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    • 1. 发明申请
    • Method for Manufacturing LiMnPO4
    • 制造LiMnPO4的方法
    • US20090184296A1
    • 2009-07-23
    • US12084200
    • 2006-10-27
    • Motoshi IsonoThierry DrezenIvan ExnarIvo Teerlinck
    • Motoshi IsonoThierry DrezenIvan ExnarIvo Teerlinck
    • H01B1/02C01B25/30
    • C01B25/45C01B25/377H01M4/136H01M4/1397H01M4/5825H01M4/624H01M10/052
    • The main object of the invention is to obtain LiMnPO4 having an excellent crystalline and a high purity at a lower temperature. The present invention provides a method for manufacturing LiMnPO4 including the steps of: precipitating for obtaining precipitate of manganese hydroxide (Mn(OH)x) by adding a precipitant to a Mn source solution in which a Mn source is dissolved; reducing for obtaining a reduced dispersion solution by dispersing the precipitate in a reducing solvent; adding for obtaining an added dispersion solution by adding a Li source solution and a P source solution to the reduced dispersion solution; pH adjusting for adjusting the pH of the added dispersion solution in the range of 3 to 6 to obtain a pH-adjusted dispersion solution; and synthesizing for synthesizing by reacting the pH-controlled dispersion solution by a heating under pressure condition.
    • 本发明的主要目的是获得在较低温度下具有优异结晶性和高纯度的LiMnPO4。 本发明提供了一种LiMnPO4的制造方法,包括以下步骤:通过在其中溶解Mn源的Mn源溶液中加入沉淀剂来沉淀氢氧化锰(Mn(OH)x)的沉淀物; 还原以通过将沉淀物分散在还原溶剂中来获得降低的分散溶液; 添加用于通过向还原的分散溶液中加入Li源溶液和P源溶液来获得添加的分散溶液; pH调节用于调节添加的分散液的pH在3至6的范围内,以获得pH调节的分散液; 并通过在压力条件下加热使pH控制的分散液反应合成合成。
    • 2. 发明授权
    • Method for manufacturing LiMnPO4
    • 制造LiMnPO4的方法
    • US07749658B2
    • 2010-07-06
    • US12084200
    • 2006-10-27
    • Motoshi IsonoThierry DrezenIvan ExnarIvo Teerlinck
    • Motoshi IsonoThierry DrezenIvan ExnarIvo Teerlinck
    • H01M4/50
    • C01B25/45C01B25/377H01M4/136H01M4/1397H01M4/5825H01M4/624H01M10/052
    • The main object of the invention is to obtain LiMnPO4 having an excellent crystalline and a high purity at a lower temperature. The present invention provides a method for manufacturing LiMnPO4 including the steps of: precipitating for obtaining precipitate of manganese hydroxide (Mn(OH)x) by adding a precipitant to a Mn source solution in which a Mn source is dissolved; reducing for obtaining a reduced dispersion solution by dispersing the precipitate in a reducing solvent; adding for obtaining an added dispersion solution by adding a Li source solution and a P source solution to the reduced dispersion solution; pH adjusting for adjusting the pH of the added dispersion solution in the range of 3 to 6 to obtain a pH-adjusted dispersion solution; and synthesizing for synthesizing by reacting the pH-controlled dispersion solution by a heating under pressure condition.
    • 本发明的主要目的是获得在较低温度下具有优异结晶性和高纯度的LiMnPO4。 本发明提供了一种LiMnPO4的制造方法,包括以下步骤:通过在其中溶解Mn源的Mn源溶液中加入沉淀剂来沉淀氢氧化锰(Mn(OH)x)的沉淀物; 还原以通过将沉淀物分散在还原溶剂中来获得降低的分散溶液; 添加用于通过向还原的分散溶液中加入Li源溶液和P源溶液来获得添加的分散溶液; pH调节用于调节添加的分散液的pH在3至6的范围内,以获得pH调节的分散液; 并通过在压力条件下加热使pH控制的分散液反应合成合成。
    • 6. 发明授权
    • Synthesis of nanoparticles of lithium metal phosphate positive material for lithium secondary battery
    • 锂二次电池锂金属磷酸盐正极材料纳米颗粒的合成
    • US08313863B2
    • 2012-11-20
    • US12296204
    • 2006-04-06
    • Ivan ExnarThierry Drezen
    • Ivan ExnarThierry Drezen
    • H01M4/13
    • H01M4/5825C01B25/45H01M4/136H01M4/1397H01M4/625H01M10/052
    • Novel process for the preparation of finely divided, nano-structured, olivine lithium metal phosphates (LiMPO4) (where metal M is iron, cobalt, manganese, nickel, vanadium, copper, titanium and mix of them) materials have been developed. This so called Polyol” method consists of heating of suited precursor materials in a multivalent, high-boiling point multivalent alcohol like glycols with the general formula HO—(—C2H4O—), —H where n=1-10 or HO—(—C3H6O—)n—H where n=1-10, or other polyols with the general formula HOCH2—(—C3H5OH—)n—H where n=1-10, like for example the tridecane-1,4,7,10,13-pentaol. A novel method for implementing the resulting materials as cathode materials for Li.-ion batteries is also developed.
    • 已经开发了用于制备精细分散的纳米结构的橄榄石锂金属磷酸盐(LiMPO4)(其中金属M是铁,钴,锰,镍,钒,铜,钛和它们的混合物)的新方法。 这种所谓的多元醇方法包括在多价,高沸点多价醇如乙二醇中加热合适的前体材料,通式为HO - ( - C 2 H 4 O - )-H,其中n = 1-10或HO - ( - C 3 H 6 O - )n-H,其中n = 1-10,或其它n = 1-10的通式为HOCH 2 - ( - C 3 H 5 OH))n -H的其它多元醇,例如十三烷-1,4,7,10, 13-pentaol。 还开发了用于将所得材料用作锂离子电池的阴极材料的新颖方法。