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    • 10. 发明申请
    • ELECTROCHEMICAL CELL STACK
    • US20190131648A1
    • 2019-05-02
    • US16210435
    • 2018-12-05
    • NGK INSULATORS, LTD.
    • Makoto OHMORI
    • H01M8/1253H01M8/02H01M8/1213C04B35/48B32B18/00
    • An electrochemical cell stack according to a second aspect of the present invention includes an electrochemical cell and a manifold supporting a base end of the electrochemical cell. The electrochemical cell includes an electric conductive support substrate and a power generation unit disposed on the support substrate. Additionally, a gas flow path is provided in the support substrate. The power generation unit includes an anode disposed on a first main surface of the support substrate, a cathode, and a solid electrolyte layer disposed between the anode and the cathode. Additionally, the solid electrolyte layer contains a zirconia-based material as a main component thereof. The solid electrolyte layer includes a base end portion positioned on a side of the base end and a separated portion positioned separated from the base end. The base end portion includes a first area covering within 3 μm from an anode side surface, and a second area provided on the first area. An intensity ratio of tetragonal zirconia to cubic zirconia in a Raman spectrum in the first area is greater than an intensity ratio of tetragonal zirconia to cubic zirconia in the Raman spectrum in the second area.