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    • 1. 发明授权
    • Polypropylene fibers
    • 聚丙烯纤维
    • US6146758A
    • 2000-11-14
    • US303728
    • 1999-05-03
    • Mohan R. GownderEduardo E. ZamoraJay Nguyen
    • Mohan R. GownderEduardo E. ZamoraJay Nguyen
    • C08F4/642C08F4/6592C08F110/00C08F110/06D01F6/06
    • D01F6/06Y10T428/2913Y10T428/2967
    • Process for the production of polypropylene fibers from polypropylene polymers produced by the polymerization of polypropylene in the presence of a metallocene catalyst characterized by a bridged racemic bis(indenyl) ligand substituted at the proximal position. The polypropylene contains 0.5 to 2% 2,1 insertions and has an isotacticity of at least 95% meso diads and is heated to a molten state and extruded to form a fiber preform. The preform is subjected to spinning at a spinning speed of at least 500 meters per minutes and subsequent drawing at a speed of at least 1,500 meters per minute to provide a draw ratio of at least 3 to produce a continuous polypropylene fiber. The draw speed and/or the draw ratio can be varied to produce fibers of different mechanical properties. Different polypropylene polymers produced by different metallocene catalysts can be used. Such fibers can be characterized by having an elongation at break of at least 100% and a specific toughness of at least 0.5 grams per denier.
    • 通过在茂金属催化剂存在下聚丙烯聚合生产聚丙烯聚丙烯的方法,其特征在于在近端位置被取代的桥连外消旋双(茚基)配体。 聚丙烯含有0.5至2%的2,1插入并且具有至少95%的内消旋二聚体的全同立构规整度,并被加热至熔融状态并挤出以形成纤维预制件。 以每分钟至少500米的纺丝速度进行纺丝,然后以至少1500米/分钟的速度拉伸,以提供至少3的拉伸比,以生产连续的聚丙烯纤维。 拉伸速度和/或拉伸比可以变化以产生不同机械性能的纤维。 可以使用由不同茂金属催化剂制备的不同的聚丙烯聚合物。 这种纤维的特征在于具有至少100%的断裂伸长率和至少0.5克/旦尼尔的比韧度。
    • 2. 发明授权
    • Process of making polypropylene fiber
    • 制造聚丙烯纤维的工艺
    • US5908594A
    • 1999-06-01
    • US936254
    • 1997-09-24
    • Mohan R. GownderEduardo E. ZamoraJay Nguyen
    • Mohan R. GownderEduardo E. ZamoraJay Nguyen
    • C08F4/642C08F4/6592C08F110/00C08F110/06D01F6/06D01D5/16
    • D01F6/06Y10T428/2913Y10T428/2967
    • Process for the production of polypropylene fibers from polypropylene polymers produced by the polymerization of polypropylene in the presence of a metallocene catalyst characterized by a bridged racemic bis(indenyl) ligand substituted at the proximal position. The polypropylene contains 0.5 to 2% 2,1 insertions and has an isotacticity of at least 95% meso diads and is heated to a molten state and extruded to form a fiber preform. The preform is subjected to spinning at a spinning speed of at least 500 meters per minutes and subsequent drawing at a speed of at least 1,500 meters per minute to provide a draw ratio of at least 3 to produce a continuous polypropylene fiber. The draw speed and/or the draw ratio can be varied to produce fibers of different mechanical properties. Different polypropylene polymers produced by different metallocene catalysts can be used. Such fibers can be characterized by having an elongation at break of at least 100% and a specific toughness of at least 0.5 grams per denier.
    • 通过在茂金属催化剂存在下聚丙烯聚合生产聚丙烯聚丙烯的方法,其特征在于在近端位置被取代的桥连外消旋双(茚基)配体。 聚丙烯含有0.5至2%的2,1插入并且具有至少95%的内消旋二聚体的全同立构规整度,并被加热至熔融状态并挤出以形成纤维预制件。 以每分钟至少500米的纺丝速度进行纺丝,然后以至少1500米/分钟的速度拉伸,以提供至少3的拉伸比,以生产连续的聚丙烯纤维。 拉伸速度和/或拉伸比可以变化以产生不同机械性能的纤维。 可以使用由不同茂金属催化剂制备的不同的聚丙烯聚合物。 这种纤维的特征在于具有至少100%的断裂伸长率和至少0.5克/旦尼尔的比韧度。