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1. 发明申请

US20110255085A1 SPECTROMETER, SPECTROMETRY, AND SPECTROMETRY PROGRAM 有权
标题翻译：光谱仪，光谱仪和光谱计划
公开(公告)号：US20110255085A1
公开(公告)日：2011-10-20
申请号：US13141152
申请日：2009-09-08
申请人： Motoyuki Watanabe , Kazuya Iguchi , Kengo Suzuki
发明人： Motoyuki Watanabe , Kazuya Iguchi , Kengo Suzuki
IPC分类号： G01J3/30
CPC分类号： G01N21/645 , G01J3/02 , G01J3/0262 , G01J3/0267 , G01J3/0291 , G01J3/4406 , G01J3/443 , G01N2201/0632 , G01N2201/065
摘要： A spectroscopic measurement apparatus 1A comprises an integrating sphere 20 in which a sample S is located, a spectroscopic analyzer 30 dispersing the light to be measured from the sample S and obtaining a wavelength spectrum, and a data analyzer 50. The analyzer 50 includes an object range setting section which sets a first object range corresponding to excitation light and a second object range corresponding to light emission from the sample S in a wavelength spectrum, and a sample information analyzing section which determines a luminescence quantum yield of the sample S, determines a measurement value Φ0 of the luminescence quantum yield from results of a reference measurement and a sample measurement, and determines, by using factors β, γ regarding stray light in the reference measurement, an analysis value Φ of the luminescence quantum yield with the effect of stray light reduced by Φ=βΦ0+γ. This realizes a spectroscopic measurement apparatus, a measurement method, and a measurement program which can reduce the effect of stray light generated in a spectrometer.
摘要翻译：分光测量装置1A包括其中位于样品S的积分球20，从样品S分散被测光并获得波长谱的光谱分析仪30和数据分析器50.分析器50包括物体范围设定部，其设定与激发光对应的第一对象范围和与波长光谱中的来自样品S的发光对应的第二对象范围，以及确定样品S的发光量子产率的样本信息分析部，通过参考测量和样品测量的结果，发光量子产率的测量值Φ0，并且通过使用参考测量中关于杂散光的因子＆bgr;γ来确定发光量子产率的分析值Φ，其效果为杂散光减少Φ=＆bgr;Φ0+γ。这实现了可以降低在光谱仪中产生的杂散光的影响的光谱测量装置，测量方法和测量程序。

2. 发明授权

US08462337B2 Spectrometer, spectrometry, and spectrometry program 有权
标题翻译：光谱仪，光谱测定和光谱测定程序
公开(公告)号：US08462337B2
公开(公告)日：2013-06-11
申请号：US13141152
申请日：2009-09-08
申请人： Motoyuki Watanabe , Kazuya Iguchi , Kengo Suzuki
发明人： Motoyuki Watanabe , Kazuya Iguchi , Kengo Suzuki
IPC分类号： G01J1/04 , G01J3/30
CPC分类号： G01N21/645 , G01J3/02 , G01J3/0262 , G01J3/0267 , G01J3/0291 , G01J3/4406 , G01J3/443 , G01N2201/0632 , G01N2201/065
摘要： A spectroscopic measurement apparatus 1A comprises an integrating sphere 20 in which a sample S is located, a spectroscopic analyzer 30 dispersing the light to be measured from the sample S and obtaining a wavelength spectrum, and a data analyzer 50. The analyzer 50 includes an object range setting section which sets a first object range corresponding to excitation light and a second object range corresponding to light emission from the sample S in a wavelength spectrum, and a sample information analyzing section which determines a luminescence quantum yield of the sample S, determines a measurement value Φ0 of the luminescence quantum yield from results of a reference measurement and a sample measurement, and determines, by using factors β, γ regarding stray light in the reference measurement, an analysis value Φ of the luminescence quantum yield with the effect of stray light reduced by Φ=βΦ0+γ. This realizes a spectroscopic measurement apparatus, a measurement method, and a measurement program which can reduce the effect of stray light generated in a spectrometer.
摘要翻译：分光测量装置1A包括其中位于样品S的积分球20，从样品S分散被测光并获得波长谱的光谱分析仪30和数据分析器50.分析器50包括物体范围设定部，其设定与激发光对应的第一对象范围和与波长光谱中的来自样品S的发光对应的第二对象范围，以及确定样品S的发光量子产率的样本信息分析部，通过参考测量和样品测量的结果测量发光量子产率的测量值Phi0，并且通过使用参考测量中关于杂散光的因子β，γ来确定具有杂散效应的发光量子产率的分析值Phi 光减少Phi = betaPhi0 +γ。这实现了可以降低在光谱仪中产生的杂散光的影响的光谱测量装置，测量方法和测量程序。

3. 发明授权

US06897953B2 Method for measuring fluorescence, apparatus for measuring fluorescence and apparatus for evaluating sample using it 有权
标题翻译：用于测量荧光的方法，用于测量荧光的装置和用于评估样品的装置
公开(公告)号：US06897953B2
公开(公告)日：2005-05-24
申请号：US10276979
申请日：2001-06-07
申请人： Motoyuki Watanabe , Kazuya Iguchi
发明人： Motoyuki Watanabe , Kazuya Iguchi
IPC分类号： G01N21/64 , G01J3/30 , H01J5/08
CPC分类号： G01N21/6408
摘要： In a fluorescence measuring method and apparatus, a sample S is irradiated with pulsed pumping light supplied from a pumping light source. Fluorescence generated by the sample S is detected by a photodetector by way of a condensing optical system and a spectroscope. The fluorescence time waveform is subjected to a data analysis in a data processing unit in a controller. This computes waveform data and physical quantities such as fluorescence lifetime. The pumping light time waveform is fixedly arranged with respect to a time axis used for data analysis. Fitting calculations are carried out while moving the fluorescence time waveform and fitting range from an initial position earlier than a pumping light peak to a later end position, and optimal measurement waveform data is selected according to a predetermined selection criterion. Waveform data is thus computed accurately and efficiently regardless of fluctuations in the fluorescence time waveform.
摘要翻译：在荧光测量方法和装置中，用从泵浦光源提供的脉冲泵浦光照射样品S. 由光检测器通过聚光光学系统和分光镜检测由样品S产生的荧光。荧光时间波形在控制器中的数据处理单元中进行数据分析。这可以计算波形数据和物理量，如荧光寿命。泵浦光时间波形相对于用于数据分析的时间轴固定地布置。在将荧光时间波形和拟合范围从早于泵浦光峰值的初始位置移动到稍后的终点位置的同时进行拟合计算，并根据预定的选择标准选择最佳测量波形数据。因此无论荧光时间波形的波动如何，都能准确高效地计算波形数据。

4. 发明授权

US08587779B2 Spectrometer 有权
标题翻译：光谱仪
公开(公告)号：US08587779B2
公开(公告)日：2013-11-19
申请号：US13126523
申请日：2009-09-24
申请人： Kazuya Iguchi , Kengo Suzuki
发明人： Kazuya Iguchi , Kengo Suzuki
IPC分类号： G01J3/28
CPC分类号： G01N21/0332 , G01J3/0254 , G01J3/0286 , G01J3/0291 , G01N21/255 , G01N21/645 , G01N2201/065
摘要： A spectrometer 1A is provided with an integrating sphere 20 for observing measured light emitted from a sample S of a measurement target, and a Dewar vessel 50 which retains a medium R for regulating temperature of the sample S, so as to cover the sample S and a second container portion 50b of which is located so as to face the interior of the integrating sphere 20. The sample S can be easily regulated at a desired temperature with the use of the Dewar vessel 50 retaining the medium R so as to cover the sample S. As the second container portion 50b is located so as to face the interior of the integrating sphere 20, the temperature of the sample S is regulated by the medium R, while inhibiting an external ambience around the integrating sphere from affecting the sample S. Therefore, the sample S can be efficiently regulated at a desired temperature.
摘要翻译：光谱仪1A设置有用于观察从测量对象的样品S发射的测量光的积分球20和保持用于调节样品S的温度的介质R的杜瓦容器50，以覆盖样品S和其第二容器部分50b定位成面对积分球20的内部。使用保持介质R的杜瓦容器50以便覆盖样品，可以容易地将样品S调节到期望的温度当第二容器部分50b定位成面对积分球20的内部时，样品S的温度由介质R调节，同时抑制积分球周围的外部环境影响样品S. 因此，可以将样品S有效地调节到期望的温度。

5. 发明授权

US08643839B2 Spectrometer 有权
标题翻译：光谱仪
公开(公告)号：US08643839B2
公开(公告)日：2014-02-04
申请号：US13131777
申请日：2009-09-24
申请人： Kazuya Iguchi , Kengo Suzuki
发明人： Kazuya Iguchi , Kengo Suzuki
IPC分类号： G01J3/28 , G01J1/46
CPC分类号： G01N21/15 , G01J1/04 , G01J3/02 , G01J3/0254 , G01J3/0286 , G01J3/0291 , G01N21/0332 , G01N21/255 , G01N21/474 , G01N21/645 , G01N2021/158 , G01N2021/6419 , G01N2021/6471 , G01N2021/6484 , G01N2201/065 , G01N2201/0833
摘要： A spectrometer is provided with an integrating sphere 20, inside which a sample S of a measurement target is disposed and which is adapted for observing measured light emitted from the sample S, and a Dewar vessel 50 which retains a refrigerant R for cooling the sample S and at least a portion of which is located so as to face the interior of the integrating sphere 20. Gas generated from the refrigerant R is introduced through predetermined gaps G1-G6 functioning as a gas introduction path and through a plurality of communicating passages 64 formed in a support pedestal 61, into the integrating sphere 20. The gas introduced into the integrating sphere 20 absorbs water in the integrating sphere 20 to decrease the temperature in the integrating sphere 20, so as to prevent dew condensation from occurring on a portion of a second container portion 50b of the Dewar vessel 50 exposed in the integrating sphere 20. This can prevent occurrence of dew condensation even in the case where the sample S is measured in a cooled state at a desired temperature.
摘要翻译：光谱仪设置有积分球20，测量对象的样品S在其内设置并且用于观察从样品S发射的测量的光;以及杜瓦容器50，其保留用于冷却样品S的制冷剂R 并且其至少一部分位于积分球20的内部。从制冷剂R产生的气体通过用作气体引入路径的预定间隙G1-G6引入并形成多个连通通道64 在支撑基座61内，进入积分球20.导入积分球20的气体吸收积分球20内的水，以降低积分球20的温度，以防止在一部分第二容器部分50b暴露在积分球20中，即使在槽在所需温度下以冷却状态测量。

6. 发明授权

US08525989B2 Spectrometer, spectrometry, and spectrometry program 有权
标题翻译：光谱仪，光谱测定和光谱测定程序
公开(公告)号：US08525989B2
公开(公告)日：2013-09-03
申请号：US13000466
申请日：2009-06-10
申请人： Kazuya Iguchi , Kengo Suzuki
发明人： Kazuya Iguchi , Kengo Suzuki
IPC分类号： G01J3/28
CPC分类号： G01N21/64 , G01N21/31 , G01N21/474 , G01N21/51 , G01N2201/065
摘要： A spectroscopic measurement apparatus comprises an integrating sphere in which a sample is located, an irradiation light supplying section supplying excitation light via an entrance aperture to the interior of the integrating sphere, a sample container holding the sample in the interior of the integrating sphere, a spectroscopic analyzer dispersing the light to be measured from an exit aperture and obtaining a wavelength spectrum, and a data analyzer performing data analysis of the wavelength spectrum. The analyzer includes a correction data obtaining section which obtains correction data of the wavelength spectrum considering light absorption by the sample container, and a sample information analyzing section which corrects and analyzes the wavelength spectrum to obtain sample information. This realizes a spectroscopic measurement apparatus, a measurement method, and a measurement program which can preferably perform spectroscopic measurement of the sample held by the sample container in the integrating sphere.
摘要翻译：光谱测量装置包括：样品所在的积分球;经由入射孔向积分球的内部供给激发光的照射光供给部，将样品保持在积分球的内部的样品容器，分光分析器，从出射孔分散待测光，得到波长光谱;以及数据分析仪进行波长谱的数据分析。该分析器包括校正数据获取部分，其获取考虑了样品容器的光吸收的波长谱的校正数据;以及样本信息分析部，其校正并分析波长谱以获得样本信息。这实现了可以优选地在积分球中对样品容器保持的样品进行光谱测量的光谱测量装置，测量方法和测量程序。

7. 发明申请

US20110098962A1 SPECTROMETER, SPECTROMETRY, AND SPECTROMETRY PROGRAM 有权
标题翻译：光谱仪，光谱仪和光谱计划
公开(公告)号：US20110098962A1
公开(公告)日：2011-04-28
申请号：US13000466
申请日：2009-06-10
申请人： Kazuya Iguchi , Kengo Suzuki
发明人： Kazuya Iguchi , Kengo Suzuki
IPC分类号： G06F19/00 , G01J3/30
CPC分类号： G01N21/64 , G01N21/31 , G01N21/474 , G01N21/51 , G01N2201/065
摘要： A spectroscopic measurement apparatus 1A comprises an integrating sphere 20 in which a sample S is located, an irradiation light supplying section 10 supplying excitation light via an entrance aperture 21 to the interior of the integrating sphere 20, a sample container 400 holding the sample S in the interior of the integrating sphere 20, a spectroscopic analyzer 30 dispersing the light to be measured from an exit aperture 22 and obtaining a wavelength spectrum, and a data analyzer 50 performing data analysis of the wavelength spectrum. The analyzer 50 includes a correction data obtaining section which obtains correction data of the wavelength spectrum considering light absorption by the sample container 400, and a sample information analyzing section which corrects and analyzes the wavelength spectrum to obtain sample information. This realizes a spectroscopic measurement apparatus, a measurement method, and a measurement program which can preferably perform spectroscopic measurement of the sample held by the sample container in the integrating sphere.
摘要翻译：光谱测量装置1A包括：样品S所在的积分球20，经由入射孔21向积分球20内部供给激发光的照射光供给部10，将样品S保持在的样品容器400 积分球20的内部，从出射孔22分散被测光并获得波长光谱的光谱分析器30以及进行波长谱的数据分析的数据分析器50。分析器50包括校正数据获取部分，其获取考虑到样品容器400的光吸收的波长谱的校正数据;以及样本信息分析部，其校正和分析波长谱以获得样本信息。这实现了可以优选地在积分球中对样品容器保持的样品进行光谱测量的光谱测量装置，测量方法和测量程序。

8. 发明申请

US20110205537A1 SPECTROMETER 有权
标题翻译：光谱仪
公开(公告)号：US20110205537A1
公开(公告)日：2011-08-25
申请号：US13126523
申请日：2009-09-24
申请人： Kazuya Iguchi , Kengo Suzuki
发明人： Kazuya Iguchi , Kengo Suzuki
IPC分类号： G01J3/28
CPC分类号： G01N21/0332 , G01J3/0254 , G01J3/0286 , G01J3/0291 , G01N21/255 , G01N21/645 , G01N2201/065
摘要： A spectrometer 1A is provided with an integrating sphere 20 for observing measured light emitted from a sample S of a measurement target, and a Dewar vessel 50 which retains a medium R for regulating temperature of the sample S, so as to cover the sample S and a second container portion 50b of which is located so as to face the interior of the integrating sphere 20. The sample S can be easily regulated at a desired temperature with the use of the Dewar vessel 50 retaining the medium R so as to cover the sample S. As the second container portion 50b is located so as to face the interior of the integrating sphere 20, the temperature of the sample S is regulated by the medium R, while inhibiting an external ambience around the integrating sphere from affecting the sample S. Therefore, the sample S can be efficiently regulated at a desired temperature.
摘要翻译：光谱仪1A设置有用于观察从测量对象的样品S发射的测量光的积分球20和保持用于调节样品S的温度的介质R的杜瓦容器50，以覆盖样品S和其第二容器部分50b定位成面对积分球20的内部。使用保持介质R的杜瓦容器50以便覆盖样品，可以容易地将样品S调节到期望的温度当第二容器部分50b定位成面对积分球20的内部时，样品S的温度由介质R调节，同时抑制积分球周围的外部环境影响样品S. 因此，可以将样品S有效地调节到期望的温度。

9. 发明申请

US20100108869A1 PHOTODETECTOR AND JIG FOR SAMPLE HOLDER 有权
标题翻译： PHOTODETECTOR和JIG FOR SAMPLE HOLDER
公开(公告)号：US20100108869A1
公开(公告)日：2010-05-06
申请号：US12529253
申请日：2007-03-01
申请人： Kazuya Iguchi , Kengo Suzuki
发明人： Kazuya Iguchi , Kengo Suzuki
IPC分类号： G01J1/02 , G01N21/64
CPC分类号： G01N21/64 , G01J1/02 , G01J1/0223 , G01J3/0254 , G01N21/4738 , G01N2021/4735 , G01N2201/0632 , G01N2201/065
摘要： A photodetecting device 1 includes an integrating sphere 20 for observing light to be measured generated according to irradiation of a sample with excitation light and a sample holder 60 removably attached to the integrating sphere 20, the integrating sphere 20 has an excitation light introducing hole 201 for introducing the excitation light and a sample introducing hole 205 for introducing a cell C held by the sample holder 60, the sample holder 60 is locked to the sample introducing hole 205 and holds the cell C for accommodating the sample, and the cell is disposed so that an entrance surface of the cell C, through which the excitation light enters the cell C, inclines relative to the surface perpendicular to the optical axis L of the excitation light.
摘要翻译：光检测装置1包括用于观察根据具有激发光的样品的照射产生的待测光的积分球20和可移除地附接到积分球20的样品保持器60，积分球20具有用于引入激发光和用于引入由样品保持器60保持的电池C的样品引入孔205，将样品保持器60锁定到样品引入孔205并保持用于容纳样品的电池C，并且将电池设置为激发光通过其进入电池C的电池C的入射面相对于垂直于激发光的光轴L的表面倾斜。

10. 发明授权

US08324561B2 Photodetector and jig for sample holder 有权
标题翻译：用于样品架的光电检测器和夹具
公开(公告)号：US08324561B2
公开(公告)日：2012-12-04
申请号：US12529253
申请日：2007-03-01
申请人： Kazuya Iguchi , Kengo Suzuki
发明人： Kazuya Iguchi , Kengo Suzuki
IPC分类号： G01J1/04 , G01N21/01 , G01N21/63
CPC分类号： G01N21/64 , G01J1/02 , G01J1/0223 , G01J3/0254 , G01N21/4738 , G01N2021/4735 , G01N2201/0632 , G01N2201/065
摘要： A photodetecting device 1 includes an integrating sphere 20 for observing light to be measured generated according to irradiation of a sample with excitation light and a sample holder 60 removably attached to the integrating sphere 20, the integrating sphere 20 has an excitation light introducing hole 201 for introducing the excitation light and a sample introducing hole 205 for introducing a cell C held by the sample holder 60, the sample holder 60 is locked to the sample introducing hole 205 and holds the cell C for accommodating the sample, and the cell is disposed so that an entrance surface of the cell C, through which the excitation light enters the cell C, inclines relative to the surface perpendicular to the optical axis L of the excitation light.
摘要翻译：光检测装置1包括用于观察根据具有激发光的样品的照射产生的待测光的积分球20和可移除地附接到积分球20的样品保持器60，积分球20具有用于引入激发光和用于引入由样品保持器60保持的电池C的样品引入孔205，将样品保持器60锁定到样品引入孔205并保持用于容纳样品的电池C，并且将电池设置为激发光通过其进入电池C的电池C的入射面相对于垂直于激发光的光轴L的表面倾斜。

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