01J23/46 , B01J23/56 , B01J23/66 , B01J23/89 , B01J37/02 , C10G35/09 , B01J21/04 , B01J21/12 , B01J23/42 , B01J23/52
CPC分类号： C10G35/09 , B01J23/468 , B01J23/56 , B01J23/66 , B01J23/89 , B01J37/0203
摘要： A metallic reforming catalyst, preferably consisting of platinum and iridium or compounds thereof, with or without a third metal component of either Groups IB, IIB, IIIA, IVA, VB, VIB or VIIB on a porous carrier provides excellent conversion of naphtha to C.sub.5 .sup.+ product. A method of incorporating the metals or metal compounds on the carrier and preparing the finished catalyst using dimethyl sulfoxide is a novel procedure and provides unexpected catalytic properties. Novel reforming operations using these catalysts under moderate or severe conditions do not drastically alter the product yield.
摘要翻译：金属重整催化剂，优选由铂和铱或其化合物组成，具有或不具有第IB，IIB，IIIA，IVA，VB，VIB或VIIB族的第三金属组分在多孔载体上提供了优异的石脑油转化为C5' +>产品。将金属或金属化合物并入载体上并使用二甲基亚砜制备最终催化剂的方法是一种新的方法，并提供了意想不到的催化性能。在中等或严重条件下使用这些催化剂的新型重整操作不会显着改变产物产率。

8. 发明授权

US4971766A Apparatus for FCC process with catalyst separation 失效
标题翻译： FCC催化分离装置
公开(公告)号：US4971766A
公开(公告)日：1990-11-20
申请号：US437064
申请日：1989-11-16
申请人： Nai Y. Chen , Billy K. Huh , Thomas E. Degnan
发明人： Nai Y. Chen , Billy K. Huh , Thomas E. Degnan
IPC分类号： C10G11/18
CPC分类号： C10G11/18
摘要： An FCC or fluidized catalytic cracking process and apparatus for converting heavy metals laden crudes is disclosed. The heavy feed, conventional catalyst and an additive or vanadium getter contact the feed in a riser reactor. The additive is segregated from conventional FCC catalyst upstream of the conventional FCC regenerator. An elutriating, upflow riser reactor may be used with a coarse, rapidly settling getter. A fine, slowly settling getter may be used, with getter segregation achieved by using an elutriating cyclone on the riser outlet, an elutriating catalyst stripper, a sieve, or the like. The spent getter may be used once through, regenerated in a separate getter regenerator, or used as a source of fuel. Alumina and sponge coke are preferred getters.
摘要翻译：公开了一种FCC或流化催化裂化方法和用于转化重金属负载原油的装置。重料，常规催化剂和添加剂或钒吸附剂在提升管反应器中接触进料。该添加剂与常规FCC再生器上游的常规FCC催化剂分离。淘汰式上升式提升管式反应器可与粗，快速沉降的吸气剂一起使用。可以使用细的缓慢沉降的吸气剂，通过在提升管出口，淘洗催化剂汽提器，筛子等上使用淘洗旋风来实现吸气剂分离。废吸气剂可以一次使用，在单独的吸气剂再生器中再生，或用作燃料来源。氧化铝和海绵焦炭是优选的吸气剂。

9. 发明授权

US4877581A Catalyst for dewaxing hydrocarbon feedstock 失效
标题翻译：用于脱蜡烃原料的催化剂
公开(公告)号：US4877581A
公开(公告)日：1989-10-31
申请号：US239257
申请日：1988-09-01
申请人： Nai Y. Chen , Dennis E. Walsh
发明人： Nai Y. Chen , Dennis E. Walsh
IPC分类号： B01J29/44 , B01J29/74 , C10G45/64
CPC分类号： C10G45/64 , B01J29/44
摘要： A paraffin conversion process for hydroisomerizing a nitrogen and wax-containing hydrocarbon feedstock comprising contacting the feedstock with a catalyst including a ZSM-11 zeolite characterized by an alpha value from about 10 to 50, in combination with a Group VIII metal hydrogenation-dehydrogenation component of platinum or palladium at a temperature of about 400.degree. F. to about 850.degree. F. and at a pressure of from about 200 to about 2000 psig.
摘要翻译：一种用于使含氮和含蜡的烃原料加氢异构化的链烷烃转化方法，包括使原料与包含Z值为约10至50的α值的ZSM-11沸石的催化剂结合，与第VIII族金属加氢脱氢组分铂或钯，温度为约400°F至约850°F，压力为约200至约2000psig。

10. 发明授权

US4827068A Aromatization with catalyst comprising noble-metal containing titanosilicate having the structure of zeolite beta 失效
标题翻译：用含有β沸石结构的含有钛酸硅酸的贵金属的催化剂进行芳构化
公开(公告)号：US4827068A
公开(公告)日：1989-05-02
申请号：US138974
申请日：1987-12-29
申请人： Nai Y. Chen , Sharon B. McCullen
发明人： Nai Y. Chen , Sharon B. McCullen
IPC分类号： B01J29/89 , C07C1/20 , C07C5/41 , C07C11/20 , C07C2/52
CPC分类号： C07C5/417 , B01J29/89 , C07C1/20 , C07C2529/89 , Y02P30/42
摘要： Aromatization of non-aromatics is carried out by contacting with a titanosilicate having the structure of zeolite beta which contains noble metal.
摘要翻译：通过与含有贵金属的β沸石结构的钛硅酸盐接触来进行非芳族化合物的芳构化。

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