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1. 发明申请

US20080299379A1 COMPOSITE MATERIAL AND METHOD OF MAKING THE COMPOSITE MATERIAL 有权
标题翻译：复合材料及复合材料的制备方法
公开(公告)号：US20080299379A1
公开(公告)日：2008-12-04
申请号：US12129828
申请日：2008-05-30
申请人： Myron J. Maurer , Gavin D. Vogel , Byoung-Ho Choi , Warren H. Griffin , Kalyan Sehanobish
发明人： Myron J. Maurer , Gavin D. Vogel , Byoung-Ho Choi , Warren H. Griffin , Kalyan Sehanobish
IPC分类号： B32B3/10
CPC分类号： B60R21/04 , B29C44/352 , Y10T428/249953 , Y10T428/249976 , Y10T428/249977
摘要： An improved energy absorbing member comprising, an thermoplastic cellular polymer in contact with a structural element such as a metal guard rail or automotive door, wherein the cellular polymer has an average cell size of at least about 0.75 mm and at least one of CE/CT, CV/CT and CH/CT is about 0.25 to about 0.4 said one of CE/CT, CV/CT and CH/CT having a compressive efficiency of at least 70% at a 60% strain, CE, CV and CH being the compressive strength of the cellular polymer in each of three orthogonal directions E, V and H where one of these directions is the direction of maximum compressive strength in the foam and CT equals the sum of CE, CV and CH.
摘要翻译：一种改进的能量吸收构件，包括与诸如金属护栏或汽车门的结构元件接触的热塑性多孔聚合物，其中所述多孔聚合物具有至少约0.75mm的平均泡孔尺寸和CE / CT中的至少一种，在60％应变下，CV / CT和CH / CT约为0.25至约0.4，所述CE / CT，CV / CT和CH / CT之一具有至少70％的压缩效率，CE，CV和CH为在三个正交方向E，V和H中的每个方向上的多孔聚合物的抗压强度，其中这些方向之一是泡沫中的最大抗压强度的方向和CT等于CE，CV和CH的总和。

2. 发明授权

US07931963B2 Composite material and method of making the composite material 有权
标题翻译：复合材料和复合材料的制备方法
公开(公告)号：US07931963B2
公开(公告)日：2011-04-26
申请号：US12129828
申请日：2008-05-30
申请人： Myron J. Maurer , Gavin D. Vogel , Byoung-Ho Choi , Warren H. Griffin , Kalyan Sehanobish
发明人： Myron J. Maurer , Gavin D. Vogel , Byoung-Ho Choi , Warren H. Griffin , Kalyan Sehanobish
IPC分类号： B32B3/26
CPC分类号： B60R21/04 , B29C44/352 , Y10T428/249953 , Y10T428/249976 , Y10T428/249977
摘要： An improved energy absorbing member comprising, an thermoplastic cellular polymer in contact with a structural element such as a metal guard rail or automotive door, wherein the cellular polymer has an average cell size of at least about 0.75 mm and at least one of CE/CT, CV/CT and CH/CT is about 0.25 to about 0.4 said one of CE/CT, CV/CT and CH/CT having a compressive efficiency of at least 70% at a 60% strain, CE, CV and CH being the compressive strength of the cellular polymer in each of three orthogonal directions E, V and H where one of these directions is the direction of maximum compressive strength in the foam and CT equals the sum of CE, CV and CH.
摘要翻译：一种改进的能量吸收构件，包括与诸如金属护栏或汽车门的结构元件接触的热塑性多孔聚合物，其中所述多孔聚合物具有至少约0.75mm的平均泡孔尺寸和CE / CT中的至少一种，在60％应变下，CV / CT和CH / CT约为0.25至约0.4，所述CE / CT，CV / CT和CH / CT之一具有至少70％的压缩效率，CE，CV和CH为在三个正交方向E，V和H中的每个方向上的多孔聚合物的抗压强度，其中这些方向之一是泡沫中的最大抗压强度的方向和CT等于CE，CV和CH的总和。

3. 发明申请

US20100087555A1 QUALITY POLYMER FOAM FROM FLUORINATED ALKENE BLOWING AGENTS 有权
标题翻译：来自氟化铝沸腾剂的质量聚合物泡沫
公开(公告)号：US20100087555A1
公开(公告)日：2010-04-08
申请号：US12527131
申请日：2008-03-10
申请人： Van-chau Vo , Richard T. Fox , Warren H. Griffin
发明人： Van-chau Vo , Richard T. Fox , Warren H. Griffin
IPC分类号： C08J9/16 , C08J9/14
CPC分类号： C08J9/127 , B29C44/54 , C08J9/146 , C08J9/149 , C08J9/16 , C08J2201/03 , C08J2203/06 , C08J2203/10 , C08J2203/12 , C08J2203/14 , C08J2203/142 , C08J2203/162 , C08J2325/06
摘要： Alkenyl aromatic polymer foam comprising a polymer matrix containing one or more polymer and defining a plurality of cells having an average cell size wherein: (a) the alkenyl aromatic polymer foam has: —(i) an average cell size that is in a range of 0.02 and 5 millimeters; —(ii) a density of 64 kilograms per cubic meter or less; —(iii) an open cell content less than 30 percent; and—(iv) a cell size variation of 30% or less; and wherein the foam further comprises one or more fluorinated alkene blowing agent at a concentration of 0.03 moles or more and 0.3 moles or less per 100 grams of polymer foam.
摘要翻译：烯烃芳族聚合物泡沫体，其包含含有一种或多种聚合物并且限定多个具有平均泡孔尺寸的泡孔的聚合物基质，其中：（a）链烯基芳族聚合物泡沫体具有：（i）平均泡孔尺寸在 0.02和5毫米; - （ii）每立方米或以下的密度为64公斤; - （iii）开放细胞含量低于30％; 和（iv）30％以下的细胞大小变化; 并且其中所述泡沫体还包含一种或多种浓度为0.03摩尔以上且0.3摩尔或更少每100克聚合物泡沫的氟化烯烃发泡剂。

4. 发明授权

US06476080B2 Blowing agent compositions containing hydrofluorocarbons and a low-boiling alcohol and/or low-boiling carbonyl compound 有权
标题翻译：含有氢氟烃和低沸点醇和/或低沸点羰基化合物的发泡剂组合物
公开(公告)号：US06476080B2
公开(公告)日：2002-11-05
申请号：US09999277
申请日：2001-11-29
申请人： John D. Duffy , Warren H. Griffin
发明人： John D. Duffy , Warren H. Griffin
IPC分类号： C08J914
CPC分类号： C08J9/149 , C08J9/127 , C08J2203/06 , C08J2203/12 , C08J2203/14 , C08J2203/142
摘要： The present invention relates to blowing agent compositions that contain at least one hydrofluorocarbon having a boiling point of 30° C. or higher and lower than about 120° C., at least one hydrofluorocarbon having a boiling point lower than 30° C., and at least one component selected from low-boiling alcohols and low-boiling carbonyl compounds. The present invention also relates to processes for preparing polymeric foam using such blowing agent compositions, as well as polymeric foams and foamable polymer compositions containing such blowing agent compositions.
摘要翻译：本发明涉及含有至少一种沸点为30℃以上且低于约120℃的氢氟烃的至少一种沸点低于30℃的氢氟烃的发泡剂组合物，以及至少一种选自低沸点醇和低沸点羰基化合物的组分。本发明还涉及使用这种发泡剂组合物以及包含这种发泡剂组合物的聚合物泡沫和可发泡聚合物组合物制备聚合物泡沫体的方法。

5. 发明授权

US5688832A Low molecular weight alkenyl aromatic polymer foam 失效
标题翻译：低分子量链烯基芳族聚合物泡沫
公开(公告)号：US5688832A
公开(公告)日：1997-11-18
申请号：US612943
申请日：1996-03-12
申请人： Andrew N. Paquet , Warren H. Griffin
发明人： Andrew N. Paquet , Warren H. Griffin
IPC分类号： C08J9/12 , C08J9/08
CPC分类号： C08J9/122 , C08J2325/04
摘要： Disclosed is a foam structure of desirable mechanical strength made with a low molecular weight alkenyl aromatic polymer material and an inorganic blowing agent. The polymer material has an alkenyl aromatic polymer of a weight average molecular weight of 100,000 to 165,000. The foam structure can be made in processes with reduced pressure drop.
摘要翻译： PCT No.PCT / US94 / 10491 Sec。 371日期：1996年3月12日 102（e）1996年3月12日PCT PCT 1994年9月16日PCT公布。公开号WO95 / 10560 日期1995年04月20日公开是用低分子量链烯基芳族聚合物材料和无机发泡剂制成的理想机械强度的泡沫结构。聚合物材料具有重均分子量为100,000至165,000的链烯基芳族聚合物。泡沫结构可以在压降降低的过程中制成。

6. 发明授权

US5286757A Foamable composition and process for making large cell size alkenyl aromatic polymer foam structure with 1,1-difluoroethane 失效
公开(公告)号：US5286757A
公开(公告)日：1994-02-15
申请号：US66453
申请日：1993-05-24
申请人： Roy E. Smith , Warren H. Griffin , Deborah L. Koesis , Dennis R. Lantz
发明人： Roy E. Smith , Warren H. Griffin , Deborah L. Koesis , Dennis R. Lantz
IPC分类号： C08J9/14
CPC分类号： B29C44/352 , C08J9/149 , C08J2325/00 , Y10S521/91
摘要： Disclosed is a process for making extruded, closed-cell alkenyl aromatic polymer foam structure having an average cell size of from about 0.3 to about 3.0 millimeters. The process comprises: a) heating an alkenyl aromatic polymer material having greater than 50 percent by weight alkenyl aromatic monomeric units to form a melt polymer material; b) incorporating into the melt polymer material at an elevated pressure a blowing agent comprising at least 50 percent by weight 1,1-difluoroethane (HFC-152a) based upon the total weight of the blowing agent to form a foamable gel; c) cooling the foamable gel to an optimum foaming temperature prior to extrusion through a die; and d) extruding the foamable gel through a die to form the foam structure. Further disclosed is a foamable gel capable of forming an alkenyl aromatic polymer foam structure having an average cell size of from about 0.3 to about 3.0 millimeters.

7. 发明授权

US08198340B2 Quality polymer foam from fluorinated alkene blowing agents 有权
标题翻译：来自氟化烯烃发泡剂的优质聚合物泡沫
公开(公告)号：US08198340B2
公开(公告)日：2012-06-12
申请号：US12527131
申请日：2008-03-10
申请人： Van-Chau Vo , Richard T. Fox , Warren H. Griffin
发明人： Van-Chau Vo , Richard T. Fox , Warren H. Griffin
IPC分类号： C08J9/00 , C08J9/12 , C08J9/14 , C08J9/22
CPC分类号： C08J9/127 , B29C44/54 , C08J9/146 , C08J9/149 , C08J9/16 , C08J2201/03 , C08J2203/06 , C08J2203/10 , C08J2203/12 , C08J2203/14 , C08J2203/142 , C08J2203/162 , C08J2325/06
摘要： Alkenyl aromatic polymer foam comprising a polymer matrix containing one or more polymer and defining a plurality of cells having an average cell size wherein: (a) the alkenyl aromatic polymer foam has: —(i) an average cell size that is in a range of 0.02 and 5 millimeters; —(ii) a density of 64 kilograms per cubic meter or less; —(iii) an open cell content less than 30 percent; and —(iv) a cell size variation of 30% or less; and wherein the foam further comprises one or more fluorinated alkene blowing agent at a concentration of 0.03 moles or more and 0.3 moles or less per 100 grams of polymer foam.
摘要翻译：烯烃芳族聚合物泡沫体，其包含含有一种或多种聚合物并且限定多个具有平均泡孔尺寸的泡孔的聚合物基质，其中：（a）链烯基芳族聚合物泡沫体具有：（i）平均泡孔尺寸在 0.02和5毫米; - （ii）每立方米或以下的密度为64公斤; - （iii）开放细胞含量低于30％; 和（iv）30％以下的细胞大小变化; 并且其中所述泡沫体还包含一种或多种浓度为0.03摩尔以上且0.3摩尔或更少每100克聚合物泡沫的氟化烯烃发泡剂。

8. 发明授权

US5276063A Foamable composition and process for making large cell size alkenyl aromatic polymer foam structure with 1,1-difluoroethane 失效
标题翻译：可泡沫组合物和制备具有1,1-二氟乙烷的大单元尺寸链烯基芳族聚合物泡沫结构的方法
公开(公告)号：US5276063A
公开(公告)日：1994-01-04
申请号：US73854
申请日：1993-06-08
申请人： Roy E. Smith , Warren H. Griffin , Deborah L. Kocsis , Dennis R. Lantz
发明人： Roy E. Smith , Warren H. Griffin , Deborah L. Kocsis , Dennis R. Lantz
IPC分类号： C08J9/14
CPC分类号： B29C44/352 , C08J9/149 , C08J2325/00 , Y10S521/91
摘要： Disclosed is a process for making extruded, closed-cell alkenyl aromatic polymer foam structure having an average cell size of from about 0.3 to about 3.0 millimeters. The process comprises: a) heating an alkenyl aromatic polymer material having greater than 50 percent by weight alkenyl aromatic monomeric units to form a melt polymer material; b) incorporating into the melt polymer material at an elevated pressure a blowing agent comprising at least 50 percent by weight 1,1-difluoroethane (HFC-152a) based upon the total weight of the blowing agent to form a foamable gel; c) cooling the foamable gel to an optimum foaming temperature prior to extrusion through a die; and d) extruding the foamable gel through a die to form the foam structure. Further disclosed is a foamable gel capable of forming an alkenyl aromatic polymer foam structure having an average cell size of from about 0.3 to about 3.0 millimeters.
摘要翻译：公开了一种制备平均泡孔尺寸为约0.3至约3.0毫米的挤出的闭孔烯基芳族聚合物泡沫结构的方法。该方法包括：a）加热具有大于50重量％链烯基芳族单体单元的烯基芳族聚合物材料以形成熔融聚合物材料; b）在升高的压力下将基于发泡剂总重量的至少50重量％的1,1-二氟乙烷（HFC-152a）的发泡剂并入熔融聚合物材料中以形成可发泡凝胶; c）在通过模具挤出之前将可发泡凝胶冷却至最佳发泡温度; 和d）通过模头挤出可发泡凝胶以形成泡沫结构。还公开了能够形成平均泡孔尺寸为约0.3至约3.0毫米的烯基芳族聚合物泡沫结构的可发泡凝胶。

9. 发明申请

US20100292355A1 ALKENYL-AROMATIC FOAM HAVING GOOD SURFACE QUALITY, HIGH THERMAL INSULATING PROPERTIES AND LOW DENSITY 审中-公开
标题翻译：具有良好表面质量的ALKENYL-AROMATIC泡沫，高热绝缘性能和低密度
公开(公告)号：US20100292355A1
公开(公告)日：2010-11-18
申请号：US12596178
申请日：2008-04-18
申请人： Mark A. Barger , Charles A. Berglund , Clive P. Bosnyak , Stephanie A. Donati , John Gordon-Duffy , Warren H. Griffin , Ing-Feng Hu , Jean-Francois Koenig , Simon Lee , Creston D. Shmidt , Roy E. Smith , Chau V. Vo
发明人： Mark A. Barger , Charles A. Berglund , Clive P. Bosnyak , Stephanie A. Donati , John Gordon-Duffy , Warren H. Griffin , Ing-Feng Hu , Jean-Francois Koenig , Simon Lee , Creston D. Shmidt , Roy E. Smith , Chau V. Vo
IPC分类号： C08J9/04 , C08J9/00
CPC分类号： C08J9/146 , C08J9/149 , C08J2325/04
摘要： Prepare an alkenyl-aromatic foam having good surface quality, high thermal insulating properties and low density using an extrusion method by expanding a foamable polymer composition of an alkenyl-aromatic polymer composition containing less than 20 weight-percent covalently bonded halogens and having a polydispersity of less than 2.5 and a water solubility greater than 0.09 moles per kilogram and 2.2 moles per kilogram or less at 130 degrees Celsius and 101 kilopascals pressure and 0.8-2 moles per kilogram of a blowing agent containing 0.4 moles per kilogram or more of a chlorine-free fluorinated blowing agents and water at a concentration of at least 0.22 moles per kilogram; wherein moles per kilogram are relative to kilograms of alkenyl-aromatic polymer. The resulting foam has a density of 64 kilograms per cubic meter or less and a thermal conductivity of 32 milliwatts per meter-Kelvin or less after 180 days.
摘要翻译：使用挤出方法制备具有良好表面质量，高绝热性和低密度的烯基 - 芳族泡沫体，其通过使包含少于20重量％共价键合的卤素的烯基 - 芳族聚合物组合物的可发泡聚合物组合物膨胀并具有多分散性小于2.5，水溶解度大于0.09摩尔/千克，在130摄氏度和101千帕斯卡压力下为2.2摩尔/千克或更小，每千克含有0.4摩尔/千克或更多氯气的发泡剂为0.8-2摩尔，游离氟化发泡剂和浓度至少为0.22摩尔/千克的水; 其中每千克的摩尔数相对于千克的烯基 - 芳族聚合物。生成的泡沫体的密度为64千克/立方米或更小，并且180天后的热导率为32毫瓦/米 - 开尔文或更低。

10. 发明授权

US06599946B2 Blowing agent composition and polymeric foam containing a normally-liquid hydroflurocarbon and carbon dioxide 有权
标题翻译：发泡剂组合物和含有常液态氢氟烃和二氧化碳的聚合物泡沫
公开(公告)号：US06599946B2
公开(公告)日：2003-07-29
申请号：US10286565
申请日：2002-11-01
申请人： John D. Duffy , Warren H. Griffin
发明人： John D. Duffy , Warren H. Griffin
IPC分类号： C08J914
CPC分类号： C08J9/146 , C08J9/0066 , C08J9/122 , C08J9/144 , C08J9/149 , C08J2203/06 , C08J2203/12 , C08J2203/142 , C08J2203/182 , C08J2203/202
摘要： The present invention relates to blowing agent compositions for polymeric foams that contain carbon dioxide and a hydrofluorocarbon having a boiling point of 14° C. or higher and lower than about 120° C. The present invention also relates to processes for preparing polymeric foam using such blowing agent compositions, foamable polymer compositions containing such blowing agents, and polymeric foams containing such blowing agent compositions. Suitable blowing agent combinations include: (a) a composition containing carbon dioxide and at least one hydrofluorocarbon having a boiling point of 30° C. to about 120° C. that is essentially free of other low boiling ethers and hydrocarbons; (b) a composition containing greater than 50 weight-percent carbon dioxide and at least one hydrofluorocarbon having a boiling point of 14° C. or higher to about 120° C.; and (c) carbon dioxide and one hydrofluorocarbon having a boiling point of 14° C. or higher and lower than about 120° C.
摘要翻译：本发明涉及含有二氧化碳的聚合物泡沫的发泡剂组合物和沸点为14℃或更高且低于约120℃的氢氟烃。本发明还涉及使用这种方法制备聚合物泡沫的方法发泡剂组合物，含有这种发泡剂的可发泡聚合物组合物和含有这种发泡剂组合物的聚合物泡沫。合适的发泡剂组合包括：（a）含有二氧化碳和至少一种沸点为30℃至约120℃，其基本上不含其它低沸点醚和烃; （b）含有大于50重量％二氧化碳和至少一种沸点为14℃或更高至约120℃的氢氟烃的组合物; 和（c）二氧化碳和沸点为14℃以上且低于约120℃的一种氢氟烃。

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