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1. 发明授权

US5919601A Radiation-sensitive compositions and printing plates 失效
标题翻译：辐射敏感组合物和印版
公开(公告)号：US5919601A
公开(公告)日：1999-07-06
申请号：US745534
申请日：1996-11-12
申请人： My T. Nguyen , Shashikant Saraiya , Frederic E. Mikell , Ken-ichi Shimazu , S. Peter Pappas , Robert W. Hallman , Ajay Shah , Hans-Joachim Timpe , Celin Savariar-Hauck
发明人： My T. Nguyen , Shashikant Saraiya , Frederic E. Mikell , Ken-ichi Shimazu , S. Peter Pappas , Robert W. Hallman , Ajay Shah , Hans-Joachim Timpe , Celin Savariar-Hauck
IPC分类号： B41C1/10 , B41M5/36 , G03F7/004 , G03F7/038 , G03C1/77 , G03F7/09
CPC分类号： B41C1/1008 , G03F7/0045 , G03F7/038 , B41C2210/02 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/262 , Y10S430/127
摘要： Radiation-sensitive compositions, printing plates containing such compositions, imageable by infrared and ultraviolet/visible radiation and imaging method using same. The compositions comprise a thermal-activated acid generator; a crosslinking resin; a binder resin comprising a polymer containing reactive pendant groups selected from hydroxy, carboxylic acid, sulfonamide, and alkoxymethylamides; an infrared absorber; and optionally a UV/visible radiation-activated acid generator for UV/visible sensitization.
摘要翻译：辐射敏感组合物，含有这种组合物的印版，可通过红外和紫外/可见光辐照成像，并使用它们的成像方法。组合物包含热活化酸产生剂; 交联树脂; 包含含有选自羟基，羧酸，磺酰胺和烷氧基甲基酰胺的反应性侧基的聚合物的粘合剂树脂; 红外吸收体; 以及可选地用于UV /可见光敏化的UV /可见光辐射活化酸发生剂。

2. 发明授权

US06352812B1 Thermal digital lithographic printing plate 有权
标题翻译：热数码平版印刷版
公开(公告)号：US06352812B1
公开(公告)日：2002-03-05
申请号：US09301866
申请日：1999-04-29
申请人： Ken-Ichi Shimazu , Jayanti Patel , Shashikant Saraiya , Nishith Merchant , Celin Savariar-Hauck , Hans-Joachim Timpe , Christopher D. McCullough
发明人： Ken-Ichi Shimazu , Jayanti Patel , Shashikant Saraiya , Nishith Merchant , Celin Savariar-Hauck , Hans-Joachim Timpe , Christopher D. McCullough
IPC分类号： G03F709
CPC分类号： B41M5/42 , B41C1/1016 , B41C2201/04 , B41C2210/02 , B41C2210/06 , B41C2210/14 , B41C2210/24 , B41C2210/26 , B41C2210/262 , B41C2210/264 , B41C2210/266 , B41M5/368 , B41M5/44 , B41M5/465
摘要： A thermal lithographic printing plate, which can be imaged by thermal energy typically by imagewise exposure with an infrared emitting laser, a thermal printing head, etc., is made up of a hydrophilic substrate, and a composite layer structure composed of two layer coatings. Preferably, the first layer of the composite is composed of an aqueous developable polymer mixture containing a photothermal conversion material which is contiguous to the hydrophilic substrate. The second layer of the composite is composed of one or more non-aqueous soluble polymers which are soluble or dispersible in a solvent which does not dissolve the first layer. The plate is exposed with an infrared laser or a thermal print head, and upon aqueous development of the imaged plate, the exposed portions are removed exposing hydrophilic substrate surfaces receptive to conventional aqueous fountain solutions. The unexposed portions contain the ink-receptive image areas. The second layer may also contain a photothermal conversion material. Alternatively, the composite layer may be free of photothermal conversion material when thermal imaging is carried out using a thermal printing head.
摘要翻译：可以通过热能成像通过用红外发射激光成像曝光，热打印头等来成像的热平版印刷版由亲水基材和由两层涂层组成的复合层结构构成。优选地，复合材料的第一层由包含与亲水基底邻接的光热转换材料的水性可显影聚合物混合物组成。复合材料的第二层由一种或多种可溶于或不溶于不溶于第一层的溶剂中的非水溶性聚合物组成。该板用红外激光或热打印头曝光，并且在成像板的水性显影时，去除曝光部分，暴露接受常规水性喷泉溶液的亲水底物表面。未曝光部分包含吸墨图像区域。第二层也可以含有光热转换材料。或者，当使用热敏打印头进行热成像时，复合层可以不含光热转换材料。

3. 发明授权

US06261740B1 Processless, laser imageable lithographic printing plate 失效
标题翻译：无源激光可成像平版印刷版
公开(公告)号：US06261740B1
公开(公告)日：2001-07-17
申请号：US09244339
申请日：1999-02-04
申请人： My T. Nguyen , Shashikant Saraiya , Ken-Ichi Shimazu , S. Peter Pappas , Robert Hallman , Ajay Shah , Omkar J. Natu , Jayanti Patel
发明人： My T. Nguyen , Shashikant Saraiya , Ken-Ichi Shimazu , S. Peter Pappas , Robert Hallman , Ajay Shah , Omkar J. Natu , Jayanti Patel
IPC分类号： G03C176
CPC分类号： B41C1/1033 , B41C1/1041 , B41M5/368 , B41N1/006
摘要： A lithographic printing surface is prepared using a thermal lithographic printing plate which requires no chemical development to remove areas of the imaged plate. The processless thermal lithographic printing plate has a sheet substrate; a hydrophilic layer on the sheet substrate; and a thermally sensitive imaging layer on the hydrophilic layer. The hydrophilic layer contains about 30 weight % of an aluminosilicate or clay, and preferably has an exterior surface which is micro-porous. The imaging layer preferably is micro-porous. The imaging layer is exposed imagewise using infrared laser radiation to produce an imaged layer. The imaged layer is treated with a conditioner liquid to produce a lithographic printing surface. By this method, the printing plate can be digitally imaged by infrared laser radiation so that the exposed areas become ink receptive and the non-exposed areas repel ink after simple treatment with a conditioner such as an aqueous surfactant solution such as a fountain solution containing an amphoteric surfactant.
摘要翻译：使用不需要化学显影去除成像板的区域的热平版印刷版制备平版印刷表面。无机热平版印刷版具有片状基材; 在所述片基材上的亲水层; 和亲水层上的热敏成像层。亲水层包含约30重量％的硅铝酸盐或粘土，并且优选具有微孔的外表面。成像层优选是微孔的。使用红外激光辐射使成像层成像曝光以产生成像层。用调理液处理成像层以产生平版印刷表面。通过这种方法，可以通过红外激光辐射对印版进行数字成像，使得曝光区域变为油墨接受，并且在用诸如表面活性剂水溶液的简单处理之后，非曝光区域排斥墨，所述表面活性剂水溶液例如含有两性表面活性剂。

4. 发明授权

US5948596A Digital printing plate comprising a thermal mask 失效
标题翻译：包括热掩模的数字印版
公开(公告)号：US5948596A
公开(公告)日：1999-09-07
申请号：US863770
申请日：1997-05-27
申请人： Xing-Fu Zhong , Ken-ichi Shimazu , S. Peter Pappas , Tore Harms , Thi Do , Shashikant Saraiya , William P. Keaveney
发明人： Xing-Fu Zhong , Ken-ichi Shimazu , S. Peter Pappas , Tore Harms , Thi Do , Shashikant Saraiya , William P. Keaveney
IPC分类号： B41C1/10 , G03C1/73
CPC分类号： B41C1/1016 , B41C2201/04 , B41C2210/02 , B41C2210/04 , B41C2210/06 , B41C2210/16 , B41C2210/24
摘要： Presensitized lithographic plates are prepared which permit direct formation of printable images on plates by digital computerization without the intervening formation of a photographic image with a quality that allows the plates to be used for high volume printing applications. The lithographic printing plate has a structure which contains a substrate; a positive or negative working photosensitive layer; and a thermally sensitive masking layer which is opaque to the actinic radiation but which is soluble in an aqueous medium. The masking layer contains a heat softenable disperse phase which is insoluble in the aqueous medium; a polymeric continuous phase which is soluble or swellable in the aqueous medium; and a colorant which strongly absorbs radiant energy and converts the radiant energy to heat. In use the masking layer is digitally exposed to a computer controlled laser image so that exposed image areas of the masking are insolublized in the aqueous medium; soluble areas of the mask layer are then removed to form an opaque image mask on the photosensitive layer which is then exposed to actinic radiation passing through the mask to solubilize or insolubilize exposed areas of the photosensitive layer; the photosensitive layer is then developed with the developer liquid to remove the soluble areas and any overlying mask areas to form the lithographic printing plate. Both wet and waterless lithographic printing plates may be digitally prepared in this manner.
摘要翻译：制备预感光刻平板，其允许通过数字计算机化在板上直接形成可印刷图像，而不用介质形成摄影图像，其质量允许将板用于大容量印刷应用。平版印刷版具有包含基板的结构; 正或负工作感光层; 以及对光化辐射不透明但可溶于水性介质的热敏屏蔽层。掩蔽层含有不溶于水介质的可热软化分散相; 在水性介质中可溶或溶胀的聚合物连续相; 以及强烈吸收辐射能并将辐射能转化为热的着色剂。在使用中，掩模层被数字地暴露于计算机控制的激光图像，使得掩蔽的曝光图像区域在水性介质中被分散; 然后去除掩模层的可溶性区域以在感光层上形成不透明图像掩模，然后将其暴露于通过掩模的光化辐射，以增溶或不溶化感光层的曝光区域; 然后用显影剂液体显影感光层以除去可溶性区域和任何覆盖的掩模区域以形成平版印刷版。湿式和无水平版印刷版可以以这种方式数字地制备。

5. 发明授权

US5846685A Radiation sensitive diazo sulfo-acrylic adducts and method for producing a printing plate 失效
标题翻译：辐射敏感重氮磺基丙烯酸加合物及其印刷方法
公开(公告)号：US5846685A
公开(公告)日：1998-12-08
申请号：US797675
申请日：1997-01-31
申请人： S. Peter Pappas , Jianbing Huang , Ajay Shah , Shashikant Saraiya
发明人： S. Peter Pappas , Jianbing Huang , Ajay Shah , Shashikant Saraiya
IPC分类号： G03F7/021 , G03F7/095
CPC分类号： G03F7/021
摘要： A radiation sensitive composition containing an adduct of a diazonium resin having pendant diazonium groups, with a sulfonated acrylic copolymer having pendant sulfonate groups. The sulfonated acrylic copolymer contains an acrylic moiety and a sulfonated styryl or acrylic moiety. The copolymer may optionally contain styryl moieties. The composition is useful as a radiation sensitive layer in imaging elements for graphic arts applications and is particularly useful in preparing durable, long-wear, printing plates.
摘要翻译：一种辐射敏感性组合物，其含有具有侧面重氮基团的重氮化合物的加合物和具有磺酸根基侧基的磺化丙烯酸共聚物。磺化丙烯酸共聚物含有丙烯酸部分和磺化苯乙烯基或丙烯酸部分。共聚物可以任选地含有苯乙烯基部分。该组合物可用作用于图形艺术应用的成像元件中的辐射敏感层，并且在制备耐用的长寿命印刷版中特别有用。

6. 发明申请

US20110053085A1 LITHOGRAPHIC PRINTING PLATE PRECURSORS AND STACKS 有权
标题翻译： LITHOGRAPHIC印刷机前置和堆叠
公开(公告)号：US20110053085A1
公开(公告)日：2011-03-03
申请号：US12546769
申请日：2009-08-25
申请人： Jianbing Huang , Shashikant Saraiya , Frederic E. Mikell , Eiji Hayakawa , Hirokazu Fujii , Akira Igarashi
发明人： Jianbing Huang , Shashikant Saraiya , Frederic E. Mikell , Eiji Hayakawa , Hirokazu Fujii , Akira Igarashi
IPC分类号： G03F7/20 , G03F7/004
CPC分类号： B41C1/1016 , B41C2201/02 , B41C2210/02 , B41C2210/04 , B41C2210/06 , B41C2210/14 , B41C2210/24 , B41C2210/262 , G03F7/092
摘要： Lithographic printing plate precursors have been designed so that they can be stored, shipped, and used in stacks without interleaf paper between individual precursors. This is achieved by incorporating polymeric particles having an average diameter of from about 3 to about 20 μm into the outermost precursor layer such as an imageable layer or topcoat. The polymeric particles comprise a core of a crosslinked polymer and have grafted hydrophilic polymeric surface groups that are grafted onto the particle surfaces by polymerizing hydrophilic monomers in the presence of the crosslinked polymeric particles. The lithographic printing plates can be either negative- or positive-working elements.
摘要翻译：已经设计了平版印刷版前体，使得它们可以在堆叠中储存，运输和使用，而不需要在各个前体之间的中间纸。这通过将具有约3至约20μm的平均直径的聚合物颗粒结合到最外层前体层（例如可成像层或顶涂层）中来实现。聚合物颗粒包含交联聚合物的核心并且具有通过在交联的聚合物颗粒的存在下聚合亲水单体而接枝到颗粒表面上的接枝的亲水聚合物表面基团。平版印刷版可以是负片或正片元件。

7. 发明授权

US08053162B2 Substrate and imageable element with hydrophilic interlayer 有权
标题翻译：具有亲水中间层的基材和可成像元件
公开(公告)号：US08053162B2
公开(公告)日：2011-11-08
申请号：US12140545
申请日：2008-06-17
申请人： Ting Tao , Shashikant Saraiya , Eric E. Clark , Frederic E. Mikell
发明人： Ting Tao , Shashikant Saraiya , Eric E. Clark , Frederic E. Mikell
IPC分类号： G03F7/00 , G03F7/26
CPC分类号： B41N3/036 , B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/08 , B41C2210/22 , B41C2210/24 , G03F7/16 , Y10T428/24612 , Y10T428/273 , Y10T428/31609 , Y10T428/31725
摘要： A substrate useful for forming lithographic printing plate precursors includes a metal or polymer support and an interlayer comprising a trialkoxysilyl polyethylene glycol acrylate having the following Structure (I): wherein R1 and R2 are independently hydrogen or C1 to C6 alkyl, C1 to C6 alkenyl, C1 to C6 alkoxy, C1 to C6 acyl, C1 to C6 acyloxy, phenyl, halo, or cyano groups, or R1 and R2 together can form a cyclic group, R3 is hydrogen, or a C1 to C6 alkyl, phenyl, halo, or cyano group, R4 and R5 are independently hydrogen or methyl groups, R6 is hydrogen or a C1 to C12 alkyl group, X1 is —O— or —NR— wherein R is hydrogen or an alkyl or aryl group, X2 is —NR′— wherein R′ is hydrogen or an alkyl or aryl group, m is an integer of from 15 to 200, and n is an integer of from 1 to 12. The lithographic printing plates can be negative-working and particularly useful for on-press development and have a sulfuric acid-anodized aluminum support.
摘要翻译：用于形成平版印刷版前体的底物包括金属或聚合物载体和包含具有以下结构（I）的三烷氧基甲硅烷基聚乙二醇丙烯酸酯的中间体：其中R 1和R 2独立地为氢或C 1至C 6烷基，C 1至C 6烯基， C 1至C 6烷氧基，C 1至C 6酰基，C 1至C 6酰氧基，苯基，卤素或氰基，或者R 1和R 2可一起形成环状基团，R 3为氢或C 1至C 6烷基，苯基，卤素或氰基，R 4和R 5独立地是氢或甲基，R 6是氢或C 1至C 12烷基，X 1是-O-或-NR-，其中R是氢或烷基或芳基，X 2是-NR'- 其中R'为氢或烷基或芳基，m为15至200的整数，n为1至12的整数。平版印刷版可以是负性的并且特别适用于印刷机的发展并具有硫酸阳极氧化铝载体。

8. 发明授权

US07732118B2 Negative-working imageable elements and methods of use 失效
标题翻译：负面的可成像元素和使用方法
公开(公告)号：US07732118B2
公开(公告)日：2010-06-08
申请号：US11746816
申请日：2007-05-10
申请人： Ting Tao , Shashikant Saraiya , Eric Clark , Frederic E. Mikell
发明人： Ting Tao , Shashikant Saraiya , Eric Clark , Frederic E. Mikell
IPC分类号： G03C1/00 , G03F7/26
CPC分类号： G03F7/033 , B41C1/1008 , B41C2210/04 , B41C2210/06 , B41C2210/08 , B41C2210/22 , B41C2210/24
摘要： A radiation-sensitive composition includes a radically polymerizable component, initiator composition, a radiation absorbing compound, and a polymeric binder having recurring units that are derived from various ethylenically unsaturated polymerizable monomers provided that at least 40 mol % of the recurring units have a tertiary carbon atom in the backbone and the rest of the recurring units have a secondary or quaternary carbon atom in the backbone. This composition can be used to provide negative-working imageable elements that can be imaged and developed to provide lithographic printing plates that have desired imaging speed and excellent run length without the need for a post-exposure backing step.
摘要翻译：辐射敏感组合物包括可自由基聚合的组分，引发剂组合物，辐射吸收化合物和具有衍生自各种烯属不饱和可聚合单体的重复单元的聚合物粘合剂，只要至少40mol％的重复单元具有叔碳原子骨架中的原子，其余的重复单元在主链中具有仲或季碳原子。该组合物可用于提供可成像和显影的负性可成像元件，以提供具有期望的成像速度和优异的行程长度的平版印刷版，而不需要后曝光背衬步骤。

9. 发明申请

US20080008957A1 Negative-working radiation-sensitive compositions and imageable elements 审中-公开
标题翻译：负性辐射敏感组合物和可成像元件
公开(公告)号：US20080008957A1
公开(公告)日：2008-01-10
申请号：US11475694
申请日：2006-06-27
申请人： Heidi M. Munnelly , Shashikant Saraiya , Kevin D. Wieland , Frederic E. Mikell , Paul R. West
发明人： Heidi M. Munnelly , Shashikant Saraiya , Kevin D. Wieland , Frederic E. Mikell , Paul R. West
IPC分类号： G03C1/00
CPC分类号： G03F7/027 , B41C1/1008 , B41C2210/04 , B41C2210/06 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41M5/368 , B41N1/083 , G03F7/033 , G03F7/085
摘要： A radiation-sensitive composition includes a radically polymerizable component and an initiator composition capable of generating radicals sufficient to initiate polymerization of the radically polymerizable component upon exposure to imaging radiation. This composition also includes a radiation absorbing compound, a polymeric binder having poly(alkylene glycol) side chains, and a nonionic phosphate acrylate that has a molecular weight of at least 250. This composition can be used to prepare a negative-working imageable element that is sensitive to suitable imaging radiation and can be imaged at relatively low energy, developed either on-press or off-press, and then used for printing without a post-exposure baking step.
摘要翻译：辐射敏感组合物包括自由基聚合组分和引发剂组合物，其能够产生足以在暴露于成像辐射时引发可自由基聚合组分的聚合的自由基。该组合物还包括辐射吸收化合物，具有聚（亚烷基二醇）侧链的聚合物粘合剂和分子量至少为250的非离子磷酸丙烯酸酯。该组合物可用于制备负性可成像元件，对合适的成像辐射敏感，可以在相对较低的能量下成像，可以在印刷机上或压印机上显影，然后用于没有后曝光烘烤步骤的印刷。

10. 发明申请

US20100028806A1 METHOD OF PREPARING LITHOGRAPHIC PRINTING PLATES 有权
标题翻译：制备平版印刷板的方法
公开(公告)号：US20100028806A1
公开(公告)日：2010-02-04
申请号：US12181371
申请日：2008-07-29
申请人： Jayanti Patel , Paul R. West , Shashikant Saraiya , Nicki R. Miller , Frederic E. Mikell
发明人： Jayanti Patel , Paul R. West , Shashikant Saraiya , Nicki R. Miller , Frederic E. Mikell
IPC分类号： G03F7/20
CPC分类号： G03F7/033 , B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/10 , B41C2210/20 , B41C2210/22 , B41C2210/24 , G03F7/3035 , G03F7/322
摘要： A negative-working lithographic printing plate precursor can be imaged with infrared radiation and processed in a single step using a single processing solution having a pH of from about 3 to 11. The precursor has a primary polymeric binder that comprises recurring units derived from one or more N-alkoxymethyl(meth)acrylamides, provided that such recurring units are present in the primary polymeric binder in an amount of at least 10% based on the total dry primary polymeric binder weight. In addition, the primary polymeric binder is present in an amount of from about 12 to about 70% based on total imageable layer dry weight. The imaged precursor can be processed off-press or on-press.
摘要翻译：负性平版印刷版前体可以用红外线辐射成像，并使用pH为约3至11的单一处理溶液在单一步骤中进行处理。前体具有主要聚合物粘合剂，其包含衍生自一个或多个更多的N-烷氧基甲基（甲基）丙烯酰胺，条件是这种重复单元以基于总干主要聚合物粘合剂重量的至少10％的量存在于初级聚合物粘合剂中。此外，基于总可成像层干重，初级聚合物粘合剂的存在量为约12至约70％。成像的前体可以被压制或印刷机处理。

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