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1. 发明授权

US3838096A Glass fiber-reinforced plastics and process for producing the same 失效
标题翻译：玻璃纤维增强塑料及其制造方法
公开(公告)号：US3838096A
公开(公告)日：1974-09-24
申请号：US20512971
申请日：1971-12-06
申请人： NITTO BOSEKI CO LTD
发明人： NAGASAWA T , HASHIMOTO R , TAMAKI K , KUROIWA K , NARITA K
IPC分类号： C03C25/32 , C08C19/25 , C08L67/06 , C08G51/04
CPC分类号： C08C19/25 , C03C25/323 , C08K9/06 , C08L15/00 , C08L67/06 , C08L2666/08
摘要： A GLSS FIBER-REINFORCED PLASTIC WHICH COMPRISES A GLASS FIBER, AN UNSATURATED POLYESTER RESIN AND A NOVEL REACTION PRODUCT OF A POLYBUTADIENE HAVING 1,3-STRUCTURE CONTENT OF ABOUT 50 MOLE PERCENT TO SUBSTANTIALLU 100 MOLE PERCENT WITH A MERCAPTO-ORGANOSILANE REPRESENTED BY THE GENERAL FORMULA,

HS-(CH2)N-SI(-R1)(-R2)-R3

WHEREIN R1, R2, AND R3, WHICH MAY THE SAME OR DIFFERENT, ARE INDIVIDUALLY A HYDROLYZABLE GROUP CAPABLE OF REACTING WITH A GLASS FIBER, SELECTED, FOR EXAMPLE, FROM THE ROUP CONSISTING OF ALKOXY GROUPS, ACETOXY GROUP AND HALOGENS; AND N IS AN INTEGER OF 1 TO 4, SAID REACTION PRODUCT BEING PRESENT AT THE INTERFACE BETWEEN AID GLASS FIBER AND SAID RESIN, AND SAID RESIN BEING CURED. IN THIS PLASTIC, THE ADHESION BETWEEN THE GLASS FIBER AND THE UNSATURATED POLYESTER RESIN IS GREATLY IMPROVED, BY THE ABOVE-MENTIONED REACTION PRODUCT PRESENT AT THE INTERFACE BETWEEN SAID TWO MATERIALS.

2. 发明授权

US3789049A Glass fiber-reinforced epoxy resin or polyester resin composition and method for manufacturing same 失效
标题翻译：玻璃纤维增强环氧树脂或聚酯树脂组合物及其制造方法
公开(公告)号：US3789049A
公开(公告)日：1974-01-29
申请号：US3789049D
申请日：1971-12-20
申请人： NITTO BOSEKI CO LTD
发明人： NARITA K , NAGASAWA T , KUROIWA K
IPC分类号： C03C25/36 , C08C19/40 , C08G59/34 , C08G59/40 , C08J5/08 , C08L63/00 , C08G51/10
CPC分类号： C08G59/027 , C03C25/36 , C08C19/40 , C08G59/4085 , C08J5/08 , C08J2363/00 , C08J2367/06 , C08L63/00
摘要： A GLASS FIBER-REINFORCED, EPOXY RESIN OR UNSATURATED POLYESTER RESIN COMPOSITION COMPRISING GLASS FIBER, AN EPOXY RESIN OR AN UNSATURATED POLYESTER RESIN, AND, AT THE INTERFACE OF SAID GLASS FIBER AND RESIN, A REACTION PRODUCT OF A PARTIALLY EPOXIDIED POLYBUTADIENE HAVING AT LEAST ABOUT 50 MOLE PERCENT OF 1,2-STRUCTURE WITH A MERCAPTOORGANOSILANE OF THE FORMULA,

HS-(CH2)N-SI(-R1)(-R2)-R3

WHEREIN R1, R2 AND R3, WHICH MAY BE THE SAMD OR DIFFERENT, REPRESENT HYDROLYZABLE RADICALS CAPABLE OF REACTING WITH GLASS FIBER, FOR EXAMPLE, ALKOXY GROUPS HAVING 1 TO 3 CARBON ATOMS, ACETOXY GROUPS OR HALOGEN ATOMS, AND N IS AN INTEGER OF FROM 1 TO 4. BY THE PRESENCE OF SAID REACTION PRODUCT AT THE INTERFACE, THE ADHESION BETWEEN THE GLASS FIBER AND THE RESIN IS IMPROVED AND THERE IS OBTAINED A REINFORCED PLASTIC HAVING A HIGH STRENGTH AND EXCELLENT TRANSPARENCY.

3. 发明授权

US3852290A Thiocarbonates 失效
标题翻译：三氯甲烷
公开(公告)号：US3852290A
公开(公告)日：1974-12-03
申请号：US28741072
申请日：1972-09-08
申请人： NITTO BOSEKI CO LTD
发明人： NARITA K , NAGASAWA T , KUROIWA K
IPC分类号： C07D207/16 , C07D209/20 , C07D239/38 , C07D51/36
CPC分类号： C07D239/38 , C07D207/16 , C07D209/20 , Y02P20/582
摘要： Thiolcarbonates represented by the formula,

The thiolcarbonates can be easily produced by reacting an alkali metal salt of 2-mercaptopyrimidine with phosgene, and reacting the resulting thiolchloroformate with an alcohol (R3OH), or by reacting a 2-mercaptopyrimidine with a halo-carbonic acid ester.

WHEREIN R1 and R2 are individually a hydrogen atom or a methyl group, and R3 is a straight chain or branched chain saturated or unsaturated alkyl group having 1 to 5 carbon atoms or is a benzyl or benzhydryl group which may be nuclear substituted, are quite useful for protecting the amino or imino groups of amines, hydrazines, amino acids and peptides with groups of the formula

D R A W I N G
摘要翻译：由式WHEREIN R1和R2表示的硫醇碳酸酯分别为氢原子或甲基，R3为具有1至5个碳原子的直链或支链饱和或不饱和烷基，或可为苄基或二苯甲基，核取代对于保护具有下式基团的胺，肼，氨基酸和肽的氨基或亚氨基非常有用。硫醇碳酸酯可以容易地通过使2-巯基嘧啶的碱金属盐与光气反应，并使所得的硫醇氯甲酸酯与醇（R3OH）反应，或通过使2-巯基嘧啶与卤代碳酸酯反应。

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